arXiv subjects

Ichiro Terasaki

Publications and source records attributed to Ichiro Terasaki.

At least 37 records · Page 2Linked to original sources

arXiv2014

Non-uniform magnetic system driven by non-magnetic ion substitution in CaRu1-xScxO3:Two-component analysis

We have studied magnetic and transport properties in polycrystalline CaRu1-xScxO3 for 0 =< x =< 0.20 in order to clarify the substitution effects of a non-magnetic trivalent ion. We find that a ferromagnetic transition with Tc = 30 K is observed in Sc-substituted samples. The composition dependence of the Curie-Weiss temperature implies that the magnetic susceptibility has a paramagnetic contribution with negative theta and a ferromagnetic contribution with positive theta. The field dependence of magnetization at 2 K is also understood as a summation of the ferromagnetic and paramagnetic components. These results suggest that CaRu1-xScxO3 is a non-uniform magnetic system. The relationship between the ferromagnetic ordering and the transport properties is also discussed.

cond-mat.str-el↗

arXiv2014

Unconventional magnetism in the layered oxide LaSrRhO$_4$

We have prepared polycrystalline samples of LaSrRh$_{1-x}$Ga$_x$O$_4$ and LaSr$_{1-x}$Ca$_x$RhO$_4$,and have measured the x-ray diffraction, resistivity, Seebeck coefficient, magnetization and electron spin resonance in order to evaluate their electronic states. The energy gap evaluated from the resistivity and the Seebeck coefficient systematically changes with the Ga concentration, and suggests that the system changes from a small polaron insulator to a band insulator. We find that all the samples show Curie-Weiss-like susceptibility with a small Weiss temperature of the order of 1 K, which is seriously incompatible with the collective wisdom that a trivalent rhodium ion is nonmagnetic. We have determined the $g$ factor to be $g$=2.3 from the electron spin resonance, and the spin number to be $S$=1 from the magnetization-field curves by fitting with a modified Brillouin function. The fraction of the $S$=1 spins is 2--5%, which depends on the degree of disorder in the La/Sr/Ca-site, which implies that disorder near the apical oxygen is related to the magnetism of this system. A possible origin for the magnetic Rh$^{3+}$ ions is discussed.

cond-mat.str-el↗

arXiv2013

Optical Conductivity Measurement of a Dimer-Mott to Charge-Order Phase Transition in a Two-Dimensional Quarter-Filled Organic Salt Compound

We report a novel insulator-insulator transition arising from the internal charge degrees of freedom in the two-dimensional quarter-filled organic salt beta-(meso-DMBEDT-TTF)2PF6. The optical conductivity spectra above Tc = 70 K display a prominent feature of the dimer-Mott insulator, characterized by a substantial growth of a dimer peak near 0.6 eV with decreasing temperature. The dimer-peak growth is rapidly quenched as soon as a peak of the charge order shows up below Tc, indicating a competition between the two insulating phases. Our infrared imaging spectroscopy has further revealed a spatially competitive electronic phases far below Tc, suggesting a nature of quantum phase transition driven by material-parameter variations.

cond-mat.str-el↗

arXiv2013

Spin state of Co$^{3+}$ in LaCo$_{1-x}$Rh$_{x}$O$_{3}$ investigated by structural phenomena

Neutron diffraction for a polycrystalline sample of LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$ and synchrotron x-ray diffraction for polycrystalline samples of LaCo$_{0.9}$Rh$_{0.1}$O$_{3}$ and LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$ have been carried out in order to investigate the structural properties related with the spin state of Co$^{3+}$ ions. We have found that the values of the Co(Rh)-O bond lengths in the Co(Rh)O$_{6}$ octahedron of LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$ are nearly identical at 10 K. The lattice volume for the Rh$^{3+}$ substituted samples decreases with the thermal expansion coefficient similar to that of LaCoO$_{3}$ from room temperature, and ceases to decrease around 70 K. These experimental results favor a mixed state consisting of the high-spin-state and low-spin-state Co$^{3+}$ ions, and suggest that the high-spin-state Co$^{3+}$ ions are thermally excited in addition to those pinned by the substituted Rh$^{3+}$ ions.

