arXiv subjects

Ian U. Roederer

Publications and source records attributed to Ian U. Roederer.

At least 19 recordsLinked to original sources

arXiv2026

The future of high-resolution UV spectroscopy: Science with a UV Échelle spectrograph on the Habitable Worlds Observatory, or a dedicated mission

High-resolution UV spectroscopy serves a diversity of science cases, from small bodies to planets, stars, and galaxies, but is currently limited to the Hubble Space Telescope and bright targets. Major advances require increasing sensitivity by at least one order of magnitude. Here we present the UV science cases for PEGASUS (Planets, Earths, Galaxies, And Stars UV Spectrograph), a UV Échelle high-resolution spectrograph concept, with $R = λ/δλ\sim 100\,000$ (full range 10 000-140 000) and covering 90--400 nm, with a foreseen extension to at least 800 nm. PEGASUS is ideally suited for the Habitable Worlds Observatory (HWO), enabling transformative science across the UV/optical wavelength ranges. PEGASUS will be unique in high sensitivity (effective area) and high spectral resolution -- an uncharted territory -- as well as robustness, thanks to the simplicity of its design. Its UV science cases include: I) Formation and evolution of planets and their habitability: properties of exoplanets and atmospheres, protoplanetary disks, Solar System bodies; II) Stellar lives and deaths at their extremes: the first stars and the origin of the elements, compact and massive stars, Supernovae; III) Gas and metals in the baryon cycle of galaxies: the interstellar, circumgalactic, and intergalactic medium and their roles in galaxy growth. These are essential for the Astro Decadal 2020 Survey, Voyage 2050, and HWO. While this paper focuses on high-impact science enabled by UV high-resolution spectroscopy, PEGASUS will extend into the optical regime and lower spectral resolution, making it a multi-purpose, widely used, workhorse spectrograph for HWO.

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arXiv2026

Early Exploration of the Scientific Discovery Space for the Habitable Worlds Observatory

The Habitable Worlds Observatory (HWO) is a future NASA flagship mission concept identified by the Astro2020 Decadal Survey as the highest priority for large space missions. HWO should conduct "transformative astrophysics" and search for biosignatures in the atmospheres of approximately 25 potentially Earth-like planets. To further the early-stage development of HWO, NASA formed the Science, Technology, Architecture Review Team (START). In turn, START invited the scientific community to join working groups to explore the potential discovery space. In this paper, we present 70 science cases that resulted from this process. The cases address four scientific pillars: growth of galaxies (15 cases), evolution of the elements (13 cases), solar systems in context (32 cases), and living worlds (10 cases). Combined, they would address 27 of the 30 science questions and discovery areas identified by Astro2020. The 140 observing programs needed for the 70 investigations encompass a rich variety of spectroscopic (for 87% of science cases) and photometric (for 30%) observations extending from the UV to the NIR. Additionally, high-contrast and polarimetric capabilities would be needed for 34% and 27% of science cases, respectively. Access to UV wavelengths is critical: 83% of science cases need data at wavelengths <400 nm, and 26% extend to <100 nm. In the NIR, 26% of science cases need observations at wavelengths >=2000 nm. Pursuing the full portfolio of science would also necessitate precise astrometry for planet mass measurement, rapid response capabilities, a large instantaneous field of regard, non-sidereal tracking, saturation mitigation strategies, and high dynamic range.

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arXiv2026

The \emph{R}-process Alliance: A Bright, Strongly \emph{R}-process-enhanced Extremely Metal-poor Star Observed with GHOST

We present a detailed chemical-abundance and kinematic analysis of four extremely metal-poor (EMP; [Fe/H] $\leq -3.0$) stars identified from \textit{Gaia} BP/RP data in our ongoing search for the most primitive stars. This includes a primary target, \textit{Gaia}~DR3~2563539603865382656 (hereafter G256353), a strongly $r$-process-enhanced star with [Eu/Fe]~$= +1.20$ and [Ba/Eu]~$= -0.64$. Our results are based on high-resolution, high-signal-to-noise GHOST spectra from Gemini-South. For the full sample, we statistically match the light-element abundances with those predicted from Population\,III supernova models. The ``best-fit'' model suggests massive progenitors with stellar masses of M$_{\star}\sim$ 20-30\,M$_\odot$. In addition, we determine orbital histories for all of the stars. We find that Gaia~DR3~2887334237669844480 appears to be kinematically associated with Atari, an accreted structure in the Galactic disk. This star has low abundance ratios of strontium ([Sr/Fe] = $-$1.09) and barium ([Ba/Fe] = $-$0.37), which supports an accretion origin. For G256353, we determine chemical abundances for 15 neutron-capture elements. We compare the observed heavy-element pattern for G256353 with that of the Sun, HD~222925, and two neutron star merger models. The $r$-process elements in G256353 align reasonably well with HD~222925, the scaled-Solar pattern (except for the first peak), and a recent predicted pattern associated with neutron star mergers. This consistency reinforces the universality of the main $r$-process across diverse astrophysical environments.

