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J. A. Borchers

Publications and source records attributed to J. A. Borchers.

17 recordsLinked to original sources

Absence of magnetic interactions in Ni-Nb ferromagnet-superconductor bilayers

Studies of ferromagnet-superconductor hybrid systems have uncovered magnetic interactions between the competing electronic orderings. The electromagnetic (EM) proximity effect predicts the formation of a spontaneous vector potential inside a superconductor placed in proximity to a ferromagnet. In this work, we use a Nb superconducting layer and Ni ferromagnetic layer to test for such magnetic interactions. We use the complementary, but independent, techniques of polarised neutron reflectometry and detection Josephson junctions to probe the magnetic response inside the superconducting layer at close to zero applied field. In this condition, Meissner screening is negligible, so our measurements examine only additional magnetic and screening contributions from proximity effects. We report the absence of any signals originating from EM proximity effect in zero applied field. Our observations indicate that either EM proximity effect is below the detection resolution of both of our experiments or may indicate a new phenomenon that requires extension of current theory. From our measurements, we estimate a limit of the size of the zero field EM proximity effect in our Ni-Nb samples to be $\pm0.27$ mT.

cond-mat.supr-con↗

Spin Canting in Exchange Coupled Bi-Magnetic Nanoparticles: Interfacial Effects and Hard / Soft Layer Ordering

We investigate the spatial distribution of spin orientation in magnetic nanoparticles consisting of hard and soft magnetic layers. The nanoparticles are synthesized in a core / shell spherical morphology where the magnetically hard, high anisotropy layer is CoFe$_2$O$_4$ (CFO) while the lower anisotropy material is Fe$_3$O$_4$ (FO). The nanoparticles have a mean diameter of $\sim$9.2 - 9.6 nm and are synthesized as two variants: a conventional hard / soft core / shell structure with a CFO core / FO shell (CFO@FO) and the inverted structure FO core / CFO shell (FO@CFO). High resolution electron microscopy confirms the coherent spinel structure across the core / shell boundary in both variants while magnetometry indicates the nanoparticles are superparamagnetic at 300 K and develop a considerable anisotropy at reduced temperatures. Low temperature \textit{M vs. H} loops suggest a multi-step reversal process. Temperature dependent small angle neutron scattering (SANS) with full polarization analysis reveals a strong perpendicular plane alignment of the spins near zero field, indicative of spin canting, but the perpendicular alignment quickly disappears upon application of a weak field and little spin ordering parallel to the field until the coercive field is reached. Above the coercive field of the sample, spins orient predominantly along the field direction. At both zero field and near saturation, the parallel magnetic SANS peak coincides with the structural peak, indicating the magnetization is uniform throughout the nanoparticle volume, while near the coercive field the parallel scattering peak shifts to higher momentum transfer (Q), suggesting that the coherent scattering volume is smaller and likely originates in the softer Fe$_3$O$_4$ portion of the nanoparticle.

cond-mat.mes-hall↗

Distortions to the penetration depth and coherence length of superconductor/normal-metal superlattices

Superconducting ($S$) thin film superlattices composed of Nb and a normal metal spacer ($N$) have been extensively utilized in Josephson junctions given their favorable surface roughness compared to Nb films of comparable thickness. In this work, we characterize the London penetration depth and Ginzburg-Landau coherence lengths of $S/N$ superlattices using polarized neutron reflectometry and electrical transport. Despite the normal metal spacer layers being only approximately 8% of the total superlattice thickness, we surprisingly find that the introduction of these thin $N$ spacers between $S$ layers leads to a dramatic increase in the measured London penetration depth compared to that of a single Nb film of comparable thickness. Using the measured values for the effective in- and out-of-plane coherence lengths, we quantify the induced anisotropy of the superlattice samples and compare to a single Nb film sample. From these results, we find that that the superlattices behave similarly to layered 2D superconductors.

