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I. Luk'yanchuk

Publications and source records attributed to I. Luk'yanchuk.

18 recordsLinked to original sources

Topological polarization networking in uniaxial ferroelectrics

Discovery of topological polarization textures has put ferroelectrics at the frontier of topological matter science. High-symmetry ferroelectric oxide materials allowing for freedom of the polarization vector rotation offer a fertile ground for emergent topological polar formations, like vortices, skyrmions, merons, and Hopfions. It has been commonly accepted that uniaxial ferroelectrics do not belong in the topological universe because strong anisotropy imposes insurmountable energy barriers for topological excitations. Here we show that uniaxial ferroelectrics provide unique opportunity for the formation of topological polarization networks comprising branching intertwined domains with opposite counterflowing polarization. We report that they host the topological state of matter: a crisscrossing structure of topologically protected colliding head-to-head and tail-to-tail polarization domains, which for decades has been considered impossible from the electrostatic viewpoint. The domain wall interfacing the counterflowing domains is a multiconnected surface, propagating through the whole volume of the ferroelectric.

cond-mat.mtrl-sci↗

The ferroelectric field-effect transistor with negative capacitance

Integrating ferroelectric negative capacitance (NC) into the field-effect transistor (FET) promises to break fundamental limits of power dissipation known as Boltzmann tyranny. However, realizing the stable static negative capacitance in the non-transient non-hysteretic regime remains a daunting task. The problem stems from the lack of understanding of how the fundamental origin of the NC due to the emergence of the domain state can be put in use for implementing the NC FET. Here we put forth an ingenious design for the ferroelectric domain-based field-effect transistor with the stable reversible static negative capacitance. Using dielectric coating of the ferroelectric capacitor enables the tunability of the negative capacitance improving tremendously the performance of the field-effect transistors.

cond-mat.mes-hall↗

Tip-induced domain protrusion in ferroelectric films with in-plane polarization

Charge manipulation and fabrication of stable domain patterns in ferroelectric materials by scanning probe microscopy open up broad avenues for the development of tunable electronics. Harnessing the polarization energy and electrostatic forces with specific geometry of the system enables producing the nanoscale domains by-design. Along with that, domain engineering requires mastery of underlying physical mechanisms that govern the domain formation. Here, we present a theoretical description of the domain formation by a scanning probe microscopy tip in a ferroelectric film with strong in-plane anisotropy of polarization. We demonstrate that local charge injection produces wedge-shaped domains that propagate along the anisotropy axis, whereas the tip-written lines of charge generate a comb-like domain structure. The results of our calculations agree with earlier experimental observations and allow for the optimization of the targeted domain structures.

cond-mat.mtrl-sci↗

Controllable skyrmion chirality in ferroelectrics

Chirality, an intrinsic handedness, is one of the most intriguing fundamental phenomena in nature. Materials composed of chiral molecules find broad applications in areas ranging from nonlinear optics and spintronics to biology and pharmaceuticals. However, chirality is usually an invariable inherent property of a given material that cannot be easily changed at will. Here, we demonstrate that ferroelectric nanodots support skyrmions the chirality of which can be controlled and switched. We devise protocols for realizing control and efficient manipulations of the different types of skyrmions. Our findings open the route for controlled chirality with potential applications in ferroelectric-based information technologies.

cond-mat.mes-hall↗

Built-in electric field induces polarization rotation in bilayer BiFeO3/(Ba,Sr)TiO3 thin films

The crystal structure of BiFeO3/BaxSr1-xTiO3 (BFO/BST) heterostructures with x = 0.2, 0.6 and 0.8, grown on single-crystal MgO (001) substrate was investigated by x-ray diffraction and Raman spectroscopy in order to determine the influence of mismatch-induced strains and spontaneous polarization in BST buffer layers on BFO layers. The lattice parameter of the BFO layers was shown to decrease with increasing concentration of Ba ions, despite the increasing in-plain lattice parameters of tetragonal unit cells of BST layers. The rhombohedral angle of the crystal structure of BFO layers demonstrates an increase towards the ideal cubic perovskite structure with the appearance of the built-in electric field, induced by the spontaneous polarization in buffer layers. This result provides a remarkable tool for the control of polarization in BFO layers and other ferroelectric films in general, by changing the built-in electric field from ferroelectric buffer layer without changing a single crystal substrate.

