arXiv subjects

Jörg Wrachtrup

Publications and source records attributed to Jörg Wrachtrup.

At least 19 recordsLinked to original sources

arXiv2026

Scalable integration of silicon carbide color centers into nanophotonic structures

Color centers in silicon carbide are a promising platform for quantum technologies, offering long-coherence electron and nuclear spins for storing and manipulating quantum information, as well as single-photon emission for quantum communication. Low photon collection efficiency is commonly addressed by integrating color centers into nanophotonic devices. Here, we report a scalable method for the deterministic integration of color centers into silicon carbide nanopillars, using the same nanoscale mask for both implantation of oxygen-related color centers (PL5, PL6) and subsequent nanopillar fabrication via dry etching. This approach solves the issue of low color center creation yield in nanostructures, with figures of merit comparable to bulk samples. We demonstrate count rate enhancements of up to one order of magnitude for PL5 and four times for PL6, while preserving spin coherence times. Our method is directly applicable to other solid-state platforms, offering a scalable route to efficiently integrate color centers into nanostructures.

quant-ph↗

arXiv2026

Electrostatic Stabilization of Near-Surface Quantum Sensors via Dielectric Interface Engineering

Control of charge-state stability in near-surface quantum defects is critical for nanoscale sensing, yet remains particularly challenging under ultra-high vacuum (UHV), where surface-induced band bending destabilizes the metrologically relevant charge-state. Here, we present a robust and reproducible approach for stabilizing shallowly implanted (< 10 nm deep) nitrogen-vacancy (NV) centers in near-UHV conditions (P = $3 \times 10^{-9}$ mbar) based on dielectric interface engineering. Through measurements on individually addressable NV centers, we demonstrate that a TiO2 coating on the diamond suppresses surface-induced electrostatic fields, yielding a 79% increase n NV- population and a 45% enhancement in NV-spin resonance contrast at room temperature. Coherent control measurements further reveal suppressed charge-state conversion dynamics. These results establish dielectric screening as a powerful and reproducible strategy to engineer charge transition energetics of NV centers in scanning-probe-compatible geometries under extreme conditions.

quant-ph↗

arXiv2026

Revealing and reducing growth-induced interfacial disorder in preferentially aligned nitrogen-vacancy centers in diamond

Nitrogen-vacancy (NV) centers in chemical-vapor-deposition (CVD) diamond can form preferentially oriented ensembles with high sensing performance and low densities of lattice defects. Thin films of this material are a cornerstone of various imaging modalities. However, nitrogen injection needed to produce such films can transiently drive growth out of equilibrium, generating interfacial strain and spin defects that degrade NV coherence. Here, we investigate this disorder in $^{12}\text{C}$-enriched, preferentially oriented NV layers grown on (111) diamond using two nitrogen-injection procedures, combined with nanometer-scale selective plasma etching and NV spin-coherence measurements. Pulsed nitrogen injection produces a pronounced nitrogen overshoot within a 60--80 nm interfacial region, generating excessive amounts of defects. By contrast, smooth nitrogen delivery through mass flow controllers substantially suppresses interfacial disorder, yielding coherence properties close to the theoretical limit imposed by spin-bath noise. A 50-nm NV layer is used to demonstrate proton nuclear magnetic resonance detection. This work reveals the role of interfacial disorder associated with the nitrogen-doping procedure and provides a route to growing high-quality, thin NV-doped layers for quantum-sensing applications.

quant-ph↗

arXiv2026

High-cooperativity coupling and spin-resolved extinction of tin-vacancy centers in a diamond-like microcavity

