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Itamar Procaccia

Publications and source records attributed to Itamar Procaccia.

At least 163 records · Page 9Linked to original sources
arXiv2009

Statistical Mechanics and Dynamics of a 3-Dimensional Glass-Forming System

In the context of a classical example of glass-formation in 3-dimensions we exemplify how to construct a statistical mechanical theory of the glass transition. At the heart of the approach is a simple criterion for verifying a proper choice of up-scaled quasi-species that allow the construction of a theory with a finite number of 'states'. Once constructed, the theory identifies a typical scale $ξ$ that increases rapidly with lowering the temperature and which determines the $α$-relaxation time $τ_α$ as $τ_α\sim \exp(μξ/T)$ with $μ$ a typical chemical potential. The theory can predict relaxation times at temperatures that are inaccessible to numerical simulations.

cond-mat.stat-mech↗
arXiv2009

Locality and Non-locality in Elasto-plastic Responses of Amorphous Solids

A number of current theories of plasticity in amorphous solids assume at their basis that plastic deformations are spatially localized. We present in this paper a series of numerical experiments to test the degree of locality of plastic deformation. These experiments increase in terms of the stringency of the removal of elastic contributions to the observed elasto-plastic deformations. It is concluded that for all our simulational protocols the plastic deformations are not localized, and their scaling is sub-extensive. We offer a number of measures of the magnitude of the plastic deformation, all of which display sub-extensive scaling characterized by non-trivial exponents. We provide some evidence that the scaling exponents governing the sub-extensive scaling laws are non-universal, depending on the degree of disorder and on the parameters of the systems. Nevertheless understanding what determines these exponents should shed considerable light on the physics of amorphous solids.

cond-mat.stat-mech↗
arXiv2009

Drying Patterns: Sensitivity to Residual Stresses

Volume alteration in solid materials is a common cause of material failure. Here we investigate the crack formation in thin elastic layers attached to a substrate. We show that small variations in the volume contraction and substrate restraint can produce widely different crack patterns ranging from spirals to complex hierarchical networks. The networks are formed when there is no prevailing gradient in material contraction whereas spirals are formed in the presence of a radial gradient in the contraction of a thin elastic layer.

cond-mat.mtrl-sci↗
arXiv2008

Turbulent Fluxes in Stably Stratified Boundary Layers

We present an extended version of an invited talk given on the International Conference "Turbulent Mixing and Beyond". The dynamical and statistical description of stably stratified turbulent boundary layers with the important example of the stable atmospheric boundary layer in mind is addressed. Traditional approaches to this problem, based on the profiles of mean quantities, velocity second-order correlations, and dimensional estimates of the turbulent thermal flux run into a well known difficulty, predicting the suppression of turbulence at a small critical value of the Richardson number, in contradiction with observations. Phenomenological attempts to overcome this problem suffer from various theoretical inconsistencies. Here we present an approach taking into full account all the second-order statistics, which allows us to respect the conservation of total mechanical energy. The analysis culminates in an analytic solution of the profiles of all mean quantities and all second-order correlations removing the unphysical predictions of previous theories. We propose that the approach taken here is sufficient to describe the lower parts of the atmospheric boundary layer, as long as the Richardson number does not exceed an order of unity. For much higher Richardson numbers the physics may change qualitatively, requiring careful consideration of the potential Kelvin-Helmoholtz waves and their interaction with the vortical turbulence.

