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Ihor Korolov

Publications and source records attributed to Ihor Korolov.

At least 19 recordsLinked to original sources

A Nonlinear Two-Sheath Circuit Model for Low-Pressure Symmetric and Asymmetric Capacitively Coupled Radio-Frequency Plasmas

We develop a nonlinear self-consistent two-sheath circuit model for low-pressure capacitively coupled plasmas that applies to geometrically symmetric as well as asymmetric discharges. The quasineutral plasma bulk is represented by an inductive-resistive element and coupled to stationary particle and electron-energy balances. Both boundary sheaths are treated dynamically using a lncosh sheath charge-voltage model with bounded differential elastance, based on a Riccati closure for the differential sheath width. The model recovers the quadratic depletion-sheath relation in the small-charge limit, while the characteristic sheath scales are determined from the RF-averaged sheath voltages using a collisionless Child-Langmuir/Bohm closure. The resulting four-variable RF subsystem contains the two sheath charges, the blocking-capacitor voltage, and the discharge current. In the symmetric monofrequent limit, the two sheath nonlinearities compensate strongly and the dc self-bias vanishes, whereas geometrical or electrical asymmetry breaks this compensation and enhances harmonic generation and plasma-series-resonance oscillations.

physics.plasm-ph↗

Non-invasive monitoring of process-relevant plasma parameters by Fiber PROES in capacitively coupled Ar/CF$_4$ plasmas

Monitoring changes of process-relevant plasma parameters, such as the electron density and ion flux to the wafer, is essential for the development and control of plasma processes. However, invasive plasma diagnostics, such as probe measurements, typically cannot be applied to commercial reactors. At the example of a low pressure capacitive radio frequency discharge operated in different mixtures of CF$_4$ and Ar, we demonstrate that changes of such plasma parameters can be monitored non-invasively by phase resolved optical emission spectroscopy via optical fibers (Fiber PROES), for which the ports are usually available at industrial plasma sources. In this way, the spatio-temporally resolved dynamics of energetic electrons are tracked by observing a selected emission line. By measuring the electron density and ion flux directly via probe and retarding field energy analyzer diagnostics as a function of driving voltage and pressure, changes of these plasma parameters, including hysteresis effects, are found to be correlated with transitions of the electron power absorption mode revealed by Fiber PROES. Such mode transitions cause the electron energy distribution function (EEDF) to change and, thus, affect such plasma parameters. Based on these findings, Fiber PROES can be used as a non-invasive diagnostic for the monitoring and knowledge-based development of plasma processes.

physics.plasm-ph↗

Characterization of a laser filament-induced plasma in air at 10 kHz using optical emission spectroscopy

The increasing availability of high-power Yb-based ultrafast laser-amplifier systems has opened the possibility of air filamentation at high repetition rates >1 kHz. In this new regime, accumulation effects cannot be ruled out, therefore, characterizing the plasma parameters and afterglow plasma-chemical kinetics becomes increasingly relevant. In this work, we use optical emission spectroscopy to measure nanosecond dynamics of gas temperature and electron temperature, species-specific decay times, and electron density of an atmospheric air laser filament produced by high average power femtosecond laser at a high repetition rate of 10 kHz. The molecular excitation mechanisms behind the nitrogen photoemissions are derived from vibrational distributions and temporal behavior of the studied emission bands. The presented diagnostic technique offers a complementary but more holistic measurement approach to optical probe schemes to characterize the laser-filament-induced plasma wake for high repetition rate filaments.

physics.plasm-ph↗

Two-dimensional spatially resolved measurements of helium metastable densities by tunable diode laser absorption spectroscopy in atmospheric pressure RF plasma jets

