arXiv subjects

Hiroshi Eisaki

Publications and source records attributed to Hiroshi Eisaki.

At least 37 records · Page 2Linked to original sources

arXiv2023

Dynamics of non-thermal states in optimally-doped $Bi_2Sr_2Ca_{0.92}Y_{0.08}Cu_2O_{8+δ}$ revealed by mid-infrared three-pulse spectroscopy

In the cuprates, the opening of a d-wave superconducting (SC) gap is accompanied by a redistribution of spectral weight at energies two orders of magnitude larger than this gap. This indicates the importance to the pairing mechanism of on-site electronic excitations, such as orbital transitions or charge transfer excitations. Here, we resort to a three-pulse pump-probe scheme to study the broadband non-equilibrium dielectric function in optimally-doped $Bi_2Sr_2Ca_{0.92}Y_{0.08}Cu_2O_{8+δ}$ and we identify two distinct dynamical responses: i) a blueshift of the central energy of an interband excitation peaked at 2 eV and ii) a change in spectral weight in the same energy range. Photoexcitation with near-IR and mid-IR pulses, with photon energies respectively above and below the SC gap, reveals that the transient changes in the central energy are not modified by the onset of superconductivity and do not depend on the pump photon energy. Conversely, the spectral weight dynamics strongly depends on the pump photon energy and has a discontinuity at the critical temperature. The picture that emerges is that, while high-energy pulses excite quasiparticles in both nodal and thermally inaccessible antinodal states, photoexcitation by low-energy pulses mostly accelerates the condensate and creates excitations predominantly at the nodes of the SC gap. These results, rationalized by kinetic equations for d-wave superconducting gaps, indicate that dynamical control of the momentum-dependent distribution of non-thermal quasiparticles may be achieved by the selective tuning of the photoexcitation.

cond-mat.supr-con↗

arXiv2023

Spontaneous breaking of mirror symmetry beyond critical doping in Pb-Bi2212

Identifying ordered phases and their underlying symmetries is the first and most important step toward understanding the mechanism of high-temperature superconductivity; critical behaviors of ordered phases are expected to be correlated with superconductivity. Efforts to find such ordered phases have been focused on symmetry breaking in the pseudogap region while the Fermi liquid-like metal region beyond the so-called critical doping $p_{c}$ has been regarded as a trivial disordered state. Here, we used rotational anisotropy second harmonic generation and uncovered a broken mirror symmetry in the Fermi liquid-like phase in (Bi,Pb)$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ with $p = 0.205 > p_{c}$. By tracking the temperature evolution of the symmetry-breaking response, we verify an order parameter-like behavior with the onset temperature $T_{up}$ at which the strange metal to Fermi liquid-like-metal crossover takes place. Complementary angle-resolved photoemission study showed that the quasiparticle coherence between $\mathrm{CuO_{2}}$ bilayers is enhanced in proportion to the symmetry-breaking response as a function of temperature, indicating that the change in metallicity and symmetry breaking are linked. These observations contradict the conventional quantum disordered scenario for over-critical-doped cuprates and provide new insight into the nature of the quantum critical point in cuprates.

cond-mat.supr-con↗

arXiv2023

Na-catalyzed rapid synthesis and characterization of intercalated graphite CaC6

In this study, we conducted experiments on CaC6 for elucidating the Na-catalyzed formation mechanism and achieving rapid mass synthesis of graphite intercalation compounds (GICs). Rapidly synthesized CaC6 was characterized by analysis of its crystal structure and physical properties. We found that the formation of the reaction intermediate Na-GIC (NaCx, x = 64) requires a larger amount of Na than is intercalated between the graphite interlayers. The requirement for excess Na may provide insights into the mechanism of Na-catalyzed GIC formation. A Na-to-C molar mixing ratio of 1.5-2.0:6 was suitable for the efficient formation of CaC6 under heat treatment at 250°C for 2 h, and the catalytic Na remaining in the sample was demonstrably reduced to a Na:Ca ratio of approximately 3:97. The upper critical field Hc2 was enhanced approximately three times compared to those of previous reports. Based on X-ray diffraction and experimental parameter analysis, we concluded that the enhancement of Hc2 was attributed to the disordered stacking sequence in CaC6, possibly because of the rapid and low-temperature formation. Physical properties derived from specific heat measurements were comparable to those of high-quality CaC6, which is slowly synthesized using the molten Li-Ca alloy method. This study provides new avenues for future research and exploration in the rapid mass synthesis of GICs as practical materials, for applications such as battery electrodes and superconducting wires.