physics.flu-dyn↗
arXiv2008

Theory of Specific Heat in Glass Forming Systems

Experimental measurements of the specific heat in glass-forming systems reveal anomalies in the temperature dependence of the specific heat, including the so called "specific heat peak" in the vicinity of the glass transition. The aim of this paper is to provide theoretical explanations of these anomalies in general and a quantitative theory in the case of a simple model of glass-formation. We first present new simulation results for the specific heat in a classical model of a binary mixture. We show that in addition to the formerly observed specific heat peak there is a second peak at lower temperatures which was not observable in earlier simulations. Second, we present a general relation between the specific heat and the bulk modulus and thus offer a smooth connection between the liquid and amorphous solid states. The central result of this paper is a connection between the micro-melting of clusters in the system and the appearance of specific heat peaks. We relate the two peaks to changes in the bulk and shear moduli. We propose that the phenomenon of glass-formation is accompanied by a fast change in the bulk and the shear moduli, but these fast changes occur in different ranges of the temperature. Lastly, we demonstrate how to construct a theory of the frequency dependent complex specific heat, expected from heterogeneous clustering in the liquid state of glass formers. A specific example is provided in the context of our model for the dynamics of glycerol. The theoretical frequency dependent specific heat agrees well with experimental measurements on glycerol. We conclude the paper by stating that there is nothing universal about the temperature dependence of the specific heat in glass formers - unfortunately one needs to understand each case by itself.

cond-mat.stat-mech↗
arXiv2008

Non-Universality of the Specific Heat in Glass Forming Systems

We present new simulation results for the specific heat in a classical model of a binary mixture glass-former in two dimensions. We show that in addition to the formerly observed specific heat peak there is a second peak at lower temperatures which was not observable in earlier simulations. This is a surprise, as most texts on the glass transition expect a single specific heat peak. We explain the physics of the two specific heat peaks by the micro-melting of two types of clusters. While this physics is easily accessible, the consequences are that one should not expect any universality in the temperature dependence of the specific heat in glass formers.

cond-mat.mtrl-sci↗
arXiv2008

Quantitative Theory of a Time-Correlation Function in a One-Component Glass-Forming Liquid with Anisotropic Potential

The Shintani-Tanaka model is a glass-forming system whose constituents interact via anisotropic potential depending on the angle of a unit vector carried by each particle. The decay of time-correlation functions of the unit vectors exhibits the characteristics of generic relaxation functions during glass transitions. In particular it exhibits a 'stretched exponential' form, with the stretching index beta depending strongly on the temperature. We construct a quantitative theory of this correlation function by analyzing all the physical processes that contribute to it, separating a rotational from a translational decay channel. Interestingly, the separate decay function of each of these processes is temperature independent. Taken together with temperature-dependent weights determined a-priori by statistical mechanics one generates the observed correlation function in quantitative agreement with simulations at different temperatures. This underlines the danger of concluding anything about glassy relaxation functions without detailed physical scrutiny.

cond-mat.stat-mech↗
arXiv2008

The Stability of an Expanding Circular Cavity and the Failure of Amorphous Solids

Recently, the existence and properties of unbounded cavity modes, resulting in extensive plastic deformation failure of two-dimensional sheets of amorphous media, were discussed in the context of the athermal Shear-Transformation-Zones (STZ) theory. These modes pertain to perfect circular symmetry of the cavity and the stress conditions. In this paper we study the shape stability of the expanding circular cavity against perturbations, in both the unbounded and the bounded growth regimes (for the latter the unperturbed theory predicts no catastrophic failure). Since the unperturbed reference state is time dependent, the linear stability theory cannot be cast into standard time-independent eigenvalue analysis. The main results of our study are: (i) sufficiently small perturbations are stable, (ii) larger perturbations within the formal linear decomposition may lead to an instability; this dependence on the magnitude of the perturbations in the linear analysis is a result of the non-stationarity of the growth, (iii) the stability of the circular cavity is particularly sensitive to perturbations in the effective disorder temperature; in this context we highlight the role of the rate sensitivity of the limiting value of this effective temperature. Finally we point to the importance of the form of the stress-dependence of the rate of STZ transitions. The present analysis indicates the importance of nonlinear effects that were not taken into account yet. Even more importantly, the analysis suggests that details of the constitutive relations appearing in the theory can be constrained by the modes of macroscopic failure in these amorphous systems.

