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Izaskun Jiménez-Serra

Publications and source records attributed to Izaskun Jiménez-Serra.

At least 19 recordsLinked to original sources

Frontiers of chemical complexity in the interstellar medium: unveiling the cosmic origins of life

The interstellar medium (ISM) contains a rich molecular inventory that provides a unique window into the chemistry operating during star and planet formation and its connection to prebiotic chemistry. More than 350 interstellar molecules are currently known, including increasingly complex organic molecules and species containing elements beyond the second row of the periodic table. Yet the limits that interstellar chemical complexity can reach, its evolution from molecular clouds to planetary systems, and its contribution to the molecular feedstock of life remain poorly constrained. Addressing these questions requires sensitive, broadband observations capable of detecting multiple weak rotational transitions of molecular species, such as amino acids, nucleobases, sugars and lipids, towards star- and planet-forming environments. Current facilities, including ALMA, are limited by instantaneous spectral coverage, sensitivity (especially on extended spatial scales), and the trade-off between total bandwidth and integration time. The proposed ALMA2040 facility would overcome these limitations through at least a tenfold improvement in spectral-line sensitivity, high-fidelity imaging from sub-arcsecond to tens-of-arcsecond scales, and ultra-broad instantaneous frequency coverage from 35 to 950 GHz at high spectral resolution. These capabilities would allow systematic detections of species with molecular abundances with respect to H$_2$ below 10$^{-11}$, facilitating the identification of new complex and heavy-element-bearing species through multiple transitions, and providing complete molecular inventories across evolutionary stages. ALMA2040 would thus make it possible to comprehensively investigate the emergence and evolution of chemical complexity, and to determine whether molecular precursors of prebiotic chemistry are widespread throughout the Galaxy.

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Chemical Demographics of Star-forming Regions

Our understanding of complex organic chemistry during the formation of stars and planets is shaped by a handful of cherry-picked sources with bright molecular emission lines. This observational bias impedes our assessment of how universal chemical complexity is during star formation. The lack of systematic wideband spectral surveys for statistically significant samples of protostars and cores is a major roadblock to properly probing how COM inventories and abundances depend on the vast range of physical conditions, local cloud and global galactic environments, and evolutionary timescales of low- and high-mass star formation. In turn, this limits our ability to constrain and test physicochemical models, which depend critically on these parameters. The next-generation ALMA2040, with a 10x improvement in line sensitivity, is required to observe COMs, that we perceive as common today, in a fraction of the observing time that is needed today with ALMA. Such capabilities will propel us into the era of chemical demographics, whereby wideband (>100 GHz) spectral surveys at high sensitivity (routinely probing COM abundances down to 0.01% relative to CH3OH) will be executed towards >1000-10000 prestellar and protostellar sources. With robust chemical inventories towards large source sample sizes, we will be able to probe for dependencies of chemical complexity on mass regime, feedback processes in a cluster, Galactic position, metallicity, and time-variable accretion. Only with statistically significant samples at high sensitivity will we be able to assess the ubiquity and homogeneity of COM chemistry across the protostellar mass spectrum and natal cores. Constraining the diversity and availability of such species is critical for our understanding of the chemical reservoir available for planet formation, which eventually shapes (exo)planetary atmosphere compositions.

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The complex organic molecular content in the L1517B starless core

Recent observations of the pre-stellar core L1544 and the younger starless core L1498 have revealed that complex organic molecules (COMs) are enhanced in the gas phase toward their outer and intermediate-density shells. Our goal is to determine the level of chemical complexity toward the starless core L1517B, which seems younger than L1498, and compare it with the other two previously studied cores to see if there is a chemical evolution within the cores. We have carried out 3 mm high-sensitivity observations toward two positions in the L1517B starless core: the core's centre and the position where the methanol emission peaks (at a distance of $\sim$5000 au from the core's centre). Our observations reveal that a lower number of COMs and COM precursors are detected in L1517B with respect to L1498 and L1544, and also show lower abundances. Besides methanol, we only detected CH$_3$O, H$_2$CCO, CH$_3$CHO, CH$_3$CN, CH$_3$NC, HCCCN, and HCCNC. Their measured abundances are $\sim$3 times larger toward the methanol peak than toward the core's centre, mimicking the behaviour found toward the more evolved cores L1544 and L1498. We propose that the differences in the chemical complexity observed between the three studied starless cores are a consequence of their evolution, with L1517B being the less evolved one, followed by L1498 and L1544. Chemical complexity in these cores seems to increase over time, with N-bearing molecules forming first and O-bearing COMs forming at a later stage as a result of the catastrophic depletion of CO.

