arXiv subjects

Hui Guo

Publications and source records attributed to Hui Guo.

At least 19 recordsLinked to original sources

arXiv2026

Interpretable physics-informed retrieval-augmented generation language model for end-to-end inorganic crystal synthesis planning

Synthesis planning for inorganic materials requires predicting both synthesizability and viable routes by linking microscopic thermodynamic stability with macroscopic synthesis methods, precursors, and processing conditions. Here, we develop an interpretable Physics-Informed Retrieval-Augmented Generation Language Model (PIRAG-LM) for end-to-end inorganic crystal synthesis planning. We construct a material-centered Structured Synthesis Knowledge Base (SSKB) containing route-level records for 13,820 experimentally synthesized inorganic crystals. PIRAG-LM retrieves historical precedents using chemical, structural, and thermodynamic similarity, then employs a structured LLM reasoning module to propose routes, precursors, and processing conditions and assess thermodynamic feasibility, kinetics, and accessibility. It achieves 91.4% accuracy in synthesis-method prediction, compared with 72.1% for the LLM alone, and generalizes to materials reported after the knowledge cutoff. Because the framework relies on retrieval rather than parametric memorization, its performance can be improved by expanding the SSKB without retraining the language model. Guided by PIRAG-LM, we experimentally synthesize five new compounds: BaMo0.3In0.7O2.95, BaNb0.4In0.6O2.9, Hg[B(CN)4]2, CoCo(CN)6, and SrNb2Fe2(PO4)6, via solid-state and solution routes. These results demonstrate an interpretable machine-learning approach that helps bridge computational materials discovery and experimental realization.

cond-mat.mtrl-sci↗

arXiv2026

Realization of Air-Stable Two-Dimensional Superconductor Nb2Pd3Te5 With Quasi-One-Dimensional Pair Density Modulation

Two-dimensional (2D) superconductors provide a fertile platform for exploring reduced-dimensional superconductivity and emergent quantum phenomena. Incorporating quasi-one-dimensional (quasi-1D) structural motifs into 2D superconductors offers a powerful route to engineer strong electronic anisotropy, enabling unconventional superconducting states and anisotropic superconducting transport functionalities. However, such systems remain rarely realized. Here we report the realization of a 2D superconductor Nb2Pd3Te5, exhibiting an intrinsic quasi-1D pair density modulation. Monolayer and bilayer Nb2Pd3Te5 is synthesized via van-der-Waals epitaxy. Using ultralow-temperature scanning tunneling microscopy/spectroscopy, we observe the quasi-1D crystal structure and superconductivity below ~0.6 K with a pronounced quasi-1D pair density modulation. Remarkably, both monolayer and bilayer Nb2Pd3Te5 show strong air stability. Our findings establish atomically 2D Nb2Pd3Te5 as a robust and promising platform for exploring novel low-dimensional quantum phenomena and anisotropy-enabled superconducting devices.

cond-mat.mtrl-sci↗

arXiv2026

(Mis)Understanding Benign Overfitting in Equity Return Prediction

Highly overparameterized models often predict well despite interpolating training data in complex domains, challenging the classical bias--variance tradeoff. We investigate whether this ``benign overfitting'' phenomenon extends to equity return prediction. Consistent with recent statistical theory, we document two key phenomena: first, a double descent pattern in the ridgeless model's prediction risk; and second, that while the optimal ridge model consistently outperforms its ridgeless counterpart, this performance gap becomes negligible at large parameter-to-observation ratios. Ultimately, however, both models fail to outperform a simple historical average. This empirical evidence aligns with our asymptotic results under the null hypothesis of zero slope coefficients, suggesting that standard equity predictors lack true forecasting power---even within highly flexible, nonlinear machine learning architectures. These findings reconcile modern and classical machine learning in asset pricing: in the absence of a true signal, they asymptotically collapse to the historical average benchmark.