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arXiv2026

The $R$-Process Alliance: The $R$-Process Enhancement of Stars from Chemodynamically Tagged Groups in the Milky Way Halo

As part of the ongoing work of the $R$-Process Alliance (RPA), detailed abundance measurements of 29 heavy elements in three metal-poor stars, 2MASS J14592981$-$3852558, 2MASS J19445483$-$4039459, and 2MASS J15211026$-$0607566, are presented based on an analysis of high-resolution ($R\sim 80,000$), high signal-to-noise ``portrait'' spectra from the Magellan Inamori Kyocera Echelle (MIKE) spectrograph on the Magellan-Clay Telescope at Las Campanas Observatory. The selected targets were identified as $r$-process-enhanced metal-poor stars in previous RPA snapshot analyses. They have also been linked to possible chemodynamically tagged groups, indicating that the stars may have formed in dwarf galaxies that were later accreted into the Milky Way halo. These stars have also been tentatively linked to the Thamnos structure. The detailed chemical abundances in this work confirm that 2MASS J14592981$-$3852558 and J15211026$-$0607566 are $r$-II stars, while 2MASS J19445483$-$4039459 is found to lie just below the threshold for $r$-I status. The $r$-II stars show signs of slight enhancement in fission fragments compared to 2MASS J19445483$-$4039459. Based on radioactive age dating with Th, the $r$-process material in the two $r$-II stars is found to be old (with ages $>10$ Gyr); neither star shows signs of an actinide boost. The varying elemental compositions suggest that these stars likely did not originate in the same environment, though each could be consistent with originating in the Thamnos progenitor.

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arXiv2026

The $R$-Process Alliance: Actinide Abundances, Variation, and Evolution in Metal-Poor Stars

The actinides, including thorium (Th), are the heaviest observable elements synthesized in the universe, holding clues to the extremes of the astrophysical and nuclear conditions of $r$-process sites. We present Th abundances based on high-resolution spectroscopy for 47 metal-poor stars, the largest homogeneously analyzed sample to date. The chemical evolution of Th exhibits a decrease in dispersion in [Th/H] and [Th/Fe] from $\sim$0.6 dex at the lowest metallicities to $\sim$0.2 dex at higher metallicities. We also find that Th and the lanthanides Eu and Dy are co-produced remarkably well, with average [Th/Eu]$\sim0.0$ across $-3.0 \lesssim$ [Fe/H] $\lesssim -1.5$, as well as across stars with $0.0\lesssim$ [Eu/Fe] $\lesssim2.5$. Even so, the absolute range of $\logε$(Th/Eu) is 1.02 dex, with an observed standard deviation of $\pm0.20$ dex and an intrinsic standard deviation of $\pm0.11$ dex at the lowest metallicities. We infer that $68\%$ of $r$-process events have $\logε$(Th/Eu) yields that only vary within a factor of $\pm1.3$ or $\pm30\%$, while $5\%$ of $r$-process events have $\logε$(Th/Eu) yields that vary by factors $>3.3$ approaching $\sim$10. This serves as a strong constraint for the nuclear and astrophysical models of $r$-process sites, and suggests that achieving an $r$-process site that is both prompt and produces a robust $\logε$(Th/Eu) ratio is a challenge for current models.

