arXiv subjects

Hyun-Myung Chun

Publications and source records attributed to Hyun-Myung Chun.

At least 19 recordsLinked to original sources

arXiv2026

Nonequilibrium Fluctuation-Response Theory in the Frequency Domain

We establish a unified fluctuation-response theory in the frequency domain for nonequilibrium steady states governed by overdamped Langevin dynamics and Markov jump processes. The central identity is an exact fluctuation-response relation that reconstructs the power spectrum of general observables from local responses measured at the same frequency. This relation applies to state-dependent observables, current-like observables, and their combinations, and reveals how local dynamics shape global fluctuations. From this identity, we derive a hierarchy of relations in the frequency domain, including response uncertainty relations, kinetic and thermodynamic uncertainty relations, the equilibrium fluctuation-dissipation theorem, and Harada-Sasa relations. This establishes an overarching framework for fluctuation-response theory in the frequency domain. Applications to stochastic networks and driven diffusive systems demonstrate how the theory decomposes fluctuation spectra into local contributions and reveals frequency-dependent tradeoffs between fluctuations, response, and dissipation.

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arXiv2026

Fluctuation-Response Theory for Nonequilibrium Langevin Dynamics

We establish a unified fluctuation-response relation for Langevin dynamics. By exploiting the common mathematical structures underlying fluctuations and responses of empirical density and current, we derive a unified identity that generalizes the fluctuation-dissipation theorem from equilibrium to nonequilibrium settings. This relation connects global fluctuations of observables with their local responses to perturbations in force, mobility, and temperature. We further derive finite-time fluctuation-response inequalities, leading to response uncertainty relations that complement the identity by providing more practical bounds. These derivations establish a unified theoretical framework linking the fluctuation-dissipation theorem and thermodynamic uncertainty relations. Using the $F_1$-ATPase molecular motor model, we illustrate how these response-based bounds constrain the long-time diffusion coefficient.

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arXiv2025

Power-efficiency trade-off for finite-time quantum harmonic Otto heat engine via phase-space approach

Thermodynamic constraints impose a trade-off between power and efficiency in heat engines, preventing the simultaneous achievement of high power and high efficiency. For classical microscopic engines, explicit inequalities have been discovered, demonstrating the inherent inevitability of this power-efficiency trade-off. However, extensions of these results to quantum engines have so far been limited to cases of slow operation. In this study, we derive a power-efficiency trade-off relation for a paradigmatic quantum engine operating within a finite time, specifically the Otto cycle of a quantum harmonic oscillator. By utilizing a phase-space approach based on quasi-probability representations, we establish a universal trade-off relation applicable to arbitrary time-dependent protocols during the adiabatic processes. Our results reveal that the power of the quantum engine vanishes as the efficiency approaches the quantum mechanical efficiency bound, which is stricter than the Carnot bound. Furthermore, we identify the conditions under which the upper bound is attained, which indicate maximum power is achieved when the generation of quantum coherence is reduced, and the difference in time durations of the isochoric processes increases. These findings are validated through numerical calculations, which confirm their applicability across various types of protocols for heat engine cycles.

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arXiv2024

Fluctuation-response inequalities for kinetic and entropic perturbations

We derive fluctuation-response inequalities for Markov jump processes that link the fluctuations of general observables to the response to perturbations in the transition rates within a unified framework. These inequalities are derived using the Cramér-Rao bound, enabling broader applicability compared to existing fluctuation-response relations formulated for static responses of current-like observables. The fluctuation-response inequalities are valid for a wider class of observables and are applicable to finite observation times through dynamic responses. Furthermore, we extend these inequalities to open quantum systems governed by the Lindblad quantum master equation and find the quantum fluctuation-response inequality, where dynamical activity plays a central role.

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arXiv2024

Thermodynamic constraints on kinetic perturbations of homogeneous driven diffusions

We analyze the static response to kinetic perturbations of nonequilibrium steady states that can be modeled as diffusions. We demonstrate that kinetic response is purely a nonequilibirum effect, measuring the degree to which the Fluctuation-Dissipation Theorem is violated out of equilibrium. For driven diffusions in a flat landscape, we further demonstrate that such response is constrained by the strength of the nonequilibrium driving via quantitative inequalities.

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arXiv2023

Heterogeneous Mean First-Passage Time Scaling in Fractal Media

The mean first passage time~(MFPT) of random walks is a key quantity characterizing dynamic processes on disordered media. In a random fractal embedded in the Euclidean space, the MFPT is known to obey the power law scaling with the distance between a source and a target site with a universal exponent. We find that the scaling law for the MFPT is not determined solely by the distance between a source and a target but also by their locations. The role of a site in the first passage processes is quantified by the random walk centrality. It turns out that the site of highest random walk centrality, dubbed as a hub, intervenes in first passage processes. We show that the MFPT from a departure site to a target site is determined by a competition between direct paths and indirect paths detouring via the hub. Consequently, the MFPT displays a crossover scaling between a short distance regime, where direct paths are dominant, and a long distance regime, where indirect paths are dominant. The two regimes are characterized by power laws with different scaling exponents. The crossover scaling behavior is confirmed by extensive numerical calculations of the MFPTs on the critical percolation cluster in two dimensional square lattices.