stat.ML↗

arXiv2026

Teach-to-Reason: Competition-Guided Reasoning with a Self-Improving Teacher

Chest X-ray visual question answering (CXR VQA) requires models not only to predict correct answers, but also to produce reliable medical reasoning. However, existing reinforcement-learning-based training typically relies on answer-level rewards, which are often too coarse to improve chain-of-thought (CoT) quality and can become ineffective when group-level advantages collapse to zero. We propose \textbf{Teach-to-Reason (T2R)}, a framework that introduces comparison-based supervision into CoT optimization through a self-improving \emph{Teacher} and a competition-guided \emph{Reasoner}. As the Teacher is iteratively strengthened via self-competition, the Reasoner is optimized against progressively stronger Teacher-generated references. We further introduce a case-wise reward design that preserves the original reward-induced positive/negative partition when it is informative, and restores supervision from competition scores when the original reward signal degenerates. Experiments on multiple CXR open-ended VQA benchmarks show that T2R consistently outperforms strong baselines, indicating that comparison-based supervision, when integrated in a controlled and principled manner, provides a more effective training signal for reasoning optimization.

cs.CV↗

arXiv2026

Modulation of charge density waves in a twisted vortex moire superlattice

Twisted moire superlattices in van-der-Waals heterostructures provide a powerful platform for engineering correlated states through moire-band reconstruction. However, whether globally coherent electronic orders can be continuously manipulated at the nanoscale remains largely unexplored. Reconstructed moire structures in small-angle and near-commensurate regime feature continuously varying local environments, offering new opportunities for nanoscale manipulation of correlated phases. Here, we report the modulation of charge density wave (CDW) states in a twisted vortex moire superlattice formed between monolayer VTe2 and superconducting NbSe2. Scanning tunneling microscopy/spectroscopy reveals that the intrinsic long-range CDW of monolayer VTe2 is reconstructed into inequivalent local phases with distinct stability and coherence within a single moire unit cell, including suppressed CDW order and enhanced short-range CDW correlations persisting to room temperature. First-principles calculations show that the reconstructed CDW landscape originates from strong local strain variation, where compressive strain substantially stabilizes the charge order. Furthermore, the modulated CDW states exhibit competing interplay with proximity-induced superconductivity. Our results establish vortex moire superlattices as a versatile platform for nanoscale manipulation of correlated electronic orders in low-dimensional quantum materials.

cond-mat.mtrl-sci↗

arXiv2026

Discovery of a nonsymmorphic superconductor with spontaneous rotational symmetry breaking and nontrivial zero modes

Topological superconductivity has attracted great interest due to its fundamental significance for realizing Majorana quasiparticles and fault-tolerant quantum computation. Nonsymmorphic superconductors, with symmetry-protected nontrivial electronic structures, offer a promising route to exotic topological superconducting states, yet experimental realizations remain scarce. Here we identify nonsymmorphic compound PtPb4 as a robust platform hosting superconductivity with spontaneous rotational symmetry breaking and nontrivial zero-energy modes. PtPb4 crystallizes in a frustrated Shastry-Sutherland lattice and exhibits nontrivial band topology. By combining in-plane and out-of-plane resistivity measurements, pronounced twofold anisotropy is observed in both the superconducting state and the upper critical field, evidencing spontaneous rotational symmetry breaking. Scanning tunneling microscopy/spectroscopy further reveal twofold-symmetric magnetic vortices, providing direct real-space evidence for the symmetry-broken superconducting state. Notably, a robust zero-energy vortex bound state emerges and persists without spatial splitting over extended distances, consistent with the characteristics expected for Majorana bound state. These findings uncover an exotic superconducting state in PtPb4 and establish a promising platform for exploring topological superconductivity and superconducting quantum devices.

cond-mat.supr-con↗

arXiv2026

Cs$_4$Cr$_7$Te$_{10}$: Interwoven Reconstructed Archimedean and Kagome Lattices with a Possible Phase Transition near 130 K

Chromium-based materials with complex lattice geometries provide an important platform for investigating correlated electronic and magnetic states. However, Cr-based compounds with unusual crystal geometries are still rarely reported. Here, we report a new Cr-based compound, Cs$_4$Cr$_7$Te$_{10}$, featuring interwoven Cr and Te sublattices that can be viewed as reconstructed networks derived from Archimedean (3.4.6.4) tiling and the kagome lattice, respectively. Transport measurements reveal the semiconducting nature in Cs$_4$Cr$_7$Te$_{10}$. Magnetization measurements show a weak anisotropy between H//b and H//ac planes, and uncover an anomaly near 130 K that is insensitive to the applied magnetic fields. Specific-heat measurements further confirm this transition, indicating its bulk thermodynamic nature. The associated entropy change is as small as 0.41 J mol^-1 K^-1, ruling out a structural phase transition and pointing to a possible electronic and/or magnetic phase transition. These results provide a new route for designing complex crystal geometries and exploring their associated emergent phenomena.