cond-mat.mtrl-sci↗
arXiv2008

Quantitative Theory of a Relaxation Function in a Glass-Forming System

We present a quantitative theory for a relaxation function in a simple glass-forming model (binary mixture of particles with different interaction parameters). It is shown that the slowing down is caused by the competition between locally favored regions (clusters) which are long lived but each of which relaxes as a simple function of time. Without the clusters the relaxation of the background is simply determined by one typical length which we deduce from an elementary statistical mechanical argument. The total relaxation function (which depends on time in a nontrivial manner) is quantitatively determined as a weighted sum over the clusters and the background. The `fragility' in this system can be understood quantitatively since it is determined by the temperature dependence of the number fractions of the locally favored regions.

cond-mat.mtrl-sci↗
arXiv2008

Ageing and Relaxation in Glass Forming Systems

We propose that there exists a generic class of glass forming systems that have competing states (of crystalline order or not) which are locally close in energy to the ground state (which is typically unique). Upon cooling, such systems exhibit patches (or clusters) of these competing states which become locally stable in the sense of having a relatively high local shear modulus. It is in between these clusters where ageing, relaxation and plasticity under strain can take place. We demonstrate explicitly that relaxation events that lead to ageing occur where the local shear modulus is low (even negative), and result in an increase in the size of local patches of relative order. We examine the ageing events closely from two points of view. On the one hand we show that they are very localized in real space, taking place outside the patches of relative order, and from the other point of view we show that they represent transitions from one local minimum in the potential surface to another. This picture offers a direct relation between structure and dynamics, ascribing the slowing down in glass forming systems to the reduction in relative volume of the amorphous material which is liquid-like. While we agree with the well known Adam-Gibbs proposition that the slowing down is due to an entropic squeeze (a dramatic decrease in the number of available configurations), we do not agree with the Adam-Gibbs (or the Volger-Fulcher) formulae that predict an infinite relaxation time at a finite temperature. Rather, we propose that generically there should be no singular crisis at any finite temperature: the relaxation time and the associated correlation length (average cluster size) increase at most super-exponentially when the temperature is lowered.

cond-mat.stat-mech↗
arXiv2008

Random Vortex-Street Model for a Self-Similar Plane Turbulent Jet

We ask what determines the (small) angle of turbulent jets. To answer this question we first construct a deterministic vortex-street model representing the large scale structure in a self-similar plane turbulent jet. Without adjustable parameters the model reproduces the mean velocity profiles and the transverse positions of the large scale structures, including their mean sweeping velocities, in a quantitative agreement with experiments. Nevertheless the exact self similar arrangement of the vortices (or any other deterministic model) necessarily leads to a collapse of the jet angle. The observed (small) angle results from a competition between vortex sweeping tending to strongly collapse the jet and randomness in the vortex structure, with the latter resulting in a weak spreading of the jet.

nlin.CD↗
arXiv2008

Ergodicity and Slowing Down in Glass-Forming Systems with Soft Potentials: No Finite-Temperature Singularities

The aim of this paper is to discuss some basic notions regarding generic glass forming systems composed of particles interacting via soft potentials. Excluding explicitly hard-core interaction we discuss the so called `glass transition' in which super-cooled amorphous state is formed, accompanied with a spectacular slowing down of relaxation to equilibrium, when the temperature is changed over a relatively small interval. Using the classical example of a 50-50 binary liquid of N particles with different interaction length-scales we show that (i) the system remains ergodic at all temperatures. (ii) the number of topologically distinct configurations can be computed, is temperature independent, and is exponential in N. (iii) Any two configurations in phase space can be connected using elementary moves whose number is polynomially bounded in N, showing that the graph of configurations has the `small world' property. (iv) The entropy of the system can be estimated at any temperature (or energy), and there is no Kauzmann crisis at any positive temperature. (v) The mechanism for the super-Arrhenius temperature dependence of the relaxation time is explained, connecting it to an entropic squeeze at the glass transition. (vi) There is no Vogel-Fulcher crisis at any finite temperature T>0

cond-mat.dis-nn↗
arXiv2008

Finite-time Singularities in Surface-Diffusion Instabilities are Cured by Plasticity