Helium metastable species play a critical role in sustaining radio-frequency (RF) driven micro atmospheric pressure plasma jets through Penning ionization and for the generation of reactive oxygen and nitrogen species (RONS). Their densities are typically measured using tunable diode laser absorption spectroscopy (TDLAS). Most spatially resolved TDLAS approaches rely on mechanical scanning of a narrow laser beam across the plasma, which is time-consuming and limits spatial resolution. In this work, we present an advanced two-dimensional (2D) TDLAS method that enables direct spatial mapping of helium metastable densities without the need for mechanical scanning. A rotating optical diffuser is employed to suppress speckle interference and generate uniform illumination across the plasma region. The absorption profile is captured using a short-wavelength infrared camera equipped with a telecentric lens, achieving high spatial resolution (approximately 10 μm) across the entire field of view. This approach significantly enhances both data quality and acquisition speed. The improved 2D TDLAS system is applied to measure helium metastable densities in plasma jets with structured electrodes driven by different tailored voltage waveforms. The results show very good qualitative agreement with fluid simulations and previously reported experimental data.

physics.plasm-ph↗

Synergistic control of radical generation in a radio frequency atmospheric pressure plasma jet via voltage waveform tailoring and structured electrodes

The synergy between voltage waveform tailoring and structured electrodes is investigated in a radio-frequency (RF) atmospheric-pressure microplasma jet operated in helium with a 0.1% oxygen admixture. The device incorporates rectangular trenches in both electrodes and is driven by "Peaks" and "Valleys" waveforms synthesized from four harmonics (base frequency $f_{\rm b} = 13.56$~MHz, $V_{\rm pp} = 500$~V, $P=$1.2~W). Two-dimensional plasma fluid simulations, together with spatially and temporally resolved optical diagnostics (Phase-Resolved Optical Emission Spectroscopy and Tunable Diode Laser Absorption Spectroscopy), are used to demonstrate that the combination of asymmetric voltage waveforms with electrode structuring leads to strong spatial localization of electron power absorption and radical generation. This synergy results in a single pronounced maximum inside a trench at either the powered or grounded electrode, depending on the applied waveform, unlike a symmetric excitation, which produces a spatially symmetric enhancement at both electrodes. The effect is attributed to the interplay between waveform-induced sheath dynamics and geometric focusing provided by the trenches, enabling electrically reversible and selective enhancement of electron power absorption at a chosen location.

physics.plasm-ph↗

Electronegativity effects on plasma dynamics in He/O$_2$ RF microplasma jets at atmospheric pressure

This work investigates the transitions between ohmic mode and Penning-Gamma mode in a capacitively coupled radio frequency micro atmospheric pressure plasma jets (CCRF $μ$APPJ) operated in He/O$_2$ mixtures by comparing phase-resolved optical emission spectroscopy (PROES) measurements of helium excitation with numerical simulations. The simulations employ a hybrid model that treats electrons kinetically via PIC/MCC, while ions and neutrals are modeled fluid dynamically. These results reveal that increasing electronegativity causes inhomogeneities in the bulk electric field, consequently modulating electron impact excitation dynamics. A good agreement was found between experiments and simulations.

physics.plasm-ph↗

Overcoming Discharge Inhibition in n-Butane Oxidation: Two-Component BaTiO3 and Mn-Cu Mixed Oxide Coatings

A twin surface dielectric barrier discharge on the microsecond scale was used in combination with a two-component coating to oxidize 300 ppm n-butane as a model volatile organic compound to CO2 and H2O in synthetic air at room temperature and at 160 °C. The integration of BaTiO3 as a base material for the coating allowed the successful use of otherwise discharge-ignition-inhibiting materials such as MnO2-CuO applied as a full coating. Application of pure BaTiO3 led to highly porous coatings that do not hinder the discharge ignition and show a negligible influence on n-butane conversion while reducing byproduct formation. Thus, BaTiO3 was identified as a suitable structure-directing agent in two-component coatings, using 1:1 and 1:2 ratios of BaTiO3:catalyst coatings. Coated electrode configurations were compared to their respective uncoated state to highlight the coating-induced changes. The two-component coatings strongly increased the CO2 selectivity, reaching a maximum of 91.6 % at an energy density of 450 J/L and 160 °C for the 1:2 ratio, corresponding to an increase of 51.0 % relative to the uncoated electrode.

