arXiv subjects

J. Cernicharo

Publications and source records attributed to J. Cernicharo.

At least 91 records · Page 5Linked to original sources

arXiv2021

Space and laboratory discovery of HC3S+

We report the detection in TMC-1 of the protonated form of C3S. The discovery of the cation HC3S+ was carried through the observation of four harmonically related lines in the Q band using the Yebes 40m radiotelescope, and is supported by accurate ab initio calculations and laboratory measurements of its rotational spectrum. We derive a column density N(HC3S+) = (2.0 +/- 0.5)e11 cm-2, which translates to an abundance ratio C3S/HC3S+ of 65 +/- 20. This ratio is comparable to the CS/HCS+ ratio (35 +/- 8) and is a factor of about ten larger than the C3O/HC3O+ ratio previously found in the same source. However, the abundance ratio HC3O+/HC3S+ is 1.0 +/- 0.5, while C3O/C3S is just 0.11. We also searched for protonated C2S in TMC-1, based on ab initio calculations of its spectroscopic parameters, and derive a 3sigma upper limit of N(HC2S+) < 9e11 cm-2 and a C2S/HC2S+ > 60. The observational results are compared with a state-of-the-art gas-phase chemical model and conclude that HC3S+ is mostly formed through several pathways: proton transfer to C3S, reaction of S+ with c-C3H2, and reaction between neutral atomic sulfur and the ion C3H3+.

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arXiv2021

Discovery of the acetyl cation, CH3CO+, in space and in the laboratory

Using the Yebes 40m and IRAM 30m radiotelescopes, we detected two series of harmonically related lines in space that can be fitted to a symmetric rotor. The lines have been seen towards the cold dense cores TMC-1, L483, L1527, and L1544. High level of theory ab initio calculations indicate that the best possible candidate is the acetyl cation, CH3CO+, which is the most stable product resulting from the protonation of ketene. We have produced this species in the laboratory and observed its rotational transitions Ju = 10 up to Ju = 27. Hence, we report the discovery of CH3CO+ in space based on our observations, theoretical calculations, and laboratory experiments. The derived rotational and distortion constants allow us to predict the spectrum of CH3CO+ with high accuracy up to 500 GHz. We derive an abundance ratio N(H2CCO)/N(CH3CO+) = 44. The high abundance of the protonated form of H2CCO is due to the high proton affinity of the neutral species. The other isomer, H2CCOH+, is found to be 178.9 kJ/mol above CH3CO+. The observed intensity ratio between the K=0 and K=1 lines, 2.2, strongly suggests that the A and E symmetry states have suffered interconversion processes due to collisions with H and/or H2, or during their formation through the reaction of H3+ with H2CCO.

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arXiv2020

Detection of infrared fluorescence of carbon dioxide in R Leonis with SOFIA/EXES

We report on the detection of hot CO2 in the O-rich AGB star R Leo based on high spectral resolution observations in the range 12.8-14.3 um carried out with the Echelon-cross-Echelle Spectrograph (EXES) mounted on the Stratospheric Observatory for Infrared Astronomy (SOFIA). We have found ~240 CO2 emission lines in several vibrational bands. These detections were possible thanks to a favorable Doppler shift that allowed us to avoid contamination by telluric CO2 features. The highest excitation lines involve levels at an energy of ~7000 K. The detected lines are narrow (average deconvolved width ~2.5 km/s) and weak (usually <10% the continuum). A ro-vibrational diagram shows that there are three different populations, warm, hot, and very hot, with rotational temperatures of ~550, 1150, and 1600 K, respectively. From this diagram, we derive a lower limit for the column density of ~2.2E+16 cm^{-2}. Further calculations based on a model of the R Leo envelope suggest that the total column density can be as large as 7.0E+17 cm^{-2} and the abundance with respect to H2 ~2.5E-05. The detected lines are probably formed due to de-excitation of CO2 molecules from high energy vibrational states, which are essentially populated by the strong R Leo continuum at 2.7 and 4.2 um.