cond-mat.mtrl-sci↗

arXiv2023

Doping-dependent superconducting physical quantities of K-doped BaFe$_2$As$_2$ obtained through infrared spectroscopy

We investigated four single crystals of K-doped BaFe$_2$As$_2$ (Ba-122), Ba$_{1-x}$K$_x$Fe$_2$As$_2$ with $x$ = 0.29, 0.36, 0.40, and 0.51, using infrared spectroscopy. We explored a wide variety of doping levels, from under- to overdoped. We obtained the superfluid plasma frequencies ($Ω_{\mathrm{sp}}$) and corresponding London penetration depths ($λ_{\mathrm{L}}$) from the measured optical conductivity spectra. We also extracted the electron-boson spectral density (EBSD) functions using a two-parallel charge transport channel approach in the superconducting (SC) state. From the extracted EBSD functions, the maximum SC transition temperatures ($T_c^{\mathrm{Max}}$) were determined using a generalized McMillan formula and the SC coherence lengths ($ξ_{\mathrm{SC}}$) were calculated using the timescales encoded in the EBSD functions and reported Fermi velocities. We identified some similarities and differences in the doping-dependent SC quantities between the K-doped Ba-122 and the hole-doped cuprates. We expect that the various SC quantities obtained across the wide doping range will provide helpful information for establishing the microscopic pairing mechanism in Fe-pnictide superconductors.

cond-mat.supr-con↗

arXiv2023

Smectic Pair Density Wave Order in EuRbFe4As4

The pair density wave (PDW) is a novel superconducting state in which Cooper pairs carry center-of-mass momentum in equilibrium, leading to the breaking of translational symmetry. Experimental evidence for such a state exists in high magnetic field and in some materials that feature density wave orders that explicitly break translational symmetry. However, evidence for a zero-field PDW state that exists independent of other spatially ordered states has so far been elusive. Here, we show that such a state exists in the iron pnictide superconductor EuRbFe4As4 (Eu-1144), a material that features coexisting superconductivity (Tc ~ 37K) and magnetism (Tm ~ 15 K). We show from the Spectroscopic Imaging Scanning Tunneling Microscopy (SI-STM) measurements that the superconducting gap at low temperature has long-range, unidirectional spatial modulations with an incommensurate period of ~8 unit cells. Upon raising the temperature above Tm, the modulated superconductor disappears, but a uniform superconducting gap survives to Tc. When an external magnetic field is applied, gap modulations disappear inside the vortex halo. The SI-STM and bulk measurements show the absence of other density wave orders, showing that the PDW state is a primary, zero-field superconducting state in this compound. Both four-fold rotational symmetry and translation symmetry are recovered above Tm, indicating that the PDW is a smectic order.

cond-mat.supr-con↗

arXiv2023

Dramatically Accelerated Formation of Graphite Intercalation Compounds Catalyzed by Sodium

Graphite intercalation compounds (GICs) have a variety of functions due to their rich material variations, and thus,innovative methods for their synthesis are desired for practical applications. We have discovered that Na has a catalytic property that dramatically accelerates the formation of GICs. We demonstrate that LiC6n (n = 1, 2), KC8, KC12n (n = 2, 3, 4), and NaCx are synthesized simply by mixing alkali metals and graphite powder with Na at room temperature (~25 °C), and AEC6 (AE = Ca, Sr, Ba) are synthesized by heating Na-added reagents at 250 °C only for a few hours. The NaCx, formed by the mixing of C and Na, is understood to act as a reaction intermediate for a catalyst, thereby accelerating the formation of GICs by lowering the activation energy of intercalation. The Na-catalyzed method, which enables the rapid and mass synthesis of homogeneous GIC samples in a significantly simpler manner than conventional methods, is anticipated to stimulate research and development for GIC applications.

cond-mat.mtrl-sci↗

arXiv2023

Light-induced coherent interlayer transport in stripe-ordered ${\rm La}_{1.6-x}{\rm Nd}_{0.4}{\rm Sr}_{x}{\rm CuO}_{4}$