cond-mat.supr-con↗

Octahedral tilt independent magnetism in confined GdTiO$_3$ films

Polarized neutron reflectometry measurements are presented exploring the evolution of ferrimagnetism in GdTiO$_3$ films as they are confined between SrTiO$_3$ layers of variable thicknesses. As GdTiO$_3$ films approach the thin layer limit and are confined within a substantially thicker SrTiO$_3$ matrix, the TiO$_6$ octahedral tilts endemic to GdTiO$_3$ coherently relax toward the undistorted, cubic phase of SrTiO$_3$. Our measurements reveal that the ferrimagnetic state within the GdTiO$_3$ layers survives as the TiO$_6$ octahedral tilts in the GdTiO$_3$ layers are suppressed. Furthermore, our data suggest that a magnetic dead layer develops within the GdTiO$_3$ layer at each GdTiO$_3$/ SrTiO$_3$ interface. The ferrimagnetic moment inherent to the core GdTiO$_3$ layers is negligibly (in models with dead layers) or only weakly (in models without dead layers) impacted as the octahedral tilt angles are suppressed by more than 50$\%$ and the $t_{2g}$ bandwidth is dramatically renormalized.

cond-mat.mes-hall↗

Interface-driven ferromagnetism within the quantum wells of a rare earth titanate superlattice

Here we present polarized neutron reflectometry measurements exploring thin film heterostructures comprised of a strongly correlated Mott state, GdTiO$_3$, embedded with SrTiO$_3$ quantum wells. Our results reveal that the net ferromagnetism inherent to the Mott GdTiO$_3$ matrix propagates into the nominally nonmagnetic SrTiO$_3$ quantum wells and tracks the magnetic order parameter of the host Mott insulating matrix. Beyond a well thickness of 5 SrO layers, the magnetic moment within the wells is dramatically suppressed, suggesting that quenched well magnetism comprises the likely origin of quantum critical magnetotransport in this thin film architecture. Our data demonstrate that the interplay between proximate exchange fields and polarity induced carrier densities can stabilize extended magnetic states within SrTiO$_3$ quantum wells.

cond-mat.str-el↗

Deposition Order Dependent Magnetization Reversal in Pressure Graded Co/Pd films

Magnetization reversal mechanisms and depth-dependent magnetic profile have been investigated in Co/Pd thin films magnetron-sputtered under continuously varying pressure with opposite deposition orders. For samples grown under increasing pressure, magnetization reversal is dominated by domain nucleation, propagation and annihilation; an anisotropy gradient is effectively established, along with a pronounced depth-dependent magnetization profile. However, in films grown under decreasing pressure, disorders propagate vertically from the bottom high-pressure region into the top low-pressure region, impeding domain wall motion and forcing magnetization reversal via rotation; depth-dependent magnetization varies in an inverted order, but the spread is much suppressed.

cond-mat.mtrl-sci↗

Delta Doping of Ferromagnetism in Antiferromagnetic Manganite Superlattices

We demonstrate that delta-doping can be used to create a dimensionally confined region of metallic ferromagnetism in an antiferromagnetic (AF) manganite host, without introducing any explicit disorder due to dopants or frustration of spins. Delta-doped carriers are inserted into a manganite superlattice (SL) by a digital-synthesis technique. Theoretical consideration of these additional carriers show that they cause a local enhancement of ferromagnetic (F) double-exchange with respect to AF superexchange, resulting in local canting of the AF spins. This leads to a highly modulated magnetization, as measured by polarized neutron reflectometry. The spatial modulation of the canting is related to the spreading of charge from the doped layer, and establishes a fundamental length scale for charge transfer, transformation of orbital occupancy and magnetic order in these manganites. Furthermore, we confirm the existence of the canted, AF state as was predicted by de Gennes [P.-G. de Gennes, Phys. Rev. 118, 141 (1960)], but had remained elusive.