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Inventories of Rich Carbon-Chain Chemistry in Prestellar and Starless Cores in the Perseus Molecular Cloud

Carbon-chain molecules serve as an important reservoir of reactive organic matter that will eventually be incorporated into protoplanetary disks, planets, and cometary material. Prestellar and starless cores are composed of cold (~ 10 K) and dense (~ 10$^5$ cm$^{-3}$) clumps of gas and dust within molecular clouds, and are nurseries for low-mass stars and planetary systems. Surveys of starless cores have focused on the study of complex organic molecules, COMs, whereas observations of carbon-chains in starless cores are limited. We analyze the carbon-chain inventories of 15 prestellar and starless cores in the Perseus Molecular Cloud. Using Yebes 40m single-dish observations, we detect CS, CCS, CCCS, HC$_3$N, DC$_3$N, and HC$_5$N in at least 10/15 cores and HC$_7$N in 4/15 cores. Our study also finds related isotopologues, where $^{13}$CS, C$^{34}$S, C$^{13}$CS, CC$^{34}$S, H$^{13}$CCCN, HC$^{13}$CCN, HCC$^{13}$CN, HC$^{13}$CCCCN, HCC$^{13}$CCCN, HCCC$^{13}$CCN, HCCCCC$^{15}$N, and DCCCCCN are detected. We report detection statistics, compare column density ratios with Taurus, Serpens, and protostar sources, examine DC$_3$N/HC$_3$N deuterium fractionation, and investigate the relative abundances and correlations between cyanopolyyne (HC$_n$N) and sulfur-bearing (C$_n$S) carbon-chains. The diverse suite of species detected reveals the richness of carbon-chain chemistry in Perseus and illustrates how local environmental conditions, such as density, temperature, and proximity to protostellar activity, shape each core's molecular inventory and relative evolutionary phase. Our findings provide a glimpse into the carbon-chain reservoir of starless and prestellar cores in Perseus, which may ultimately be inherited by emerging protoplanetary disks and later integrated into planetary systems and biologically relevant material.

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Thioacetaldehyde (CH3CHS) on interstellar ices: a key molecule to unravel two chemical dichotomies in the ISM

Thioacetaldehyde (CH3CHS), recently detected in TMC-1, has an abundance approximately 36 times lower than its oxygen analog, acetaldehyde (CH3CHO). This makes the CH3CHS/CH3CHO pair the one with the largest column density difference among the detected oxygen/sulfur analogue pairs in this cloud. We investigate the hydrogenation pathways of CH3CHS to address two chemical dichotomies in the ISM: (i) the differenciation between CH3CHS and CH3CHO, and (ii) the apparent absence of both CH3CHS in the G+0.693-0.027 molecular cloud and ethyl mercaptan (CH3CH2SH), in TMC-1. Our results reveal a complex scheme that involves multiple competing reactions, highlighting an efficient sequence of consecutive hydrogenations that can lead to CH3CH2SH. This finding suggests that the high S/O ratio observed for thioacetaldehyde in TMC-1 (~36), and even more pronounced in G+0.693-0.027 ($\geq$112), may result from its conversion via hydrogenation on the ice surface, contrary to the case of CH3CHO, which is more resistant to that chemical process. The straightforward hydrogenation of CH3CHS on ices, which can also take place even in the gas-phase at 150 K, provides a reliable explanation for its non-detection in G+0.693-0.027, where grain-surface chemistry is expected to play an important role, favoring the conversion of CH3CHS into CH3CH2SH, which is indeed detected in G+0.693-0.027. In contrast, TMC-1 represents a more pristine gas-phase environment, where grain-surface chemistry has a lower impact. Under these conditions, CH3CHS can persist, while CH3CH2SH remains undetected. Overall, our results show the entirely different reactivity that contributes to the chemical complexity of two of the largest interstellar sulfur factories.