We have investigated the photoexcited transient responses of stripe-ordered phase in a cuprate superconductor, ${\rm La}_{1.6-x}{\rm Nd}_{0.4}{\rm Sr}_{x}{\rm CuO}_{4}~(x = 0.12)$ using optical-pump terahertz (THz)-probe spectroscopy. Upon the near-infrared photoexcitation with the electric field polarized along the $c$-axis, a clear plasma edge appears in the THz reflection spectrum along the $c$-axis with its position nearly coinciding with the Josephson plasma resonance of similarly doped ${\rm La}_{2-x}{\rm Sr}_{x}{\rm CuO}_{4}~(x = 0.125)$ in the low-temperature superconducting phase. The appearance of light-induced plasma edge sustains up to the onset temperature of the charge-stripe order, indicating the inherent interplay between the light-induced phase and the charge-stripe order. The optical conductivity spectrum of the light-induced state is mostly reproduced by the Drude model with a scattering rate as small as a few meV, and its imaginary part does not exhibit $1/ω$-divergence behavior in any temporal region after the photoexcitation. We discuss the possible origin of the observed coherent interlayer transport behavior as manifested by the narrow Drude response in the THz reflectivity along the $c$-axis.

cond-mat.supr-con↗

arXiv2023

Stripe Symmetry of Short-range Charge Density Waves in Cuprate Superconductors

The omnipresence of charge density waves (CDWs) across almost all cuprate families underpins a common organizing principle. However, a longstanding debate of whether its spatial symmetry is stripe or checkerboard remains unresolved. While CDWs in lanthanum- and yttrium-based cuprates possess a stripe symmetry, distinguishing these two scenarios has been challenging for the short-range CDW in bismuth-based cuprates. Here, we employed high-resolution resonant inelastic x-ray scattering to uncover the spatial symmetry of the CDW in Bi$_2$Sr$_{2-x}$La$_{x}$CuO$_{6+δ}$. Across a wide range of doping and temperature, anisotropic CDW peaks with elliptical shapes were found in reciprocal space. Based on Fourier transform analysis of real-space models, we interpret the results as evidence of unidirectional charge stripes, hosted by mutually 90$^\circ$-rotated anisotropic domains. Our work paves the way for a unified symmetry and microscopic description of CDW order in cuprates.

cond-mat.str-el↗

arXiv2022

Identification of a Critical Doping for Charge Order Phenomena in Bi-2212 Cuprates via RIXS

Identifying quantum critical points (QCPs) and their associated fluctuations may hold the key to unraveling the unusual electronic phenomena observed in cuprate superconductors. Recently, signatures of quantum fluctuations associated with charge order (CO) have been inferred from the anomalous enhancement of CO excitations that accompany the reduction of the CO order parameter in the superconducting state. To gain more insight about the interplay between CO and superconductivity, here we investigate the doping dependence of this phenomenon throughout the Bi-2212 cuprate phase diagram using resonant inelastic x-ray scattering (RIXS) at the Cu L3- edge. As doping increases, the CO wavevector decreases, saturating at a commensurate value of 0.25 r.l.u. beyond a characteristic doping pc, where the correlation length becomes shorter than the apparent periodicity (4a0). Such behavior is indicative of the fluctuating nature of the CO; and the proliferation of CO excitations in the superconducting state also appears strongest at pc, consistent with expected behavior at a CO QCP. Intriguingly, pc appears to be near optimal doping, where the superconducting transition temperature Tc is maximal.

