Improved Photocatalytic Performance via Air-Plasma Modification of Titanium Dioxide: Insights from Experimental and Simulation Investigation
Commercial titanium dioxide is successfully plasma-treated under ambient conditions for different time periods, leading to reduced crystallite size and the creation of oxygen vacancies. Density functional theory-based calculations reveal the emergence of additional localized states close to the conduction band, primarily associated with under-coordinated titanium atoms in non-stoichiometric titanium-oxide systems. The plasma-treated samples exhibit improved photocatalytic performance in the degradation of methylene blue compared to untreated samples. Moreover, the 4-hour plasma-treated photocatalyst demonstrates commendable stability and reusability. This work highlights the potential of cost-effective plasma treatment as a simple modification technique to significantly enhance the photocatalytic capabilities of titanium dioxide.