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ACES VIII: A Survey of Compact, High-Velocity Features Observed in CS(2-1)

The extreme kinematics of the Milky Way's Central Molecular Zone (CMZ) are influenced by processes such as dynamical shearing, cloud collisions, and stellar feedback. These events are visible in molecular data as vertically spiked features in position-velocity (PV) diagrams referred to as high velocity dispersion compact clouds (HVCCs). Using ALMA CMZ Exploration Survey (ACES) CS (2-1) molecular data, we identify a total of 235 HVCC candidates, 163 of which are visually identified, and an additional 72 identified via automated dendrogram methods. For each HVCC we catalog and report the physical and kinematic properties, explore line ratios of the cold dense gas tracer \HNCO with C-shock tracers, classify the morphology of their PV diagrams, and view their position-position-velocity distribution. The sample includes structures which are compact (d<5 pc) and have large velocity extents (20 km/s $<Δ\mathrm{V} <$ 140 km/s), with most structures showing thin, `spiked' PV morphologies. We highlight areas of high ratios between HNCO and C-shock tracers along the edge of known orbital streams, implying a buildup of bar lane gas accreting onto the CMZ. We also find a collection of HVCCs overlapping with the 50 km/s cloud and known circumnuclear disk features. This catalog will be used for future investigation of nuclear inflow and determining dominant mechanisms disrupting average CMZ gas flows.

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ACES VII. Compact Continuum Source Catalog of the Central Molecular Zone

The Central Molecular Zone (CMZ) resides in the inner few hundred parsecs of our Galaxy, and despite being the largest reservoir of dense molecular gas in the Milky Way, it has a relatively low present-day star formation rate (SFR) of $\sim0.08~M_{\odot}~\text{yr}^{-1}$. Continuum and spectral line observations from the Atacama Large Millimeter/submillimeter Array (ALMA) CMZ Exploration Survey (ACES) provide the first full-coverage, high-resolution map of the inner 200 parsecs of the CMZ at 3 mm. In this paper we present the ACES catalog of compact continuum sources, the most complete catalog of potential sites of star formation in the CMZ to date. Using an automated dendrogram-based source extraction procedure in combination with a by-eye morphological classification scheme, we produce a `full' catalog of 1735 detections in total. Additionally, we use spectral index measurements to generate a `filtered' catalog of 567 sources with minimal contamination from non-thermal filaments and extended free-free emission. We find that 359 ($\sim63\%$) of the filtered catalog sources are located at column densities $< 10^{23}$ cm$^{-2}$, outside of the densest molecular cloud regions, 195 of which have not been identified in previous surveys. After cross-referencing with various catalogs generated from data at different wavelengths, we consider it likely that many of these newly discovered detections are produced by pre/protostellar sources or compact HII regions.

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A JWST, ALMA and VLA survey of the Ophiuchus-A star-forming region: Unveiling hidden dust mass and connecting infrared outflows to their radio origins

We present an infrared, millimetre, and radio survey of 20 Class 0-III young stellar objects in the Ophiuchus A L1688 star-forming cluster, combining high-resolution (7-25 au) VLA and JWST observations with archival ALMA data. We implement physically motivated models to derive dust and ionised gas properties, spectral behaviour and their relative contributions through the millimetre-centimetre radio spectral energy distribution. Our models reveal circumstellar dust disks that are, on average, tens to hundreds of times more massive than millimetre-only estimates (subject to uncertainties arising from the choice of dust opacity) and contain millimetre-sized grains even at the Class 0 stage. Owing to the VLA's high resolution we are able to connect outflows to their origins, detecting protostellar jet emission on scales of 10s-1000s au. Our results represent a homogeneous characterisation of the dust and ionised gas properties in Ophiuchus and present a potential solution to the long-standing 'missing disk mass' problem. However, our understanding is still limited by resolution and sensitivity at frequencies <40 GHz. Future facilities like the SKA and ngVLA are needed to provide the necessary capabilities to fully spatially resolve this emission (<0.18") even in one of the closest star-forming regions.

