arXiv subjects

Hirokazu Hori

Publications and source records attributed to Hirokazu Hori.

At least 19 recordsLinked to original sources

arXiv2025

Motional representation; the ability to predict odor characters using molecular vibrations

The prediction of odor characters is still impossible based on the odorant molecular structure. We designed a CNN-based regressor for computed parameters in molecular vibrations (CNN\_vib), in order to investigate the ability to predict odor characters of molecular vibrations. In this study, we explored following three approaches for the predictability; (i) CNN with molecular vibrational parameters, (ii) logistic regression based on vibrational spectra, and (iii) logistic regression with molecular fingerprint(FP). Our investigation demonstrates that both (i) and (ii) provide predictablity, and also that the vibrations as an explanatory variable (i and ii) and logistic regression with fingerprints (iii) show nearly identical tendencies. The predictabilities of (i) and (ii), depending on odor descriptors, are comparable to those of (iii). Our research shows that odor is predictable by odorant molecular vibration as well as their shapes alone. Our findings provide insight into the representation of molecular motional features beyond molecular structures.

physics.chem-ph↗

arXiv2022

Mathematical modeling of morphological changes in photochromic crystals by catastrophe theory

Photochromic diarylethene is known to exhibit reversible photoisomerization under irradiation with ultraviolet (UV) and visible light. Besides reversible optical properties upon light irradiation, a variety of discontinuous morphological changes are reported in the literature, such as sudden crystal bending, cracking, and photosalient effects, which are caused simply by UV and visible light irradiation. These morphological phenomena with discontinuities are micro-scale changes caused by photoisomerization at the nanoscale and lead to the realization of important functions as optical devices. However, the theoretical models behind these phenomena are not well understood. In this paper, we construct a mathematical model that can treat diverse phenomena in a unified model by using swallow-tail catastrophe, a higher-order catastrophe than cusp catastrophe, from the seven elementary catastrophes that can describe discontinuities in the phenomena. By introducing the hyperbolic operating curves in the model, intrinsic properties of the photochromic crystals are represented. The induced morphogenesis, such as bending, cracking, and photosalient, are systematically classified by the proposed catastrophe model, which even implies unexplored operating conditions of the crystals and explains known phenomena. The proposed catastrophe-theory-based modeling provides a foundation for understanding and discovering the versatile morphogenesis in photochromic crystals. Furthermore, the proposed approach provides a basis for understanding and discovering various morphological changes in photochromic crystals and similar systems.

physics.optics↗

arXiv2022

History-dependent nano-photoisomerization by optical near-field in photochromic single crystals

We demonstrate history-dependent or dynamic nano-photoisomerization by sequential formation of multiple memory pathways in photochromic crystals via optical near-field interactions. We observed the incident photons passing through the photoisomerization memory pathways by a double-probe optical near-field microscope, with one probe located on the front surface for local excitation and the other on the rear surface for near-field observation. By carrying out localized near-field excitation twice but at spatially different positions, we observed negatively correlated near-field output patterns between the first memory pathway and the second memory pathway. That is, the added memory pathway was formed exclusively to the previously formed memory pathway. We also confirmed that the first memory pathway was preserved after the second memory pathway was formed. This result indicates that photoisomerization by an optical near-field in diarylethene crystals has a history dependence, leading to brain-like dynamic information memorization using light-matter interactions on the nanometer-scale.

physics.optics↗

arXiv2021

Order recognition by Schubert polynomials generated by optical near-field statistics via nanometre-scale photochromism