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arXiv2020

Yebes 40 m radio telescope and the broad band NANOCOSMOS receivers at 7 mm and 3 mm for line surveys

Yebes 40\,m radio telescope is the main and largest observing instrument at Yebes Observatory and it is devoted to Very Long Baseline Interferometry (VLBI) and single dish observations since 2010. It has been covering frequency bands between 2\,GHz and 90\,GHz in discontinuous and narrow windows in most of the cases, to match the current needs of the European VLBI Network (EVN) and the Global Millimeter VLBI Array (GMVA). Nanocosmos project, a European Union funded synergy grant, opened the possibility to increase the instantaneous frequency coverage to observe many molecular transitions with single tunnings in single dish mode. This reduces the observing time and maximises the output from the telescope. We present the technical specifications of the recently installed 31.5-50 GHz (Q band) and 72-90.5 GHz (W band) receivers along with the main characteristics of the telescope at these frequency ranges. We have observed IRC+10216, CRL 2688 and CRL 618, which harbour a rich molecular chemistry, to demonstrate the capabilities of the new instrumentation for spectral observations in single dish mode. The results show the high sensitivity of the telescope in the Q band. The spectrum of IRC+10126 offers a signal to noise ratio never seen before for this source in this band. On the other hand, the spectrum normalised by the continuum flux towards CRL\,618 in the W band demonstrates that the 40~m radio telescope produces comparable results to those from the IRAM 30~m radio telescope, although with a smaller sensitivity. The new receivers fulfil one of the main goals of Nanocosmos and open the possibility to study the spectrum of different astrophysical media with unprecedented sensitivity.

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arXiv2020

Tentative detection of HC5NH+ in TMC-1

Using the Yebes 40m radio telescope, we report the detection of a series of seven lines harmonically related with a rotational constant B0=1295.81581 +/- 0.00026 MHz and a distortion constant D0=27.3 +/- 0.5 Hz towards the cold dense cloud TMC-1. Ab initio calculations indicate that the best possible candidates are the cations HC5NH+ and NC4NH+. From a comparison between calculated and observed rotational constants and other arguments based on proton affinities and dipole moments, we conclude that the best candidate for a carrier of the observed lines is the protonated cyanodiacetylene cation, HC5NH+. The HC5N/HC5NH+ ratio derived in TMC-1 is 240, which is very similar to the HC3N/HC3NH+ ratio. Results are discussed in the framework of a chemical model for protonated molecules in cold dense clouds.

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arXiv2020

Discovery of HC3O+ in space: The chemistry of O-bearing species in TMC-1

Using the Yebes 40m and IRAM 30m radio telescopes, we detected a series of harmonically related lines with a rotational constant B0=4460.590 +/- 0.001 MHz and a distortion constant D0=0.511 +/- 0.005 kHz towards the cold dense core TMC-1. High-level-of-theory ab initio calculations indicate that the best possible candidate is protonated tricarbon monoxide, HC3O+. We have succeeded in producing this species in the laboratory and observed its J = 2-1 and 3-2 rotational transitions. Hence, we report the discovery of HC3O+ in space based on our observations, theoretical calculations, and laboratory experiments. We derive an abundance ratio N(C3O)/N(HC3O+) = 7. The high abundance of the protonated form of C3O is due to the high proton affinity of the neutral species. The chemistry of O-bearing species is modelled, and predictions are compared to the derived abundances from our data for the most prominent O-bearing species in TMC-1.

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arXiv2020

The abundance of S- and Si-bearing molecules in O-rich circumstellar envelopes of AGB stars

Aims: We aim to determine the abundances of SiO, CS, SiS, SO, and SO$_2$ in a large sample of oxygen-rich AGB envelopes covering a wide range of mass loss rates to investigate the potential role that these molecules could play in the formation of dust in these environments. Methods:We surveyed a sample of 30 oxygen-rich AGB stars in the $λ$ 2 mm band using the IRAM 30m telescope. We performed excitation and radiative transfer calculations based on the LVG method to model the observed lines of the molecules and to derive their fractional abundances in the observed envelopes. Results:We detected SiO in all 30 targeted envelopes, as well as CS, SiS, SO, and SO$_2$ in 18, 13, 26, and 19 sources, respectively. Remarkably, SiS is not detected in any envelope with a mass loss rate below $10^{-6}$ M$_{\odot}$ yr$^{-1}$, whereas it is detected in all envelopes with mass loss rates above that threshold. From a comparison with a previous, similar study on C-rich sources, it becomes evident that the fractional abundances of CS and SiS show a marked differentiation between C-rich and O-rich sources, being two orders of magnitude and one order of magnitude more abundant in C-rich sources, respectively, while the fractional abundance of SiO turns out to be insensitive to the C/O ratio. The abundance of SiO in O-rich envelopes behaves similarly to C-rich sources, that is, the denser the envelope the lower its abundance. A similar trend, albeit less clear than for SiO, is observed for SO in O-rich sources. Conclusions: The marked dependence of CS and SiS abundances on the C/O ratio indicates that these two molecules form more efficiently in C- than O-rich envelopes. The decline in the abundance of SiO with increasing envelope density and the tentative one for SO indicate that SiO and possibly SO act as gas-phase precursors of dust in circumstellar envelopes around O-rich AGB stars.

