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J. A. Rodriguez-Rivera

Publications and source records attributed to J. A. Rodriguez-Rivera.

At least 19 recordsLinked to original sources

Field-direction sensitivity of Kondo hybridization in UTe$_2$

Neutron scattering experiments on the spin-triplet superconductor UTe$_2$ have established that the dominant low-energy magnetic response is along Brillouin zone boundaries, resembling the magnetic susceptibility of narrow-gap interband excitations. We report a study of the sensitivity of these excitations to magnetic field along the crystallographic $\hat{a}$-axis. Up to fields of $μ_0 H$=13 T, the maximal inelastic neutron spectral weight increases in energy transfer, with a pronounced increase in $d\hbarω_{peak}/dH$ near $μ_0 H$=7 T. This behavior parallels the field and temperature dependent features of the electrical resistivity that are associated with Kondo hybridization. Our measurements suggest that $\hat{a}$-axis fields near $μ_0 H$=7~T induce a change in the hybridization between heavy $f$-electrons and the bare conduction band.

cond-mat.str-el

Magnetic field tuned superconducting and normal phase magnetism in CeCo$_{0.5}$Rh$_{0.5}$In$_{5}$

By tuning superconductivity with an applied magnetic field, we use neutrons to compare the magnetic ordered phases in superconducting and normal states of CeCo$_{0.5}$Rh$_{0.5}$In$_{5}$. At zero field, CeCo$_{0.5}$Rh$_{0.5}$In$_{5}$ displays both superconductivity ($T_{c}$=1.3 K) and spatially long-ranged commensurate $\uparrow\downarrow\uparrow\downarrow$ antiferromagnetism ($T_{N}$=2.5 K, $\vec{Q}_{0}=({1\over 2}, {1\over 2}, {1\over 2})$). Neutron spectroscopy fails to measure propagating magnetic excitations with only temporally overdamped fluctuations observable. On applying a magnetic field we find anisotropic behavior in the static magnetism. When the field is along the crystallographic $c$-axis, no change in the static magnetic response is observable. However when the field is oriented within the $a-b$ plane, an increase in $T_{N}$ and change in the critical response are measured. At low temperatures in the superconducting phase, the elastic magnetic intensity increases linearly ($\propto |H|$) with small $a-b$ oriented fields. However, this trend is interrupted at intermediate fields where commensurate block $\uparrow\uparrow\downarrow\downarrow$ magnetism with propagation vector $\vec{Q}=({1\over 2}, {1\over 2}, {1\over 4})$ forms. For large applied fields in the [1 $\overline{1}$ 0] direction which completely suppresses superconductivity, weakly incommensurate magnetic order along $L$ is observed to replace the commensurate response present in the superconducting and vortex phases. We suggest field-induced incommensurate static magnetism, present in the normal state of superconducting and antiferromagnetic CeCo$_{0.5}$Rh$_{0.5}$In$_{5}$ for $a-b$ plane oriented magnetic fields. We speculate that these field dependent properties are tied to the field induced anisotropy associated with the local Ce$^{3+}$ crystal field environment of the tetragonal `115' structure.

cond-mat.str-el

Connection between f-electron correlations and magnetic excitations in UTe2

The detailed anisotropy of the low-temperature, low-energy magnetic excitations of the candidate spin-triplet superconductor UTe$_2$ is revealed using inelastic neutron scattering. The magnetic excitations emerge from the Brillouin zone boundary at the high symmetry $Y$ and $T$ points and disperse along the crystallographic $\hat{b}$-axis. In applied magnetic fields to at least $μ_0 H=11$~T along the $\hat{c}-$axis, the magnetism is found to be field-independent in the $(hk0)$ plane. The scattering intensity is consistent with that expected from U$^{3+}$/U$^{4+}$ $f$-electron spins with preferential orientation along the crystallographic $\hat{a}$-axis, and a fluctuating magnetic moment of 2.3(7) $μ_B$. These characteristics indicate that the excitations are due to intraband spin excitons arising from $f$-electron hybridization.

cond-mat.str-el

Anisotropic excitonic magnetism from discrete $\mathrm{C}_{4}$ symmetry in CeRhIn$_{5}$