We have previously observed an irregular spatial distribution of photon transmission through a photochromic crystal photoisomerized by a local optical near-field excitation, manifesting complex branching processes via the interplay of deformation of the material and near-field photon transfer therein. Furthermore, by combining such naturally constructed complex photon transmission with a simple photon detection protocol, Schubert polynomials, the foundation of versatile permutation operations in mathematics, have been generated. In this study, we demonstrate an order recognition algorithm inspired by Schubert calculus using optical near-field statistics via nanometre-scale photochromism. More specifically, by utilizing Schubert polynomials generated via optical near-field patterns, we show that the order of slot machines with initially unknown reward probability is successfully recognized. We emphasize that, unlike conventional algorithms in the literature, the proposed principle does not estimate the reward probabilities. Instead, it exploits the inversion relations contained in the Schubert polynomials. To quantitatively evaluate the impact of the Schubert polynomials generated from an optical near-field pattern, order recognition performances are compared with uniformly distributed and spatially strongly skewed probability distributions, where the optical near-field pattern outperforms the others. We found that the number of singularities contained in Schubert polynomials and that of the given problem or considered environment exhibits a clear correspondence, indicating that superior order recognition performances may be attained if the singularity of the given problem is presupposed. This study paves a new way toward nanophotonic intelligent devices and systems by the interplay of complex natural processes and mathematical insights gained by Schubert calculus.

physics.optics↗

arXiv2020

Entangled and correlated photon mixed strategy for social decision making

Collective decision making is important for maximizing total benefits while preserving equality among individuals in the competitive multi-armed bandit (CMAB) problem, wherein multiple players try to gain higher rewards from multiple slot machines. The CMAB problem represents an essential aspect of applications such as resource management in social infrastructure. In a previous study, we theoretically and experimentally demonstrated that entangled photons can physically resolve the difficulty of the CMAB problem. This decision-making strategy completely avoids decision conflicts while ensuring equality. However, decision conflicts can sometimes be beneficial if they yield greater rewards than non-conflicting decisions, indicating that greedy actions may provide positive effects depending on the given environment. In this study, we demonstrate a mixed strategy of entangled- and correlated-photon-based decision-making so that total rewards can be enhanced when compared to the entangled-photon-only decision strategy. We show that an optimal mixture of entangled- and correlated-photon-based strategies exists depending on the dynamics of the reward environment as well as the difficulty of the given problem. This study paves the way for utilizing both quantum and classical aspects of photons in a mixed manner for decision making and provides yet another example of the supremacy of mixed strategies known in game theory, especially in evolutionary game theory.

quant-ph↗

arXiv2020

Entangled N-photon states for fair and optimal social decision making

Situations involving competition for resources among entities can be modeled by the competitive multi-armed bandit (CMAB) problem, which relates to social issues such as maximizing the total outcome and achieving the fairest resource repartition among individuals. In these respects, the intrinsic randomness and global properties of quantum states provide ideal tools for obtaining optimal solutions to this problem. Based on the previous study of the CMAB problem in the two-arm, two-player case, this paper presents the theoretical principles necessary to find polarization-entangled N-photon states that can optimize the total resource output while ensuring equality among players. These principles were applied to two-, three-, four-, and five-player cases by using numerical simulations to reproduce realistic configurations and find the best strategies to overcome potential misalignment between the polarization measurement systems of the players. Although a general formula for the N-player case is not presented here, general derivation rules and a verification algorithm are proposed. This report demonstrates the potential usability of quantum states in collective decision making with limited, probabilistic resources, which could serve as a first step toward quantum-based resource allocation systems.

quant-ph↗

arXiv2020

Experimental demonstration of random walk by probability chaos using single photons

In our former work (Sci. Rep. 4: 6039, 2014), we theoretically and numerically demonstrated that chaotic oscillation can be induced in a nanoscale system consisting of quantum dots between which energy transfer occurs via optical near-field interactions. Furthermore, in addition to the nanoscale implementation of oscillators, it is intriguing that the chaotic behavior is associated with probability derived via a density matrix formalism. Indeed, in our previous work (Sci. Rep. 6: 38634, 2016) we examined such oscillating probabilities via diffusivity analysis by constructing random walkers driven by chaotically driven bias. In this study, we experimentally implemented the concept of probability chaos using a single-photon source that was chaotically modulated by an external electro-optical modulator that directly yielded random walkers via single-photon observations after a polarization beam splitter. An evident signature was observed in the resulting ensemble average of the time-averaged mean square displacement. Although the experiment involved a scaled-up, proof-of-concept model of a genuine nanoscale oscillator, the experimental observations clearly validate the concept of oscillating probability, paving the way toward future ideal nanoscale systems.

