arXiv subjects

J. B. He

Publications and source records attributed to J. B. He.

27 records · Page 2Linked to original sources

arXiv2011

Superconductivity and normal state properties of single-crystalline Tl0.47Rb0.34Fe1.63Se2 as seen via 77Se and 87Rb NMR

We report both 77Se and 87Rb NMR studies on Tl0.47Rb0.34Fe1.63Se2 single-crystalline superconductors (T_c about 32 K). Singlet superconductivity is decisively determined by a sharp drop of the Knight shift K(T) below T_c, after subtracting the superconducting diamagnetic effect. However, the Hebel-Slichter coherence peak below T_c is not observed in the spin-lattice relaxation rate 1/T_1, even with a low in-plane NMR field of 2.6 Tesla. Just above T_c, no evidence of low-energy spin fluctuation is found in the spin-lattice relaxation rate on both the 77Se and the 87Rb sites. Upon warming, however, the Knight shifts and the spin-lattice relaxation rates of both nuclei increase substantially with temperature. In particular, the Knight shift is nearly isotropic and follow a function fit of K=a+bT^2 from T_c up to 300 K. These normal state properties may be an indication of thermally activated spin fluctuations. Our observations should put a strong constraint to the theory of magnetism and superconductivity in the newly discovered iron-based superconductors.

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arXiv2011

On the Structure of Vacancy Ordered Superconducting Alkali Metal Iron Selenide

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered vacancy structure with a ({\sqrt}5 x {\sqrt}5 x 1) super cell. The tetragonal unit cell, space group I4/m, possesses lattice parameters at 250K of a = b = 8.729(2) Å and c = 14.120(3) Å, a = b = 8.7186(12) Å and c = 14.0853(19) Å and at 295 K, a = b = 8.8617(16) Å and c = 15.304(3) Å for the three crystals, respectively. The structure contains two iron sites; one is almost completely empty, whilst the other is fully occupied. There are similarly two alkali metal sites that are occupied in the range of 72.2(2) % to 85.3(3) %. The inclusion of alkali metals and the presence of vacancies within the structure allows for considerable relaxation of the FeSe4 tetrahedron, compared with members of the Fe(Te, Se, S) series, and the resulting shift of the Se - F - Se bond angles to less distorted geometry could be important in understanding the associated increase in the superconducting transition temperature. The structure of these superconductors distinguishes themselves from the structure of the non-superconducting phases by an almost complete absence of Fe on the (0 0.5 0.25) site as well as lower alkali metal occupancy that ensures an exact Fe2+ oxidation state, which are clearly critical parameters in the promotion of superconductivity.

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arXiv2011

Common Fermi Surface Topology and Nodeless Superconducting Gap in K0.68Fe1.79Se2 and (Tl0.45K0.34)Fe1.84Se2 Superconductors Revealed from Angle-Resolved Photoemission Spectroscopy

We carried out high resolution angle-resolved photoemission measurements on the electronic structure and superconducting gap of K_0.68Fe_1.79Se_2 (T_c=32 K) and (Tl_0.45K_0.34)Fe_1.84Se_2 (T_c=28 K) superconductors. In addition to the electron-like Fermi surface near M(π,π), two electron-like Fermi pockets are revealed around the zone center Γ(0,0) in K0.68Fe1.79Se_2. This observation makes the Fermi surface topology of K_0.68Fe_1.79Se_2 consistent with that of (Tl,Rb)_xFe_{2-y}Se_2 and (Tl,K)_xFe_{2-y}Se_2 compounds. A nearly isotropic superconducting gap (Δ) is observed along the electron-like Fermi pocket near the M point in K_0.68Fe_1.79Se_2 (Δ\sim 9 meV) and (Tl_0.45K_0.34)Fe_1.84Se_2 (Δ\sim 8 meV). The establishment of a universal picture on the Fermi surface topology and superconducting gap in the A_xFe_2-ySe_2 (A=K, Tl, Cs, Rb and etc.) superconductors will provide important information in understanding the superconductivity mechanism of the iron-based superconductors.

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arXiv2011

A Novel Large Moment Antiferromagnetic Order in K0.8Fe1.6Se2 Superconductor

The discovery of cuprate high Tc superconductors has inspired searching for unconventional su- perconductors in magnetic materials. A successful recipe has been to suppress long-range order in a magnetic parent compound by doping or high pressure to drive the material towards a quantum critical point, which is replicated in recent discovery of iron-based high TC superconductors. The long-range magnetic order coexisting with superconductivity has either a small magnetic moment or low ordering temperature in all previously established examples. Here we report an exception to this rule in the recently discovered potassium iron selenide. The superconducting composition is identified as the iron vacancy ordered K0.8Fe1.6Se2 with Tc above 30 K. A novel large moment 3.31 μB/Fe antiferromagnetic order which conforms to the tetragonal crystal symmetry has the unprecedentedly high an ordering temperature TN = 559 K for a bulk superconductor. Staggeredly polarized electronic density of states thus is suspected, which would stimulate further investigation into superconductivity in a strong spin-exchange field under new circumstance.