cond-mat.supr-con↗

arXiv2022

Charge Transport in Ba$_{1-x}$Rb$_{x}$Fe$_{2}$As$_{2}$ Single Crystals

Recent studies in heavily hole-doped iron-based superconductor RbFe$_2$As$_2$ have suggested the emergence of novel electronic nematicity directed along the Fe-As direction, 45$^\circ$ rotated from the usual nematicity ubiquitously found in BaFe$_2$As$_2$ and related materials. This motivates us to study the physical properties of Ba$_{1-x}$Rb$_{x}$Fe$_{2}$As$_{2}$, details of which remain largely unexplored. Here we report on the normal-state charge transport in Ba$_{1-x}$Rb$_{x}$Fe$_{2}$As$_{2}$ superconductors by using high-quality single crystals in the range of Rb concentration $0.14\le x \le 1.00$. From the systematic measurements of the temperature dependence of electrical resistivity $ρ(T)$, we find a signature of a deviation from the Fermi liquid behavior around the optimal composition, which does not seem related to the antiferromagnetic quantum criticality but has a potential link to hidden nematic quantum criticality. In addition, electron correlations derived from the coefficient of $T^2$ resistivity show a marked increase with Rb content near the heavily hole-doped end, consistent with the putative Mott physics near the $3d^5$ electron configuration in iron-based superconductors.

cond-mat.supr-con↗

arXiv2022

Hidden Structural and Superconducting Phase Induced in Antiperovskite Arsenide SrPd$_{3}$As

Enriching the material variation often contributes to the progress of materials science. We have discovered for the first time antiperovskite arsenide SrPd$_{3}$As and revealed a hidden structural and superconducting phase in Sr(Pd$_{1-x}$Pt$_{x}$)$_{3}$As. The Pd-rich samples (0 $\leq$ x $\leq$ 0.2) had the same non-centrosymmetric (NCS) tetragonal structure (a space group of $I41md$) as SrPd$_{3}$P. For the samples with 0.3 $\leq$ x $\leq$ 0.7, a centrosymmetric (CS) tetragonal structure ($P4/nmm$) identical to that of SrPt$_{3}$P was found to appear, accompanied by superconductivity at a transition temperature ($T_\mathrm{c}$) up to 3.7 K. In the samples synthesized with Pt-rich nominal compositions (0.8 $\leq$ x $\leq$ 1.0), Sr$_{2}$(Pd,Pt)$_{8-y}$As$_{1+y}$ with an intergrowth structure (CS-orthorhombic with Cmcm) was crystallized. The phase diagram obtained for Sr(Pd,Pt)$_{3}$As was analogous to that of (Ca,Sr)Pd$_{3}$P in that superconductivity ($T_\mathrm{c}$ $\geq$ 2 K) occurred in the CS phases induced by substitutions to the NCS phases. This study indicates the potential for further material variation expansion and the importance of elemental substitutions to reveal hidden phases in related antiperovskites.

cond-mat.supr-con↗

arXiv2022

High-pressure synthesis and superconductivity of the novel Laves phase BaIr2

Superconductors comprising 5d transition metals of Ir and Pt have been widely explored because they have the potential of unique superconductivity caused by the strong spin-orbit interaction (SOI). We successfully synthesized BaIr2, the last Laves phase remaining unsynthesized in the MgCu2-type AM2 (A = Ca, Sr, Ba; M = Rh, Pd, Ir, Pt). BaIr2 was crystallized at 925 C under a pressure of 3.3 GPa via a solid-state reaction between Ba and Ir powders; it was found to have the longest a-lattice constant of 8.038(1) A among AM2. BaIr2 exhibited bulk superconductivity at a transition temperature (Tc) of 2.7 K. BaIr2 was found to have a type-II superconductor with an upper critical field of 67.7 kOe, which was above the Pauli paramagnetic limit (50 kOe). The electron-phonon coupling constant and normalized specific heat jump were measured to be 0.63 and 1.2, respectively, indicating that BaIr2 is a weak-coupling superconductor. The electronic-structure calculations for BaIr2 revealed that the Ir-5d states are dominant at the Fermi energy (EF) and the density of states at the EF is strongly affected by SOI as in the case of CaIr2 and SrIr2.

cond-mat.supr-con↗

arXiv2022

Cuprates phase diagram deduced from magnetic susceptibility: what is the `true' pseudogap line?