The tin-vacancy (SnV) center in diamond is a promising spin-photon interface for quantum networks, combining favorable optical properties with spin coherence above 1K. Unfolding the full potential requires cavity enhancement to increase photon-emitter coupling efficiency. Here, we demonstrate cavity-enhanced light-matter coupling of SnV centers in a fully tunable Fabry-Pérot microcavity operating at temperatures down to 1K with in-situ magnetic field control. We access the diamond-like regime of hybrid cavity modes through integration of low-roughness diamond membranes, where the field is concentrated inside the diamond and Purcell enhancement is maximized. Diamond-like modes deliver a more than two-fold increase in the effective Purcell factor over air-like modes, reaching $C_0 = 4.1(1)$ compared to $C_0 = 1.85(5)$ in the air-like case, while simultaneously relaxing mechanical stability requirements. Resonant probing reveals coherent cavity-emitter coupling with 96% extinction contrast and a coherent cooperativity of $C = 4.0(14)$. By applying a magnetic field, we further achieve spin-resolved cavity extinction, observing spin-selective optical transitions with a contrast of ${\cal C}_{\rm spin} = 0.91$. These results establish SnV centers in diamond coupled to open Fabry-Pérot microcavities as a promising platform for efficient spin-photon interfaces.

quant-ph↗

arXiv2026

Electrically Reconfigurable Silicon Carbide Nanophotonic Cavities on Thin-Film Lithium Niobate

Interfacing integrated photonics with solid-state spin defects holds great promise for future quantum networks, but the scaling of spin-photon architectures is hindered by frequency mismatches arising from fabrication-induced variations in photonic cavity resonances and the inhomogeneous optical transition frequencies of individual spins. These challenges call for a photonic platform with deterministic and wide-range tunability. Here, we demonstrate a hybrid nanophotonic platform based on direct bonding of silicon carbide photonic crystal nanocavity arrays onto thin-film lithium niobate on insulator, enabling deterministic electrical tuning of multiple SiC nanocavities into mutual spectral resonance. By exploiting the strong electro-optic response of lithium niobate, we achieve continuous and wide-range cavity tuning of 380 GHz ($\sim$1.1 nm), sufficient to compensate both cavity disorder and spin inhomogeneity. The nanocavities balance strong optical confinement with electrical tunability, exhibiting a theoretical Purcell factor of approximately 400. This hybrid platform enables electrically reconfigurable spin-photon interfaces for large-scale integrated quantum photonics.

physics.optics↗

arXiv2026

Color-Center-Compatible Freestanding Diamond Directional Couplers for Quantum Photonics

Freestanding all-diamond color-center photonics is a promising platform for optical integration of spin-based quantum defects. Within this geometry, we realize a key building block for quantum-network interconnects: a directional coupler that acts as an on-chip beam splitter. We design and simulate directional couplers with triangular cross sections using eigenmode and finite-difference time-domain simulations and target near-50:50 splitting at visible wavelengths. We fabricate the devices directly from bulk single-crystal diamond by angled oxygen reactive-ion-beam etching followed by a dry post-release hard-mask removal process. Room-temperature measurements at $λ_0\approx 637 \mathrm{nm}$ yield a mean coupling ratio of $C^\mathrm{meas}=46(16) \%$. Finally, we integrate SnV$^{-}$ centers into the nanophotonic structures and observe near-lifetime-limited optical linewidths and coherent optical Rabi oscillations without post-fabrication annealing, identifying the platform as a viable route towards integrated diamond quantum photonics.

physics.optics↗

arXiv2026

Enhanced security in Quantum Token protocols using Hybrid Spin-Photon Interfaces

Quantum token protocols enable unforgeable quantum tokens promising unconditional security beyond classical cryptographic assumptions. We show here that the three stages of the Quantum token protocols involving the preparation, storage and verification can be made more secure when involving spin-photon interfaces that leverage high fidelity hybrid tripartite (spin-photon-spin) entanglement, Bell state measurements and highly coherent spin quantum memories. Further we describe the physical implementation of various stages of the protocol using the hybrid electron and nuclear spins in diamond interfaced with time-bin photons.

quant-ph↗

arXiv2026

Near-limit quantum control beyond analytic tractability in many-body spin systems

