I. Webman | Searcharxiv

arXiv2005

Theory of De-Pinning of Monolayer Films Adsorbed on a Quartz Crystal Microbalance

In quartz crystal microbalance (QCM) studies of the friction between an adsorbed monolayer film and a metallic substrate, the films are observed to slide relative to the substrate under inertial forces of order $10^{-14}dyn$ per film atom, a force much smaller than all theoretical estimates of the force that surface defects are capable of exerting. In this letter we propose, in order to resolve this issue, that if the defect potentials have a range of greater than an atomic spacing, the net force on a relatively stiff film due to the defects is likely to be extremely small. Line defects (e.g., step and facet edges and grain boundaries) as well as more localized defects (e.g., vacancies) are considered.

cond-mat.mtrl-sci↗

arXiv2004

Lack of Pinning for Rigid Sliding Monolayers in Microbalance Experiments

Recent work on the dynamics of monolayers on a metallic substrate attached to a quartz oscillator has provided interesting data on kinetic friction at the microscopic level. Sliding of the film relative to the substrate is often observed even in situations in which theory seems to predict that the film should be pinned by substrate imperfections. In this letter we propose, in order to attempt to resolve this issue, that if the defect potentials have a range of a little more than an atomic spacing, the net forces on the film due to the defects are likely to be quite small due to cancellations.

cond-mat.mtrl-sci↗