Anisotropy in strongly correlated materials is a central parameter in determining the electronic ground state and is tuned through the local crystalline electric field. This is notably the case in the CeCo$_{x}$Rh$_{1-x}$In$_{5}$ system where the ground-state wave function can provide the basis for antiferromagnetism and/or unconventional superconductivity. We develop a methodology to understand the local magnetic anisotropy and experimentally investigate with neutron spectroscopy applied to antiferromagnetic ($T_{N}$=3.8 K) CeRhIn$_{5}$ which is isostructural to $d$-wave superconducting ($T_{c}$=2.3 K) CeCoIn$_{5}$. Through diagonalizing the local crystal field Hamiltonian with discrete tetragonal $\mathrm{C}_{4}$ point group symmetry and coupling these states with the Random Phase Approximation (RPA), we find two distinct modes polarized along the crystallographic $c$ and $a-b$ planes, agreeing with experiment. The anisotropy and bandwidth, underlying the energy scale of these modes, are tuneable with a magnetic field which we use experimentally to separate in energy single and multiparticle excitations thereby demonstrating the instability of excitations polarized within the crystallographic $a-b$ plane in CeRhIn$_{5}$. We compare this approach to a $S_{eff}={1\over 2}$ parameterizations and argue for the need to extend conventional SU(2) theories of magnetic excitations to utilize the multi-level nature of the underlying crystal-field basis states constrained by the local point-group $\mathrm{C}_{4}$ symmetry.

cond-mat.str-el

Unraveling the magnetic ground-state in alkali-metal lanthanide oxide Na$_2$PrO$_3$

A comprehensive set of muon spin spectroscopy and neutron scattering measurements supported by ab-initio and model Hamiltonian simulations have been used to investigate the magnetic ground state of Na$_2$PrO$_3$. $μ$SR reveals Néel antiferromagnetic order below $T_{\rm N}\! \sim\! 4.9$ K, with a small static magnetic moment $m_{\rm static}\!\leq \! 0.22$~$μ_{\rm B}/{\rm Pr}$ collinearly aligned along the $c-$axis. Inelastic neutron measurements reveal the full spectrum of crystal field excitations and confirm that the Pr$^{4+}$ ground state wave function deviates significantly from the $Γ_7$ limit relevant to the Kitaev model. Single and two magnon excitations are observed in the ordered state below $T_N=4.6$ K and are well described by non-linear spin wave theory from the Néel state using a magnetic Hamiltonian with Heisenberg exchange $J=1$ meV and symmetric anisotropic exchange $Γ/J=0.1$, corresponding to an XY model. Intense two magnon excitations are accounted for by $g$-factor anisotropy $g_\mathrm{z}/g_\pm = 1.29$. A fluctuating moment $δm^2 = 0.57(22)$ $μ_{\rm B}^2/{\rm Pr}$ extracted from the energy and momentum integrated inelastic neutron signal is reduced from expectations for a local $J=1/2$ moment with average $g$-factor $g_{\rm avg}\approx 1.1$. Together, the results demonstrate that the small moment in Na$_2$PrO$_3$ arises from crystal field and covalency effects and that the material does not exhibit significant quantum fluctuations..

cond-mat.str-el

Continuum of magnetic excitations in the Kitaev honeycomb iridate D$_3$LiIr$_2$O$_6$

Inelastic neutron scattering (INS) measurements of powder D$_3(^{7}$Li)($^{193}$Ir)$_2$O$_6$ reveal low energy magnetic excitations with a scattering cross section that is broad in $|Q|$ and consistent with a Kitaev spin-liquid (KSL) state. The magnetic nature of the excitation spectrum is demonstrated by longitudinally polarized neutron studies. The total magnetic moment of 1.7(2)$μ_B$/Ir inferred from the total magnetic scattering cross section is consistent with the effective moment inferred from magnetic susceptibility data and expectations for the $J_{\rm eff}=1/2$ single ion state. The rise in the dynamic correlation function ${\cal S}(Q,ω)$ for $\hbarω<5~$meV can be described by a nearest-neighbor Kitaev model with interaction strength $K\approx-13(5)$~meV. Exchange disorder associated with the mixed D-Li site could play an important role in stabilizing the low $T$ quantum fluctuating state.

cond-mat.str-el

Acoustic lattice instabilities at the magneto-structural transition in Fe$_{1.057(7)}$Te

