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Hua Tong

Publications and source records attributed to Hua Tong.

31 records · Page 2Linked to original sources

Experimental Test on Edwards Volume Ensemble of Tapped Granular Packings

Using X-ray tomography, we experimentally investigate granular packings subject to mechanical tapping for three types of beads with different friction coefficients. We validate Edwards volume ensemble in these three-dimensional granular systems and establish a granular version of thermodynamic zeroth law. Within Edwards framework, we also explicitly clarify how friction influences granular statistical mechanics as modifying the density of states, which allows us to determine the entropy as a function of packing fraction and friction subsequently. Additionally, we obtain a granular jamming phase diagram based on geometric coordination number and packing fraction.

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Jamming in confined geometry: Criticality of the jamming transition and implications of structural relaxation in confined supercooled liquids

In marginally jammed solids confined by walls, we calculate the particle and ensemble averaged value of an order parameter, $\left<Ψ(r)\right>$, as a function of the distance to the wall, $r$. Being a microscopic indicator of structural disorder and particle mobility in solids, $Ψ$ is by definition the response of the mean square particle displacement to the increase of temperature in the harmonic approximation and can be directly calculated from the normal modes of vibration of the zero-temperature solids. We find that, in confined jammed solids, $\left<Ψ(r)\right>$ curves at different pressures can collapse onto the same master curve following a scaling function, indicating the criticality of the jamming transition. The scaling collapse suggests a diverging length scale and marginal instability at the jamming transition, which should be accessible to sophisticatedly designed experiments. Moreover, $\left<Ψ(r)\right>$ is found to be significantly suppressed when approaching the wall and anisotropic in directions perpendicular and parallel to the wall. This finding can be applied to understand the $r$-dependence and anisotropy of the structural relaxation in confined supercooled liquids, providing another example of understanding or predicting behaviors of supercooled liquids from the perspective of the zero-temperature amorphous solids.

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Friction-controlled entropy-stability competition in granular systems

Using cyclic shear to drive a two dimensional granular system, we determine the structural characteristics for different inter-particle friction coefficients. These characteristics are the result of a competition between mechanical stability and entropy, with the latter's effect increasing with friction. We show that a parameter-free maximum-entropy argument alone predicts an exponential cell order distribution, with excellent agreement with the experimental observation. We show that friction only tunes the mean cell order and, consequently, the exponential decay rate and the packing fraction. We further show that cells, which can be very large in such systems, are short-lived, implying that our systems are liquid-like rather than glassy.

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Coupling between particle shape and long-range interaction in the high-density regime

By using long-range interacting polygons, we experimentally probe the coupling between particle shape and long-range interaction. For two typical space-filling polygons, square and triangle, we find two types of coupling modes that predominantly control the structure formation. Specifically, the rotational ordering of squares brings a lattice deformation that produces a hexagonal-to-rhombic transition in the high-density regime, whereas the alignment of triangles introduces a large geometric frustration that causes an order-to-disorder transition. Moreover, the two coupling modes lead to small and large "internal roughness" of the two systems, and thus predominantly control their structure relaxations. Our study thus provides a physical picture to the coupling between long-range interaction effect and short-range shape effect in the high-density regime unexplored before.

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Intermittent rearrangements accompanying thermal fluctuations distinguish glasses from crystals

It is a persistent problem in condensed matter physics that glasses exhibit vibrational and thermal properties that are markedly different from those of crystals. While recent works have advanced our understanding of vibrational excitations in glasses at the harmonic approximation limit, efforts in understanding finite-temperature anharmonic processes have been limited. It is well known that phonons in crystals couple through phonon-phonon interactions, an extremely efficient mechanism for anharmonic decay that is also important in glasses. Here, however, we show that an additional anharmonic channel of different origin emerges in the case of glasses, which induces intermittent rearrangements of particles. We have found that thermal vibrations in glasses trigger transitions among numerous different local minima of the energy landscape, which, however, are located within the same wide (meta)basin. These processes generate motions that are different from both diffusive and out-of-equilibrium aging dynamics. We suggest that the intermittent rearrangements accompanying thermal fluctuations are crucial features distinguishing glasses from crystals.