physics.plasm-ph↗

Electron dynamics of three distinct discharge modes of a cross-field atmospheric pressure plasma jet

This paper investigates the electron dynamics in three distinct discharge modes of a cross-field atmospheric pressure plasma jet, the COST-Jet. Thereby, the discharge modes are the non-neutral, the quasi-neutral, and the constricted mode. Using a hybrid Particle-In-Cell/Monte-Carlo Collisions (PIC/MCC) simulation, the study systematically varies the applied voltage and driving frequency to explore the operation modes and their relations. The results reveal that at low input power, the COST-Jet operates in a non-neutral mode, characterized by a discharge close to extinction, analogous to the chaotic mode observed in other plasma devices. As power increases, the jet transitions to a quasi-neutral mode, which aligns with the well-known Ω- and Penning modes, comparable to the bullet mode in parallel-field jets. At the highest power levels, the COST-Jet enters a constricted mode, where the plasma significantly densifies and constricts towards the electrodes along the entire discharge channel. Experimental validation using phase-resolved optical emission spectroscopy (PROES) supports the simulation findings, particularly identifying the constricted mode as a distinct operational regime. These insights into the mode transitions of the COST-Jet under varying operational conditions help optimize plasma applications in various fields.

physics.plasm-ph↗

Decoupling NO production and UV emission intensity over the E-H mode transition in a low-pressure inductively coupled plasma device

A low-pressure double-inductively coupled plasma device is used to study the fundamental plasma parameters, plasma chemistry, and UV photon emission from the first excited state of nitric oxide, NO(A), in gas mixtures of nitrogen and oxygen. In addition to the gas mixture, rf power and gas pressure are varied, and the E-H mode transition of the inductively coupled plasma is studied specifically. The gas temperature and UV photon emission are measured by optical emission spectroscopy (OES), the absolute density of the nitric oxide electronic ground state by laser-induced fluorescence (LIF), as well as electron density and electron temperature by a multipole resonance probe (MRP). A simple collisional-radiative model for UV emission from NO(A) is developed, which takes the measured densities of ground state nitric oxide and electrons, as well as the electron temperature and neutral gas temperature, as input parameters. The results reveal the links between the absolute densities of ground state nitric oxide, the excitation of this species driven by electron impact and collisions with nitrogen metastables, quenching of the nitrogen metastables, and the resulting UV photon emission rate. The density of ground state nitric oxide is shown to increase with power, while the discharge remains in E-mode, and to decrease significantly with the transition into H-mode, when sufficient rf power is deposited in the discharge. Despite the lower densities of ground state nitric oxide in H-mode, the UV photon emission intensity increases continuously with higher rf powers and over the E-H transition. This effect is shown to be caused by increased excitation of NO(A) by nitrogen metastables in H-mode, which is sufficient to overcompensate the decrease in ground state nitric oxide density.

physics.plasm-ph↗

The role of flow field dynamics in enhancing volatile organic compound conversion in a surface dielectric barrier discharge system

