arXiv subjects

Jérémy Chastenet

Publications and source records attributed to Jérémy Chastenet.

At least 19 recordsLinked to original sources

arXiv2026

Growth of Aromatic Hydrocarbon Dust Particles in the Extremely Metal-poor Galaxy Sextans A

The mid-infrared spectrum of star-forming, high metallicity galaxies is dominated by emission features from aromatic and aliphatic bonds in small carbonaceous dust grains, often referred to as polycyclic aromatic hydrocarbons (PAHs). In metal-poor galaxies, the abundance of PAHs relative to the total dust sharply declines, but the origin of this deficit is unknown. We present JWST observations that detect and resolve emission from PAHs in the 7% Solar metallicity galaxy Sextans A, representing the lowest metallicity detection of PAH emission to date. In contrast to higher metallicity galaxies, the clumps of PAH emission are compact (0.5-1.5$''$ or 3-10 pc), which explains why PAH emission evaded detection by lower resolution instruments. Ratios between the 3.3, 7.7, and 11.3 $μ$m PAH features indicate that the PAH grains in Sextans A are small and neutral, with no evidence of significant processing from radiation fields. These results favor inhibited grain growth over enhanced destruction as the origin of the low PAH abundance in Sextans A. The compact clumps of PAH emission are likely active sites of in-situ PAH growth within a dense, well-shielded phase of the interstellar medium. Our results show that PAHs can form and survive in extremely metal-poor environments common early in the evolution of the Universe.

astro-ph.GA↗

arXiv2026

Variations in the 3.3 $μ$m Polycyclic Aromatic Hydrocarbon Feature Across Nearby Galaxies Driven by Metallicity and Radiation Field Spectrum

We use JWST NIRCam imaging to investigate the 3.3 $μ$m polycyclic aromatic hydrocarbon (PAH) feature in nearby galaxies. NIRCam observations of the 3.3 $μ$m feature are emerging as a powerful tool for studying the structure of the interstellar medium (ISM) and the conditions of the dust at ~0".1 resolution. These maps require accurate subtraction of the underlying continuum emission. We present an empirical method to isolate the PAH-correlated emission in the F335M filter using the F300M and F360M filters for continuum subtraction. We find that the slope of the F335M/F300M versus F360M/F300M colors for PAH-correlated emission shows a dependence on local ISM properties, with the strongest dependence on specific star formation rate. Weaker emission features captured by these bands appear suppressed relative to the main 3.3 $μ$m feature in regions of active star formation. We find trends in the 3.3/7.7 and 3.3/11.3 $μ$m ratios that suggest changes in PAH size, charge, and heating by a varying radiation field spectrum. We find decreases in both band ratios with increasing metallicity, which we attribute to a shift to smaller PAH populations at low metallicity. Comparison to optical ionized gas line ratios and dust models show that variations in the interstellar radiation field spectrum influence the PAH feature ratios. This analysis supports inhibited growth formation scenarios for the observed PAH band ratio trends with metallicity and emphasizes the importance of considering the local radiation field characteristics and gas-phase metallicity when using these band ratios as PAH property diagnostics.

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arXiv2026

Survival of very small carbonaceous dust grains in the inner-CGM of NGC 891 from JWST/MIRI MRS