physics.optics↗

arXiv2019

Entangled-photon decision maker

The competitive multi-armed bandit (CMAB) problem is related to social issues such as maximizing total social benefits while preserving equality among individuals by overcoming conflicts between individual decisions, which could seriously decrease social benefits. The study described herein provides experimental evidence that entangled photons physically resolve the CMAB in the 2-arms 2-players case, maximizing the social rewards while ensuring equality. Moreover, we demonstrated that deception, or outperforming the other player by receiving a greater reward, cannot be accomplished in a polarization-entangled-photon-based system, while deception is achievable in systems based on classical polarization-correlated photons with fixed polarizations. Besides, random polarization-correlated photons have been studied numerically and shown to ensure equality between players and deception prevention as well, although the CMAB maximum performance is reduced as compared with entangled photon experiments. Autonomous alignment schemes for polarization bases were also experimentally demonstrated based only on decision conflict information observed by an individual without communications between players. This study paves a way for collective decision making in uncertain dynamically changing environments based on entangled quantum states, a crucial step toward utilizing quantum systems for intelligent functionalities.

physics.optics↗

arXiv2019

Generation of Schubert polynomial series by nanophotonics

Generation of irregular time series based on physical processes is indispensable in computing and artificial intelligence. In this report, we propose and experimentally demonstrate the generation of Schubert polynomials, which is the foundation of versatile permutations in mathematics, via optical near-field processes introduced in a photochromic crystal of diarylethene, which optical near-field excitation on the surface of a photochromic single crystal yields a chain of local photoisomerization, forming a complex pattern on the opposite side of the crystal. The incoming photon travels through the nanostructured photochromic crystal, and the exit position of the photon exhibits a versatile pattern. We experimentally generated Schubert matrices, corresponding to Schubert polynomials, via optical near-field density mapping. The versatility and correlations of the generated patterns could be reconfigured in either a soft or hard manner by adjusting the photon detection sensitivity. This is the first study of Schubert polynomial generation by physical processes or nanophotonics, paving the way toward future nano-scale intelligence devices and systems.

physics.optics↗

arXiv2018

Category theory as a foundation for soft robotics

Soft robotics is an emerging field of research where the robot body is composed of compliant and soft materials. It allows the body to bend, twist, and deform to move or to adapt its shape to the environment for grasping, all of which are difficult for traditional hard robots with rigid bodies. However, the theoretical basis and design principles for soft robotics are not well-founded despite their recognized importance. For example, the control of soft robots is outsourced to morphological attributes and natural processes; thus, the coupled relations between a robot and its environment are particularly crucial. In this paper, we propose a mathematical foundation for soft robotics based on category theory, which is a branch of abstract math where any notions can be described by objects and arrows. It allows for a rigorous description of the inherent characteristics of soft robots and their relation to the environment as well as the differences compared to conventional hard robots. We present a notion called the category of mobility that well describes the subject matter. The theory was applied to a model system and analysis to highlight the adaptation behavior observed in universal grippers, which are a typical example of soft robotics. This paper paves the way to developing a theoretical background and design principles for soft robotics.