A free material surface which supports surface diffusion becomes unstable when put under external non-hydrostatic stress. Since the chemical potential on a stressed surface is larger inside an indentation, small shape fluctuations develop because material preferentially diffuses out of indentations. When the bulk of the material is purely elastic one expects this instability to run into a finite-time cusp singularity. It is shown here that this singularity is cured by plastic effects in the material, turning the singular solution to a regular crack.

cond-mat.dis-nn↗
arXiv2007

Universal Model of Finite-Reynolds Number Turbulent Flow in Channels and Pipes

In this Letter we suggest a simple and physically transparent analytical model of the pressure driven turbulent wall-bounded flows at high but finite Reynolds numbers Re. The model gives accurate qualitative description of the profiles of the mean-velocity and Reynolds-stresses (second order correlations of velocity fluctuations) throughout the entire channel or pipe in the wide range of Re, using only three Re-independent parameters. The model sheds light on the long-standing controversy between supporters of the century-old log-law theory of von-Kàrmàn and Prandtl and proposers of a newer theory promoting power laws to describe the intermediate region of the mean velocity profile.

nlin.CD↗
arXiv2007

Detecting and localizing the foci in human epileptic seizures

We consider the electrical signals recorded from a subdural array of electrodes placed on the pial surface of the brain for chronic evaluation of epileptic patients before surgical resection. A simple and computationally fast method to analyze the interictal phase synchrony between such electrodes is introduced and developed with the aim of detecting and localizing the foci of the epileptic seizures. We evaluate the method by comparing the results of surgery to the localization predicted here. We find an indication of good correspondence between the success or failure in the surgery and the agreement between our identification and the regions actually operated on.

physics.med-ph↗
arXiv2007

Statistical Mechanics of the Glass Transition in One-Component Liquids with Anisotropic Potential

We study a recently introduced model of one-component glass-forming liquids whose constituents interact with anisotropic potential. This system is interesting per-se and as a model of liquids like glycerol (interacting via hydrogen bonds) which are excellent glass formers. We work out the statistical mechanics of this system, encoding the liquid and glass disorder using appropriate quasi-particles (36 of them). The theory provides a full explanation of the glass transition phenomenology, including the identification of a diverging length scale and a relation between the structural changes and the diverging relaxation times.

cond-mat.mtrl-sci↗
arXiv2007

Theory of Relaxation Dynamics in Glass-Forming Hydrogen-Bonded Liquids

We address the relaxation dynamics in hydrogen-bonded super-cooled liquids near the glass transition, measured via Broad-Band Dielectric Spectroscopy (BDS). We propose a theory based on decomposing the relaxation of the macroscopic dipole moment into contributions from hydrogen bonded clusters of $s$ molecules, with $s_{min}\le s \le s_{max}$. The existence of $s_{max}$ is due to dynamical arrest and its value may depend on the cooling protocol and on the aging time. The existence of $s_{max}$ is translated into a sum-rule on the concentrations of clusters of size $s$. We construct the statistical mechanics of the super-cooled liquid subject to this sum-rule as a constraint, to estimate the temperature-dependent density of clusters of size $s$. With a theoretical estimate of the relaxation time of each cluster we provide predictions for the real and imaginary part of the frequency dependent dielectric response. The predicted spectra and their temperature dependence are in accord with measurements, explaining a host of phenomenological fits like the Vogel-Fulcher fit and the stretched exponential fit. Using glycerol as a particular example we demonstrate quantitative correspondence between theory and experiments. The theory also demonstrates that the $α$ peak and the "excess wing" stem from the same physics in this material. The theory also shows that in other hydrogen -bonded glass formers the "excess wing" can develop into a $β$ peak, depending on the molecular material parameters (predominantly the surface energy of the clusters). We thus argue that $α$ and $β$ peaks can stem from the same physics. Finally we address the BDS in constrained geometries (pores) and explain why recent experiments on glycerol did not show a deviation from bul k spectra.

cond-mat.soft↗