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The Nearest Galactic Nucleus: Studying the Galactic Centre with SKA-Mid

The Galactic Centre is the nearest nucleus of a galaxy and the most extreme environment that we can observe down to physical scales of a few hundred astronomical units. There is no other region in the Milky Way that can match its unique characteristics, such as its stellar density, turbulence and temperature of the interstellar medium, strong large scale magnetic field, concentration of stellar remnants, or mean star formation rate. The Galactic Centre is a unique target to understand the physics of galactic nuclei and study a large number of rare objects, such as extremely massive stars and stellar remnants, at a well-defined distance. The Galactic Centre has been and is being studied intensively with the most advanced facilities. In this chapter, we advocate for a large-area, multi-wavelength continuum survey with the Square Kilometre Array of an area of about 2.0deg x 0.4deg (~290pc x 60pc), centred on the massive black hole Sagittarius A* and for repeated deep observations of the nuclear star cluster over a decade, which will allow the community to address multiple science problems with single dataset.

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Ionized gas emission in protoplanetary disks with the SKAO

Protoplanetary disks represent a crucial stage in the evolution of Young Stellar Objects towards the formation of fully formed planetary systems. While substantial progress has been made in the last decades in the characterization of the dust and molecular gas in these systems, the ionized component remains poorly understood. Ionized gas traces important processes such as photoevaporation, accretion, disk winds, and jets, and therefore is key to studying disk dynamics, evolution, and ultimately planet formation. In this paper, we investigate the capabilities of the forthcoming SKA telescope to probe this component in protoplanetary disks within nearby star forming regions. We present state-of-the-art simulations of photoevaporative, magneto-thermal, and magnetohydrodynamic winds, and generate theoretical predictions and synthetic SKAO observations to assess its potential in detecting and characterizing free-free emission and Hydrogen recombination lines. Finally, we discuss synergies with complementary facilities and how they will provide a comprehensive, multi-scale view of disk winds and offer critical insights on the mechanisms driving disk evolution and the onset of planet formation.

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Substructures in Planet-Forming Disks with the SKAO

Disks of gas and dust orbiting young stars are the arenas and material reservoirs for planet formation. Over the past decade, multiwavelength observations, from infrared to radio, have resolved the spatial distribution of hundreds of protoplanetary disks in nearby star-forming regions, revealing a diverse zoo of substructures. These substructures are morphological features such as rings, gaps, spirals, vortices, asymmetries, warps, or clumps that trace variations in density, temperature, or composition relative to an otherwise smooth distribution of gas and dust. Many unknowns persist as to the origin of these substructures, their role in planet assembly, and their true properties. SKA-Mid Band 5b continuum observations, offering angular resolutions of $\sim 0.05''$ ($\sim 0.15''$) with AA4 (AA*) at $12.5$ GHz / $2.4$ cm, will enable new progress at this frontier. In this chapter, we outline the open questions in the field of disk substructure that SKA-Mid is uniquely poised to address, with a lens on dust thermal emission.

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Chemical Complexity in the Early Stages of Star Formation in the SKAO Era

About 350 molecules have been identified in the interstellar medium (ISM), including complex molecules relevant to prebiotic chemistry. A remarkable level of molecular diversity has been observed from the earliest stages of star formation, providing the initial chemical inventory inherited by planetary systems. Radio observations have played a pivotal role in these discoveries, starting with the identification of the first polyatomic molecule, $\text{NH}_3$ (Cheung et al. 1968). (Sub-)millimeter observations have revealed complex organic molecules of prebiotic relevance, including formamide ($\text{NH}_2\text{CHO}$), glycolaldehyde ($\text{CH}_2\text{OHCHO}$), and even urea ($(\text{NH}_2)_2\text{CO}$), and hydroxylamine ($\text{NH}_2\text{OH}$), which are possible precursors of RNA nucleotides (Ceccarelli et al. 2023; Jiménez-Serra et al. 2020). However, in dense protostellar regions, dust opacity hampers the detection of molecular emission. Additionally, large molecules and those containing heavy atoms, which have rotational transitions at lower frequencies, often remain inaccessible to current instruments. The Square Kilometre Array Observatory (SKAO) will provide an unprecedented combination of sensitivity and angular resolution at radio wavelengths. This will allow for the detection of prebiotic species and offer new insights into the chemical pathways that shape emerging planetary systems (Jiménez-Serra et al. 2022). This chapter details the scientific questions and advancements that the SKAO, and more specifically, SKA-Mid equipped with the Band 5 receivers, will pursue in the field of astrochemistry, focusing on the chemical complexity in both high-mass and solar-type star-forming regions.