cond-mat.mtrl-sci↗

arXiv2026

Weight Group-wise Post-Training Quantization for Medical Foundation Model

Foundation models have achieved remarkable results in medical image analysis. However, its large network architecture and high computational complexity significantly impact inference speed, limiting its application on terminal medical devices. Quantization, a technique that compresses models into low-bit versions, is a solution to this challenge. In this paper, we propose a post-training quantization algorithm, Permutation-COMQ. It eliminates the need for backpropagation by using simple dot products and rounding operations, thereby removing hyperparameter tuning and simplifying the process. Additionally, we introduce a weight-aware strategy that reorders the weight within each layer to address the accuracy degradation induced by channel-wise scaling during quantization, while preserving channel structure. Experiments demonstrate that our method achieves the best results in 2-bit, 4-bit, and 8-bit quantization.

cs.CV↗

arXiv2026

Evidence-Based Actor-Verifier Reasoning for Echocardiographic Agents

Echocardiography plays an important role in the screening and diagnosis of cardiovascular diseases. However, automated intelligent analysis of echocardiographic data remains challenging due to complex cardiac dynamics and strong view heterogeneity. In recent years, visual language models (VLM) have opened a new avenue for building ultrasound understanding systems for clinical decision support. Nevertheless, most existing methods formulate this task as a direct mapping from video and question to answer, making them vulnerable to template shortcuts and spurious explanations. To address these issues, we propose EchoTrust, an evidence-driven Actor-Verifier framework for trustworthy reasoning in echocardiography VLM-based agents. EchoTrust produces a structured intermediate representation that is subsequently analyzed by distinct roles, enabling more reliable and interpretable decision-making for high-stakes clinical applications.

cs.CV↗

arXiv2026

$\mathrm{Cs_3V_9Te_{13}}$: A New Vanadium-Based Material with a Reuleaux-Triangle-Like Lattice and a Possible Phase Transition near 48 K

Exploring and synthesizing materials with new crystal structures provides an important route to discovering exotic quantum phenomena. However, materials with unconventional lattice geometries remain largely unexplored. Here, we report the discovery of a new vanadium-based material, $\mathrm{Cs_3V_9Te_{13}}$, featuring a Reuleaux-triangle-like lattice. Electrical transport and magnetic measurements consistently reveal an anomaly near 48 K, and this feature shows little sensitivity to the applied magnetic field. A corresponding anomaly is also observed in the Hall coefficient near 48 K, indicating a marked change in the carrier response. In addition, temperature-dependent x-ray diffraction results indicate no obvious structural change across 48 K. Taken together, these results suggest that the anomaly is not induced by the structural transition, but associated to a possible electronic and/or magnetic phase transition. High-pressure transport measurements and first-principles calculations further reveal a highly tunable electronic state in $\mathrm{Cs_3V_9Te_{13}}$, with the kagome-like electronic feature and pressure-suppressed antiferromagnetism. These results demonstrate this material, with its structurally novel Reuleaux-triangle-like lattice, as a new platform for exploring the interplay between nontrivial lattice geometry and emergent physical phenomena.

cond-mat.mtrl-sci↗

arXiv2026

Addressing both variable selection and misclassified responses with parametric and semiparametric methods

While variable selection has received extensive attention in the literature, its exploration in the presence of response measurement error remains underexplored. In this paper, we investigate this important problem within the context of binary classification with error-prone responses. We present valid variable selection procedures to address the complexities of response errors. Leveraging validation data, we introduce both parametric and semiparametric methodologies to accommodate the mismeasurement effects. By rigorously establishing theoretical results, we offer insights and justifications of the validity of the proposed methods. By properly choosing {the} penalty function and regularization parameter, we demonstrate that the resulting estimators possess the oracle property. To assess the finite sample properties of the proposed methods, we conduct numerical studies that confirm the effectiveness of our proposed methods.