cs.RO↗

arXiv2018

Category Theoretic Analysis of Photon-based Decision Making

Decision making is a vital function in this age of machine learning and artificial intelligence, yet its physical realization and theoretical fundamentals are still not completely understood. In our former study, we demonstrated that single-photons can be used to make decisions in uncertain, dynamically changing environments. The two-armed bandit problem was successfully solved using the dual probabilistic and particle attributes of single photons. In this study, we present a category theoretic modeling and analysis of single-photon-based decision making, including a quantitative analysis that is in agreement with the experimental results. A category theoretic model reveals the complex interdependencies of subject matter entities in a simplified manner, even in dynamically changing environments. In particular, the octahedral and braid structures in triangulated categories provide a better understanding and quantitative metrics of the underlying mechanisms of a single-photon decision maker. This study provides both insight and a foundation for analyzing more complex and uncertain problems, to further machine learning and artificial intelligence.

physics.optics↗

arXiv2018

Local reservoir model for choice-based learning

Decision making based on behavioral and neural observations of living systems has been extensively studied in brain science, psychology, and other disciplines. Decision-making mechanisms have also been experimentally implemented in physical processes, such as single photons and chaotic lasers. The findings of these experiments suggest that there is a certain common basis in describing decision making, regardless of its physical realizations. In this study, we propose a local reservoir model to account for choice-based learning (CBL). CBL describes decision consistency as a phenomenon where making a certain decision increases the possibility of making that same decision again later, which has been intensively investigated in neuroscience, psychology, etc. Our proposed model is inspired by the viewpoint that a decision is affected by its local environment, which is referred to as a local reservoir. If the size of the local reservoir is large enough, consecutive decision making will not be affected by previous decisions, thus showing lower degrees of decision consistency in CBL. In contrast, if the size of the local reservoir decreases, a biased distribution occurs within it, which leads to higher degrees of decision consistency in CBL. In this study, an analytical approach on local reservoirs is presented, as well as several numerical demonstrations. Furthermore, a physical architecture for CBL based on single photons is discussed, and the effects of local reservoirs is numerically demonstrated. Decision consistency in human decision-making tasks and in recruiting empirical data are evaluated based on local reservoir. In summary, the proposed local reservoir model paves a path toward establishing a foundation for computational mechanisms and the systematic analysis of decision making on different levels.

stat.ML↗

arXiv2018

Scalable photonic reinforcement learning by time-division multiplexing of laser chaos

Reinforcement learning involves decision making in dynamic and uncertain environments and constitutes a crucial element of artificial intelligence. In our previous work, we experimentally demonstrated that the ultrafast chaotic oscillatory dynamics of lasers can be used to solve the two-armed bandit problem efficiently, which requires decision making concerning a class of difficult trade-offs called the exploration-exploitation dilemma. However, only two selections were employed in that research; thus, the scalability of the laser-chaos-based reinforcement learning should be clarified. In this study, we demonstrated a scalable, pipelined principle of resolving the multi-armed bandit problem by introducing time-division multiplexing of chaotically oscillated ultrafast time-series. The experimental demonstrations in which bandit problems with up to 64 arms were successfully solved are presented in this report. Detailed analyses are also provided that include performance comparisons among laser chaos signals generated in different physical conditions, which coincide with the diffusivity inherent in the time series. This study paves the way for ultrafast reinforcement learning by taking advantage of the ultrahigh bandwidths of light wave and practical enabling technologies.

cs.ET↗

arXiv2016

Single photon in hierarchical architecture for physical reinforcement learning: Photon intelligence

Understanding and using natural processes for intelligent functionalities, referred to as natural intelligence, has recently attracted interest from a variety of fields, including post-silicon computing for artificial intelligence and decision making in the behavioural sciences. In a past study, we successfully used the wave-particle duality of single photons to solve the two-armed bandit problem, which constitutes the foundation of reinforcement learning and decision making. In this study, we propose and confirm a hierarchical architecture for single-photon-based reinforcement learning and decision making that verifies the scalability of the principle. Specifically, the four-armed bandit problem is solved given zero prior knowledge in a two-layer hierarchical architecture, where polarization is autonomously adapted in order to effect adequate decision making using single-photon measurements. In the hierarchical structure, the notion of layer-dependent decisions emerges. The optimal solutions in the coarse layer and in the fine layer, however, conflict with each other in some contradictive problems. We show that while what we call a tournament strategy resolves such contradictions, the probabilistic nature of single photons allows for the direct location of the optimal solution even for contradictive problems, hence manifesting the exploration ability of single photons. This study provides insights into photon intelligence in hierarchical architectures for future artificial intelligence as well as the potential of natural processes for intelligent functionalities.