Two contradictory phase diagrams have dominated the literature of high-$T_c$ cuprate superconductors. Does the pseudogap line cross the superconducting $T_c$-dome or not? To answer, we have revisited the experimental magnetic susceptibility and knight shift of four different compounds, La$_{1-x}$Sr$_x$CuO$_4$, Bi$_2$Sr$_2$Ca$_{1-x}$Y$_x$Cu$_2$O$_8$, Bi$_2$Sr$_2$CaCu$_2$O$_{8+y}$, and YBa$_2$Cu$_3$O$_{6+y}$, as a function of temperature and doping. The susceptibility can be described by the same function for all materials, having a magnetic and an electronic contributions. The former is the 2D antiferromagnetic (AF) square lattice response, with a characteristic temperature of magnetic correlations $T_{max}$. The latter is the `Pauli' term, revealing the gap opening in the electronic density of states at the pseudogap temperature $T^*$. From precise fits of the data, we find that $T_{max}(p)$ decreases linearly as a function of doping ($p$) over a wide range, but saturates abruptly in the overdoped regime. Concomitantly, $T^*(p)$ is {\it linear and tangent} to the dome, either crossing or approaching $T_{max}(p)$ at the top of the dome, indicating a qualitative change of behavior from underdoped to overdoped regimes. Contrary to the idea that the pseudogap terminates just above optimal doping, our analysis suggests that the gap exists throughout the phase diagram. It is consistent with a pseudogap due to hole pairs, or `pairons', above $T_c$. We conclude that $T_{max}$, reflecting the AF magnetic correlations, has often been misinterpreted as the pseudogap temperature $T^*$.

cond-mat.supr-con↗

arXiv2021

Posttreatment Effects on the Crystal Structure and Superconductivity of Ca-Free Double-Layered Cuprate Sr$_2$SrCu$_2$O$_{4+y}$F$_{2-y}$

We report the effects of low-temperature postannealing on the structural and superconducting properties of the recently discovered Ca-free double-layered cuprate, Sr$_2$SrCu$_2$O$_{4+y}$F$_{2-y}$. Although the as-synthesized sample prepared under high pressure has a tetragonal structure with a rock-salt-type blocking layer (the so-called $T$-phase), we found that the symmetry of the structure lowered to that of an orthorhombic system when annealed with CuF$_2$. The structural refinements reveal that such a topochemical reaction leads not only to the removal of excess O$^{2-}$ from the apical site but also to the intercalation of extra F$^-$ into the interstitial site. The orthorhombic phase exhibits bulk superconductivity at a critical temperature of 107 K, which is significantly higher than that of the $T$-phase ($\sim$50 K). Meanwhile, the $T$-phase turns into another structure possessing a fluorite-type blocking layer without apical fluorine (known as the $T^\prime$-phase) by annealing without CuF$_2$. Density functional theory calculations show that the $T^\prime$-phase is more stable than the $T$-phase. This is the first report on the formation of a $T^\prime$-type double-layered cuprate. Furthermore, the structural stability of the three phases of Sr$_2$SrCu$_2$O$_{4+y}$F$_{2-y}$ is discussed in terms of lattice matching between the blocking and conducting layers.

cond-mat.supr-con↗

arXiv2021

Antiperovskite superconductor LaPd$_{3}$P with noncentrosymmetric cubic structure

Antiperovskites are a promising candidate structure for the exploration of new materials. We discovered an antiperovskite phosphide, LaPd$_{3}$P, following our recent synthesis of $A$Pd$_{3}$P ($A$ = Ca, Sr, Ba). While $A$Pd$_{3}$P and (Ca,Sr)Pd$_{3}$P were found to be tetragonal or orthorhombic systems, LaPd$_{3}$P is a new prototype cubic system ($a$ = 9.0317(1) A) with a noncentrosymmetric space group ($I-43m$). LaPd$_{3}$P exhibited superconductivity with a transition temperature ($T_\mathrm{c}$) of 0.28 K. The upper critical field, Debye temperature, and Sommerfeld constant ($γ$) were determined as 0.305(8) kOe, 267(1) K, 6.06(4) mJ mol-1 K-2 f.u.-1, respectively. We performed first-principles electronic band structure calculations for LaPd$_{3}$P and compared the theoretical and experimental results. The calculated Sommerfeld constant (2.24 mJ mol-1 K-2 f.u.-1) was much smaller than the experimental value of $γ$ because the Fermi energy ($E_\mathrm{F}$) was located slightly below the density of states (DOS) pseudogap. This difference was explained by the increase in the DOS at $E_\mathrm{F}$ due to the approximately 5 at.% La deficiency (hole doping) in the sample. The observed Tc value was much lower than that estimated using the Bardeen-Cooper-Schrieffer equation. To explain the discrepancy, we examined the possibility of an unconventional superconductivity in LaPd$_{3}$P arising from the lack of space inversion symmetry.