As quantum control approaches hardware-imposed performance limits, weak effects omitted by reduced models become consequential. Assumptions required for analytic tractability then cease to guide control design and instead constrain further improvement. Here, we relax such assumptions and use simulation-guided stochastic tree search to navigate combinatorially large, discrete pulse-sequence spaces for robust many-body spin control. Experimentally, in a solid-state spin ensemble, the resulting computationally discovered pulse sequences substantially outperform analytically optimized baselines, despite being excluded by construction from analytic design criteria. Importantly, these unconventional sequences expose predictive structural features that enable rapid neural network--based performance evaluation. This efficiency gain makes the combinatorial scaling tractable and expands the control alphabet from 8 symmetry-restricted pulses to over 26,000 hardware-resolved options. The resulting fine-grained design freedom provides the control resolution required to reliably address weak, performance-limiting effects, unlocking qualitatively different spin-control capabilities beyond decades of traditional sequence design. Together, these results show that near performance limits, simplifying assumptions can become a primary constraint on quantum control in realistic hardware, and must be repurposed to guide computational discovery.

quant-ph↗

arXiv2026

RF-free driving of nuclear spins with color centers in silicon carbide

Color centers that enable nuclear-spin control without RF fields offer a powerful route towards simplified and scalable quantum devices. Such capabilities are especially valuable for quantum sensing and computing platforms that already find applications in biology, materials science, and geophysics. A key challenge is the coherent manipulation of nearby nuclear spins, which serve as quantum memories and auxiliary qubits but conventionally require additional high-power RF fields which increase the experimental complexity and overall power consumption. Finding systems where both electron and nuclear spins can be controlled using a single MW source is therefore highly desirable. Here, using a modified divacancy center in silicon carbide, we show that coherent control of a coupled nuclear spin is possible without any RF fields. Instead, MW pulses driving the electron spin also manipulate the nuclear spin through hyperfineenhanced effects, activated by a precisely tilted external magnetic field. We demonstrate high-fidelity nuclear-spin control, achieving 89% two-qubit tomography fidelity and nearly T1-limited nuclear coherence times. This approach offers a simplified and scalable route for future quantum applications.

quant-ph↗

arXiv2026

Optically Addressable Molecular Spins at 2D Surfaces

Optically addressable spins at material surfaces have represented a long-standing ambition in quantum sensing, providing atomic resolution and quantum-limited sensitivity. However, they are constrained by a finite depth at which the quantum spins can be stabilized. Here, we demonstrate a hybrid molecular-2D architecture that realizes quantum spin sensors directly on top of the surface. By anchoring spin-active molecules onto hexagonal boron nitride (hBN), we eliminate the depth of the quantum sensor while also exhibiting robust spin properties from 4~K to room temperature (RT). The Hahn-echo spin coherence time exceeds $T_2 = 3.4~\upmu\text{s}$ at 4~K, outperforming values in bulk organic crystals and overturning the prevailing expectation that spin inevitably deteriorates upon approaching the surface. By chemically tuning the molecule through deuteration, $T_2$ improves by more than 10-fold, and under dynamic decoupling, coherence is prolonged to the intrinsic lifetime limit, exceeding 300~$\upmu\text{s}$. Proximal proton spins and the magnetic response of two-dimensional magnets beneath the hBN layer have been detected at RT. These molecular spins form surface quantum sensors with long coherence, optical addressability, and interfacial versatility, enabling a scalable, adaptable architecture beyond what conventional solid-state platforms offer.

quant-ph↗

arXiv2025

Localization and coherent control of 25 nuclear spins in Silicon Carbide

Optically addressable spin defects are excellent candidate platform for quantum sensing and quantum network. Nuclear spins coupled to color centers naturally enable long lived quantum memories and local qubits registers. To fully leverage this potential precise characterization of the surrounding nuclear-spin environment augmented with refined DFT models is required. In this work, we report angstrom-level 3D localization of 25 nuclear spins around a single V2 center in 4H Silicon Carbide. Utilizing specially placed robust nuclear memory as a highly efficient readout ancilla for readout, we apply correlation based spectroscopy and by selecting multi-spin chains up to length four, we access and characterize extended nuclear spin cluster. Using the coupling map we reconstruct their couplings to the central electron spin and neighboring nuclei. This work paves the way towards advanced quantum register applications on Silicon Carbide platform.

