arXiv subjects

Hui-Tian Wang

Publications and source records attributed to Hui-Tian Wang.

At least 37 records · Page 2Linked to original sources

arXiv2022

Helium-bearing superconductor at high pressure

Helium (He) is the most inert noble gas at ambient conditions. It adopts a hexagonal close packed structure (P63/mmc) and remains in the insulating phase up to 32 TPa. In contrast, lithium (Li) is one of the most reactive metals at zero pressure, while its cubic high-pressure phase (Fd-3m) is a weak metallic electride above 475 GPa. Strikingly, a stable compound of Li5He2 (R-3m) was formed by mixing Fd-3m Li with P63/mmc He above 700 GPa. The presence of helium promotes the lattice transformation from Fd-3m Li to Pm-3m Li, and tuns the three-dimensional distributed interstitial electrons into the mixture of zero- and two-dimensional anionic electrons. This significantly increases the degree of metallization at the Fermi level, consequently, the coupling of conductive anionic electrons with the Li-dominated vibrations is the key factor to the formation of superconducting electride Li5He2 with a transition temperature up to 26 K, dynamically stable to pressures down to 210 GPa.

cond-mat.supr-con↗

arXiv2022

Customizable Laguerre-Gaussian Perfect Vortex Beams

The recognition in the 1990s that vortex beams (VBs), paraxial light beams with optical vortices, carry orbital angular momentum (OAM), has benefited applications ranging from optical manipulation to high-dimensional classical and quantum information communications. The transverse profiles of common VBs, e.g., Laguerre-Gaussian beam and high-order Bessel beam, are hollow donuts whose radii grow up with OAM inevitably. The inherently unperfect character of the VBs that the radius is always positively correlated with OAM, restricts the application of the VBs in many scenarios like fiber optic data transmission, spatial OAM mode (de)multiplexing communication, and particle manipulation, which call for VBs to have the same scale with distinct OAM or even the small vortex ring for large OAM. Here, we derived a theory based on the most widely used Laguerre-Gaussian beam to generate a brand new type of VB with OAM-independent radii that moves away from the common unperfect constraint, called Laguerre-Gaussian Perfect Vortex Beam (LGPVB). LGPVBs have the self-similar property like common Laguerre-Gaussian beams but can self-heal after suffering disturbance and always remain 'perfection' when propagating. Our Fourier-space design not only allows us to shape the LGPVB's propagating intensity at will, but it also gives LGPVB the fascinating potential to arbitrarily self-accelerate while still perfectly propagating, self-similar, and self-healing. This customizable self-healing LGPVB, whose properties inform our most expectations of VBs, offers a better alternative for application scenarios of common VBs in a wide range of areas.

physics.optics↗

arXiv2022

Versatile Non-diffracting Perfect Vortex Beams

The rapid scale broadening and divergence increasing of vortex beams (VBs) with orbital angular momentum (OAM), e.g., Laguerre-Gaussian beams, severely impede the wide applications of VBs ranging from optical manipulation to high-dimensional quantum information communications, which call for VBs to have the same transverse scale and divergence for distinct OAM or even the small vortex ring for large OAM. Non-diffracting beams, on the other hand, that are capable of overcoming diffraction without divergence, are very evocative and indeed appealing in numerous applications including atom optics and medical imaging. Here, we propose theoretically and demonstrate experimentally a brand new type of VB having OAM-independent radii meanwhile holding propagation-invariant without divergence as well as self-healing properties, named non-diffracting perfect vortex beam (NDPVB). We work out a versatile toolkit based on Fourier-space analysis to multidimensionally customize NDPVBs at will so that it is of propagating intensity and phase controllability with intriguing customizable behaviors of self-accelerating, self-similar, and self-rotating. This goes beyond tailoring the transverse plane to the higher-dimensional propagating characteristics in structured light beams. A deeper insight into the internal flow revealed and confirmed that the multidimensional customization of NDPVBs is dominated by inducing corresponding multidimensional internal flow, facilitating our understanding of how our design scheme of propagating properties manipulates the internal flows, unveiling the nature of structure formation and behavior transformation of structured light beams.

physics.optics↗

arXiv2022

Experimental Demonstration of Quantum Pseudotelepathy

Quantum pseudotelepathy is a strong form of nonlocality. Different from the conventional non-local games where quantum strategies win statistically, e.g., the Clauser-Horne-Shimony-Holt game, quantum pseudotelepathy in principle allows quantum players to with probability 1. In this work, we report a faithful experimental demonstration of quantum pseudotelepathy via playing the non-local version of Mermin-Peres magic square game, where Alice and Bob cooperatively fill in a 3 by 3 magic square. We adopt the hyperentanglement scheme and prepare photon pairs entangled in both the polarization and the orbital angular momentum degrees of freedom, such that the experiment is carried out in a resource-efficient manner. Under the locality and fair-sampling assumption, our results show that quantum players can simultaneously win all the queries over any classical strategy.