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Emergence and percolation of rigid domains during colloidal glass transition

Using video microscopy, we measure local spatial constraints in disordered binary colloidal samples, ranging from dilute fluids to jammed glasses, and probe their spatial and temporal correlations to local dynamics during the glass transition. We observe the emergence of significant correlations between constraints and local dynamics within the Lindemann criterion, which coincides with the onset of glassy dynamics in supercooled liquids. Rigid domains in fluids are identified based on local constraints, and demonstrate a percolation transition near glass transition, accompanied by the emergence of dynamical heterogeneities. Our results show that the spatial constraints instead of the geometry of amorphous structures is the key that connects the complex spatial-temporal correlations in disordered materials.

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Decoupling between thermodynamics and dynamics during rejuvenation in colloidal glasses

We rejuvenate well-aged quasi-2D binary colloidal glasses by thermal cycling, and systematically measure both the statistical responses and particle-level structural evolutions during rejuvenation. While the moduli and boson peak are continuously rejuvenated with increasing number of cycles, the mean square displacement (MSD) fluctuates significantly between different groups of thermal cycles. The decoupling between the thermodynamical and dynamical evolutions suggests different microscopic origins for different bulk properties of glasses. We find that a small fraction of structural rearrangements triggered by thermal cycling could alter the whole elastic continuum and lead to the significant thermodynamic rejuvenation, while localized defects could be activated and deactivated at the positions close to the rearrangements with significantly high mobility change and hence result in the fluctuated dynamics even with only about 10% of particles as fast regions. Our results offer a comprehensive picture for the microscopic mechanisms underlying bulk glass rejuvenation, which could be readily used to refine glass properties or to formulate further statistical theories in glassy systems.

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Realizing negative Poisson's ratio in unstressed spring networks

When randomly displacing the nodes of a crystalline and unstressed spring network, we find that the Possion's ratio decreases with the increase of structural disorder and even becomes negative. Employing our finding that longer springs tend to contribute more to the shear modulus but less to the bulk modulus, we are able to achieve negative Poisson's ratio with lower structural disorder by attributing each spring a length dependent stiffness. Even with perfect crystalline structure, the network can have negative Possion's ratio, if the stiffness of each spring is set by its virtual length after a virtual network distortion. We also reveal that the nonaffine contribution arising from the structural or spring constant disorder produced in some cooperative way by network distortion is essential to the emergence of negative Poisson's ratio.

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Role of disorder in determining the vibrational properties of mass-spring networks

By introducing four fundamental types of disorders into a two-dimensional triangular lattice separately, we determine the role of each type of disorder in the vibration of the resulting mass-spring networks. We are concerned mainly with the origin of the boson peak and the connection between the boson peak and the transverse Ioffe-Regel limit. For all types of disorders, we observe the emergence of the boson peak and Ioffe-Regel limits. With increasing disorder, the boson peak frequency $ω_{BP}$, transverse Ioffe-Regel frequency $ω_{IR}^T$, and longitudinal Ioffe-Regel frequency $ω_{IR}^L$ all decrease. We find that there are two ways for the boson peak to form: developing from and coexisting with (but remaining independent of) the transverse van Hove singularity without and with local coordination number fluctuation. In the presence of a single type of disorder, $ω_{IR}^T\ge ω_{BP}$, and $ω_{IR}^T\approx ω_{BP}$ only when the disorder is sufficiently strong and causes spatial fluctuation of the local coordination number. Moreover, if there is no positional disorder, $ω_{IR}^T\approx ω_{IR}^L$. Therefore, the argument that the boson peak is equivalent to the transverse Ioffe-Regel limit is not general. Our results suggest that both local coordination number and positional disorder are necessary for the argument to hold, which is actually the case for most disordered solids such as marginally jammed solids and structural glasses. We further combine two types of disorders to cause disorder in both the local coordination number and lattice site position. The density of vibrational states of the resulting networks resembles that of marginally jammed solids well. However, the relation between the boson peak and the transverse Ioffe-Regel limit is still indefinite and condition-dependent.