cond-mat.str-el↗

arXiv2013

X-ray crystal structure analysis and the Ru valence of Ba4Ru3O10 single crystals

We present the single-crystalline x-ray diffraction study on the Ba4Ru3O10 consisting of the corner-shared Ru3O12 trimers. The crystal structure is re-determined from 78 to 300 K across an antiferromagnetic transition at 105 K. The orthorhombic symmetry (Cmca, space group No. 64) is preserved at all temperatures measured. This structure presents exceptionally long Ru-O distances characterized by a significant distribution within the Ru3O12 trimer. A bond valence sum calculation suggests that the charge disproportionation within the Ru3O12 trimer emerges even at room temperature, which we ascribe to molecular orbital formation in the Ru3O12 trimer, as supported by recent theoretical calculations. Based on the analyzed crystal structure, the electronic states and the nature of the phase transition at 105 K are discussed.

cond-mat.str-el↗

arXiv2013

Dielectric Anomaly in the Quasi-One-Dimensional Frustrated Spin-1/2 System Rb$_{2}$(Cu$_{1-x}$M$_{x}$)$_{2}$Mo$_{3}$O$_{12}$ (M=Ni and Zn)

Dielectric and magnetic properties have been studied for poly-crystalline samples of quasi-one-dimensional frustrated spin-1/2 system Rb$_{2}$(Cu$_{1-x}$M$_{x}$)$_{2}$Mo$_{3}$O$_{12}$(M=Ni and Zn) which does not exhibit a three-dimensional magnetic transition due to quantum spin fluctuation and low dimensionality. A broad peak in the magnetic susceptibility - temperature curves originated from a short range helical ordering at low temperature is suppressed by the Ni and Zn substitution for Cu sites. The capacitance is found to anomalously increase with decreasing T below ~50 K, which is also suppressed by the impurity doping. The behavior of the anomalous capacitance component is found to be strongly connected with that of the magnetic susceptibility for Rb$_{2}$(Cu$_{1-x}$M$_{x}$)$_{2}$Mo$_{3}$O$_{12}$ which indicates that the low-temperature dielectric response is driven by the magnetism.

cond-mat.str-el↗

arXiv2012

Photo-Seebeck Effect in ZnO

We examine how the photo-induced carriers contribute the thermoelectric transport, i.e. the nature of the photo-Seebeck effect, in the wide-gap oxide semiconductor ZnO for the first time. We measure the electrical conductivity and the Seebeck coefficient with illuminating light. The light illumination considerably changes the Seebeck coefficient as well as the conductivity, which is sensitive to the photon energy of the illuminated light. By using a simple parallel-circuit model, we evaluate the contributions of the photo-induced carriers to the conductivity and the Seebeck coefficient, whose relationship shows a remarkable resemblance to that in doped semiconductors. Our results also demonstrate that the light illumination increases both the carrier concentration and the mobility, which can be compared with impurity-doping case for ZnO. Future prospects for thermoelectrics using light are discussed.

cond-mat.mtrl-sci↗

arXiv2012

High-temperature thermoelectric properties of the double-perovskite ruthenium oxide (Sr$_{1-x}$La$_x$)$_2$ErRuO$_6$

We have prepared polycrystalline samples of (Sr$_{1-x}$La$_x$)$_2$ErRuO$_6$ and (Sr$_{1-x}$La$_x$)$_2$YRuO$_6$, and have measured the resistivity, Seebeck coefficient, thermal conductivity, susceptibility and x-ray absorption in order to evaluate the electronic states and thermoelectric properties of the doped double-perovskite ruthenates. We have observed a large Seebeck coefficient of -160 $μ$V/K and a low thermal conductivity of 7 mW/cmK for $x$=0.1 at 800 K in air. These two values are suitable for efficient oxide thermoelectrics, although the resistivity is still as high as 1 $Ω$cm. From the susceptibility and x-ray absorption measurements, we find that the doped electrons exist as Ru$^{4+}$ in the low spin state. On the basis of the measured results, the electronic states and the conduction mechanism are discussed.