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arXiv2020

Discovery of HC4NC in TMC-1: A study of the isomers of HC3N, HC5N, and HC7N

We present a study of the isocyano isomers of the cyanopolyynes HC3N, HC5N, and HC7N in TMC-1 and IRC+10216 carried out with the Yebes 40m radio telescope. This study has enabled us to report the detection, for the first time in space, of HCCCCNC in TMC-1 and to give upper limits for HC6NC in the same source. In addition, the deuterated isotopologues of HCCNC and HNCCC were detected, along with all 13C substitutions of HCCNC, also for the first time in space. The abundance ratios of HC3N and HC5N, with their isomers, are very different in TMC-1 and IRC+10216, namely, N(HC5N)/N(HC4NC) is 300 and >2100, respectively. We discuss the chemistry of the metastable isomers of cyanopolyynes in terms of the most likely formation pathways and by comparing observational abundance ratios between different sources.

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arXiv2020

Interstellar nitrile anions: Detection of C3N- and C5N- in TMC-1

We report on the first detection of C3N- and C5N- towards the cold dark core TMC-1 in the Taurus region, using the Yebes 40 m telescope. The observed C3N/C3N- and C5N/C5N- abundance ratios are 140 and 2, respectively; that is similar to those found in the circumstellar envelope of the carbon-rich star IRC+10216. Although the formation mechanisms for the neutrals are different in interstellar (ion-neutral reactions) and circumstellar clouds (photodissociation and radical-neutral reactions), the similarity of the C3N/C3N- and C5N/C5N- abundance ratios strongly suggests a common chemical path for the formation of these anions in interstellar and circumstellar clouds. We discuss the role of radiative electronic attachment, reactions between N atoms and carbon chain anions Cn-, and that of H- reactions with HC3N and HC5N as possible routes to form CnN-. The detection of C5N- in TMC-1 gives strong support for assigning to this anion the lines found in IRC+10216, as it excludes the possibility of a metal-bearing species, or a vibrationally excited state. New sets of rotational parameters have been derived from the observed frequencies in TMC-1 and IRC+10216 for C5N- and the neutral radical C5N.

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arXiv2020

Chemical equilibrium in AGB atmospheres: Successes, failures, and prospects for small molecules, clusters, and condensates

Chemical equilibrium has proven extremely useful to predict the chemical composition of AGB atmospheres. Here we use a recently developed code and an updated thermochemical database, including gaseous and condensed species involving 34 elements, to compute the chemical equilibrium composition of AGB atmospheres of M-, S-, and C-type stars. We include for the first time TixCy clusters, with x = 1-4 and y = 1-4, and selected larger clusters ranging up to Ti13C22, for which thermochemical data is obtained from quantum chemical calculations. We find that in general chemical equilibrium reproduces well the observed abundances of parent molecules in circumstellar envelopes of AGB stars. There are however severe discrepancies, of various orders of magnitude, for some parent molecules: HCN, CS, NH3, and SO2 in M-type stars, H2O and NH3 in S-type stars, and the hydrides H2O, NH3, SiH4, and PH3 in C-type stars. Several molecules not yet observed in AGB atmospheres, like SiC5, SiNH, SiCl, PS, HBO, and the metal-containing molecules MgS, CaS, CaOH, CaCl, CaF, ScO, ZrO, VO, FeS, CoH, and NiS, are good candidates for detection with observatories like ALMA. The first condensates predicted are carbon, TiC, and SiC in C-rich atmospheres and Al2O3 in O-rich outflows. The most probable gas-phase precursors of dust are acetylene, atomic carbon, and/or C3 for carbon dust, SiC2 and Si2C for SiC dust, and atomic Al and AlOH, AlO, and Al2O for Al2O3 dust. In the case of TiC dust, atomic Ti is probably the main supplier of titanium. However, chemical equilibrium predicts that clusters like Ti8C12 and Ti13C22 become the major reservoirs of titanium at the expense of atomic Ti in the region where condensation of TiC is expected to occur, suggesting that the assembly of large TixCy clusters could be related to the formation of the first condensation nuclei of TiC.

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arXiv2020

New molecular species at redshift z=0.89

We present the first detections of CH3SH, C3H+, C3N, HCOOH, CH2CHCN, and H2CN in an extragalactic source. Namely the spiral arm of a galaxy located at z=0.89 on the line of sight to the radio-loud quasar PKS 1830-211. OCS, SO2, and NH2CN were also detected, raising the total number of molecular species identified in that early time galaxy to 54, not counting isotopologues. The detections were made in absorption against the SW quasar image, at 2 kpc from the galaxy centre, over the course of a Q band spectral line survey made with the Yebes 40 m telescope (rest-frame frequencies: 58.7-93.5 GHz). We derived the rotational temperatures and column densities of those species, which are found to be subthermally excited. The molecular abundances, and in particular the large abundances of C3H+ and of several previously reported cations, are characteristic of diffuse or translucent clouds with enhanced UV radiation or strong shocks.