quant-ph↗

arXiv2022

Manipulating propagation and evolution of polarization singularities in composite Bessel-like fields

Structured optical fields embedded with polarization singularities (PSs) have attracted extensive attention due to their capability to retain topological invariance during propagation. Many advances in PSs research have been made over the past 20 years in the areas of mathematical description, generation and detection technologies, propagation dynamics, and applications. However, one of the most crucial and difficult tasks continues to be manipulating PSs with multiple degrees of freedom, especially in three-dimensional (3D) tailored optical fields. We propose and demonstrate the longitudinal PS lines obtained by superimposing Bessel-like modes with orthogonal polarization states on composite vector optical fields (VOFs). The embedded PSs in the fields can be manipulated to propagate robustly along arbitrary trajectories, or to annihilate, revive, and transform each other at on-demand positions in 3D space, allowing complex PSs topological morphology and intensity pattern to be flexibly customized. Our findings could spur further research into singular optics and help with applications such as micromanipulation, microstructure fabrication, and optical encryption.

physics.optics↗

arXiv2022

Unusual phase transition of layer-stacked borophene under pressure

The 8-Pmmn borophene, a boron analogue of graphene, hosts tilted and anisotropic massless Dirac fermion quasiparticles owing to the presence of the distorted graphene-like sublattice. First-principles calculations show that the stacked 8-Pmmn borophene is transformed into the fused three-dimensional borophene under pressure, being accompanied by the partially bond-breaking and bond-reforming. Strikingly, the fused 8-Pmmn borophene inherits the Dirac band dispersion resulting in an unusual semimetal-semimetal transition. A simple tight-binding model derived from graphene qualitatively reveals the underlying physics due to the maximum preservation of graphene-like substructure after the phase transition, which contrasts greatly to the transformation of graphite into diamond associated with the semimetal-insulator transition.

cond-mat.mtrl-sci↗

arXiv2022

Nonlinear manipulation of orbital angular momentum spectra with second- and third- harmonic generation in a quasi-periodically poled crystal

Optical orbital angular momentum (OAM), as an important degree of freedom of light, has been attracted extensive attention, due to its intrinsic feature of natural discrete infinite dimension. Manipulation of OAM spectra is crucial for many impressive applications from classical to quantum realms, in particular, nonlinear manipulation of OAM spectra. Here we realized the nonlinear manipulation of OAM spectra by using the simultaneous second- and third-harmonic generation in a single nonlinear crystal of quasi-periodically poled potassium titanyl phosphate, for fundamental waves with a variety of OAM spectra, especially for customized OAM spectra of the second and third harmonics. The experimental results confirmed the theoretical predictions. Our approach not only provides a novel way to manipulate OAM spectra at new shorter wavelengths that are hard to be directly generated, but also may find new applications towards multiplexing in classical optics and high-dimensional information processing in quantum optics.

physics.optics↗

arXiv2022

Third-harmonic generation of spatially structured light in a quasi-periodically poled crystal

Nonlinear optical processes of spatially structured light, including optical vortex and vector optical fields, have stimulated a lot of interesting physical effects and found a variety of important applications ranging from optical imaging to quantum information processing. However, high harmonic generation of vector optical fields with space-varying polarization states is still a challenge. Here we demonstrate third harmonic generation of spatially structured light including vector optical fields, in a nonlinear Sagnac interferometer containing a carefully designed quasi-periodically poled potassium titanyl phosphate for the first time. The experimental results are in good agreement with the theoretical predictions. Our results will enable to manipulate spatially structured light or photons at new wavelengths and carrying higher orbital angular momentum. Our approach has the potential applications for the research of optical skyrmions and may open up new opportunities to produce spatially structured entangled photons for quantum communication and computation.

physics.optics↗

arXiv2022

Ultrahigh-Pressure Magnesium Hydrosilicates as Reservoirs of Water in Early Earth

The origin of water on the Earth is a long-standing mystery, requiring a comprehensive search for hydrous compounds, stable at conditions of the deep Earth and made of Earth-abundant elements. Previous studies usually focused on the current range of pressure-temperature conditions in the Earth's mantle and ignored a possible difference in the past, such as the stage of the core-mantle separation. Here, using ab initio evolutionary structure prediction, we find that only two magnesium hydrosilicate phases are stable at megabar pressures, $α$-Mg$_2$SiO$_5$H$_2$ and $β$-Mg$_2$SiO$_5$H$_2$, stable at 262-338 GPa and >338 GPa,respectively (all these pressures now lie within the Earth's iron core). Both are superionic conductors with quasi-one-dimensional proton diffusion at relevant conditions. In the first 30 million years of Earth's history, before the Earth's core was formed, these must have existed in the Earth, hosting much of Earth's water. As dense iron alloys segregated to form the Earth's core, Mg$_2$SiO$_5$H$_2$ phases decomposed and released water. Thus, now-extinct Mg$_2$SiO$_5$H$_2$ phases have likely contributed in a major way to the evolution of our planet.