We present new spectroscopic observations of the inner circumgalactic medium (CGM) of NGC 891 taken with the Mid-Infrared Imager/Medium Resolution Spectroscopy instrument onboard JWST, in four positions: two near the bulge and two at galactocentric radii (r) of ~ 1.5, 4.7 kpc. Each pair of pointings has one position along the minor axis (h) at ~ 0.5 kpc and one at ~ 1 kpc away from the mid-plane. We analyse both 1D spectra and 3D cubes using the dust emission model PAHFIT to extract properties of typical mid-IR features. These spectra reveal that the earlier reported mid-IR emission out to 4 kpc is dominated by the emission of polycyclic aromatic hydrocarbons (PAHs), and not hot dust continuum, providing direct evidence of the survival of PAHs in the inner CGM of NGC 891. Comparing PAH band ratios with other environments (Orion, M51), it is obvious that the 11.2 $μ$m PAH feature -- and not the usual 7.7 $μ$m -- dominates in NGC 891, which seems to imply the presence of more neutral, large PAHs in the CGM. Overall, PAH-to-continuum ratios show little variations with scale-height and radius in NGC 891, which suggests little PAH processing. However, we do see a decrease in the PAH feature strengths with the [Ne III]/[Ne II] ratio, pointing at elevated dust processing with increased radiation field hardness. We also confirm a tight correlation between H2 and PAH features, suggesting that both tracers must be co-spatial and, hence, implying that PAH emission predominantly arises from cool dense parts of cloudlets entrained in galactic outflows. Finally, we report the clear detection of a previously unidentified PAH feature at 16.72 $μ$m.

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arXiv2025

Polycyclic aromatic hydrocarbons destruction in star-forming regions across 42 nearby galaxies

Polycyclic aromatic hydrocarbons (PAHs) are widespread in the interstellar medium (ISM) of Solar metallicity galaxies, where they play a critical role in ISM heating, cooling, and reprocessing stellar radiation. The PAH fraction, the abundance of PAHs relative to total dust mass, is a key parameter in ISM physics. Using JWST and MUSE observations of 42 galaxies from the PHANGS survey, we analyze the PAH fraction in over 17 000 H II regions spanning a gas-phase oxygen abundance of 12+log(O/H) = 8.0-8.8 (Z ~ 0.2-1.3 Zsun), and ~400 isolated supernova remnants (SNRs). We find a significantly lower PAH fraction toward H II regions compared to a reference sample of diffuse ISM areas at matched metallicity. At 12+log(O/H) > 8.2, the PAH fraction toward H II regions is strongly anti-correlated with the local ionization parameter, suggesting that PAH destruction is correlated with ionized gas and/or hydrogen-ionizing UV radiation. At lower metallicities, the PAH fraction declines steeply in both H II regions and the diffuse ISM, likely reflecting less efficient PAH formation in metal-poor environments. Carefully isolating dust emission from the vicinity of optically-identified supernova remnants, we see evidence for selective PAH destruction from measurements of lower PAH fractions, which is, however, indistinguishable at ~50 pc scales. Overall, our results point to ionizing radiation as the dominant agent of PAH destruction within H II regions, with metallicity playing a key role in their global abundance in galaxies.

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arXiv2025

Characterization of Two Cool Galaxy Outflow Candidates Using Mid-Infrared Emission from Polycyclic Aromatic Hydrocarbons

We characterize two candidate cool galactic outflows in two relatively low mass, highly inclined Virgo cluster galaxies: NGC4424 and NGC4694. Previous analyses of observations using the Atacama Large Millimeter Array (ALMA) carbon monoxide (CO) line emission maps did not classify these sources as cool outflow hosts. Using new high sensitivity, high spatial resolution, JWST mid-infrared photometry in the polycyclic aromatic hydrocarbon (PAH)-tracing F770W band, we identify extended structures present off of the stellar disk. The identified structures are bright in the MIRI F770W and F2100W bands, suggesting they include PAHs as well as other dust grains. As PAHs have been shown to be destroyed in hot, ionized gas, these structures are likely to be outflows of cool (T$\leq 10^4$K) gas. This work represents an exciting possibility for using mid infrared observations to identify and measure outflows in lower mass, lower star formation galaxies.

