arXiv subjects

J. Buršík

Publications and source records attributed to J. Buršík.

3 recordsLinked to original sources

arXiv2024

Microwave magnetic excitations in U-type hexaferrite Sr$_4$CoZnFe$_{36}$O$_{60}$ ceramics

Microwave (MW) transmission, absorption, and reflection loss spectra of the ferrimagnetic U-type hexaferrite Sr$_4$CoZnFe$_{36}$O$_{60}$ ceramics were studied from 100 MHz to 35 GHz at temperatures between 10 and 390 K. 9 MW magnetic excitations with anomalous behavior near the ferrimagnetic phase transitions were revealed. They also change under the application of weak bias magnetic field (0 - 700 Oe) at room temperature. 6 pure magnetic modes are assigned to dynamics of the magnetic domain walls and inhomogeneous magnetic structure of the ceramics, to the natural ferromagnetic resonance (FMR) and to the higher-frequency magnons. Three modes are considered as the magnetodielectric ones with dominating influence of the magnetic properties on their temperature and field dependences. Presence of the natural FMR in all ferrimagnetic phases proves existence of the non-zero internal magnetization and magnetocrystalline anisotropy. Splitting of the FMR into the two components without magnetic bias was observed in the collinear phase and is attributed to a change of the magnetocrystalline anisotropy during the phase transition. The high-frequency FMR component critically slows down to the phase transition. At room temperature, the FMR splitting and essential suppression of the higher-frequency modes was revealed under the weak bias field (300 - 700 Oe). The highly nonlinear MW response and the FMR splitting are caused by the gradual evolution of the polydomain magnetic structure to a monodomain one. The high number of magnetic excitations observed in the MW region confirms the suitability of using hexaferrite Sr$_4$CoZnFe$_{36}$O$_{60}$ ceramics as MW absorbers, shielding materials and highly tunable filters.

cond-mat.mtrl-sci↗

arXiv2018

Spin Seebeck effect in $\varepsilon$-Fe$_2$O$_3$ thin layer with high coercive field

Spin Seebeck effect has been investigated in Pt/$\varepsilon$-Fe$_2$O$_3$ bilayers. The $\varepsilon$-Fe$_2$O$_3$ thin layer with $40-70$~nm thickness were deposited by a spin-coating method on Y:ZrO$_2$(100) substrates. The prepared layers are highly oriented with the easy magnetic $a$-axis parallel to the film surface. The magnetic hysteresis loops measured at room temperature with magnetic field parallel to the layer exhibit coercive fields up to 11.6~kOe, which is so far the highest value measured for $\varepsilon$-Fe$_2$O$_3$ thin layer samples. The shape of the spin Seebeck hysteresis loops is similar to the shape of magnetization for single phase layers with coercive field around 10~kOe. In some prepared layers a small amount of secondary soft ferrimagnetic phase is revealed by a constricted shape of magnetization loops, in contrast to spin Seebeck loops, where no constriction is observed. A difference in encountered in the case of layers with a small amount ($1-2$~volume\%) of secondary soft ferrimagnetic phase, which is revealed by a constricted shape of magnetization loops, in contrast to spin Seebeck loops, where no constriction is observed.

cond-mat.mtrl-sci↗

arXiv2012

Stabilization of the high-spin state of Co$^{3+}$ in LaCo$_{1-x}$Rh$_{x}$O$_3$

The rhodium doping in the LaCo$_{1-x}$Rh$_{x}$O$_3$ perovskite series ($x=0.02-0.5$) has been studied by X-ray diffraction, electric transport and magnetization measurements, complemented by electronic structure GGA+U calculations in supercell for different concentration regimes. No charge transfer between Co$^{3+}$ and Rh$^{3+}$ is evidenced. The diamagnetic ground state of LaCoO$_3$, based on Co$^{3+}$ in low-spin (LS) state, is disturbed even by a small doping of Rh. The driving force is the elastic energy connected with incorporation of a large Rh$^{3+}$ cation into the matrix of small LS Co$^{3+}$ cations, which is relaxed by formation of large Co$^{3+}$ in high-spin (HS) state in the next-nearest sites to the inserted Rh atom. With increasing temperature, the population of Co$^{3+}$ in HS state increases through thermal excitation, and a saturated phase is obtained close to room temperature, consisting of a nearest-neighbor correlation of small (LS Co$^{3+}$) and large (HS Co$^{3+}$ and LS Rh$^{3+}$) cations in a kind of double perovskite structure. The stabilizing role of elastic and electronic energy contributions is demonstrated in supercell calculations for dilute Rh concentration compared to other dopants with various trivalent ionic radius.

cond-mat.mtrl-sci↗