cond-mat.mtrl-sci↗

arXiv2012

Ga$^{3+}$-substitution effects in the weak ferromagnetic oxide LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$

Magnetization and x-ray diffraction have been measured on polycrystalline samples of LaCo$_{0.8-y}$Rh$_{0.2}$Ga$_{y}$O$_{3}$ for $0 \leq y \leq 0.15$ in order to understand the spin state of Co$^{3+}$ through the Ga$^{3+}$ substitution effect. The ferromagnetic order in LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$ below 15 K is dramatically suppressed by the Ga$^{3+}$ substitution, where the ferromagnetic volume fraction is linearly decreased. The normal state susceptibility also systematically decreases with the Ga content, from which we find that one Ga$^{3+}$ ion reduces 4.6 $μ_{\rm B}$ per formula unit. We have evaluated how the concentration of the high-spin state Co$^{3+}$ changes with temperature by using an extended Curie-Weiss law, and have found that the substituted Rh$^{3+}$ ion stabilizes the high-spin state Co$^{3+}$ ion down to low temperatures. We find that Ga$^{3+}$ preferentially replaces the high-spin state Co$^{3+}$, which makes a remarkable contrast to our previous finding that Rh$^{3+}$ preferentially replaces the low-spin state Co$^{3+}$. These results strongly suggest that the magnetically excited state of LaCoO$_{3}$ at room temperature is a mixed state of high-spin state Co$^{3+}$ and low-spin state Co$^{3+}$.

cond-mat.str-el↗

arXiv2011

Weak Ferromagnetism in LaCo1-xRhxO3: Anomalous Magnetism Emerging between Two Nonmagnetic End Phases

Magnetization has been measured for polycrystalline samples of LaCo1-xRhxO3 (0 {\leq} x {\leq} 0.9) in order to investigate magnetism induced in the solid solution of two nonmagnetic end phases of LaCoO3 and LaRhO3. It is found that a ferromagnetic transition is observed below 15 K in the range of x from 0.1 to 0.4. The effective Bohr magnetic moment evaluated from the temperature dependence of magnetic susceptibility at around room temperature is independent of x for 0 < x < 0.5 (approximately 3 μB per formula unit), and rapidly decreases above x = 0.5. On the basis of detailed magnetization measurements, the spin state and magnetic ordering of LaCo1-xRhxO3 are discussed.

cond-mat.str-el↗

arXiv2011

High-temperature oxide thermoelectrics

We have evaluated the power factor of transition metal oxides at high temperatures using the Heikes formula and the Ioffe-Regel conductivity. The evaluated power factor is found to be nearly independent of carrier concentration in a wide range of doping, and well explains the experimental data for cobalt oxides. This suggests that the same power factor can be obtained with a thermopower larger than $2k_B/e$, and also suggests a reasonably high value of the dimensionless figure of merit $ZT$. We propose an oxide thermoelectric power generator by using materials having a thermopower larger than 300 $μ$V/K.

cond-mat.mtrl-sci↗

arXiv2010

Anomalous dielectric response in the dimer Mott insulator $κ$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$

We have measured and analyzed the dielectric constant of the dimer Mott insulator $κ-$(BEDT-TTF)$_2$Cu$_2$(CN)$_3$, which is known as a playground for a spin-liquid state. Most unexpectedly, this particular organic salt has nontrivial charge degrees of freedom, being characterized by a dipole-glass-like dielectric relaxation below around 60 K. This is ascribed to the charge disproportionation within the dimer due to the intersite Coulomb repulsion. In this respect, the dipole observed here is purely quantum mechanical, and thereby exhibits unexpected responses.