cond-mat.str-el↗

Optimization of spin-triplet supercurrent in ferromagnetic Josephson junctions

In the past year, several groups have observed evidence for long-range spin-triplet supercurrent in Josephson junctions containing ferromagnetic (F) materials. In our work, the spin-triplet pair correlations are created by non-collinear magnetizations between a central Co/Ru/Co "synthetic antiferromagnet" (SAF) and two outer thin F layers. Here we present data showing that the spin-triplet supercurrent is enhanced up to 20 times after our samples are subject to a large in-plane magnetizing field. This surprising result can be explained if the Co/Ru/Co SAF undergoes a "spin-flop" transition, whereby the two Co layer magnetizations end up perpendicular to the magnetizations of the two thin F layers. Direct experimental evidence for the spin-flop transition comes from scanning electron microscopy with polarization analysis and from spin-polarized neutron reflectometry.

cond-mat.supr-con↗

Vertically Graded Anisotropy in Co/Pd Multilayers

Depth-grading of magnetic anisotropy in perpendicular magnetic media has been predicted to reduce the field required to write data without sacrificing thermal stability. To study this prediction, we have produced Co/Pd multilayers with depth-dependent Co layer thickness. Polarized neutron reflectometry shows that the thickness grading results in a corresponding magnetic anisotropy gradient. Magnetometry reveals that the anisotropy gradient promotes domain nucleation upon magnetization reversal - a clear experimental demonstration of the effectiveness of graded anisotropy for reducing write-field.

cond-mat.mtrl-sci↗

Direct Observation of Magnetic Gradient in Co/Pd Pressure-Graded Media

Magnetometry and neutron scattering have been used to study the magnetic properties of pressure graded Co/Pd multilayers. The grading of the multilayer structure was done by varying the deposition pressure during sputtering of the samples. Magnetic depth profiling by polarized neutron reflectometry directly shows that for pressure-graded samples, the magnetization changes significantly from one pressure region to the next, while control samples sputtered at uniform pressure exhibit essentially uniform magnetic depth profiles. Complementary magnetometry results suggest that the observed graded magnetic profiles are due in part to a decrease in saturation magnetization for regions deposited at progressively higher pressure. Increased deposition pressure is shown to increase coercivity, and for graded samples, the absence of discrete steps in the hysteresis loops implies exchange coupling among regions deposited at different pressures.

cond-mat.mtrl-sci↗

Carrier-mediated antiferromagnetic interlayer exchange coupling in diluted magnetic semiconductor multilayers Ga$_{1-x}$Mn$_x$As/GaAs:Be

We use neutron reflectometry to investigate the interlayer exchange coupling between Ga$_{0.97}$Mn$_{0.03}$As ferromagnetic semiconductor layers separated by non-magnetic Be-doped GaAs spacers. Polarized neutron reflectivity measured below the Curie temperature of Ga$_{0.97}$Mn$_{0.03}$As reveals a characteristic splitting at the wave vector corresponding to twice the multilayer period, indicating that the coupling between the ferromagnetic layers are antiferromagnetic (AFM). When the applied field is increased to above the saturation field, this AFM coupling is suppressed. This behavior is not observed when the spacers are undoped, suggesting that the observed AFM coupling is mediated by charge carriers introduced via Be doping. The behavior of magnetization of the multilayers measured by DC magnetometry is consistent with the neutron reflectometry results.

cond-mat.str-el↗

Definitive Evidence of Interlayer Coupling Between (Ga,Mn)As Layers Separated by a Nonmagnetic Spacer

We have used polarized neutron reflectometry to study the structural and magnetic properties of the individual layers in a series of (Al,Be,Ga)As/(Ga,Mn)As/GaAs/(Ga,Mn)As multilayer samples. Structurally, we observe that the samples are virtually identical except for the GaAs spacer thickness (which varies from 3-12 nm), and confirm that the spacers contain little or no Mn. Magnetically, we observe that for the sample with the thickest spacer layer, modulation doping by the(Al,Be,Ga)As results in (Ga,Mn)As layers with very different temperature dependent magnetizations. However, as the spacer layer thickness is reduced, the temperature dependent magnetizations of the top an bottom (Ga,Mn)As layers become progressively more similar - a trend we find to be independent of the crystallographic direction along which spins are magnetized. These results definitively show that (Ga,Mn)As layers can couple across a non-magnetic spacer, and that such coupling depends on spacer thickness.

cond-mat.mtrl-sci↗

Nanoscale magnetic structure of ferromagnet/antiferromagnet manganite multilayers