This study investigates the correlation between flow fields induced by a surface dielectric barrier discharge (SDBD) system and its application for the volatile organic compound (VOC) gas conversion process. As a benchmark molecule, the conversion of n-butane is monitored using flame ionization detectors, while the flow field is analysed using planar particle image velocimetry. Two individual setups are developed to facilitate both conversion measurement and investigation of induced fluid dynamics. Varying the gap distance between two SDBD electrode plates for three different n-butane mole fractions reveals local peaks in relative conversion around gap distances of 16 mm to 22 mm, indicating additional spatially dependent effects. The lowest n-butane mole fractions exhibit the highest relative conversion, while the highest n-butane mole fraction conversion yields the greatest number of converted molecules per unit time. Despite maintaining constant energy density, the relative conversion exhibits a gradual decrease with increasing distances. The results of the induced flow fields reveal distinct vortex structures at the top and bottom electrodes, which evolve in size and shape as the gap distances increase. These vortices exhibit gas velocity magnitudes approximately seven times higher than the applied external gas flow velocity. Vorticity and turbulent kinetic energy analyses provide insights into these structures' characteristics and their impact on gas mixing. A comparison of line profiles through the centre of the vortices shows peaks in the middle gap region for the same gap distances, correlating with the observed peaks in conversion. These findings demonstrate a correlation between induced flow dynamics and the gas conversion process, bridging plasma actuator studies with the domain of chemical plasma gas conversion.

physics.plasm-ph↗

Numerical investigation of vacuum ultra-violet emission in Ar/O$_2$ inductively coupled plasmas

Controlling fluxes of vacuum ultraviolet (VUV) radiation is important in a number of industrial and biomedical applications of low pressure plasma sources because, depending on the process, VUV radiation may be desired, required to a certain degree, or unwanted. In this work, the emission of VUV radiation from O atoms is investigated in low-pressure Ar/O$_2$ inductively coupled plasma via numerical simulations. For this purpose, a self-consistent Ar/O$_2$ plasma-chemical reaction scheme has been implemented in a zero dimensional plasma chemical kinetics model and is used to investigate VUV emission from excited O atoms (3s $^5$S$^0_2$) and 3s $^3$S$^0_1$) at 130 and 135 nm. The model is extensively compared with experimental measurements of absolute VUV emission intensities, electron densities and Ar excited state densities. In addition, VUV emission intensities are investigated as a function of pressure, Ar/O$_2$ mixture, and power deposition and the dominant reaction pathways leading to VUV emission are identified and described. In general terms, absolute VUV emission intensities increase with power and oxygen fraction over the ranges investigated and peak emission intensities are found for pressures between 5-50 Pa. The emission is dominated by the 130 nm resonance line from the decay of the O(3s $^3$S$^0_1$) state to the ground state. Besides, at low pressure (0.3-1 Pa), the flux of VUV photons to surfaces is much lower than that of positive ions, whereas VUV fluxes dominate at higher pressure, $\gtrsim$5-50 Pa depending on O$_2$ fraction. Finally, oxygen atom fluxes to surfaces are, in general, larger than those of VUV photons for the parameter space investigated.

physics.plasm-ph↗

Interactions between flow fields induced by surface dielectric barrier discharge arrays

This study investigates the flow field induced by a surface dielectric barrier discharge (SDBD) system, known for its efficient pollution remediation of volatile organic compounds (VOCs). We aim to understand the flow dynamics that contribute to the high conversion observed in similar systems. Experimental techniques, including schlieren imaging and particle image velocimetry (PIV), applied with high temporal resolution, were used to analyse the flow field. Complementary, fluid simulations are employed to investigate the coupling between streamer and gas dynamics. Results show distinct fluid field behaviours for different electrode configurations, which differ in geometric complexity. The fluid field analysis of the most basic electrode design revealed behaviours commonly observed in actuator studies. The simulation results indicate the local information about the electron density as well as different temporal phases of the fluid flow. The electrode design with mostly parallel grid line structures exhibits confined vortices near the surface. In contrast, an electrode design also used in previous studies, is shown to promote strong gas transport through extended vortex structures, enhancing gas mixing and potentially explaining the high conversion observed.

physics.plasm-ph↗

Zero-dimensional and pseudo-one-dimensional models of atmospheric-pressure plasma jet in binary and ternary mixtures of oxygen and nitrogen with helium background