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Unveiling Complex Chemistry in Planet-forming Disks with the SKAO

The chemical composition of planets is inherited from that of the natal protoplanetary disk at the time of planet formation. In recent years, we have made huge progress in characterizing disk chemistry. (Sub-)millimeter interferometers, such as ALMA, allowed us to detect emission lines from simple to complex organic molecules and to probe their radial and vertical distribution in disks. On the other hand, JWST has started to unveil the composition of disk ices, and line emission from the innermost disk regions. The advent of SKA will open new domains in the field, by observing emission lines from heavier molecules including heavy carbon chains and rings, and prebiotic molecules with peak emission in the cm range. Moreover, SKA will probe molecular emission from regions which are obscured by dust opacity at mm wavelengths, hence from the disk midplane, and often from the inner 30 au region. These observations will constrain the initial conditions for disk evolution and planet formation, allowing us to predict the chemical composition of the forming planets and their atmospheres. Comparison with forthcoming results on exoplanet atmospheres and on the chemistry of pristine bodies in the Solar System will provide new hints on the origin and evolution of planetary systems including our own.

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Jets and Outflows in Young Stellar Objects with the SKAO

Jets and outflows are ubiquitous phenomena associated with the formation of young stellar objects (YSOs). They play a crucial role in removing angular momentum from the accreting system and in regulating star-formation efficiency. Theoretical studies and observations with ALMA and VLA have shown that jets and winds may have a crucial role in promoting dust growth in the envelope-disc system and in shaping the physical and chemical properties of the surrounding environment. Despite these significant advances, many fundamental questions remain unanswered regarding the acceleration, collimation, and chemical impact of jets and outflows from YSOs. The SKA-project will overcome the limitations of current mm/cm-facilities by enabling high-angular resolution and high-sensitivity cm-observations, crucial for probing jets/outflows near YSOs. Radio recombination lines, combined with proper motions, offer a unique opportunity to study the 3D-kinematics of jets. Non-thermal linearly polarised synchrotron emission will allow measuring magnetic field strength and morphology at unprecedented scales of a few au. Observations of dust emission in outflow cavities will allow studying how dust grows and is eventually transported from the disc to the envelope and back. Finally, the SKA-project will allow exploring the dust composition and chemical enrichment in shocks, where sputtering/shattering of grains cause the release of their mantles and refractory cores in the gas-phase. Complementary to ALMA's detection of simple and complex organic molecules, the SKAO will probe, for the first time, long carbon chains/rings, several Cl-, Al-, Mg-, and other metal-bearing species (missed by current sub-mm facilities).

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ALMA Central molecular zone Exploration Survey (ACES) VI: ALMA Large Program Reveals a Highly Filamentary Central Molecular Zone

The Central Molecular Zone (CMZ) of the Milky Way is the way station that primarily controls how much gas flows from the disk of the Galaxy towards the central nucleus. While this region is well documented to have extreme gas properties that clearly distinguish it from the rest of the Galaxy, the properties of the bulk molecular gas at high angular resolution are relatively unexplored. Band 3 data from the ALMA (Atacama Large Millimeter/Submillimeter Array) large program ACES (ALMA CMZ Exploration Survey) reveal the highly filamentary nature of CMZ molecular gas at high resolution (3" or 0.1pc) across the entire CMZ. Visual inspection of these data suggests that there are at least two general classes of elongated structures, which we identify as: i) large-scale (10 pc) filamentary structures (LFs) and ii) a ubiquitous population of small-scale (about 1 pc) filamentary structures (SFs). We present detailed morphological and kinematic properties towards three structures in each category, as well as their association with magnetic fields and the correlation of HNCO 4(0,4)-3(0,3) with other molecular species. Our investigation reveals that these structures are largely coherent in position-position-velocity space. The alignment with the magnetic field structure is mixed, with some parallel, some perpendicular, and some intermediate alignments. We find that LFs likely trace pieces of contiguous CMZ orbital structures and are a manifestation of global CMZ dynamics. The second class, SFs, are pervasive and may be the result of complicated turbulence and shearing dynamics in the CMZ gas flows, as seen in numerical simulations.