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arXiv2025

The radial variation of the silicate-to-carbon ratio in M31 probed by PRIMA

The properties of interstellar dust grains are being scrutinized more than ever before, with the advent of large facilities. Infrared emission from dust grains is a powerful asset than can help constrain their physical and chemical properties. Among these, the relative ratio of carbon-rich to silicate-rich grains remains one that has not yet been investigated thoroughly, due to the lack of dedicated instruments and modeling limitations. In this paper, we quantify the modeling degeneracies inherent to constraining the far-infrared (far-IR) slope of the dust emission spectral energy distribution. Used as a proxy for the silicate-to-carbon ratio, we find that recovering the far-IR slope is affected by the estimate of the local radiation field, and the input abundances of different grain species. We show that PRIMA's Hyperspectral Imaging will lead to better constrained local radiation fields which will aid -- together with PRIMA's polarization capabilities -- to better constrain the silicate-to-carbon ratio in M31, and how it spatially varies within the galaxy.

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arXiv2025

The PRIMA promise of deciphering interstellar dust evolution with observations of the nearby Universe

This paper develops a few science cases, using the PRIMA far-IR probe, aimed at achieving several breakthroughs in our understanding of the dust properties and their evolution. We argue that the specific observational capabilities of PRIMA, namely its unprecedented sensitivity over the whole far-IR range and the possibility to obtain continuous spectra between wavelengths 24 and 235 microns, are essential to progress in our understanding of the physics of the interstellar medium and galaxy evolution. Our science cases revolve around observations of nearby galaxies. We discuss the importance of detecting the IR emission of the diffuse interstellar medium of these galaxies, including very low-metallicity systems. We also discuss the opportunity of detecting various solid-state features to understand the mineralogy of interstellar grains. Finally, we stress the unique opportunity brought by the possible simultaneous measures of both the dust continuum and the far-IR fine-structure gas lines. These science cases could be distributed in a few large programs.

astro-ph.IM↗

arXiv2025

Relationships between PAHs, Small Dust Grains, H$_2$, and HI in Local Group Dwarf Galaxies NGC 6822 and WLM Using JWST, ALMA, and the VLA

We present 0.7-3.3 pc resolution mid-infrared (MIR) JWST images at 7.7 $μ$m (F770W) and 21 $μ$m (F2100W) covering the main star-forming regions of two of the closest star-forming low-metallicity dwarf galaxies, NGC6822 and Wolf-Lundmark-Melotte (WLM). The images of NGC6822 reveal filaments, edge-brightened bubbles, diffuse emission, and a plethora of point sources. By contrast, most of the MIR emission in WLM is point-like, with a small amount of extended emission. Compared to solar metallicity galaxies, the ratio of 7.7 $μ$m intensity ($I_ν^{F770W}$), tracing polycyclic aromatic hydrocarbons (PAHs), to 21 $μ$m intensity ($I_ν^{F2100W}$), tracing small, warm dust grain emission, is suppressed in these low-metallicity dwarfs. Using ALMA CO(2-1) observations, we find that detected CO intensity versus $I_ν^{F770W}$ at ~2 pc resolution in dwarfs follows a similar relationship to that at solar metallicity and lower resolution, while the CO versus $I_ν^{F2100W}$ relationship in dwarfs lies significantly below that derived from solar metallicity galaxies at lower resolution, suggesting more pronounced destruction of CO molecules at low metallicity. Finally, adding in Local Group L-Band Survey VLA 21 cm HI observations, we find that $I_ν^{F2100W}$ and $I_ν^{F770W}$ vs. total gas ratios are suppressed in NGC6822 and WLM compared to solar metallicity galaxies. In agreement with dust models, the level of suppression appears to be at least partly accounted for by the reduced galaxy-averaged dust-to-gas and PAH-to-dust mass ratios in the dwarfs. Remaining differences are likely due to spatial variations in dust model parameters, which should be an exciting direction for future work in local dwarf galaxies.