cond-mat.mtrl-sci↗

Hopfions emerge in ferroelectrics

Paradigmatic knotted solitons, Hopfions, that are characterized by topological Hopf invariant, are widely investigated in the diverse areas ranging from high energy physics, cosmology and astrophysics to biology, magneto- and hydrodynamics and condensed matter physics. Yet, while holding high promise for applications, they remain elusive and under-explored. Here we demonstrate that Hopfions emerge as a basic configuration of polarization field in confined ferroelectric nanoparticles. Our findings establish that Hopfions govern a wealth of novel functionalities in the electromagnetic response of composite nanomaterials opening route to unprecedented technological applications.

cond-mat.mes-hall↗

Harnessing ferroelectric domains for negative capacitance

The pressing quest for overcoming Boltzmann tyranny in low-power nanoscale electronics revived the thoughts of engineers of early 1930-s on the possibility of negative circuit constants. The concept of the ferroelectric-based negative capacitance (NC) devices triggered explosive activity in the field. However, most of the research addressed transient NC, leaving the basic question of the existence of the steady-state NC unresolved. Here we demonstrate that the ferroelectric nanodot capacitor hosts a stable two-domain state realizing the static reversible NC device thus opening routes for the extensive use of the NC in domain wall-based nanoelectronics.

cond-mat.mes-hall↗

Electrodynamics of ferroelectric films with negative capacitance

We construct a comprehensive theory of the electrodynamic response of ferroelectric ultra-thin films containing periodic domain textures (PDT) with 180° polarization-oriented domains. The focal point of the theory is the negative-capacitance phenomenon which naturally arises from the depolarization field induced by PDT. We derive frequency-dependent dielectric permittivity related to the PDT dynamics across the entire frequency range. We find the resonance mode of domain oscillations in the THz spectral band and the singular points in the phase of the reflected THz beam that are intimately related to the negative capacitance. Our findings provide a platform for the THz negative capacitance-based optics of ferroelectric films and for engineering the epsilon-near-zero plasmonic THz metamaterials.

cond-mat.mes-hall↗

Dirac Fermions in Graphite: the State of Art

Macroscopic concentration of massless charge carriers with linear conic spectrum - Dirac Fermions (DF) - was shown in 2004 to exist in highly oriented pyrolytic graphite (HOPG) and governs its electronic properties. These carriers can have the same nature as DF observed in graphite monolayer(graphene) and let to view HOPG as superposition of 2D carbon layers, almost independent electronically. We overview here the recent experimental evidences of 2D DF in graphite and their similarity with carriers in graphene.

cond-mat.mes-hall↗

Stability of Vortex Phases in Ferroelectric Easy-Plane nano-Cylinders

Bounded charges induced by the polarization gradient in finite-size ferroelectrics are known to produce the unfavorable depolarization electric field that suppresses the uniform ferroelectric state. To reduce the depolarization energy the non-uniform vortex (toroidal) state is formed inside ferroelectric nano-particles, nano-disks, and nano-rods. Based on self-consistent solution of Ginzburg-Landau equations coupled with electrostatic equations, we study the multivortex toroidal states appearing in the nanometric easy-plane ferroelectric cylinder. The geometrical textures, critical temperatures and stability regions for these states are calculated.

cond-mat.mtrl-sci↗

Sound modes in composite incommensurate crystals

We propose a simple phenomenological model describing composite crystals, constructed from two parallel sets of periodic inter-penetrating chains. In the harmonic approximation and neglecting thermal fluctuations we find the eigenmodes of the system. It is shown that at high frequencies there are two longitudinal sound modes with standard attenuation, while in the low frequency region there is one propagating sound mode and an over-damped phase mode. The crossover between these two regions is analyzed numerically and the dynamical structure factor is calculated. It is shown that the qualitative features of the experimentally observed spectra can be consistently described by our model.

cond-mat.mtrl-sci↗

Interaction of vortices in superconductors with kappa close to 2^(-1/2)

Using a perturbative approach to the infinitely degenerate Bogomolnyi vortex state for a superconductor with kappa = 2^(-1/2), T -> T_c, we calculate the interaction of vortices in a superconductor with kappa close to 2^(-1/2). We find, numerically and analytically, that depending on the material the interaction potential between the vortices varies with decreasing kappa from purely repulsive (as in a type-II superconductor) to purely attractive (as in a type-I superconductor) in two different ways: either vortices form a bound state and the distance between them changes gradually from infinity to zero, or this transition occurs in a discontinuous way as a result of a competition between minima at infinity and zero. We study the discontinuous transition between the vortex and Meissner states caused by the non-monotonous vortex interaction and calculate the corresponding magnetization jump.