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arXiv2011

77Se NMR Evidence of Strongly Coupled Superconductivity in K0.8Fe2-xSe2

We report the 77Se NMR Knight shift and spin-lattice relaxation studies on the superconducting state of the ternary iron selenide K0.8Fe2-xSe2 with Tc~30 K. Just below Tc, the Knight shift 77Kn shows an immediate drop, indicating a singlet pairing. The spin-lattice relaxation rate 1/77T1 decreases rapidly in the temperature range from TC to Tc/2, which can be fit with an isotropic gap of Δ~3.8\pm 0.5 k_BTc. The Hebel-Slichter coherence peak is not observed. These data give bulk evidence for a strongly coupled superconductivity with isotropic gaps in K0.8Fe2-xSe2, which is similar to other iron-based high temperature superconductors. Below Tc/2, the spin-part of the Knight shift levels off to a constant value (~0.09%), and the spin-lattice relaxation follows a 1/T1 T^2 behavior, which are not well understood.

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arXiv2011

The effect of varying Fe-content on transport properties of K intercalated iron selenide KxFe2-ySe2

We report the successful growth of high-quality single crystals of potassium intercalated iron selenide KxFe2-ySe2 by Bridgeman method. The effect of iron vacancies on transport properties was investigated by electrical resistivity and magnetic susceptibility measurements. With varying iron content, the system passes from semiconducting/insulating to superconducting state. Comparing with superconductivity, the anomalous "hump" effect in the normal state resistivity is much more sensitive to the iron deficiency. The electrical resistivity exhibits a perfect metallic behavior (R300K/R35K=42) for the sample with little iron vacancies. Our results suggest that the anomalous "hump" effect in the normal state resistivity may be due to the ordering process of the cation vacancies in this non-stoichiometric compound rather than magnetic/structure transition. A trace of superconductivity extending up to near 44 K was also detected in some crystals of KxFe2-ySe2, which has the highest Tc of the reported iron selenides.

cond-mat.supr-con↗

arXiv2010

23Na and 75As NMR Studies on NaFeAs0.8P0.2 Single Crystals

We report our $^{23}$Na and $^{75}$As NMR studies on isovalent phosphorus-doped NaFeAs$_{0.8}$P$_{0.2}$ ($T_c=$ 33 K) single crystals. Our data suggest a dramatic enhancement of the electron density of states on the Fermi surface, and a large residual electron density of state below $T_c$. However, evidence of antiferromagnetic spin fluctuations is shown by the spin-lattice relaxation rate. The penetration depth, revealed from $^{23}$Na NMR linewidth, follows the universal Uemura relation in iron pnictides. These observations suggest that the correlation effects are still important for the superconductivity in the phosphorus doped sample, although the Fermi surface is probably significantly changed upon doping.

cond-mat.supr-con↗

arXiv2010

Site-dependent NMR Spin-lattice Relaxation in the Superconducting State of an Iron Pnictide Superconductor

In a conventional superconductor, the spin-lattice relaxation rate on all nuclei should have the same temperature dependence below Tc. We performed $^{23}$Na, $^{75}$As, and $^{59}$Co NMR studies on single crystals of NaFe0.95Co0.05As, and found that spin-lattice relaxation rates show very different temperature dependent power-law behavior on three sites. We propose that such site-dependent behavior is due to the facts that the superconductor has two gaps of very different sizes. The power-law exponent of each nucleus is affected by the strength of the hyperfine coupling to the small gap. We also found that the large superconducting gap on the cobalt site is smaller than on other two sites. It suggests a local suppression of the superconducting gap on the dopant site.

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arXiv2010

Superconductivity at 33 K in "111" single crystals at ambient pressure

We have successfully grown single crystalline NaFeAs with cobalt or phosphor doping. Bulk superconductivity occurs in NaFe$_{0.95}$Co$_{0.05}$As at 19 K while much higher transition temperature is observed in NaFeAs$_{0.8}$P$_{0.2}$, in which the Tc of 33 K is even higher than the highest value realized by applying pressure in NaFeAs and all other isoelectronic element substituted samples. We discuss these behaviours by comparison with 122 and 1111 systems. We hope that our findings will help improve our understanding of iron-based superconductivity.

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