A zero-dimensional (volume-averaged) and a pseudo-one-dimensional (plug-flow) model are developed to investigate atmospheric-pressure plasma jet devices operated with He, He/O$_2$, He/N$_2$ and He/N$_2$/O$_2$ mixtures. The models are coupled with the Boltzmann equation under the two-term approximation to self-consistently calculate the electron energy distribution function (EEDF). The simulation results are verified against spatially resolved model calculations and validated against a wide variety of measurement data. The nitric oxide (NO) concentration is thoroughly characterized for a variation of the gas mixture ratio, helium flow rate and absorbed power. The concentration measurements at low power are better captured by the simulation with a larger hypothetical "effective" rate coefficient value for the reactive quenching N$_2$(A$^3Σ$,B$^3Π$) + O($^3$P) $\to$ NO + N($^2$D). This suggests that the NO production at low power is also covered by the species N$_2$(A$^3Σ$,B$^3Π$;v>0) and multiple higher N$_2$ electronically excited states instead of only N$_2$(A$^3Σ$,B$^3Π$;v=0) in this quenching. Furthermore, the O($^3$P) density measurements under the same operation conditions are also better predicted by the simulations with a consideration of the aforementioned hypothetical rate coefficient value. It is found that the contribution of the vibrationally excited nitrogen molecules N$_2$(v$\geqslant$13) to the net NO formation rate gains more significance at higher power. The vibrational distribution functions (VDFs) of O$_2$(v<41) and N$_2$(v<58) are investigated. The sensitivity of the zero-dimensional model with respect to a variation of the VDF resolutions, wall reaction probabilities and synthetic air impurity levels is presented. The simulated plasma properties are sensitive to the variation especially for a feeding gas mixture containing nitrogen.

physics.plasm-ph↗

Energy efficiency of voltage waveform tailoring for the generation of excited species in RF plasma jets operated in He/N$_2$ mixtures

Based on Tunable Diode Laser Absorption Spectroscopy (TDLAS) measurements of the spatially averaged and peak helium metastable atom densities in a capacitively coupled micro atmospheric pressure plasma jet operated in He/N$_2$ mixtures, the energy efficiency of metastable species (He-I 2$^3$S$_1$) generation is compared for three different scenarios: single frequency operation at (i) 13.56 MHz and (ii) 54.12 MHz, and Voltage Waveform Tailoring (VWT) at (iii) "valleys"-waveforms synthesized from four consecutive harmonics of 13.56 MHz. For each case, the dissipated power is measured based on a careful calibration procedure of voltage and current measurements. The results are compared to PIC/MCC simulation results and very good agreement is found. The computational results show that the choice of the surface coefficients in the simulation is important to reproduce the experimental data correctly. Due to the enhanced control of the spatio-temporal electron power absorption dynamics and, thus, of the electron energy distribution function by VWT, this approach does not only provide better control of the generation of excited and reactive species compared to single frequency excitation, but in case of helium metastables the energy efficiency is also shown to be significantly higher in case of VWT.

physics.plasm-ph↗

Electron heating mode transitions in radio-frequency driven micro atmospheric pressure plasma jets in He/O$_{2}$: A fluid dynamics approach

A two-dimensional fluid model is used to investigate the electron heating dynamics and the production of neutral species in a capacitively coupled radio-frequency micro atmospheric pressure helium plasma jet -- specifically the COST jet -- with a small oxygen admixture. Electron heating mode transitions are found to be induced by varying the driving voltage amplitude and the O$_2$ concentration numerically and experimentally. The helium metastable density, and the charged species densities are highly relevant to the electron heating dynamics. By analyzing the creation and destruction mechanisms of the negative ions, we find that the generation of negative ions strongly depends on the O$_2$ concentration. The increase of the electronegativity with the increasing O$_2$ concentration leads to an enhancement of the bulk drift electric field. The distributions of the different neutral species densities along the direction of the gas flow inside the jet, as well as in the effluent differ a lot due to the relevant chemical reaction rates and the effect of the gas flow. The simulated results show that a fluid model can be an effective tool for qualitative investigations of micro atmospheric pressure plasma jets.

