arXiv subjects

I. Sinha

Publications and source records attributed to I. Sinha.

2 recordsLinked to original sources

arXiv2012

First order phase transition in a modified Ziff-Gulari-Barshad model with self-oscillating reactant coverages

Using kinetic Monte Carlo simulations, we study the effect of oscillatory kinetics due to surface reconstructions on Ziff-Gulari-Barshad (ZGB) model discontinuous phase transition. To investigate the transition, we do extensive finite size scaling analysis. It is found that the discontinuous transition still exists. On inclusion of desorption in the model, the order-parameter probability distribution broadens but remains bimodal. That is, the first-order phase transition becomes weaker with increase in desorption rate.

cond-mat.stat-mech↗

arXiv2010

Avrami exponent under transient and heterogeneous nucleation transformation conditions

The Kolmogorov-Johnson-Mehl-Avrami model for isothermal transformation kinetics is universal under specific assumptions. However, the experimental Avrami exponent deviates from the universal value. In this context, we study the effect of transient heterogeneous nucleation on the Avrami exponent for bulk materials and also for transformations leading to nanostructured materials. All transformations are assumed to be polymorphic. A discrete version of the KJMA model is modified for this purpose. Scaling relations for transformations under different conditions are reported.

cond-mat.mtrl-sci↗