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arXiv2026

Proton-rich production of lanthanides: the $νi$ process

The astrophysical origin of the lanthanides is an open question in nuclear astrophysics. Besides the widely studied $s$, $i$, and $r$ processes in moderately-to-strongly neutron-rich environments, an intriguing alternative site for lanthanide production could in fact be robustly $\textit{proton-rich}$ matter outflows from core-collapse supernovae under specific conditions -- in particular, high-entropy winds with enhanced neutrino luminosity and fast dynamical timescales. In this environment, excess protons present after charged particle reactions have ceased can continue to be converted to neutrons by (anti-)neutrino interactions, producing a neutron capture reaction flow up to A~200. This scenario, christened the $νi$ process in a recent paper, has previously been discussed as a possibility. Here, we examine the prospects for $νi$ process through the lens of stellar abundance patterns, bolometric lightcurves, and galactic chemical evolution models, with a particular focus on hypernovae as candidate sites. We identify specific lanthanide signatures for which the $νi$ process can provide a credible alternative to $r$/$i$ processes.

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arXiv2025

The R-Process Alliance: Exploring the cosmic scatter among ten r-process sites with stellar abundances

The astrophysical origin of the rapid neutron-capture process (r-process), which produces about half of the elements heavier than iron, remains uncertain. The oldest, most metal-poor stars preserve the chemical signatures of early nucleosynthesis events and can reveal the nature of the r-process sites. We present a homogeneous chemical abundance analysis of ten r-process-enhanced, metal-poor stars that show strong enrichment in r-process elements with minimal contamination from other nucleosynthetic sources. Using high-resolution, high signal-to-noise spectra, we examined over 1400 absorption lines per star through equivalent width measurements and spectral synthesis under one-dimensional LTE assumptions with the MOOG radiative transfer code. Abundances for 54 chemical species were derived, including 29 neutron-capture elements spanning the full r-process pattern. We quantified the cosmic scatter of elemental ratios relative to Zr (light) and Eu (heavy) and found remarkably small dispersions for the rare-earth and third-peak elements, σ[La/Eu] = 0.08 dex and σ[Os/Eu] = 0.11 dex, while the light-to-heavy ratio shows slightly larger variation, σ[Zr/Eu] = 0.18 dex. A kinematic study indicates that the stars likely originated from ten distinct progenitor systems, allowing us to probe the intrinsic variation between independent r-process events. These results imply that the main r-process operates under highly uniform conditions across diverse astrophysical sites.

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arXiv2025

Rare Find: Discovery and chemo-dynamical properties of two s-process enhanced RR Lyrae stars

We report the serendipitous discovery of two RR Lyrae stars exhibiting significant s-process element enrichment, a rare class previously represented solely by TY Gruis. Our goal is to characterise these objects chemically and dynamically, exploring their origins and evolutionary histories. Using high-resolution spectroscopy from HERMES@AAT and UVES@VLT, we derived detailed chemical abundances of key s-process elements, carbon along with $α$-elements. We also employed Gaia DR3 astrometric data to analyse their kinematics, orbital properties, and classify their Galactic population membership. We compared observational results with theoretical asymptotic giant branch nucleosynthesis models to interpret their enrichment patterns. Both stars exhibit clear signatures of s-process enrichment, with significant overabundances in second-peak elements such as Ba and La compared to first-peak Y and Zr. Comparison with AGB nucleosynthesis models suggests their progenitors experienced pollution of s-process-rich material, consistent with early binary interactions. However, notable discrepancies in dilution factors highlight the need for more refined low-metallicity asymptotic giant branch (AGB) models. We also explore and discuss alternative scenarios, including sub-luminous post-AGB-like evolution or double episodes of mass transfer. Our findings confirm the existence of s-process-enhanced RR Lyrae stars and demonstrate the importance of combining chemical and dynamical diagnostics to unveil their complex evolutionary pathways. Future detailed binary evolution modelling and long-term orbital monitoring are essential to resolve their formation scenarios and assess the role of binarity in the evolution of pulsating variables.

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arXiv2025

Abundances of Rarely Detected s-process Elements Derived from the Ultraviolet Spectrum of the s-process-enhanced Metal-poor Star HD 196944

We present an analysis of the heavy-element abundances of HD 196944, a carbon-enhanced metal-poor (CEMP) star enriched with elements produced by the slow neutron-capture process (s-process). We obtained a new high-resolution ultraviolet (UV) spectrum of this star, the UV-brightest known CEMP-s star, with the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope. This spectrum extends deeper into the UV (2029 < lambda < 2303 Angstroms) than previous studies of any CEMP-s star. When combined with previous UV and optical analysis, a total of 35 elements heavier than zinc (Z = 30) can be detected in HD 196944, and upper limits are available for nine other heavy elements. The abundances can be well fit by models of s-process nucleosynthesis operating in a low-mass companion star that evolved through the asymptotic giant branch phase and transferred heavy elements to HD 196944. This s-process event did not contribute substantially to the Ga, Ge, or As abundances (31 <= Z <= 33). Our results demonstrate that UV spectroscopy can greatly expand the inventory of heavy elements detectable in CEMP-s stars.