quant-ph↗

arXiv2025

Waveguide-integrated colour centres in silicon carbide with broadband photonic crystal reflectors for efficient readout

Spin-active colour centres in 4H silicon carbide are promising candidates as building blocks for quantum information applications. To increase the photon count rate of the emitters at low temperatures, the colour centres must be integrated into nanophotonic structures and characterised under cryogenic conditions. Here, we design and fabricate waveguide structures attached with an efficient Dinosaur photonic crystal reflector at one side. The devices show broadband reflection over a range of 60 THz with a peak reflectance above 80 %. Additionally, colour centres were integrated into these structures and characterised at cryogenic conditions. The emission was collected by a tapered-waveguide-tapered-fibre interface. Although the spectral stability of the emitters must be further improved for high excitation powers, the saturation intensity in standard PLE measurements is about 104 kcps. The count rate can be further improved to about 125 kcps with a charge-resonance check measurement scheme. To highlight the relevance of our devices, we theoretically show that these count rates enable optical single-shot readout with a fidelity exceeding 98 %.

quant-ph↗

arXiv2025

Converting coherence into work with a fully quantum engine

Heat engines convert thermal energy into mechanical work. We here report the experimental realization of a fully quantum engine that converts quantum coherence into work. A single solid-state spin in diamond is fueled by a coherent bath and cyclically stores energy in a spin quantum battery. We establish quantum-enhanced performance by showing that almost 200$\%$ more work is produced after a few cycle compared to the corresponding classical engine. We obtain concrete criteria for successful coherence-to-work conversion, and highlight the importance of a coherent motor-battery interaction. This device harnesses nonclassical features during all stages of its cycle, and demonstrates the functionality of a nanomachine whose parts are all quantum coherent.

quant-ph↗

arXiv2025

Super-Moiré Spin Textures in Twisted Antiferromagnets

Stacking two-dimensional (2D) layered materials offers a powerful platform to engineer electronic and magnetic states. In general, the resulting states, such as Moiré magnetism, have a periodicity at the length scale of the Moiré unit cell. Here, we report a new type of magnetism -- dubbed a super-Moiré magnetic state -- which is characterized by long-range magnetic textures extending beyond the single Moiré unit cell -- in twisted double bilayer chromium triiodide (tDB CrI$_3$). We found that at small twist angles, the size of the spontaneous magnetic texture increases with twist angle, opposite to the underlying Moiré periodicity. The spin-texture size reaches a maximum of about 300 nm in 1.1$°$ twisted devices, an order of magnitude larger than the underlying Moiré wavelength, and vanishes at twist angles above 2$°$. Employing scanning quantum spin magnetometry, the obtained vector field maps suggest the formation of antiferromagnetic Néel-type skyrmions spanning multiple Moiré cells. The twist-angle-dependent study combined with large-scale atomistic simulations suggests that complex magnetic competition between the Dzyaloshinskii--Moriya interaction, magnetic anisotropy, and exchange interactions controlled by the relative rotation of the layers produces the topological textures which arise in the super-Moiré spin orders.

quant-ph↗

arXiv2025

Probing Vortex Dynamics in 2D Superconductors with Scanning Quantum Microscope

The visualization of the magnetic responses of a two-dimensional (2D) superconducting material on the nanoscale is a powerful approach to unravel the underlying supercurrent behavior and to investigate critical phenomena in reduced dimensions. In this study, scanning quantum microscopy is utilized to explore the local magnetic response of the 2D superconductor 2H-NbSe2. Our technique enables both static and dynamic sensing of superconducting vortices with high sensitivity and a spatial resolution down to 30 nm, unveiling unexpected phenomena linked to the intrinsic 2D nature of the superconductor, which are challenging to detect with more conventional local probes. Vortices do not arrange in a hexagonal lattice, but form a distorted vortex glass with expanding vortex size. A vortex can exhibit strong local dynamics due to thermal excitation. As the critical temperature is approached, a clear melting of the vortex glass is identified, leading to distinct configurations under different cooling conditions. Vortex fluctuations can also be probed through spin Hahn-echo measurements, which reveal the spin decoherence even well below the critical temperature -- and, intriguingly, enhanced decoherence at lower temperatures. Spatiotemporal microscopy of the magnetic dynamics associated with vortex excitations and fluctuations provides direct evidence of 2D superconducting phenomena at the nanoscale.