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arXiv2025

PAH Feature Ratios Around Stellar Clusters and Associations in 19 Nearby Galaxies

We present a comparison of observed polycyclic aromatic hydrocarbon (PAH) feature ratios in 19 nearby galaxies with a grid of theoretical expectations for near- and mid-infrared dust emission. The PAH feature ratios are drawn from Cycle 1 JWST observations and are measured for 7224 stellar clusters and 29176 stellar associations for which we have robust ages and mass estimates from HST five-band photometry. Though there are galaxy-to-galaxy variations, the observed PAH feature ratios largely agree with the theoretical models, particularly those that are skewed toward more ionized and larger PAH size distributions. For each galaxy we also extract PAH feature ratios for 200 pc-wide circular regions in the diffuse interstellar medium, which serve as a non-cluster/association control sample. Compared to what we find for stellar clusters and associations, the 3.3um/7.7um and 3.3um/11.3um ratios from the diffuse interstellar medium are $\sim 0.10-0.15$ dex smaller. When the observed PAH feature ratios are compared to the radiation field hardness as probed by the [OIII]/H$β$ ratio, we find anti-correlations for nearly all galaxies in the sample. These results together suggest that the PAH feature ratios are driven by the shape intensity of the radiation field, and that the smallest PAHs -- observed via JWST F335M imaging -- are increasingly 'processed' or destroyed in regions with the most intense and hard radiation fields.

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arXiv2024

The Resolved Behavior of Dust Mass, Polycyclic Aromatic Hydrocarbon Fraction, and Radiation Field in ~ 800 Nearby Galaxies

We present resolved $3.6-250~μ$m dust spectral energy distribution (SED) fitting for $\sim 800$ nearby galaxies. We measure the distribution of radiation field intensities heating the dust, the dust mass surface density ($Σ_{\rm d}$), and the fraction of dust in the form of polycyclic aromatic hydrocarbons (PAHs; $q_{\rm PAH}$). We find that the average interstellar radiation field ($\overline{U}$) is correlated both with stellar mass surface density ($Σ_{\star}$) and star formation rate surface density ($Σ_{\rm SFR}$), while more intense radiation fields are only correlated with $Σ_{\rm SFR}$. We show that $q_{\rm PAH}$ is a steeply decreasing function of $Σ_{\rm SFR}$, likely reflecting PAH destruction in H II regions. Galaxy integrated $q_{\rm PAH}$ is strongly, negatively correlated with specific star formation rate (sSFR) and offset from the star-forming ``main sequence'' ($Δ$MS), suggesting that both metallicity and star formation intensity play a role in setting the global $q_{\rm PAH}$. We also find a nearly constant M$_{\rm d}$/M$_\star$ ratio for galaxies on the main sequence, with a lower ratio for more quiescent galaxies, likely due to their lower gas fractions. From these results, we construct prescriptions to estimate the radiation field distribution in both integrated and resolved galaxies. We test these prescriptions by comparing our predicted $\overline{U}$ to results of SED fitting for stacked "main sequence" galaxies at $0<z<4$ from Béthermin et al. (2015) and find sSFR is an accurate predictor of $\overline{U}$ even at these high redshifts. Finally, we describe the public delivery of matched-resolution WISE and Herschel maps along with the resolved dust SED fitting results through the InfraRed Science Archive (IRSA).

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arXiv2024

PHANGS-ML: the universal relation between PAH band and optical line ratios across nearby star-forming galaxies

The structure and chemistry of the dusty interstellar medium (ISM) are shaped by complex processes that depend on the local radiation field, gas composition, and dust grain properties. Of particular importance are Polycyclic Aromatic Hydrocarbons (PAHs), which emit strong vibrational bands in the mid-infrared, and play a key role in the ISM energy balance. We recently identified global correlations between PAH band and optical line ratios across three nearby galaxies, suggesting a connection between PAH heating and gas ionization throughout the ISM. In this work, we perform a census of the PAH heating -- gas ionization connection using $\sim$700,000 independent pixels that probe scales of 40--150 pc in nineteen nearby star-forming galaxies from the PHANGS survey. We find a universal relation between $\log$PAH(11.3 \mic/7.7 \mic) and $\log$([SII]/H$α$) with a slope of $\sim$0.2 and a scatter of $\sim$0.025 dex. The only exception is a group of anomalous pixels that show unusually high (11.3 \mic/7.7 \mic) PAH ratios in regions with old stellar populations and high starlight-to-dust emission ratios. Their mid-infrared spectra resemble those of elliptical galaxies. AGN hosts show modestly steeper slopes, with a $\sim$10\% increase in PAH(11.3 \mic/7.7 \mic) in the diffuse gas on kpc scales. This universal relation implies an emerging simplicity in the complex ISM, with a sequence that is driven by a single varying property: the spectral shape of the interstellar radiation field. This suggests that other properties, such as gas-phase abundances, gas ionization parameter, and grain charge distribution, are relatively uniform in all but specific cases.