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arXiv2023

Trade-offs between number fluctuations and response in nonequilibrium chemical reaction networks

We study the response of chemical reaction networks driven far from equilibrium to logarithmic perturbations of reaction rates. The response of the mean number of a chemical species is observed to be quantitively limited by number fluctuations as well as the maximum thermodynamic driving force. We prove these trade-offs for linear chemical reaction networks and a class of nonlinear chemical reaction networks with a single chemical species. Numerical results for several model systems support the conclusion that these trade-offs continue to hold for a broad class of chemical reaction networks, though their precise form appears to depend sensitively on the deficiency of the network.

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arXiv2022

Thermodynamic constraints on the nonequilibrium response of one-dimensional diffusions

We analyze the static response to perturbations of nonequilibrium steady states that can be modeled as one-dimensional diffusions on the circle. We demonstrate that an arbitrary perturbation can be broken up into a combination of three specific classes of perturbations that can be fruitfully addressed individually. For each class, we derive a simple formula that quantitatively characterizes the response in terms of the strength of nonequilibrium driving valid arbitrarily far from equilibrium.

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arXiv2021

Nonequilibrium Green-Kubo relations for hydrodynamic transport from an equilibrium-like fluctuation-response equality

Near equilibrium, Green-Kubo relations provide microscopic expressions for macroscopic transport coefficients in terms of equilibrium correlation functions. At their core, they are based on the intimate relationship between response and fluctuations as embodied by the equilibrium fluctuation-dissipation theorem, a connection generically broken far from equilibrium. In this work, we identify a class of perturbations whose response around far-from-equilibrium steady states is linked to steady-state correlation functions via an equilibrium-like fluctuation-response equality. We then utilize this prediction to substantiate linearized hydrodynamic transport equations that describe how spatial inhomogeneities in macroscopic nonequilibrium systems relax. As a consequence, we derive nonequilibrium Green-Kubo relations for the transport coefficients of two types of hydrodynamic variables: local conserved densities and broken-symmetry modes. A byproduct of this work is to provide a theoretical foundation for the validity of Onsager's regression hypothesis around nonequilibrium steady states. Our predictions are analytically and numerically corroborated for two model systems: density diffusion in a fluid of soft, spherical active Brownian particles and phase diffusion in the noisy Kuramoto model on a square lattice.

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arXiv2020

Exactly solvable two-terminal heat engine with asymmetric Onsager coefficients: Origin of the power-efficiency bound

An engine producing a finite power at the ideal (Carnot) efficiency is a dream engine, which is not prohibited by the thermodynamic second law. Some years ago, a two-terminal heat engine with {\em asymmetric} Onsager coefficients in the linear response regime was suggested by Benenti, Saito, and Casati [Phys. Rev. Lett. {\bf 106}, 230602 (2011)], as a prototypical system to make such a dream come true with non-divergent system parameter values. However, such a system has never been realized in spite of many trials. Here, we introduce an exactly solvable two-terminal Brownian heat engine with the asymmetric Onsager coefficients in the presence of a Lorenz (magnetic) force. Nevertheless, we show that the dream engine regime cannot be accessible even with the asymmetric Onsager coefficients, due to an instability keeping the engine from reaching its steady state. This is consistent with recent trade-off relations between the engine power and efficiency, where the (cyclic) steady-state condition is implicitly presumed. We conclude that the inaccessibility to the dream engine originates from the steady-state constraint on the engine.

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arXiv2019

Free diffusion bounds the precision of currents in underdamped dynamics

The putative generalization of the thermodynamic uncertainty relation (TUR) to underdamped dynamics is still an open problem. So far, bounds that have been derived for such a dynamics are not particularly transparent and they do not converge to the known TUR in the overdamped limit. Furthermore, it was found that there are restrictions for a TUR to hold such as the absence of a magnetic field. In this article we first analyze the properties of driven free diffusion in the underdamped regime and show that it inherently violates the overdamped TUR for finite times. Based on numerical evidence, we then conjecture a bound for one-dimensional driven diffusion in a potential which is based on the result for free diffusion. This bound converges to the known overdamped TUR in the corresponding limit. Moreover, the conjectured bound holds for observables that involve higher powers of the velocity as long as the observable is odd under time-reversal. Finally, we address the applicability of this bound to underdamped dynamics in higher dimensions.

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arXiv2019

Quantum mechanical bound for efficiency of quantum Otto heat engine

The second law of thermodynamics constrains that the efficiency of heat engines, classical or quantum, cannot be greater than the universal Carnot efficiency. We discover another bound for the efficiency of a quantum Otto heat engine consisting of a harmonic oscillator. Dynamics of the engine is governed by the Lindblad equation for the density matrix, which is mapped to the Fokker-Planck equation for the quasi-probability distribution. Applying stochastic thermodynamics to the Fokker-Planck equation system, we obtain the $\hbar$-dependent quantum mechanical bound for the efficiency. It turns out that the bound is tighter than the Carnot efficiency. The engine achieves the bound in the low temperature limit where quantum effects dominate. Our work demonstrates that quantum nature could suppress the performance of heat engines in terms of efficiency bound, work and power output.