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arXiv2025

Habitable Worlds Observatory: The Nature of the Astrophysical r-process

We present the science case for characterizing the origin of the heaviest elements on the periodic table, with a focus on those produced by the rapid neutron-capture process (r-process), using the Habitable Worlds Observatory (HWO). High-resolution ultraviolet (UV) spectroscopy can increase the number of r-process elements detectable in cool stars by more than 50% relative to optical and infrared spectra. These elements are key to characterizing the physical conditions that govern the r-process and identify the nature, sites, and environments where r-process events occurred. HWO has the potential to greatly expand the sample of stars where rarely studied heavy elements can be detected beyond the Solar neighborhood to the Galactic halo, globular clusters, and dwarf galaxies.

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arXiv2025

Habitable Worlds Observatory: The Nature of the First Stars

We present the science case for characterizing the nature of the first stars using the Habitable Worlds Observatory (HWO). High-resolution ultraviolet (UV) spectroscopy with the HWO has the potential to confirm any surviving low-mass zero-metallicity first stars by placing unprecedented low limits on their metal abundances. It also has the potential to substantially increase the number of elements detectable in the spectra of known long-lived low-mass stars, which exhibit extremely low metal abundances that reveal the metals produced by the first stars. Elements important for this science case with UV transitions include C, Mg, Al, Si, P, S, Sc, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn. HWO would expand the discovery space when compared with the Hubble Space Telescope by enabling high-resolution UV spectroscopy for much fainter stars throughout the Milky Way and neighboring stellar systems.

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arXiv2025

The $R$-Process Alliance: Enrichment of $r$-process Elements in a Simulated Milky Way-like Galaxy

We study the formation of stars with varying amounts of heavy elements synthesized by the rapid neutron-capture process ($r$-process) based on our detailed cosmological zoom-in simulation of a Milky Way-like galaxy with an $N$-body/smoothed particle hydrodynamics code, ASURA. Most stars with no overabundance in $r$-process elements, as well as the strongly $r$-process enhanced $r$-II stars ([Eu/Fe] $>+0.7$), are formed in dwarf galaxies accreted by the Milky Way within the 6 Gyr after the Big Bang. In contrast, over half of the moderately enhanced $r$-I stars ($+0.3 <$ [Eu/Fe] $\leq +0.7$) are formed in the main in-situ disk after 6 Gyr. Our results suggest that the fraction of $r$-I and $r$-II stars formed in disrupted dwarf galaxies is larger the higher their [Eu/Fe] is. Accordingly, the most strongly enhanced $r$-III stars ([Eu/Fe] $> +2.0$) are formed in accreted components. These results suggest that non-$r$-process-enhanced stars and $r$-II stars are mainly formed in low-mass dwarf galaxies that hosted either none or a single neutron star merger, while the $r$-I stars tend to form in the well-mixed in-situ disk. We compare our findings with high-resolution spectroscopic observations of $r$-process-enhanced metal-poor stars in the halo and dwarf galaxies, including those collected by the R-Process Alliance. We conclude that observed [Eu/Fe] and [Eu/Mg] ratios can be employed in chemical tagging of the Milky Way's accretion history.

