arXiv subjects

Hristo Iglev

Publications and source records attributed to Hristo Iglev.

7 recordsLinked to original sources

arXiv2025

Ultrafast light-induced formation of a metastable hidden state in bismuth vanadate

Bismuth vanadate (BiVO$_4$) is a key photocatalyst for solar fuel applications, yet fundamental questions remain regarding the nature of photogenerated polaronic states and the lattice dynamics that govern its light-to-chemical pathways. Here, we use femtosecond optical pump-X-ray probe measurements to track the photoinduced electronic and structural dynamics in BiVO$_4$ across multiple length and time scales. Transient X-ray absorption spectroscopy captures sub-picosecond electron localization within VO$_4$ tetrahedra, consistent with small polaron formation, whereas time-resolved X-ray diffraction reveals a slower, multi-picosecond lattice reorganization into a hidden photoexcited state that is structurally distinct from both the monoclinic ground state and the high-temperature tetragonal phase. Supported by density functional theory, we show that hole-lattice interactions dynamically reduce the ground state monoclinic distortion, stabilizing the hidden state. Our results demonstrate that electron- and hole-lattice coupling jointly shape the excited state landscape, with implications for carrier transport, interfacial energetics, and light-to-chemical energy conversion pathways.

cond-mat.mtrl-sci↗

arXiv2022

Hot Carrier Dynamics in InAs-AlAsSb Core-Shell Nanowires

Semiconductor nanowires (NWs) have shown evidence of robust hot carrier effects due to their small dimensions. The relaxation dynamics of hot carriers in these nanostructures, generated by photo-absorption, are of great importance in optoelectronic devices and high efficiency solar cells, such as hot carrier solar cells. Among various III-V semiconductors, indium arsenide (InAs) NWs are promising candidates for their applications in advanced light harvesting devices due to their high photo-absorptivity and high mobility. Here, we investigate the hot carrier dynamics in InAs-AlAsSb core-shell NWs, as well as bare-core InAs NWs, using ultrafast pump-probe spectroscopy with widely tuned pump and probe energies. We have found a lifetime of 2.3 ps for longitudinal optical (LO) phonons and hot electron lifetimes of about 3 ps and 30 ps for carrier-carrier interactions and electron-phonon interactions, respectively. In addition, we have investigated the electronic states in the AlAsSb-shell and found that, despite the large band offset of the core-shell design in the conduction band, excited carriers remain in the shell longer than 100 ps. Our results indicate evidence of plasmon-tailored core-shell NWs for efficient light harvesting devices, which could open potential avenues for improving the efficiency of photovoltaic solar cells.

cond-mat.mtrl-sci↗

arXiv2021

Water jet space charge spectroscopy: Route to direct measurement of electron dynamics for organic systems in their natural environment

The toolbox for time-resolved direct measurements of electron dynamics covers a variety of methods. Since the experimental effort is increasing rapidly with achievable time resolution, there is an urge for simple and robust measurement techniques. Within this paper prove of concept experiments and numerical simulations are utilized to investigate the applicability of a new setup for the generation of ultrashort electron pulses in the energy range of 300 eV up to 1.6 keV. The experimental approach combines an in-vacuum liquid microjet and a few-cycle femtosecond laser system, while the threshold for electron impact ionization serves as a gate for the effective electron pulse duration. The experiments prove that electrons in the keV regime are accessible and that the electron spectrum can be easily tuned by laser intensity and focal position alignment with respect to the water jet. Numerical simulations show that a sub-picosecond temporal resolution is achievable.

hep-ex↗

arXiv2021

Ultrafast hot carrier relaxation in silicon monitored by phase-resolved transient absorption spectroscopy

The relaxation dynamics of hot carriers in silicon (100) is studied via a novel holistic approach based on phase-resolved transient absorption spectroscopy with few-cycle optical pulses. After excitation by a sub-5 fs light pulse, strong electron-phonon coupling leads to an ultrafast momentum relaxation with time constant of 10 fs. The thermalization of the hot carriers occurs on a time constant of 150 fs, visible in the temporal evolution of the collision time as extracted from the Drude model. We find an increase of the collision time from 3 fs for the shortest timescales with a saturation at approximately 18 fs. Moreover, the optical effective mass of the hot carrier ensemble evolves on ultrafast timescales as well, with a bi-exponential decrease from 0.7 $m_e$ to about 0.125 $m_e$ and time constants of 4 fs and 58 fs. The presented information on the electron mass dynamics as well as the momentum-, energy-, and collision-scattering times with unprecedented time resolution is important for all hot carrier optoelectronic devices.