Fe$_{1.057(7)}$Te undergoes a first-order tetragonal to monoclinc structural transition at T$_{S} \sim 70$ K, breaking the C$_{4}$ lattice symmetry and simultaneously breaking time reversal symmetry with bicollinear magnetic order. We investigate the soft acoustic lattice dynamics near this combined magneto-structural transition. We apply spherically neutron polarimetry to study the static magnetism near this transition, characterized with x-ray powder diffraction, and find no evidence of static incommensurate magnetic correlations near the onset of monoclinic and bicollinear antiferromagnetic order. This fixes the position of our single crystal sample in the Fe$_{1+x}$Te phase diagram in the magnetic bicollinear region and illustrates that our sample statically undergoes a transition from a paramagnetic phase to a low-temperature bicollinear phase. We then apply neutron spectroscopy to study the acoustic phonons, related to elastic deformations of the lattice. We find a temperature dependent soft acoustic branch for phonons propagating along [010] and polarized along [100]. The slope of this acoustic phonon branch is sensitive to the elastic constant $C_{66}$ and the shear modulus. The temperature dependence of this branch displays a softening with a minimum near the magneto-structural transition of T$_{S}$ $\sim$ 70 K and a recovery within the magnetically ordered low temperature phase. Soft acoustic instabilities are present in the collinear phases of the chalcogenides Fe$_{1+x}$Te where nematic order found in Fe$_{1+δ}$Se is absent. We speculate, based on localized single-ion magnetism, that the relative energy scale of magnetic spin-orbital coupling on the Fe$^{2+}$ transition metal ion is important for the presence of a nematicity in the chalcogenides.

cond-mat.str-el

Neutron scattering sum rules, symmetric exchanges, and helicoidal magnetism in MnSb$_2$O$_6$

MnSb$_{2}$O$_{6}$ is based on the noncentrosymmetric $P321$ space group with magnetic Mn$^{2+}$ ($S={5/2}$, $L\approx 0$) spins ordering below $T_{\mathrm{N}}=12$ K in a helicoidal structure. The ground state magnetic structure, expected to be built and originate from 7 Heisenberg exchange constants, has been shown to be coupled to the underlying crystallographic chirality with polar domain switching being reported. We apply neutron spectroscopy to extract these symmetric exchange constants. Given the high complexity of the magnetic exchange network, crystallographic structure and complications fitting linear spin-wave models, we take advantage of multiplexed neutron instrumentation to use the first moment sum rule of neutron scattering to estimate the 7 exchange constants. We then use these parameters to calculate the low-energy spin-waves in the Néel state to reproduce the neutron response without strong antisymmetric coupling. Using Green's response functions, the stability of long-wavelength excitations in the context of proposed magnetic structures is then discussed. The results show the presence of strong exchange constants for the chiral exchange pathways and illustrate an underlying coupling between crystallographic and magnetic ``chirality" through predominantely symmetric exchange.

cond-mat.str-el

Spin-orbital order and excitons in magnetoresistive HoBi

The magnetism of the rock-salt $fcc$ rare-earth monopnictide HoBi, a candidate topological material with extreme magnetoresistance, is investigated. From the Ho$^{3+}$ non-Kramers $J$=8 spin-orbital multiplet, the cubic crystal electric field yields six nearly degenerate low-energy levels. These constitute an anisotropic magnetic moment with a Jahn-Teller-like coupling to the lattice. In the cubic phase for $T>T_N~=~5.72(1)~K$, the paramagnetic neutron scattering is centered at $\mathbf{k}=(\frac{1}{2}\frac{1}{2}\frac{1}{2})$ and was fit to dominant antiferromagnetic interactions between Ho spins separated by $\{100\}$ and ferromagnetic interactions between spins displaced by $\{\frac{1}{2}\frac{1}{2}0\}$. For $T<T_N$, a type-II AFM long-range order with $\mathbf{k}=(\frac{1}{2}\frac{1}{2}\frac{1}{2})$ develops along with a tetragonal lattice distortion. While neutron diffraction from a multi-domain sample cannot unambiguously determine the spin orientation within a domain, the bulk magnetization, structural distortion, and our measurements of the magnetic excitations all show the easy axis coincides with the tetragonal axis. The weakly dispersive excitons for $T<T_N$ can be accounted for by a spin Hamiltonian that includes the crystal electric field and exchange interactions within the Random Phase Approximation.