cond-mat.supr-con↗

arXiv2021

Superconductivity-driven ferromagnetism and spin manipulation using vortices in the magnetic superconductor EuRbFe4As4

Magnetic superconductors are specific materials exhibiting two antagonistic phenomena, superconductivity and magnetism, whose mutual interaction induces various emergent phenomena, such as the reentrant superconducting transition associated with the suppression of superconductivity around the magnetic transition temperature (Tm), highlighting the impact of magnetism on superconductivity. In this study, we report the experimental observation of the ferromagnetic order induced by superconducting vortices in the high-critical-temperature (high-Tc) magnetic superconductor EuRbFe4As4. Although the ground state of the Eu2+ moments in EuRbFe4As4 is helimagnetism below Tm, neutron diffraction and magnetization experiments show a ferromagnetic hysteresis of the Eu2+ spin alignment. We demonstrate that the direction of the Eu2+ moments is dominated by the distribution of pinned vortices based on the critical state model. Moreover, we demonstrate the manipulation of spin texture by controlling the direction of superconducting vortices, which can help realize spin manipulation devices using magnetic superconductors.

cond-mat.supr-con↗

arXiv2021

Superconductivity of centrosymmetric and non-centrosymmetric phases in antiperovskite (Ca,Sr)Pd$_3$P

In the recently discovered antiperovskite phosphide (Ca,Sr)Pd$_3$P, centrosymmetric (CS) and non-centrosymmetric (NCS) superconducting phases appear depending on the Sr concentration, and their transition temperatures ($T_\mathrm{c}$) differ by as much as one order of magnitude. In this study, we investigated the superconducting properties and electronic band structures of CS orthorhombic (CSo) (Ca$_{0.6}$Sr$_{0.4}$)Pd$_3$P ($T_\mathrm{c}$ = 3.5 K) and NCS tetragonal (NCSt) (Ca$_{0.25}$Sr$_{0.75}$)Pd$_3$P ($T_\mathrm{c}$ = 0.32 K) samples with a focus on explaining their large $T_\mathrm{c}$ difference. Specific heat measurements indicated that CSo (Ca$_{0.6}$Sr$_{0.4}$)Pd$_3$P was an s-wave superconductor in a moderate-coupling regime with a 2$Δ$$_0$/k$_B$$T_\mathrm{c}$ value of 4.0. Low-lying phonons leading to the strong coupling in the structurally analogous SrPt$_3$P were unlikely to be present in CSo (Ca$_{0.6}$Sr$_{0.4}$)Pd$_3$P. Given that CSo (Ca$_{0.6}$Sr$_{0.4}$)Pd$_3$P and NCSt (Ca$_{0.25}$Sr$_{0.75}$)Pd$_3$P exhibited similar Debye temperatures ($Θ$$_D$) of approximately 200 K, the large $T_\mathrm{c}$ difference could not be attributed to $Θ$$_D$.$T_\mathrm{c}$ of each phase was accurately reproduced based on the Bardeen-Cooper-Schrieffer (BCS) theory using experimental data and the density of states of the Fermi level $N$(0) calculated from their band structures. We concluded that the considerable suppression of $T_\mathrm{c}$ in NCSt (Ca$_{0.25}$Sr$_{0.75}$)Pd$_3$P can be primarily attributed to the decrease in $N$(0) associated with the structural phase transition without considering the lack of inversion symmetry.

cond-mat.supr-con↗

arXiv2021

Superconducting fluctuations in overdoped Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$

Fluctuating superconductivity - vestigial Cooper pairing in the resistive state of a material - is usually associated with low dimensionality, strong disorder or low carrier density. Here, we report single particle spectroscopic, thermodynamic and magnetic evidence for persistent superconducting fluctuations in heavily hole-doped cuprate superconductor Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ ($T_c$ = 66~K) despite the high carrier density. With a sign-problem free quantum Monte Carlo calculation, we show how a partially flat band at ($π$,0) can help enhance superconducting phase fluctuations. Finally, we discuss the implications of an anisotropic band structure on the phase-coherence-limited superconductivity in overdoped cuprates and other superconductors.

cond-mat.supr-con↗