stat.ME↗

arXiv2026

DEP: A Decentralized Large Language Model Evaluation Protocol

With the rapid development of Large Language Models (LLMs), a large number of benchmarks have been proposed. However, most benchmarks lack unified evaluation standard and require the manual implementation of custom scripts, making results hard to ensure consistency and reproducibility. Furthermore, mainstream evaluation frameworks are centralized, with datasets and answers, which increases the risk of benchmark leakage. To address these issues, we propose a Decentralized Evaluation Protocol (DEP), a decentralized yet unified and standardized evaluation framework through a matching server without constraining benchmarks. The server can be mounted locally or deployed remotely, and once adapted, it can be reused over the long term. By decoupling users, LLMs, and benchmarks, DEP enables modular, plug-and-play evaluation: benchmark files and evaluation logic stay exclusively on the server side. In remote setting, users cannot access the ground truth, thereby achieving data isolation and leak-proof evaluation. To facilitate practical adoption, we develop DEP Toolkit, a protocol-compatible toolkit that supports features such as breakpoint resume, concurrent requests, and congestion control. We also provide detailed documentation for adapting new benchmarks to DEP. Using DEP toolkit, we evaluate multiple LLMs across benchmarks. Experimental results verify the effectiveness of DEP and show that it reduces the cost of deploying benchmark evaluations. As of February 2026, we have adapted over 60 benchmarks and continue to promote community co-construction to support unified evaluation across various tasks and domains.

cs.CL↗

arXiv2026

ELFO: A Python Package for Emission Line Fitting Optimization in Integral Field Spectroscopy Data

Integral field spectroscopy (IFS) provides spatially resolved spectra, enabling detailed studies that address the physical and kinematic properties of the interstellar medium. A critical step in analyzing IFS data is the decomposition of emission lines, where different velocity components are often modeled with Gaussian profiles. However, conventional fitting methods that treat each spectrum independently often yield spatial discontinuities in the fitting results. Here, we present Emission Line Fitting Optimization (ELFO), a Python package for IFS spectral fitting. ELFO uses the results of neighboring spectra to determine multiple initial guesses and selects the result that exhibits spatial smoothness. We tested ELFO on IFS data of two quasars obtained from the Multi-Unit Spectroscopic Explorer, where it successfully corrected anomalous fits, revealed previously unresolved substructures, and made large-scale kinematic structures more evident. With minor modifications, this method can also be easily adapted to other IFS data and different emission lines.

astro-ph.GA↗

arXiv2026

Diffusion Epistemic Uncertainty with Asymmetric Learning for Diffusion-Generated Image Detection

The rapid progress of diffusion models highlights the growing need for detecting generated images. Previous research demonstrates that incorporating diffusion-based measurements, such as reconstruction error, can enhance the generalizability of detectors. However, ignoring the differing impacts of aleatoric and epistemic uncertainty on reconstruction error can undermine detection performance. Aleatoric uncertainty, arising from inherent data noise, creates ambiguity that impedes accurate detection of generated images. As it reflects random variations within the data (e.g., noise in natural textures), it does not help distinguish generated images. In contrast, epistemic uncertainty, which represents the model's lack of knowledge about unfamiliar patterns, supports detection. In this paper, we propose a novel framework, Diffusion Epistemic Uncertainty with Asymmetric Learning~(DEUA), for detecting diffusion-generated images. We introduce Diffusion Epistemic Uncertainty~(DEU) estimation via the Laplace approximation to assess the proximity of data to the manifold of diffusion-generated samples. Additionally, an asymmetric loss function is introduced to train a balanced classifier with larger margins, further enhancing generalizability. Extensive experiments on large-scale benchmarks validate the state-of-the-art performance of our method.

cs.CV↗

arXiv2026

Electronic procrystalline state in moire structures

Solid state materials can display varieties of atomic structural orders ranging from crystalline to amorphous, underlying their properties and diverse functionalities. Procrystal has emerged as a new category of solids, featuring a long-range ordered lattice framework tiled with disordered atomic or molecular structures on the lattice sites, arousing great interest due to its novel structural and physical properties. However, the electronic analogue of a procrystal, dubbed as an electronic procrystalline (EPC) state, has never been experimentally observed. Here, we report the observation of an EPC state in a moire superstructure formed between a monolayer metallic NiTe2 and a superconductor NbSe2 with incommensurate lattice wavevectors. The observed EPC state exhibits a long-range periodic charge modulation at the moire scale inlaid with short-range irregular orders within each moire cell. Strikingly, the short-range charge orders inside the moire unit cells have proximately root3*root3 quasi-period, which is absent in pristine NiTe2. Intriguingly, the EPC order is also observed in the superconducting state of the moire superstructure. Furthermore, the emergent EPC state and short-range charge order, coexisting with the proximity induced superconductivity, can be precisely modulated with the thickness of NiTe2. Our findings uncover the potential of moire platform for understanding and tuning novel correlated quantum phases with this exotic procrystalline order.