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arXiv2019

IRC+10216 mass loss properties through the study of $λ$3mm emission: Large spatial scale distribution of SiO, SiS, and CS

The study of the gas in the envelopes surrounding asymptotic giant branch (AGB) stars through observations in the millimetre wavelength range provides information about the history and nature of these molecular factories. Here we present ALMA observations at subarsecond resolution, complemented with IRAM-30m data, of several lines of SiO, SiS, and CS towards the best-studied AGB circumstellar envelope, IRC+10216. We aim to characterise their spatial distribution and determine their fractional abundances mainly through radiative transfer and chemical modelling. The three species display extended emission with several enhanced emission shells. CS displays the most extended distribution reaching distances up to approximately 20''. SiS and SiO emission have similar sizes of approximately 11'', but SiS emission is slightly more compact. We have estimated fractional abundances relative to H$_2$, which on average are equal to f(SiO)$\sim$10$^{-7}$, f(SiS)$\sim$10$^{-6}$, and f(CS)$\sim$10$^{-6}$ up to the photo-dissociation region. The observations and analysis presented here show evidence that the circumstellar material displays clear deviations from an homogeneous spherical wind, with clumps and low density shells that may allow UV photons from the interstellar medium (ISM) to penetrate deep into the envelope, shifting the photo-dissociation radius inwards. Our chemical model predicts photo-dissociation radii compatible with those derived from the observations, although it is unable to predict abundance variations from the starting radius of the calculations ($\sim$10$R_{*}$), which may reflect the simplicity of the model. We conclude that the spatial distribution of the gas proves the episodic and variable nature of the mass loss mechanism of IRC+10216, on timescales of hundreds of years.

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arXiv2019

Study of CS, SiO, and SiS abundances in carbon star envelopes: Assessing their role as gas-phase precursors of dust

Aim: We aim to determine the abundances of CS, SiO, and SiS in a large sample of carbon star envelopes covering a wide range of mass loss rates to investigate the potential role that these molecules could play in the formation of dust in the surroundings of the central AGB star. Methods: We surveyed a sample of 25 carbon-rich AGB stars in the $λ$ 2 mm band, using the IRAM 30 m telescope. We performed excitation and radiative transfer calculations based on the LVG method to model the observed lines of the molecules and to derive their fractional abundances in the observed CSEs. Results: We detected CS in all 25 CSEs, SiO in 24 of them, and SiS in 17 sources. We found that CS and SiS have similar abundances in carbon star envelopes, while SiO is present with a lower abundance. We also found a strong correlation in which the denser the envelope, the less abundant are CS and SiO. The trend is however only tentatively seen for SiS in the range of high mass loss rates. Furthermore, we found a relation in which the integrated flux of the MgS dust feature at 30 um increases as the fractional abundance of CS decreases. Conclusions: The decline in the fractional abundance of CS with increasing density could be due to gas-phase chemistry in the inner envelope or to adsorption onto dust grains. The latter possibility is favored by a correlation between the CS fractional abundance and the 30 um feature, which suggests that CS is efficiently incorporated onto MgS dust around C-rich AGB stars. In the case of SiO, the observed abundance depletion with increasing density is most likely caused by an efficient incorporation onto dust grains. We conclude that CS, SiO (very likely), and SiS (tentatively) are good candidates to act as gas-phase precursors of dust in C-rich AGB envelopes.

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arXiv2019

Discovery of the first Ca-bearing molecule in space: CaNC

We report on the detection of calcium isocyanide, CaNC, in the carbon-rich evolved star IRC+10216. We derived a column density for this species of (2.0$\pm$0.5)$\times$10$^{11}$ cm$^{-2}$. Based on the observed line profiles and the modelling of its emission through the envelope, the molecule has to be produced in the intermediate and outer layers of the circumstellar envelope where other metal-isocyanides have previously been found in this source. The abundance ratio of CaNC relative to MgNC and FeCN is $\simeq$1/60 and $\simeq$1, respectively. We searched for the species CaF, CaCl, CaC, CaCCH, and CaCH$_3$ for which accurate frequency predictions are available. Only upper limits have been obtained for these molecules.