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arXiv2024

JWST MIRI and NIRCam observations of NGC 891 and its circumgalactic medium

We present new JWST observations of the nearby, prototypical edge-on, spiral galaxy NGC 891. The northern half of the disk was observed with NIRCam in its F150W and F277W filters. Absorption is clearly visible in the mid-plane of the F150W image, along with vertical dusty plumes that closely resemble the ones seen in the optical. A $\sim 10 \times 3~{\rm kpc}^2$ area of the lower circumgalactic medium (CGM) was mapped with MIRI F770W at 12 pc scales. Thanks to the sensitivity and resolution of JWST, we detect dust emission out to $\sim 4$ kpc from the disk, in the form of filaments, arcs, and super-bubbles. Some of these filaments can be traced back to regions with recent star formation activity, suggesting that feedback-driven galactic winds play an important role in regulating baryonic cycling. The presence of dust at these altitudes raises questions about the transport mechanisms at play and suggests that small dust grains are able to survive for several tens of million years after having been ejected by galactic winds in the disk-halo interface. We lay out several scenarios that could explain this emission: dust grains may be shielded in the outer layers of cool dense clouds expelled from the galaxy disk, and/or the emission comes from the mixing layers around these cool clumps where material from the hot gas is able to cool down and mix with these cool cloudlets. This first set of data and upcoming spectroscopy will be very helpful to understand the survival of dust grains in energetic environments, and their contribution to recycling baryonic material in the mid-plane of galaxies.

astro-ph.GA↗

arXiv2024

The Fraction of Dust Mass in the Form of PAHs on 10-50 pc Scales in Nearby Galaxies

Polycyclic aromatic hydrocarbons (PAHs) are a ubiquitous component of the interstellar medium (ISM) in z~0 massive, star-forming galaxies and play key roles in ISM energy balance, chemistry, and shielding. Wide field of view, high resolution mid-infrared (MIR) images from JWST provides the ability to map the fraction of dust in the form of PAHs and the properties of these key dust grains at 10-50 pc resolution in galaxies outside the Local Group. We use MIR JWST photometric observations of a sample of 19 nearby galaxies from the "Physics at High Angular Resolution in Nearby GalaxieS" (PHANGS) survey to investigate the variations of the PAH fraction. By comparison to lower resolution far-IR mapping, we show that a combination of the MIRI filters (R$_{\rm{PAH}}$ = [F770W+F1130W]/F2100W) traces the fraction of dust by mass in the form of PAHs (i.e., the PAH fraction, or q$_{\rm{PAH}}$). Mapping R$_{\rm{PAH}}$ across the 19 PHANGS galaxies, we find that the PAH fraction steeply decreases in HII regions, revealing the destruction of these small grains in regions of ionized gas. Outside HII regions, we find R$_{\rm{PAH}}$ is constant across the PHANGS sample with an average value of 3.43$\pm$0.98, which, for an illuminating radiation field of intensity 2-5 times that of the radiation field in the solar neighborhood, corresponds to q$_{\rm{PAH}}$ values of 3-6%.