cs.LG↗

arXiv2016

Percolation of optical excitation mediated by near-field interactions

Optical excitation transfer in nanostructured matter has been intensively studied in various material systems for versatile applications. Herein, we discuss the percolation of optical excitations in randomly organized nanostructures caused by optical near-field interactions governed by Yukawa potential in a two-dimensional stochastic model. The model results demonstrate the appearance of two phases of percolation of optical excitation as a function of the localization degree of near-field interaction. Moreover, it indicates sublinear scaling with percolation distance when the light localization is strong. The results provide fundamental insights into optical excitation transfer and will facilitate the design and analysis of nanoscale signal-transfer characteristics.

cond-mat.dis-nn↗

arXiv2016

Accelerated diffusion by chaotic fluctuation in probability in photoexcitation transfer system

We report a new accelerated diffusion phenomenon that is produced by a one-dimensional ran- dom walk in which the flight probability to one of the two directions (i.e., bias) oscillates dynam- ically in periodic, quasiperiodic, and chaotic manners. The probability oscillation dynamics can be physically observed in nanoscale photoexcitation transfer in a quantum-dot network, where the existence probability of an exciton at the bottom energy level of a quantum dot fluctuates dif- ferently with a parameter setting. We evaluate the ensemble average of the time-averaged mean square displacement (ETMSD) of the time series obtained from the quantum-dot network model that generates various oscillatory behaviors because the ETMSD exhibits characteristic changes depending on the fluctuating bias; in the case of normal diffusion, the asymptotic behavior of the ETMSD is proportional to the time (i.e., a linear growth function), whereas it grows nonlinearly with an exponent greater than 1 in the case of superdiffusion. We find that the diffusion can be accelerated significantly when the fluctuating bias is characterized as weak chaos owing to the transient nonstationarity of its biases, in which the spectrum contains high power at low frequen- cies. By introducing a simplified model of our random walk, which exhibits superdiffusion as well as normal diffusion, we explain the mechanism of the accelerated diffusion by analyzing the mean square displacement.

nlin.CD↗

arXiv2015

Single-photon decision maker

Decision making is critical in our daily lives and for society in general and is finding evermore practical applications in information and communication technologies. Herein, we demonstrate experimentally that single photons can be used to make decisions in uncertain, dynamically changing environments. Using a nitrogen-vacancy in a nanodiamond as a single-photon source, we demonstrate the decision-making capability by solving the multi-armed bandit problem. This capability is directly and immediately associated with single-photon detection in the proposed architecture, leading to adequate and adaptive autonomous decision making. This study makes it possible to create systems that benefit from the quantum nature of light to perform practical and vital intelligent functions.

physics.optics↗

arXiv2015

Local circular polarizations in nanostructures induced by linear polarization via optical near-fields

We previously reported [Naruse, et al. Sci. Rep. 4, 6077, 2014] that the geometrical randomness of disk-shaped silver nanoparticles, which exhibit high reflection at near-infrared wavelengths, serves as the origin of a particle-dependent localization and hierarchical distribution of optical near-fields in the vicinity of the nanostructure. In this study, we show that the induced polarizations are circular, particularly at resonant wavelengths. We formulate optical near-field processes between nanostructures, accounting for their polarizations and geometries, and attribute circular polarization to the layout-dependent phase difference between the electrical susceptibilities associated with longitudinal and transverse-electric components. This study clarifies the fundamental optical properties of random nanostructured matter and offers generic theoretical concepts for implementing nanoscale polarizations of optical near-fields.

physics.optics↗