cond-mat.mtrl-sci↗

arXiv2018

On the Warming of the Southern Hemisphere since 1955 and Recent Slowing-Down: Role of Sea Ice, Sun Spot and El Nino Variability

The importance of the sea ice retreat in the polar regions for the global warming and the role of ice-albedo feedback was recognized by various authors [1,2]. Similar to a recent study of the phenomenon in the Arctic [3] we present a semi-quantitative estimate of the mechanism for the Southern Hemisphere (SH). Using a simple model, we estimate the contribution of ice-albedo feedback to the mean temperature increase in the SH to be 0.5 +/- 0.1 K in the years 1955 to 2015, while from the simultaneous growth of the greenhouse gases (GHG) we derive a direct warming of only 0.2 +/- 0.05 K in the same period. These numbers are in nice accordance with the reported mean temperature rise of 0.75 +/- 0.1 K of the SH in 2015 since 1955 (and relative to 1880). Our data also confirm previously noticed correlations between the annual fluctuations of solar intensity and El Nino observations on the one hand and the annual variability of the SH surface temperature on the other hand. Our calculations indicate a slowing down of the temperature increase during the past few years that is likely to persist. Assuming a continuation of the present trends for the southern sea ice and GHG concentration we predict the further temperature rise to decrease by 33 % in 2015 to 2025 as compared to the previous decade.

physics.geo-ph↗

arXiv2018

Estimate of the Globing Warming Caused by the Retreat of Polar Sea Ice

The growing concentrations of the greenhouse gases CO2, CH4 and N2O (GHG) in the atmosphere are often considered as the dominant cause for the global warming during the past decades. The reported temperature data however do not display a simple correlation with the concentration changes since 1880 so that other reasons are to be considered to contribute notably. An important feature in this context is the shrinking of the polar ice caps observed in recent years. We have studied the direct effect of the loss of global sea ice since 1955 on the mean global temperature estimating the corresponding decrease of the terrestrial albedo. Using a simple 1-dimensional model the global warming of the surface is computed that is generated by the increase of GHG and the albedo change. A modest effect by the GHG of 0.08 K is calculated for the period 1880 to 1955 with a further increase by 0.18K for 1955 to 2015. A larger contribution of 0.55 +/-0.05 K is estimated for the melting of polar sea ice (MSI) in the latter period, i.e. it notably exceeds that of the GHG and may be compared with the observed global temperature rise of 1.0 +/- 0.1 K during the past 60 years. Our data also suggest a delayed response of the mean global temperature to the loss of sea ice with a time constant of approximately 20 years. The validity of the theoretical model and the interrelation between GHG-warming and MSI-effect are discussed.

physics.geo-ph↗

arXiv2017

Arctic Sea Ice and the Mean Temperature of the Northern Hemisphere

The importance of snow cover and ice extent in the Northern Hemisphere was recognized by various authors leading to a positive feedback of surface reflectivity on climate. In fact, the retreat of Arctic sea ice is accompanied by enhanced solar input in the Arctic region, i.e. a decrease of the terrestrial albedo. We have studied this effect for the past six decades and estimate the corresponding global warming in the northern hemisphere. A simple 1-dimensional model is used that includes the simultaneous increase of the greenhouse gases. Our results indicate that the latter directly cause a temperature rise of only 0.2 K in 1955 to 2015, while a notably larger effect 0.7 +/- 0.2 K is found for the loss of Arctic sea ice in the same time. These numbers comprise most of the reported mean temperature rise of 1.2 +/- 0.2 K of the northern hemisphere. The origin of the sea-ice retreat is discussed, e.g. internal variability or feedback by the CO2 concentration increase. Our data also suggest a delayed response of the global surface temperature rise to the loss of sea ice with a time constant of approximately 10 to 20 years.

physics.geo-ph↗