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arXiv2024

PHANGS-JWST: Data Processing Pipeline and First Full Public Data Release

The exquisite angular resolution and sensitivity of JWST is opening a new window for our understanding of the Universe. In nearby galaxies, JWST observations are revolutionizing our understanding of the first phases of star formation and the dusty interstellar medium. Nineteen local galaxies spanning a range of properties and morphologies across the star-forming main sequence have been observed as part of the PHANGS-JWST Cycle 1 Treasury program at spatial scales of $\sim$5-50pc. Here, we describe pjpipe, an image processing pipeline developed for the PHANGS-JWST program that wraps around and extends the official JWST pipeline. We release this pipeline to the community as it contains a number of tools generally useful for JWST NIRCam and MIRI observations. Particularly for extended sources, pjpipe products provide significant improvements over mosaics from the MAST archive in terms of removing instrumental noise in NIRCam data, background flux matching, and calibration of relative and absolute astrometry. We show that slightly smoothing F2100W MIRI data to 0.9" (degrading the resolution by about 30 percent) reduces the noise by a factor of $\approx$3. We also present the first public release (DR1.1.0) of the pjpipe processed eight-band 2-21 $μ$m imaging for all nineteen galaxies in the PHANGS-JWST Cycle 1 Treasury program. An additional 55 galaxies will soon follow from a new PHANGS-JWST Cycle 2 Treasury program.

astro-ph.GA↗

arXiv2024

PHANGS-ML: dissecting multiphase gas and dust in nearby galaxies using machine learning

The PHANGS survey uses ALMA, HST, VLT, and JWST to obtain an unprecedented high-resolution view of nearby galaxies, covering millions of spatially independent regions. The high dimensionality of such a diverse multi-wavelength dataset makes it challenging to identify new trends, particularly when they connect observables from different wavelengths. Here we use unsupervised machine learning algorithms to mine this information-rich dataset to identify novel patterns. We focus on three of the PHANGS-JWST galaxies, for which we extract properties pertaining to their stellar populations; warm ionized and cold molecular gas; and Polycyclic Aromatic Hydrocarbons (PAHs), as measured over 150 pc-scale regions. We show that we can divide the regions into groups with distinct multiphase gas and PAH properties. In the process, we identify previously-unknown galaxy-wide correlations between PAH band and optical line ratios and use our identified groups to interpret them. The correlations we measure can be naturally explained in a scenario where the PAHs and the ionized gas are exposed to different parts of the same radiation field that varies spatially across the galaxies. This scenario has several implications for nearby galaxies: (i) The uniform PAH ionized fraction on 150 pc scales suggests significant self-regulation in the ISM, (ii) the PAH 11.3/7.7 \mic~ band ratio may be used to constrain the shape of the non-ionizing far-ultraviolet to optical part of the radiation field, and (iii) the varying radiation field affects line ratios that are commonly used as PAH size diagnostics. Neglecting this effect leads to incorrect or biased PAH sizes.

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arXiv2023

Calibrating mid-infrared emission as a tracer of obscured star formation on HII-region scales in the era of JWST

Measurements of the star formation activity on cloud scales are fundamental to uncovering the physics of the molecular cloud, star formation, and stellar feedback cycle in galaxies. Infrared (IR) emission from small dust grains and polycyclic aromatic hydrocarbons (PAHs) are widely used to trace the obscured component of star formation. However, the relation between these emission features and dust attenuation is complicated by the combined effects of dust heating from old stellar populations and an uncertain dust geometry with respect to heating sources. We use images obtained with NIRCam and MIRI as part of the PHANGS--JWST survey to calibrate dust emission at 21$\rm μm$, and the emission in the PAH-tracing bands at 3.3, 7.7, 10, and 11.3$\rm μm$ as tracers of obscured star formation. We analyse $\sim$ 20000 optically selected HII regions across 19 nearby star-forming galaxies, and benchmark their IR emission against dust attenuation measured from the Balmer decrement. We model the extinction-corrected H$α$ flux as the sum of the observed H$α$ emission and a term proportional to the IR emission, with $a_{IR}$ as the proportionality coefficient. A constant $a_{IR}$ leads to extinction-corrected H$α$ estimates which agree with those obtained with the Balmer decrement with a scatter of $\sim$ 0.1 dex for all bands considered. Among these bands, 21$\rm μm$ emission is demonstrated to be the best tracer of dust attenuation. The PAH-tracing bands underestimate the correction for bright HII regions, since in these environments the ratio of PAH-tracing bands to 21$\rm μm$ decreases, signalling destruction of the PAH molecules. For fainter HII regions all bands suffer from an increasing contamination from the diffuse infrared background.