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arXiv2019

A sensitive 3 mm line survey of L483: a broad view of the chemical composition of a core around a Class 0 object

We present an IRAM 30m line survey of the dense core L483 in the 3 mm band. We detected 71 molecules (140 including different isotopologs), most of which are present in the cold and quiescent ambient cloud. Of particular interest among the detected molecules are the cis isomer of HCOOH, the complex organic molecules HCOOCH3, CH3OCH3, and C2H5OH, a wide variety of carbon chains, nitrogen oxides like N2O, and saturated molecules like CH3SH. In general, fractional molecular abundances in L483 are systematically lower than in TMC-1 (especially for carbon chains), tend to be higher than in L1544 and B1-b, and are similar to those in L1527. Apart from the overabundance of carbon chains in TMC-1, we find that L483 does not have a marked chemical differentiation with respect to starless/prestellar cores like TMC-1 and L1544, although it does chemically differentiate from Class 0 hot corino sources like IRAS 16293-2422. This fact suggests that the chemical composition of the ambient cloud of some Class 0 sources could be largely inherited from the dark cloud starless/prestellar phase. We also derived isotopic ratios for a variety of molecules, some of which show isotopic anomalies like an extreme depletion in 13C for one of the two isotopologs of c-C3H2, a drastic enrichment in 18O for SO and HNCO (SO being also largely enriched in 17O), and different abundances for the two 13C substituted species of C2H and the two 15N substituted species of N2H+. We report the first detection in space of some minor isotopologs like c-C3D. The exhaustive chemical characterization of L483 presented here, together with similar studies of other prestellar and protostellar sources, should allow us to identify the main factors that regulate the chemical composition of cores along the process of formation of low-mass protostars.

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arXiv2019

Direct estimation of electron density in the Orion Bar PDR from mm-wave carbon recombination lines

A significant fraction of the molecular gas in star-forming regions is irradiated by stellar UV photons. In these environments, the electron density (n_e) plays a critical role in the gas dynamics, chemistry, and collisional excitation of certain molecules. We determine n_e in the prototypical strongly irradiated photodissociation region (PDR), the Orion Bar, from the detection of new millimeter-wave carbon recombination lines (mmCRLs) and existing far-IR [13CII] hyperfine line observations. We detect 12 mmCRLs (including alpha, beta, and gamma transitions) observed with the IRAM 30m telescope, at ~25'' angular resolution, toward the H/H2 dissociation front (DF) of the Bar. We also present a mmCRL emission cut across the PDR. These lines trace the C+/C/CO gas transition layer. As the much lower frequency carbon radio recombination lines, mmCRLs arise from neutral PDR gas and not from ionized gas in the adjacent HII region. This is readily seen from their narrow line profiles (dv=2.6+/-0.4 km/s) and line peak LSR velocities (v_LSR=+10.7+/-0.2 km/s). Optically thin [13CII] hyperfine lines and molecular lines - emitted close to the DF by trace species such as reactive ions CO+ and HOC+ - show the same line profiles. We use non-LTE excitation models of [13CII] and mmCRLs and derive n_e = 60-100 cm^-3 and T_e = 500-600 K toward the DF. The inferred electron densities are high, up to an order of magnitude higher than previously thought. They provide a lower limit to the gas thermal pressure at the PDR edge without using molecular tracers. We obtain P_th > (2-4)x10^8 cm^-3 K assuming that the electron abundance is equal or lower than the gas-phase elemental abundance of carbon. Such elevated thermal pressures leave little room for magnetic pressure support and agree with a scenario in which the PDR photoevaporates.

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arXiv2019

Spectroscopic parameters for silacyclopropynylidene, SiC$_2$, from extensive astronomical observations toward CW Leo (IRC +10216) with the Herschel satellite

A molecular line survey has been carried out toward the carbon-rich asymptotic giant branch star CW Leo employing the HIFI instrument on board of the Herschel satellite. Numerous features from 480 GHz to beyond 1100 GHz could be assigned unambiguously to the fairly floppy SiC$_2$ molecule. However, predictions from laboratory data exhibited large deviations from the observed frequencies even after some lower frequency data from this survey were incorporated into a fit. Therefore, we present a combined fit of all available laboratory data together with data from radio-astronomical observations.

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arXiv2019

Gas infall and possible circumstellar rotation in R Leo

We present new interferometer molecular observations of R Leo taken at 1.2 mm with the Atacama Large Millimeter Array with an angular resolution up to ~0.026 arcsec. These observations permit us to resolve the innermost envelope of this star revealing the existence of a complex structure that involves extended continuum emission and molecular emission showing a non-radial gas velocity distribution. This molecular emission displays prominent red-shifted absorptions located right in front to the star typical of material infall and lateral gas motions compatible with the presence of a torus-like structure.

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