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Density affects the nature of the hexatic-liquid transition in two-dimensional melting of core-softened systems

We find that both continuous and discontinuous hexatic-liquid transitions can happen in the melting of two-dimensional solids of soft-core disks. For three typical model systems, Hertzian, harmonic, and Gaussian-core models, we observe the same scenarios. These systems exhibit reentrant crystallization (melting) with a maximum melting temperature $T_m$ happening at a crossover density $ρ_m$. The hexatic-liquid transition at a density smaller than $ρ_m$ is discontinuous. Liquid and hexatic phases coexist in a density interval, which becomes narrower with increasing temperature and tends to vanish approximately at $T_m$. Above $ρ_m$, the transition is continuous, in agreement with the Kosterlitz-Thouless-Halperin-Nelson-Young theory. For these soft-core systems, the nature of the hexatic-liquid transition depends on density (pressure), with the melting at $ρ_m$ being a plausible transition point from discontinuous to continuous hexatic-liquid transition.

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From Crystals to Disordered Crystals: A Hidden Order-Disorder Transition

We find an order-disorder transition from crystals to disordered crystals for static packings of frictionless spheres. While the geometric indicators are mostly blind to the transition, disordered crystals already exhibit properties apart from crystals. The transition approaches the close packing of hard spheres, giving rise to the singularity of the close packing point. We evidence that both the transition and properties of disordered crystals are jointly determined by the structural orders and density. Near the transition, the elastic moduli and coordination number of disordered crystals show particular pressure dependence distinct from both crystals and jammed solids.

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Mechanical properties of jammed packings of frictionless spheres under applied shear stress

By minimizing a thermodynamic-like potential, we unbiasedly sample the potential energy landscape of soft and frictionless spheres under constant shear stress. We obtain zero-temperature jammed states under desired shear stresses and investigate their mechanical properties as a function of the shear stress. As a comparison, we also obtain jammed states from the quasistatic-shear sampling in which the shear stress is not well-controlled. Although the yield stresses determined by both samplings show the same power-law scaling with the compression from point $J$, i.e.~the jamming transition point at zero temperature and shear stress, for finite size systems, the quasistatic-shear sampling leads to a lower yield stress and a higher critical volume fraction of point $J$. The shear modulus of jammed solids decreases when increasing the shear stress. However, the shear modulus does not decay to zero at yielding. This discontinuous change of the shear modulus implies the discontinuous nature of the unjamming transition under nonzero shear stress, which is further verified by the observation of a discontinuous jump of the pressure from jammed solids to shear flows. The pressure jump decreases upon decompression and approaches zero at the critical-like point $J$, in analogy with well-known phase transitions under external field. The analysis of force networks in jammed solids reveals that the force distribution is more sensitive to the increase of the shear stress near point $J$. The force network anisotropy increases with the shear stress. Weak particle contacts near the average force and under large shear stresses exhibit asymmetric angle distribution.

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Structural heterogeneity and its role in determining properties of disordered solids

We construct a new order parameter from the normal modes of vibration, based on the consideration of energy equipartition, to quantify the structural heterogeneity in disordered solids. The order parameter exhibits strong spatial correlations with low-temperature single particle dynamics and local structural entropy. To characterize the role of particles with the most defective local structures identified by the order parameter, we pin them and study how properties of disordered solids respond to the pinning. It turns out that these particles are responsible to the quasilocalized low-frequency vibration, instability, softening, and nonaffinity of disordered solids.

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