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arXiv2023

Far-infrared Polarization of the Supernova Remnant Cassiopeia A with SOFIA HAWC+

We present polarization observations of the young supernova remnant (SNR) Cas A using the High-resolution Airborne Wideband Camera-Plus (HAWC+) instrument onboard the Stratospheric Observatory for Infrared Astronomy (SOFIA). The polarization map at 154 microns reveals dust grains with strong polarization fractions (5 - 30 percent), supporting previous measurements made over a smaller region of the remnant at 850 microns. The 154 microns emission and the polarization signal is coincident with a region of cold dust observed in the southeastern shell and in the unshocked central ejecta. The highly polarized far-IR emission implies the grains are large (greater than 0.14 microns) and silicate-dominated. The polarization level varies across the SNR, with an inverse correlation between the polarization degree and the intensity and smaller polarization angle dispersion for brighter SNR emission. Stronger polarization is detected between the bright structures. This may result from a higher collision rate between the gas and dust producing a lower grain alignment efficiency where the gas density is higher. We use the dust emission to provide an estimate of the magnetic field strength in Cas A using the Davis-Chandrasekhar-Fermi method. The high polarization level is direct evidence that grains are highly elongated and strongly aligned with the magnetic field of the SNR. The dust mass from the polarized region is 0.14+-0.04 Msun, a lower limit of the amount of dust present within the ejecta of Cas A. This result strengthens the hypothesis that core-collapse SNe are an important contributor to the dust mass in high redshift galaxies.

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arXiv2023

Wide-field CO isotopologue emission and the CO-to-H$_2$ factor across the nearby spiral galaxy M101

Carbon monoxide (CO) emission is the most widely used tracer of the bulk molecular gas in the interstellar medium (ISM) in extragalactic studies. The CO-to-H$_2$ conversion factor, $α_{\rm CO}$, links the observed CO emission to the total molecular gas mass. However, no single prescription perfectly describes the variation of $α_{\rm CO}$ across all environments across galaxies as a function of metallicity, molecular gas opacity, line excitation, and other factors. Using resolved spectral line observations of CO and its isotopologues, we can constrain the molecular gas conditions and link them to a variation in the conversion factor. We present new IRAM 30-m 1mm and 3mm line observations of $^{12}$CO, $^{13}$CO, and C$^{18}$O} across the nearby galaxy M101. Based on the CO isotopologue line ratios, we find that selective nucleosynthesis and opacity changes are the main drivers of the variation in the line emission across the galaxy. Furthermore, we estimated $α_{\rm CO(1-0)}$ using different approaches, including (i) the dust mass surface density derived from far-IR emission as an independent tracer of the total gas surface density and (ii) LTE-based measurements using the optically thin $^{13}$CO(1-0) intensity. We find an average value of $α_{\rm CO}=4.4{\pm}0.9\rm\,M_\odot\,pc^{-2}(K\,km\,s^{-1})^{-1}$ across the galaxy, with a decrease by a factor of 10 toward the 2 kpc central region. In contrast, we find LTE-based values are lower by a factor of 2-3 across the disk relative to the dust-based result. Accounting for $α_{\rm CO}$ variations, we found significantly reduced molecular gas depletion time by a factor 10 in the galaxy's center. In conclusion, our result suggests implications for commonly derived scaling relations, such as an underestimation of the slope of the Kennicutt Schmidt law, if $α_{\rm CO}$ variations are not accounted for.

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