cond-mat.str-el

Fast broadband cluster spin-glass dynamics in PbFe$_{1/2}$Nb$_{1/2}$O$_{3}$

PbFe$_{1/2}$Nb$_{1/2}$O$_{3}$ (PFN) is a relaxor ferroelectric (T$_{c}$ $\sim$ 400 K) consisting of disordered magnetic Fe$^{3+}$ (S=${5\over2}$, L$\approx$0) ions resulting in a low temperature ``cluster glass" phase (W. Kleemann $\textit{et al.}$ Phys. Rev. Lett. ${\bf{105}}$, 257202 (2010)). We apply neutron scattering to investigate the dynamic magnetism of this phase in a large single crystal which displays a low temperature spin glass transition (T$_{g} \sim$ 15 K), but no observable spatially long-range antiferromagnetic order. The static response in the cluster glass phase (sampled on the timescale set by our resolution) is found to be characterized by an average magnetic spin direction that lacks any preferred direction. The dynamics that drive this phase are defined by a magnetic correlation length that gradually increases with decreasing temperature. However, below $\sim$ 50 K the spatial correlations gradually becoming more short range indicative of increasing disorder on cooling, thereby unravelling magnetism, until the low temperature glass phase sets in at T$_{g}$ $\sim$ 15 K. Neutron spectroscopy is used to characterize the spin fluctuations in the cluster glass phase and are found to be defined by a broadband of frequencies on the scale of $\sim$ THz, termed here ``fast" fluctuations. The frequency bandwidth driving the magnetic fluctuations mimics the correlation length and decreases until $\sim$ 50 K, and then increases again until the glass transition. Through investigating the low-energy acoustic phonons we find evidence of multiple distinct structural regions which form the basis of the clusters, generating a significant amount of local disorder. We suggest that random molecular fields originating from conflicting interactions between clusters is important for the destruction of magnetic order and the eventual formation of the cluster glass in PFN.

cond-mat.mtrl-sci

Spin dynamics in the skyrmion-host lacunar spinel GaV4S8

In the lacunar spinel GaV4S8, the interplay of spin, charge, and orbital degrees of freedom produces a rich phase diagram that includes an unusual Neel-type skyrmion phase composed of molecular spins. To provide insight into the interactions underlying this complex phase diagram, we study the spin excitations in GaV4S8 through inelastic neutron scattering measurements on polycrystalline and single-crystal samples. Using linear spin-wave theory, we describe the spin-wave excitations using a model where V4 clusters decorate an FCC lattice. The effective cluster model includes a ferromagnetic interaction and a weaker antisymmetric Dzyaloshinskii-Moriya (DM) interaction between the neighboring molecular spins. Our work clarifies the spin interactions in GaV4S8 and supports the picture of interacting molecular clusters.

cond-mat.str-el

Metastable antiphase boundary ordering in CaFe$_{2}$O$_{4}$

CaFe$_{2}$O$_{4}$ is an $S=5/2$ antiferromagnet exhibiting two magnetic orders which shows regions of coexistence at some temperatures. Using a Green's function formalism, we model neutron scattering data of the spin wave excitations in this material, ellucidating the microscopic spin Hamiltonian. In doing so, we suggest that the low temperature A phase order $(\uparrow\uparrow\downarrow\downarrow)$ finds its origins in the freezing of antiphase boundaries created by thermal fluctuations in a parent B phase order $(\uparrow\downarrow\uparrow\downarrow)$. The low temperature magnetic order observed in CaFe$_{2}$O$_{4}$ is thus the result of a competition between the exchange coupling along $c$, which favors the B phase, and the single-ion anisotropy which stabilizes thermally-generated antiphase boundaries, leading to static metastable A phase order at low temperatures.

cond-mat.str-el

Decay and renormalization of a longitudinal mode in a quasi-two-dimensional antiferromagnet

An ongoing challenge in the study of quantum materials, is to reveal and explain collective quantum effects in spin systems where interactions between different modes types are important. Here we approach this problem through a combined experimental and theoretical study of interacting transverse and longitudinal modes in an easy-plane quantum magnet near a continuous quantum phase transition. Our inelastic neutron scattering measurements of Ba$_{2}$FeSi$_{2}O$_{7}$ reveal the emergence, decay, and renormalization of a longitudinal mode throughout the Brillouin zone. The decay of the longitudinal mode is particularly pronounced at the zone center. To account for the many-body effects of the interacting low-energy modes in anisotropic magnets, we generalize the standard spin-wave theory. The measured mode decay and renormalization is reproduced by including all one-loop corrections. The theoretical framework developed here is broadly applicable to quantum magnets with more than one type of low energy mode.

cond-mat.str-el

Two-dimensional ferromagnetic spin-orbital excitations in the honeycomb VI$_{3}$

VI$_{3}$ is a ferromagnet with planar honeycomb sheets of bonded V$^{3+}$ ions held together by van der Waals forces. We apply neutron spectroscopy to measure the two dimensional ($J/J_{c} \approx 17$) magnetic excitations in the ferromagnetic phase, finding two energetically gapped ($Δ\approx k_{B} T_{c} \approx$ 55 K) and dispersive excitations. We apply a multi-level spin wave formalism to describe the spectra in terms of two coexisting domains hosting differing V$^{3+}$ orbital ground states built from contrasting distorted octahedral environments. This analysis fits a common nearest neighbor in-plane exchange coupling ($J$=-8.6 $\pm$ 0.3 meV) between V$^{3+}$ sites. The distorted local crystalline electric field combined with spin-orbit coupling provides the needed magnetic anisotropy for spatially long-ranged two-dimensional ferromagnetism in VI$_{3}$.