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arXiv2025

Gamma rays as a signature of r-process producing supernovae: remnants and future Galactic explosions

We consider the question of whether core-collapse supernovae (CCSNe) can produce rapid neutron capture process (r-process) elements and how future MeV gamma-ray observations could address this. Rare types of CCSNe characterized by substantial magnetic fields and rotation, known as magnetorotational supernovae (MR-SNe), are theoretically predicted to produce these elements, although direct observational evidence is lacking. We suggest that this critical question be addressed through the study of some of the eleven CCSN remnants located within 10 kpc, as well as through the detection of gamma-ray emission from a future Galactic supernova. We use a two-dimensional MR-SN model to estimate the expected gamma flux stemming from nuclear decays in the range of a few tens of keV to a few MeV. Our results indicate that an observation of Sn-126 (Sb-126) in a remnant stands out as a signature of an r-process-producing supernova. Since the neutron-rich conditions that lead to the production of the r-process could also enhance the production of Fe-60, the detection of substantial Fe-60 (Co-60) would be indicative of favorable conditions for the r-process. In the case of a future supernova explosion, when the evolution of the spectrum is studied over ten days to a few years, a rich picture emerges. At various epochs, second peak r-process isotopes such as Sb-125, I-131, Te-132, I-132 and La-140 produce gamma-ray signals that emerge above the background from explosive burning products and electron-positron annihilation. The weak r-process isotopes Nb-95, Ru-103, Rh-106 also have periods of prominence. While MR-SNe are predicted to have a relatively small main r-process contribution, third peak isotopes like Ir-194 could still be above next-generation MeV gamma instrument sensitivities.

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arXiv2025

Probing Abundance Variations among Multiple Stellar Populations in the Metal-Poor Globular Cluster NGC 2298 using Gemini-South/GHOST

Studying the abundances in metal-poor globular clusters is crucial for understanding the formation of the Galaxy and the nucleosynthesis processes in the early Universe. We observed 13 red giant stars from the metal-poor globular cluster NGC 2298 using the newly commissioned GHOST spectrograph at Gemini South. We derived stellar parameters and abundances for 36 species across 32 elements, including 16 neutron-capture elements. We find that the stars exhibit chemical anomalies among the light elements, allowing us to classify them into first-generation (8 stars) and second-generation (5 stars). We derive a mean cluster metallicity of [Fe/H]=-1.98 +/- 0.10 with no significant variation among cluster members. Most alpha- and Fe-peak elements display low star-to-star abundance dispersion, with notable exceptions for Sc, Ni, and Zn for which the dispersions in Sc vary significantly between stars from different generations to 2σlevels. Similarly, among the neutron-capture elements, we observed considerable differences in dispersion for Sr and Eu among the first and second generation stars to 2 sigma levels. We also confirm an intrinsic scatter beyond observational uncertainties for several elements using a maximum likelihood approach among stars from different generations. Additionally, we note an increase in [Sr/Eu] and [Ba/Eu] with [Mg/Fe] in first-generation stars indicating correlations between the productions of light r-process and Mg. We find the universal r-process pattern, but with larger dispersions in the main r-process than the limited-r elements. These differences in abundance dispersion, among first- and second-generation stars in NGC 2298, suggest complex and inhomogeneous early chemical enrichment processes, driven by contributions from multiple nucleosynthetic events, including massive stars and rare r-process events.

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arXiv2025

The R-Process Alliance: Hunting for gold in the near-UV spectrum of 2MASS J05383296-5904280

Context. Over the past few years, the $R$-Process Alliance (RPA) has successfully carried out a search for stars that are highly enhanced in elements produced via the rapid neutron-capture ($r$-) process. In particular, the RPA has identified a number of relatively bright, highly $r$-process-enhanced ($r$-II) stars, suitable for observations with the Hubble Space Telescope (HST), facilitating abundance derivation of elements such as gold (Au) and cadmium (Cd). Aims. This paper presents the detailed abundances derived for the metal-poor ([Fe/H] = -2.55) highly $r$-process-enhanced ([Eu/Fe] = +1.29) $r$-II star 2MASS J05383296-5904280. Methods. 1D LTE elemental abundances are derived via equivalent width and spectral synthesis using high-resolution high signal-to-noise near-UV HST/STIS and optical Magellan/MIKE spectra. Results. Abundances are determined for 43 elements, including 26 neutron-capture elements. In particular, abundances of the rarely studied elements Nb, Mo, Cd, Lu, Os, Pt, and Au are derived from the HST spectrum. These results, combined with RPA near-UV observations of two additional $r$-II stars, increase the number of Cd abundances derived for $r$-process-enriched stars from seven to ten and Au abundances from four to seven. A large star-to-star scatter is detected for both of these elements, highlighting the need for more detections enabling further investigations, specifically into possible non-LTE (local thermodynamical equilibrium) effects.