physics.geo-ph↗

arXiv2022

Electronegativity and chemical hardness of the elements under pressure

Abundant evidence has shown the emergence of exotic chemical phenomena under pressure, including the formation of unexpected compounds and strange crystal structures. In many cases, there is no convincing explanation for these phenomena and there are virtually no chemical rules or models capable of predicting or even rationalizing these phenomena. Here we calculate, as a function of pressure, two central chemical properties of atoms, electronegativity and chemical hardness, which can be seen as the first and second-order chemical potentials. Mulliken electronegativity, which equals minus the chemical potential of the electron relative to the vacuum, is appropriately modified - instead of taking the vacuum (impossible under high pressure), we take the homogeneous electron gas as reference. We find that for most elements, chemical hardness and electronegativity decrease with pressure, consistent with pressure-induced metallization. Furthermore, we discover that pressure-induced s-d orbital transfer makes Ni, Pd and Pt "pseudo-noble-gas" atoms with a closed d-shell configuration, and the elements preceding them (Fe and especially Co, Rh, Ir) electron acceptors, while the elements right after them (Cu, Ag, Zn, Cd, for example) become highly electropositive. We show the explicative and predictive power of our electronegativity and chemical hardness scales under pressure.

cond-mat.mtrl-sci↗

arXiv2021

Experimental self-testing for photonic graph states

Graph states -- one of the most representative families of multipartite entangled states, are important resources for multiparty quantum communication, quantum error correction, and quantum computation. Device-independent certification of highly entangled graph states plays a prominent role in the quantum information processing tasks. Here we have experimentally demonstrated device-independent certification for multipartite graph states, by adopting the robust self-testing scheme based on scalable Bell inequalities. Specifically, the prepared multi-qubit Greenberger-Horne-Zeilinger (GHZ) states and linear cluster states achieve a high degree of Bell violation, which are beyond the nontrivial bounds of the robust self-testing scheme. Furthermore, our work paves the way to the device-independent certification of complex multipartite quantum states.

quant-ph↗

arXiv2021

Formation of copper boride on Cu(111)

Boron forms compounds with nearly all metals, with notable exception of copper and other group IB and IIB elements. Here, we report an unexpected discovery of ordered copper boride grown epitaxially on Cu(111) under ultrahigh vacuum. Scanning tunneling microscopy experiments combined with ab initio evolutionary structure prediction reveal a remarkably complex structure of 2D-Cu8B14. Strong intra-layer p-d hybridization and a large amount of charge transfer between Cu and B atoms are the key factors for the emergence of copper boride. This makes the discovered material unique and opens up the possibility of synthesizing ordered low-dimensional structures in similar immiscible systems.

cond-mat.mtrl-sci↗

arXiv2021

Partially Diffusive Helium-Silica Compound in the Deep Interiors of Giant Planets

Helium is the second most abundant element in the universe, and together with silica, they are major components of giant planets. Exploring the reactivity and state of helium and silica under high pressure is of fundamental importance for developing and understanding of the evolution and internal structure of giant planets. Here, using first-principles calculations and crystal structure predictions, we identify four stable phases of a helium-silica compound with seven/eight-coordinated silicon atoms at pressure range of 600-4000 GPa, corresponding to the interior condition of the outer planets in the solar system. The density of HeSiO2 agrees with current structure models of the planets. This helium-silica compound exhibits a superionic-like helium diffusive state at the high pressure and high temperature conditions along the isentropes of Saturn, a metallic fluid state in Jupiter, and a solid state in the deep interiors of Uranus and Neptune. The reaction of helium and silica may lead to the erosion of the rocky core of giant planets and form a diluted core region. These results highlight the reactivity of helium under high pressure to form new compounds, and also provides evidence to help build more sophisticated interior models of giant planets.