cond-mat.str-el

Pristine quantum criticality in a Kondo semimetal

The observation of quantum criticality in diverse classes of strongly correlated electron systems has been instrumental in establishing ordering principles, discovering new phases, and identifying the relevant degrees of freedom and interactions. At focus so far have been insulators and metals. Semimetals, which are of great current interest as candidate phases with nontrivial topology, are much less explored in experiments. Here we study the Kondo semimetal CeRu$_4$Sn$_6$ by magnetic susceptibility, specific heat, and inelastic neutron scattering experiments. The power-law divergence of the magnetic Grünesien ratio reveals that, surprisingly, this compound is quantum critical without tuning. The dynamical energy over temperature scaling in the neutron response, seen throughout the Brillouin zone, as well as the temperature dependence of the static uniform susceptibility indicate that temperature is the only energy scale in the criticality. Such behavior, which has been associated with Kondo destruction quantum criticality in metallic systems, may well be generic in the semimetal setting.

cond-mat.str-el

Kitaev interactions in the Co honeycomb antiferromagnets Na$_3$Co$_2$SbO$_6$ and Na$_2$Co$_2$TeO$_6$

Co$^{2+}$ ions in an octahedral crystal field, stabilise a j$_{eff}$ = 1/2 ground state with an orbital degree of freedom and have been recently put forward for realising Kitaev interactions, a prediction we have tested by investigating spin dynamics in two cobalt honeycomb lattice compounds, Na$_2$Co$_2$TeO$_6$ and Na$_3$Co$_2$SbO$_6$, using inelastic neutron scattering. We used linear spin wave theory to show that the magnetic spectra can be reproduced with a spin Hamiltonian including a dominant Kitaev nearest-neighbour interaction, weaker Heisenberg interactions up to the third neighbour and bond-dependent off-diagonal exchange interactions. Beyond the Kitaev interaction that alone would induce a quantum spin liquid state, the presence of these additional couplings is responsible for the zigzag-type long-range magnetic ordering observed at low temperature in both compounds. These results provide evidence for the realization of Kitaev-type coupling in cobalt-based materials, despite hosting a weaker spin-orbit coupling than their 4d and 5d counterparts.

cond-mat.str-el

From one- to two-magnon excitations in the S=3/2 magnet $β$-CaCr$_2$O$_4$

We apply neutron spectroscopy to measure the magnetic dynamics in the S=3/2 magnet $β$-CaCr$_2$O$_4$ (T$_N$=21 K). The low-energy fluctuations, in the ordered state, resemble large-S linear spin-waves from the incommensurate ground state. However, at higher energy transfers, these semi-classical and harmonic dynamics are replaced by an energy and momentum broadened continuum of excitations. Applying kinematic constraints required for energy and momentum conservation, sum rules of neutron scattering, and comparison against exact diagonalization calculations, we show that the dynamics at high-energy transfers resemble low-S one-dimensional quantum fluctuations. $β$-CaCr$_2$O$_4$ represents an example of a magnet at the border between classical Néel and quantum phases, displaying dual characteristics.

cond-mat.str-el

Unravelling competing microscopic interactions at a phase boundary: a single crystal study of the metastable antiferromagnetic pyrochlore Yb$_{2}$Ge$_{2}$O$_{7}$

We report inelastic neutron scattering measurements from our newly synthesized single crystals of the structurally metastable antiferromagnetic pyrochlore Yb$_{2}$Ge$_{2}$O$_{7}$. We determine the four symmetry-allowed nearest-neighbor anisotropic exchange parameters via fits to linear spin wave theory supplemented by fits of the high-temperature specific heat. The exchange parameters so-determined are strongly correlated to the values determined for the $g$-tensor components, as previously observed for the related Yb pyrochlore Yb$_{2}$Ti$_{2}$O$_{7}$. To address this issue, we directly determined the $g$-tensor from electron paramagnetic resonance of 1% Yb-doped Lu$_{2}$Ge$_{2}$O$_{7}$, thus enabling an unambiguous determination of the exchange parameters. Our results show that Yb$_{2}$Ge$_{2}$O$_{7}$ resides extremely close to the classical phase boundary between an antiferromagnetic $Γ_5$ phase and a splayed ferromagnet phase. By juxtaposing our results with recent ones on Yb$_{2}$Ti$_{2}$O$_{7}$, our work illustrates that the Yb pyrochlore oxides represent ideal systems for studying quantum magnets in close proximity to classical phase boundaries.

cond-mat.str-el