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arXiv2025

New Stellar Parameters, Metallicities, and Elemental Abundance Ratios for 311 Metal-Poor Stars

We present equivalent widths, improved model atmosphere parameters, and revised abundances for 14 species of 11 elements derived from high resolution optical spectroscopy of 311 metal-poor stars. All of these stars had their parameters previously published by Roederer et al. We use color-Teff relationships calibrated for Gaia and 2MASS photometry to calculate improved effective temperatures. We calculate log of surface gravity values using measurements derived from Gaia parallaxes and other fundamental stellar properties. We perform a standard LTE abundance analysis using MARCS model atmospheres and the MOOG line analysis software to rederive microturbulence velocity parameters, metallicities, and abundances based on O I, Na I, Mg I, Si I, K I, Ca I, Ti I, Ti II, Cr I, Cr II, Fe I, Fe II, Ni I, and Zn I lines using the previously measured equivalent widths. On average, the new Teff values are 310 K warmer, the new log g values are higher by 0.64 dex, and the new [Fe/H] values are higher by 0.26 dex. We apply NLTE corrections to the abundances derived from O I, Na I, Mg I, Si I, K I, Fe I, and Fe II lines. Our sample contains 6 stars with [Fe/H] < -3.5, 28 stars with [Fe/H] < -3.0, and 113 stars with [Fe/H] < -2.5. Our revised abundances for these 311 stars are now in better agreement with those derived by previous studies of smaller samples of metal-poor stars in the Milky Way.

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arXiv2024

BD+44 493: Chemo-Dynamical Analysis and Constraints on Companion Planetary Masses from WIYN/NEID Spectroscopy

In this work, we present high-resolution (R~100,000), high signal-to-noise (S/N~800) spectroscopic observations for the well-known, bright, extremely metal-poor, carbon-enhanced star BD+44 493. We determined chemical abundances and upper limits for 17 elements from WIYN/NEID data, complemented with 11 abundances re-determined from Subaru and Hubble data, using the new, more accurate, stellar atmospheric parameters calculated in this work. Our analysis suggests that BD+44 493 is a low-mass (0.83Msun) old (12.1-13.2Gyr) second-generation star likely formed from a gas cloud enriched by a single metal-free 20.5Msun Population III star in the early Universe. With a disk-like orbit, BD+44 493 does not appear to be associated with any major merger event in the early history of the Milky Way. From the precision radial-velocity NEID measurements (median absolute deviation - MAD=16m/s), we were able to constrain companion planetary masses around BD+44 493 and rule out the presence of planets as small as msin(i)=2MJ out to periods of 100 days. This study opens a new avenue of exploration for the intersection between stellar archaeology and exoplanet science using NEID.

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arXiv2024

The R-Process Alliance: Fifth Data Release from the Search for R-Process-Enhanced Metal-poor Stars in the Galactic Halo with the GTC

Understanding the abundance pattern of metal-poor stars and the production of heavy elements through various nucleosynthesis processes offers crucial insights into the chemical evolution of the Milky Way, revealing primary sites and major sources of rapid neutron-capture process ($r$-process) material in the Universe. In this fifth data release from the $R$-Process Alliance, we present the detailed chemical abundances of 41 faint (down to V = 15.8) and extremely metal-poor (down to [Fe/H] = -3.3) halo stars selected from the R-Process Alliance (RPA). We obtained high-resolution spectra for these objects with the HORuS spectrograph on the Gran Telescopio Canarias. We measure the abundances of light, alpha, Fe-peak, and neutron-capture elements. We report the discovery of five CEMP, one limited-$r$, three $r$-I, and four $r$-II stars, and six Mg-poor stars. We also identify one star of a possible globular cluster origin at an extremely low metallicity at [Fe/H] = -3.0. This adds to the growing evidence of a lower limit metallicity floor for globular cluster abundances. We use the abundances of Fe-peak elements and the alpha-elements to investigate the contributions from different nucleosynthesis channels in the progenitor supernovae. We find the distribution of [Mg/Eu] as a function of [Fe/H] to have different enrichment levels, indicating different possible pathways and sites of their production. We also reveal differences in the trends of the neutron-capture element abundances of Sr, Ba, and Eu of various $r$-I and $r$-II stars from the RPA data releases, which provide constraints on their nucleosynthesis sites and subsequent evolution.

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