cond-mat.supr-con↗

arXiv2025

Readout of a solid state spin ensemble at the projection noise limit

Spin ensembles are central to quantum science, from frequency standards and fundamental physics searches to magnetic resonance spectroscopy and quantum sensing. Their performance is ultimately constrained by spin projection noise, yet solid-state implementations have so far been limited by much larger photon shot noise. Here we demonstrate a direct, quantum non-demolition readout of a mesoscopic ensemble of nitrogen-vacancy (NV) centers in diamond that surpasses the photon shot-noise limit and approaches the intrinsic spin projection noise. By stabilizing the $^{14}$N nuclear spin bath at high magnetic fields and employing repetitive nuclear-assisted spin readout, we achieve a noise reduction of 3.8 dB below the thermal projection noise level. This enables direct access to the intrinsic fluctuations of the spin ensemble, allowing us to directly observe the signatures of correlated spin states. Our results establish projection noise-limited readout as a practical tool for solid-state quantum sensors, opening pathways to quantum-enhanced metrology, direct detection of many-body correlations, and the implementation of spin squeezing in mesoscopic solid-state ensembles.

quant-ph↗

arXiv2025

Deformation-Driven Enhancement of Spin Defect Emission in Hexagonal Boron Nitride

The negatively charged boron vacancy (VB-) in hexagonal boron nitride (hBN) has been extensively investigated as it offers a novel playground for two-dimensional quantum sensing, with ultimate proximity to target samples. However, its practical sensitivity is limited by the intrinsically weak photoluminescence of the spin ensemble. Here, we report a photoluminescence enhancement of up to 30 times from VB- centers in suspended regions of hBN compared to those in substrate-supported areas. The key spin properties, such as the optically detected magnetic resonance (ODMR) contrast and linewidth, as well as the spin lifetime, of the VB- centers in this region are well preserved. Detailed investigations, including measurements of zero-field ODMR, Raman spectroscopy, and Kelvin probe force microscopy, reveal a correlation between emission enhancement and local deformation in the sample. It is concluded that the suspended regions exhibit higher local deformation compared to the supported areas, breaking the local symmetry and thereby activating otherwise forbidden or weak optical transitions of the VB- centers.

quant-ph↗

arXiv2025

Hybrid spin-phonon architecture for scalable solid-state quantum nodes

Solid-state spin systems hold great promise for quantum information processing and the construction of quantum networks. However, the considerable inhomogeneity of spins in solids poses a significant challenge to the scaling of solid-state quantum systems. A practical protocol to individually control and entangle spins remains elusive. To this end, we propose a hybrid spin-phonon architecture based on spin-embedded SiC optomechanical crystal (OMC) cavities, which integrates photonic and phononic channels allowing for interactions between multiple spins. With a Raman-facilitated process, the OMC cavities support coupling between the spin and the zero-point motion of the OMC cavity mode reaching 0.57 MHz, facilitating phonon preparation and spin Rabi swap processes. Based on this, we develop a spin-phonon interface that achieves a two-qubit controlled-Z gate with a simulated fidelity of $96.80\%$ and efficiently generates highly entangled Dicke states with over $99\%$ fidelity, by engineering the strongly coupled spin-phonon dark state which is robust against loss from excited state relaxation as well as spectral inhomogeneity of the defect centers. This provides a hybrid platform for exploring spin entanglement with potential scalability and full connectivity in addition to an optical link, and offers a pathway to investigate quantum acoustics in solid-state systems.

quant-ph↗