cond-mat.str-el↗

arXiv2009

Nonequilibrium Peierls Transition

Nonequlibrium phase transition of an open Takayama-Lin Liu-Maki chain coupled with two reservoirs is investigated by combining a mean-field approximation and a formula characterizing nonequlibrium steady states, which is obtained from the algebraic field approach to nonequlibrium statistical mechanics. When the bias voltage is chosen to be a control parameter, the phase transition between ordered and normal phases is found to be first or second order. Then, the voltage-current characteristics is S-shaped in some parameter region. In contrast, when the current is chosen to be a control parameter, all the non-trivial solutions of the self-consistent equation are found to become stable. In this case, the phase transition between the ordered and normal phases is always second order and negative differential conductivity appears at low temperature.

cond-mat.stat-mech↗

arXiv2007

Structure-Property Relationship in the Ordered-Perovskite- Related Oxide Sr3.12Er0.88Co4O10.5

Synchrotron X-ray diffraction patterns were measured and analyzed for a polycrystalline sample of the room-temperature ferromagnet Sr3.12Er0.88Co4O10.5 from 300 to 650 K, from which two structural phase transitions were found to occur successively. The higher-temperature transition at 509 K is driven by ordering of the oxygen vacancies, which is closely related to the metallic state at high temperatures. The lower-temperature transition at 360 K is of first order, at which the ferromagnetic state suddenly appears with exhibiting a jump in magnetization and resistivity. Based on the refined structure, possible spin and orbital models for the magnetic order are proposed.

cond-mat.str-el↗

arXiv2005

Giant nonlinear conduction and thyristor-like negative derivative resistance in BaIrO3 single crystals

We synthesized single-crystalline samples of monoclinic BaIrO3 using a molten flux method, and measured their magnetization, resistivity, Seebeck coefficient and nonlinear voltage-current characteristics. The magnetization rapidly increases below a ferromagnetic transition temperature TC of 180 K, where the resistivity concomitantly shows a hump-type anomaly, followed by a sharp increase below 30 K. The Seebeck coefficient suddenly increases below TC, and shows linear temperature dependence below 50 K. A most striking feature of this compound is that the anomalously giant nonlinear conduction is observed below 30 K, where a small current density of 20 A/cm2 dramatically suppresses the sharp increase in resistivity to induce a metallic conduction down to 4 K.

cond-mat.str-el↗

arXiv2003

Transport Properties of Bi$_2$Sr$_{2-x}$La$_x$CaCu$_2$O$_{8+δ}$ Single Crystals Grown by a Floating-Zone Method

A parent insulator of the Bi-based high-$T_c$ superconductor Bi$_2$Sr$_{2-x}$La$_x$CaCu$_2$O$_{8+δ}$ was successfully grown by a traveling solvent floating zone method. The in-plane resistivity $ρ_{ab}$ shows metallic behavior ($dρ_{ab}/dT >$ 0) near room temperature, although the magnitude of the resistivity is far above the Mott limit for metallic conduction. The Hall mobility of the parent insulator does not so much differ from that of an optimally doped sample. These results suggest that the system is not a simple insulator with a well-defined gap, and the hole in the parent insulator is essentially itinerant, as soon as it is doped.

cond-mat.str-el↗

arXiv2003

Large Transport Properties of Bi$_2$Sr$_{2-x}$La$_x$CaCu$_2$O$_{8+δ}$ Single Crystals Grown by a Floating-Zone Method

cond-mat.str-el↗

arXiv2002

The Effects of the Misfit Structure on Thermoelectric Properties of Bi2-xPbxSr2Co2Oy Single Crystals

In-plane anisotropy of the resistivity and thermopower was measured for single crystal Bi2-xPbxSr2Co2Oy. There is large in-plane anisotropy, which is attributed to the anisotropic pseudogap formation due to the different crystal symmetry between the square Bi2Sr2O4 layer and the triangular CuO2 layer. The magnitude of the thermopower both along a- and b-axis direction increases with Pb doping from x=0 to 0.4, where we observe discontinuous shrink of b-axis length. We attribute this to the enhancement of the misfitness. Thus, we can improve the thermoelectric properties by tuning the misfitness.

cond-mat.str-el↗