Polarized Neutron Reflectometry and magnetometry measurements have been used to obtain a comprehensive picture of the magnetic structure of a series of La{2/3}Sr{1/3}MnO{3}/Pr{2/3}Ca{1/3}MnO{3} (LSMO/PCMO) superlattices, with varying thickness of the antiferromagnetic (AFM) PCMO layers (0<=t_A<=7.6 nm). While LSMO presents a few magnetically frustrated monolayers at the interfaces with PCMO, in the latter a magnetic contribution due to FM inclusions within the AFM matrix was found to be maximized at t_A~3 nm. This enhancement of the FM moment occurs at the matching between layer thickness and cluster size, where the FM clusters would find the optimal strain conditions to be accommodated within the "non-FM" material. These results have important implications for tuning phase separation via the explicit control of strain.

cond-mat.str-el↗

Magnetic and chemical nonuniformity in Ga[1-x]Mn[x]As films as probed by polarized neutron and x-ray reflectometry

We have used complementary neutron and x-ray reflectivity techniques to examine the depth profiles of a series of as-grown and annealed Ga[1-x]Mn[x]As thin films. A magnetization gradient is observed for two as-grown films and originates from a nonuniformity of Mn at interstitial sites, and not from local variations in Mn at Ga sites. Furthermore, we see that the depth-dependent magnetization can vary drastically among as-grown Ga[1-x]Mn[x]As films despite being deposited under seemingly similar conditions. These results imply that the depth profile of interstitial Mn is dependent not only on annealing, but is also extremely sensitive to initial growth conditions. We observe that annealing improves the magnetization by producing a surface layer that is rich in Mn and O, indicating that the interstitial Mn migrates to the surface. Finally, we expand upon our previous neutron reflectivity study of Ga[1-x]Mn[x]As, by showing how the depth profile of the chemical composition at the surface and through the film thickness is directly responsible for the complex magnetization profiles observed in both as-grown and annealed films.

cond-mat.mtrl-sci↗

Effects of Capping on the (Ga,Mn)As Magnetic Depth Profile

Annealing can increase the Curie temperature and net magnetization in uncapped (Ga,Mn)As films, effects that are suppressed when the films are capped with GaAs. Previous polarized neutron reflectometry (PNR) studies of uncapped (Ga,Mn)As revealed a pronounced magnetization gradient that was reduced after annealing. We have extended this study to (Ga,Mn)As capped with GaAs. We observe no increase in Curie temperature or net magnetization upon annealing. Furthermore, PNR measurements indicate that annealing produces minimal differences in the depth-dependent magnetization, as both as-grown and annealed films feature a significant magnetization gradient. These results suggest that the GaAs cap inhibits redistribution of interstitial Mn impurities during annealing.

cond-mat.mtrl-sci↗

Annealing-Dependent Magnetic Depth Profile in Ga[1-x]Mn[x]As

We have studied the depth-dependent magnetic and structural properties of as-grown and optimally annealed Ga[1-x]Mn[x]As films using polarized neutron reflectometry. In addition to increasing total magnetization, the annealing process was observed to produce a significantly more homogeneous distribution of the magnetization. This difference in the films is attributed to the redistribution of Mn at interstitial sites during the annealing process. Also, we have seen evidence of significant magnetization depletion at the surface of both as-grown and annealed films.

cond-mat.mtrl-sci↗

Unconventional Ferromagnetic Transition in La1-xCaxMnO3

Neutron scattering has been used to study the magnetic correlations and long wavelength spin dynamics of La1-xCaxMnO3 in the ferromagnetic regime (0<=x<1/2). For x=1/3 (Tc=250K) where the magnetoresistance effects are largest the system behaves as an ideal isotropic ferromagnet at low T, with a gapless (<0.04meV) dispersion relation E=Dq^2 and D(T=0)~170 meV-A-1. However, an anomalous strongly-field-dependent diffusive component develops above ~200K and dominates the fluctuation spectrum as T approaches Tc. This component is not present at lower x.

cond-mat↗