cond-mat.mtrl-sci↗

arXiv2021

Superionic silica-water and silica-hydrogen compounds under high pressure

Silica, water and hydrogen are known to be the major components of celestial bodies, and have significant influence on the formation and evolution of giant planets, such as Uranus and Neptune. Thus, it is of fundamental importance to investigate their states and possible reactions under the planetary conditions. Here, using advanced crystal structure searches and first-principles calculations in the Si-O-H system, we find that a silica-water compound (SiO2)2(H2O) and a silica-hydrogen compound SiO2H2 can exist under high pressures above 450 and 650 GPa, respectively. Further simulations reveal that, at high pressure and high temperature conditions corresponding to the interiors of Uranus and Neptune, these compounds exhibit superionic behavior, in which protons diffuse freely like liquid while the silicon and oxygen framework is fixed as solid. Therefore, these superionic silica-water and silica-hydrogen compounds could be regarded as important components of the deep mantle or core of giants, which also provides an alternative origin for their anomalous magnetic fields. These unexpected physical and chemical properties of the most common natural materials at high pressure offer key clues to understand some abstruse issues including demixing and erosion of the core in giant planets, and shed light on building reliable models for solar giants and exoplanets.

cond-mat.mtrl-sci↗

arXiv2021

Spin-to-Orbital Angular Momentum Conversion via Light Intensity Gradient

Besides a linear momentum, optical fields carry an angular momentum (AM), which have two intrinsic components: one is spin angular momentum (SAM) related to the polarization state of the field, and the other is orbital angular momentum (OAM) caused by the helical phase due to the existence of topological azimuthal charge. The two AM components of the optical field may not be independent of each other, and the Spin-to-Orbital AM conversion (STOC) under focusing will create a spin-dependent optical vortex in the longitudinal filed. Here we demonstrate a new mechanism (or novel way, new way, specific process) for the STOC based on a radial intensity gradient. The radial phase provides an effective way to control the local AM density, which induce counterintuitive orbital motion of isotropic particles in optical tweezers without intrinsic OAM. Our work not only provides fundamental insights into the spin-orbit interaction of light, but also push towards possible applications in optical micro-manipulation.

physics.optics↗

arXiv2020

Polarization interferometric prism: a versatile tool for generation of vector fields, measurement of topological charges and implementation of a spin-orbit Controlled-Not gate

Optical vortex and vector field are two important types of structured optical fields. Due to their wide applications and unique features in many scientific realms, the generation, manipulation and measurement of such fields have attracted significant interest and become very important topics. However, most ways to generate vector fields have a trade-off among flexibility, efficiency, stability, and simplicity. Meanwhile, an easy and direct way to measure the topological charges, especially for high order optical vortex, is still a challenge. Here we design and manufacture a prism: polarization interferometric prism (PIP) as a single-element interferometer, which can conveniently convert an optical vortex to vector fields with high efficiency and be utilized to precisely measure the topological charge (both absolute value and sign) of an arbitrary optical vortex, even with a high order. Experimentally we generate a variety of vector fields with global fidelity ranging from 0.963 to 0.993 and measure the topological charge of an optical vortex by counting the number of petals uniformly distributed over a ring on the output intensity patterns. As a versatile tool to generate, manipulate and detect the spin-orbital state of single photons, PIP can also work in single-photon regime for quantum information processing. In experiment, the PIP is utilized as a spin-orbit Controlled-Not gate on the generated 28 two-qubit states, achieving the state fidelities ranging from 0.966 to 0.995 and demonstrating the feasibility of the PIP for single photons.

physics.optics↗

arXiv2020

Helium Induced Nitrogen Salt at High Pressure

The energy landscape of helium-nitrogen mixtures is explored by ab initio evolutionary searches, which predicted several stable helium-nitrogen compounds in the pressure range from 25 to 100 GPa. In particular, the monoclinic structure of HeN$_{22}$ consists of neutral He atoms, partially ionic dimers N$_{2}$$^{δ-}$, and lantern-like cages N$_{20}$$^{δ+}$. The presence of helium not only greatly enhances structural diversity of nitrogen solids, but also tremendously lowers the formation pressure of nitrogen salt. The unique nitrogen framework of (HeN$_{20}$)$^{δ+}$N$_{2}$$^{δ-}$ may be quenchable to ambient pressure even after removing helium. The estimated energy density of N$_{20}$$^{δ+}$N$_{2}$$^{δ-}$ (10.44 kJ/g) is $\sim$2.4 times larger than that of trinitrotoluene (TNT), indicating a very promising high-energy-density material.

cond-mat.mtrl-sci↗

arXiv2019

Magnetic borophenes from evolutionary search

A computation methodology based on ab initio evolutionary algorithms and the spin-polarized density functional theory was developed to predict two-dimensional (2D) magnetic materials. Its application to a model system borophene reveals an unexpected rich magnetism and polymorphism. A stable borophene with nonzero thickness was an antiferromagnetic (AFM) semiconductor from first-principles calculations, which can be further turned into a half metal by finite electron doping. In this borophene, the buckling and coupling among three atomic layers are not only responsible for the magnetism, but also result in an out-of-plane negative Poissons ratios under uniaxial tension, making it the first elemental material possessing auxetic and magnetic properties simultaneously.

cond-mat.mtrl-sci↗