physics.plasm-ph↗

Self-diffusion in two-dimensional quasi-magnetized rotating dusty plasmas

The self-diffusion phenomenon in a two-dimensional dusty plasma at extremely strong (effective) magnetic fields is studied experimentally and by means of molecular dynamics simulations. In the experiment the high magnetic field is introduced by rotating the particle cloud and observing the particle trajectories in a co-rotating frame, which allows reaching effective magnetic fields up to 3000 Tesla. The experimental results confirm the predictions of the simulations: (i) super-diffusive behavior is found at intermediate time-scales and (ii) the dependence of the self-diffusion coefficient on the magnetic field is well reproduced.

physics.plasm-ph↗

Striations in electronegative capacitively coupled radio-frequency plasmas: effects of the pressure, voltage, and electrode gap

Capacitively coupled radio-frequency (CCRF) CF_4 plasmas have been found to exhibit a self-organized striated structure at operating conditions, where the plasma is strongly electronegative and the ion-ion plasma in the bulk region (largely composed of CF_3^+ and F^- ions) resonates with the excitation frequency. In this work we explore the effects of the gas pressure, the RF voltage, and the electrode gap on this striated structure by Phase Resolved Optical Emission Spectroscopy and Particle-In-Cell/Monte Carlo Collisions simulations. The measured electronic excitation patterns at different external parameters show a good general agreement with the spatio-temporal plots of the ionization rate obtained from the simulations. For a fixed driving frequency the minima of the CF_3^+ and F^- ion densities (between the density peaks in the bulk) are comparable and independent of other external parameters. However, the ion density maxima generally increase as a function of the pressure or RF voltage, leading to the enhanced spatial modulation of plasma parameters. The striation gap (defined as the distance between two ion density peaks) is approximately inversely proportional to the pressure, while it exhibits a weak dependence on the RF voltage and the electrode gap. A transition between the striated and non-striated modes can be observed by changing either the pressure or the RF voltage; for 13.56 MHz and 18 MHz driving frequencies we present a phase diagram as a function of the pressure and voltage amplitude parameters.

physics.plasm-ph↗

Striations in electronegative capacitively coupled radio-frequency plasmas: analysis of the pattern formation and the effect of the driving frequency

Self-organized striated structures of the plasma emission have recently been observed in capacitive radio-frequency CF4 plasmas by Phase Resolved Optical Emission Spectroscopy (PROES) and their formation was analyzed and understood by Particle in Cell / Monte Carlo Collision (PIC/MCC) simulations [Y.-X. Liu, et al. Phys. Rev. Lett. 116, 255002 (2016)]. The striations were found to result from the periodic generation of double layers due to the modulation of the densities of positive and negative ions responding to the externally applied RF potential. In this work, an in-depth analysis of the formation of striations is given, as well as the effect of the driving frequency on the plasma parameters, such as the spatially modulated charged species densities, the electric field, and the electron power absorption is studied by PROES measurements, PIC/MCC simulations, and an ion-ion plasma model. The measured spatio-temporal electronic excitation patterns at different driving frequencies show a high degree of consistency with the simulation results. The striation gap (i.e., the distance between two ion density maxima) is found to be inversely proportional to the driving frequency. In the presence of striations the minimum(CF_3^+, F^-) ion densities in the bulk region exhibit an approximately quadratic increase with the driving frequency. For these densities, the eigenfrequency of the ion-ion plasma is near the driving frequency, indicating that a resonance occurs between the positive and negative ions and the oscillating electric field inside the plasma bulk. The maximum ion densities in the plasma bulk are found not to exhibit a simple dependence on the driving frequency, since these ion densities are abnormally enhanced within a certain frequency range due to the ions being focused into the "striations" by the spatially modulated electric field inside the bulk region.

physics.plasm-ph↗