cond-mat.mtrl-sci↗

arXiv2025

nncase: An End-to-End Compiler for Efficient LLM Deployment on Heterogeneous Storage Architectures

The efficient deployment of large language models (LLMs) is hindered by memory architecture heterogeneity, where traditional compilers suffer from fragmented workflows and high adaptation costs. We present nncase, an open-source, end-to-end compilation framework designed to unify optimization across diverse targets. Central to nncase is an e-graph-based term rewriting engine that mitigates the phase ordering problem, enabling global exploration of computation and data movement strategies. The framework integrates three key modules: Auto Vectorize for adapting to heterogeneous computing units, Auto Distribution for searching parallel strategies with cost-aware communication optimization, and Auto Schedule for maximizing on-chip cache locality. Furthermore, a buffer-aware Codegen phase ensures efficient kernel instantiation. Evaluations show that nncase outperforms mainstream frameworks like MLC LLM and Intel IPEX on Qwen3 series models and achieves performance comparable to the hand-optimized llama.cpp on CPUs, demonstrating the viability of automated compilation for high-performance LLM deployment. The source code is available at https://github.com/kendryte/nncase.

cs.DC↗

arXiv2025

Atomically-precise synthesis and simultaneous integration of 2D transition metal dichalcogenides enabled by nano-confinement

Two-dimensional (2D) materials, such as graphene, transition metal dichalcogenides (TMDs), and hBN, exhibit intriguing properties that are sensitive to their atomic-scale structures and can be further enriched through van der Waals (vdW) integration. However, the precise synthesis and clean integration of 2D materials remain challenging. Here, using graphene or hBN as a vdW capping layer, we create a nano-confined environment that directs the growth kinetics of 2D TMDs (e.g., NbSe2 and MoS2), enabling precise formation of TMD monolayers with tailored morphologies, from isolated monolayer domains to large-scale continuous films and intrinsically-patterned rings. Moreover, Janus S-Mo-Se monolayers are synthesized with atomic precision via vdW-protected bottom-plane chalcogen substitution. Importantly, our approach simultaneously produces ultraclean vdW interfaces. This in situ encapsulation reliably preserves air-sensitive materials, as evidenced by the enhanced superconductivity of nano-confined NbSe2 monolayers. Altogether, our study establishes a versatile platform for the controlled synthesis and integration of 2D TMDs for advanced applications.

cond-mat.mtrl-sci↗

arXiv2025

Tuning Bound States of Symmetry-Breaking Vortices via Unidirectional Charge Density Wave in a Transition-Metal Dichalcogenide Superconductor

The interplay between charge density wave (CDW) and superconducting vortex bound states are crucial for fundamental physics of superconductivity and advancing quantum nanotechnologies. However, the CDW-mediated modulation of vortex bound states, which opens up a new platform for vortex engineering, remains unexplored. Here, we report spatially anisotropic vortex states modulated by the unidirectional CDWs in a transition-metal dichalcogenide superconductor 1T''-NbTe2 using ultra-low-temperature scanning tunneling microscopy/spectroscopy. The stripe-like 3x1x3 CDW order exhibits a robust three-dimensional character across step edges and coexists with superconductivity below a critical temperature of 0.4 K. Under out-of-plane magnetic fields, we observe elliptical vortices whose elongation aligns with the CDW stripes, indicating strong coupling between vortex morphology and underlying electronic order. Remarkably, CDW domain boundaries induce abrupt changes in vortex orientation and vortex bound states, enabling controllable vortex states across CDW nanodomains. These findings establish a new pathway for manipulating superconducting vortex bound states via CDW coupling.

cond-mat.supr-con↗