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arXiv2019

Effect of a magnetic field on the thermodynamic uncertainty relation

The thermodynamic uncertainty relation provides a universal lower bound on the product of entropy production and the fluctuations of any current. While proven for Markov dynamics on a discrete set of states and for overdamped Langevin dynamics, its status for underdamped dynamics is still open. We consider a two-dimensional harmonically confined charged particle in a magnetic field under the action of an external torque. We show analytically that, depending on the sign of the magnetic field, the thermodynamic uncertainty relation does not hold for the currents associated with work and heat. A strong magnetic field can effectively localize the particle with concomitant bounded fluctuations and low dissipation. Numerical results for a three-dimensional variant and for further currents suggest that the existence of such a bound depends crucially on the specific current.

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arXiv2018

Universal Property of the Housekeeping Entropy Production

The entropy production of a nonequilibrium system with broken detailed balance is a random variable whose mean value is nonnegative. Among the total entropy production, the housekeeping entropy production is associated with the heat dissipation in maintaining a nonequilibrium steady state. We derive a Langevin-type stochastic differential equation for the housekeeping entropy production. The equation allows us to define a housekeeping entropic time $τ$. Remarkably, it turns out that the probability distribution of the housekeeping entropy production at a fixed value of $τ$ is given by the Gaussian distribution regardless of system details. The Gaussian distribution is universal for any systems, whether in the steady state or in the transient state, whether they are driven by time-independent or time-dependent driving forces. We demonstrate the universal distribution numerically for model systems.

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arXiv2017

Emergence of Nonwhite Noise in Langevin Dynamics with Magnetic Lorentz Force

We investigate the low mass limit of Langevin dynamics for a charged Brownian particle driven by the magnetic Lorentz force. In the low mass limit, velocity variables relaxing quickly are coarse-grained out to yield effective dynamics for position variables. Without Lorentz force, the low mass limit is equivalent to the high friction limit. Both cases share the same Langevin equation that is obtained by setting the mass to zero in the original Langevin equation. The equivalence breaks down in the presence of the Lorentz force. The low mass limit turns out to be singular. The system in the low mass limit is different from the system with zero mass. The low mass limit is also different from the large friction limit. We derive the effective equations of motion in the low mass limit. The resulting stochastic differential equation involves a nonwhite noise whose correlation matrix has antisymmetric components. We demonstrate the importance of the nonwhite noise by investigating the heat dissipation by the Brownian particle.

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arXiv2017

Microscopic theory for the time irreversibility and the entropy production

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation between the irreversibility and the entropy production starting from the deterministic equations of motion of the whole system consisting of a physical system and a surrounding thermal environment. The physical system is driven by a nonconservative force. The derivation assumes the Markov approximation that the environmental degrees of freedom equilibrate instantaneously. Our approach concerns the irreversibility of the whole system not only the irreversibility of the physical system only. This approach provides a guideline for the choice of the proper reverse process to a given forward process. We demonstrate our idea with an example of a charged particle in the presence of a time-varying magnetic field.

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arXiv2016

Efficiency at maximum power and efficiency fluctuations in a linear Brownian heat engine model

We investigate stochastic thermodynamics of a two-particles Langevin system. Each particle is in contact with a heat bath at different temperatures $T_1$ and $T_2~(<T_1)$, respectively. Particles are trapped by a harmonic potential and driven by a linear external force. The system can act as an autonomous heat engine performing work against the external driving force. Linearity of the system enables us to examine thermodynamic properties of the engine analytically. We find that the efficiency of the engine at maximum power $η_{MP}$ is given by $η_{MP} = 1-\sqrt{T_2/T_1}$. This universal form has been known as a characteristic of endoreversible heat engines. Our result extends the universal behavior of $η_{MP}$ to non-endoreversible engines. We also obtain the large deviation function of the probability distribution for the stochastic efficiency in the overdamped limit. The large deviation function takes the minimum value at mean efficiency $η= \barη$ and increases monotonically until it reaches plateaus when $η\leq η_L$ and $η\geq η_R$ with model dependent parameters $η_{R,L}$. It has been known for heat engines with a finite number of microscopic configurations with time-symmetric protocol that the probability of achieving the Carnot efficiency is minimum. Our result reveals that the least likeliness of the Carnot efficiency is not the generic property of heat engines.

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arXiv2015

Macroscopic Time-Reversal Symmetry Breaking at Nonequilibrium Phase Transition

We study the entropy production in a macroscopic nonequilibrium system that undergoes an order-disorder phase transition. Entropy production is a characteristic feature of nonequilibrium dynamics with broken detailed balance. It is found that the entropy production rate per particle vanishes in the disordered phase and becomes positive in the ordered phase following critical scaling laws. We derive the scaling relations for associated critical exponents. Our study reveals that a nonequilibrium ordered state is sustained at the expense of macroscopic time-reversal symmetry breaking with an extensive entropy production while a disordered state costs only a subextensive entropy production.

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