cond-mat.supr-con↗

Theory of superconductor with kappa close to 1/sqrt{2}

As was firstly shown by E. Bogomolny, the critical Ginzburg-Landay (GL) parameter kappa =1/sqrt{2} at which a superconductor changes its behavior from type-I to type-II, is the special highly degenerate point where Abrikosov vortices do not interact and therefore all vortex states have the same energy. Developing a secular perturbation theory we studied how this degeneracy is lifted when kappa is slightly different from 1\sqrt{2} or when the GL theory is extended to the higher in T-Tc terms. We constructed a simple secular functional, that depends only on few experimentally measurable phenomenological parameters and therefore is quite efficient to study the vortex state of superconductor in this transitional region of kappa. Basing on this, we calculated such vortex state properties as: critical fields, energy of the normal-superconductor interface, energy of the vortex lattice, vortex interaction energy etc. and compared them with previous results that were based on bulky solutions of GL equations.

cond-mat.supr-con↗

Comment on ''Minimal Surfaces, Screw Dislocations, and Twist Grain Boundaries''

In a recent letter, (Phys. Rev. Lett. 82, 2892(1999); cond-mat/9808306) Kamien and Lubensky calculated the energy of the surface constructed via a linear superposition of screw dislocations in SmA phase, and obtained the positive (repulsive) sign of the long-range interaction between dislocations. We would like to object that this interaction is attractive. This conclusion can be important to explain the discontinuity of the TGB - SmA phase transition in chiral liquid crystals.

cond-mat.soft↗

Thermodynamics of the incommensurate state in Rb_2WO_4: on the Lifshitz point in A`A``BX_4 compounds

We consider the evolution of the phase transition from the parent hexagonal phase $P6_{3}/mmc$ to the orthorhombic phase $Pmcn$ that occurs in several compounds of $A'A''BX_{4}$ family as a function of the hcp lattice parameter $c/a$. For compounds of $K_{2}SO_{4}$ type with $c/a$ larger than the threshold value 1.26 the direct first-order transition $Pmcn-P6_{3}/mmc$ is characterized by the large entropy jump $Rln2$. For compounds $Rb_{2}WO_{4}$, $K_{2}MoO_{4}$, $K_{2}WO_{4}$ with $c/a<1.26$ this transition occurs via an intermediate incommensurate $(Inc)$ phase. DSC measurements were performed in $Rb_{2}WO_{4}$ to characterize the thermodynamics of the $Pmcn-Inc-P6_{3}/mmc$ transitions. It was found that both transitions are again of the first order with entropy jumps $0.2Rln2 and $0.3Rln2$. Therefore, at $c/a ~ 1.26$ the $A'A''BX_{4}$ compounds reveal an unusual Lifshitz point where three first order transition lines meet. We propose the coupling of crystal elasticity with $BX_{4}$ tetrahedra orientation as a possible source of the transitions discontinuity.

cond-mat.soft↗

Basal-plane Incommensurate Phases in HCP Structures

An Ising model with competing interaction is used to study the appearance of incommensurate phases in the basal plane of an hexagonal closed-packed structure. The calculated mean-field phase diagram reveals various 1q-incommensurate and lock-in phases. The results are applied to explain the basal-plane incommensurate phase in some compounds of the A'A"BX_4 family, like K_2MoO_4, K_2WO_4, Rb_2WO4 and to describe the sequence of high-temperature phase transitions in other compounds of this family.

cond-mat.stat-mech↗

New Incommensurate Elongated-Triangle Phase in Quartz

We present for the first time the evidence for a thermodynamically stable incommensurate elongated-triangle ($ELT$) phase in quartz observed by transmission electron microscopy at structural $α-β$ transition. The phase sequence on cooling is: uniform $β$ phase - stripe incommensurate phase (ferroelastic) - incommensurate equilateral-triangle ($EQT$) phase (ferroelectric) - incommensurate $ELT$ (ferroelectric and ferroelastic) - uniform $α$ phase. The $ELT$ blocks could be responsible for the large light scattering in the vicinity of $α-β$ transition.

cond-mat↗

High Resolution 13C NMR study of oxygen intercalation in C60

Solid state high resolution $^{13}C$ NMR has been used to investigate the physical properties of pristine $C_{60}$ after intercalation with molecular oxygen. By studying the dipolar and hyperfine interactions between Curie type paramagnetic oxygen molecules and $^{13}C$ nuclei we have shown that neither chemical bonding nor charge transfer results from the intercalation. The $O_2$ molecules diffuse inside the solid $C_{60}$ and occupy the octahedral sites of the fcc crystal lattice. The presence of oxygen does not affect the fast thermal reorientation of the nearest $C_{60}$ molecules. Using Magic Angle Spinning we were able to separate the dipolar and hyperfine contributions to $^{13}C$ NMR spectra, corresponding to buckyballs adjacent to various numbers of oxygen molecules.

cond-mat↗