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A fast machine learning tool to predict the composition of astronomical ices from infrared absorption spectra

Current observations taken by James Webb Space Telescope (JWST) allow us to observe the absorption features of icy mantles that cover interstellar dust grains, which are mainly composed of $\mathrm{H_2O}$, $\mathrm{CO}$, and $\mathrm{CO_2}$, along with other minor species. Thanks to its sensitivity and spectral resolution, JWST has the potential to observe ice features towards hundreds of sources at different stages along the process of star formation. However, identifying the spectral features of the different species and quantifying the ice composition is not trivial and requires complex spectroscopic analysis. We present Automatic Ice Composition Estimator (AICE), a new tool based on artificial neural networks. Based on the infrared (IR) ice absorption spectrum between 2.5 and 10 microns, AICE predicts the ice fractional composition in terms of $\mathrm{H_2O}$, $\mathrm{CO}$, $\mathrm{CO_2}$, $\mathrm{CH_3OH}$, $\mathrm{NH_3}$, and $\mathrm{CH_4}$. To train the model, we used hundreds of laboratory experiments of ice mixtures from different databases, which were reprocessed with baseline subtraction and normalisation. Once trained, AICE takes less than one second on a conventional computer to predict the ice composition associated with the observed IR absorption spectrum, with typical errors of $\sim$3 $\%$ in the species fraction. We tested its performance on two spectra reported towards the NIR38 and J110621 background stars observed within the JWST Ice Age program, demonstrating a good agreement with previous estimations of the ice composition. The fast and accurate performance of AICE enables the systematic analysis of hundreds of different ice spectra with a modest time investment. In addition, this model can be enhanced and re-trained with more laboratory data, improving the precision of the predictions and expanding the list of predicted species.

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ALMA Central molecular zone Exploration Survey (ACES) V: CS(2-1), SO(2_3-1_2), CH3CHO(5_1,4-4_1,3), HC3N(11-10), and H40a lines data

We present data from the ALMA Central Molecular Zone Exploration Survey (ACES) Large Program, which provides broad spectral-line and 3 mm continuum coverage of the Central Molecular Zone (CMZ) at a spatial resolution of 0.1 pc. The survey delivers homogeneous, wide-field mosaics that enable direct comparisons of the physical and chemical conditions across diverse environments in the Galactic center. In this data release paper, we present the CS(2-1), SO(2_3-1_2), CH3CHO(5_1,4-4_1,3), HC3N(11-10), and H40a lines observed simultaneously within two broad spectral windows. These lines reveal pronounced spatial and chemical variations across the CMZ, tracing distinct components of molecular gas, shock-affected regions, and ionized structures. The high angular resolution and multi-line capability of the ACES dataset make it a powerful resource for future studies of gas dynamics, star formation activity, and the physical connection between the CMZ and Sgr A*.

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ALMA Central Molecular Zone Exploration Survey (ACES) II: 3mm continuum images

The ALMA Central Molecular Zone Exploration Survey, ACES, has mapped $\gtrsim1000$ square arcminutes at 3 mm toward the center of our Galaxy. ACES provides the first large-scale, high-resolution ($\sim2.5$") view of the central $\sim200$ parsecs of the Milky Way. In this work, we describe the continuum data processing and present the continuum data products. In the combined mosaic of 45 individual ALMA mosaics, the typical RMS noise achieved is $\sim0.1$ mJy per $\sim2.5$" beam, though there is a tail of substantially higher noise toward regions with bright continuum structure, especially around Sgr A* and Sgr B2. In-band spectral indices are measurable for a small fraction of the brightest and most compact sources, enabling distinction between dust-dominated and free-free- or synchrotron-dominated sources. To recover emission on large angular scales, we present the GBT MUSTANG-2 Three millimeter Extended Nucleus Survey (TENS), a new 10"resolution survey of the CMZ, which we combine with the ACES image by feathering. To demonstrate the quality and reliability of the ACES data, we compare to previously-published ALMA data obtained with higher resolution and sensitivity, finding overall good agreement with past results, but some disagreement toward the brightest sources.

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