arXiv subjects

J. Cernicharo

Publications and source records attributed to J. Cernicharo.

At least 145 records · Page 8Linked to original sources

arXiv2016

Reactivity of OH and CH3OH between 22 and 64 K: Modelling the gas phase production of CH3O in Barnard 1b

In the last years, ultra-low temperature chemical kinetic experiments have demonstrated that some gas-phase reactions are much faster than previously thought. One example is the reaction between OH and CH3OH, which has been recently found to be accelerated at low temperatures yielding CH3O as main product. This finding opened the question of whether the CH3O observed in the dense core Barnard 1b could be formed by the gas-phase reaction of CH3OH and OH. Several chemical models including this reaction and grain-surface processes have been developed to explain the observed abundance of CH$_3$O with little success. Here we report for the first time rate coefficients for the gas-phase reaction of OH and CH3OH down to a temperature of 22 K, very close to those in cold interstellar clouds. Two independent experimental set-ups based on the supersonic gas expansion technique coupled to the pulsed laser photolysis-laser induced fluorescence technique were used to determine rate coefficients in the temperature range 22-64 K. The temperature dependence obtained in this work can be expressed as k(22-64 K) = (3.6+/-0.1)e-12 (T/ 300)^(-1.0+/-0.2) cm3 molecule-1 s-1. Implementing this expression in a chemical model of a cold dense cloud results in CH3O/CH3OH abundance ratios similar or slightly lower than the value of 3e-3 observed in Barnard 1b. This finding confirms that the gas-phase reaction between OH and CH3OH is an important contributor to the formation of interstellar CH3O. The role of grain-surface processes in the formation of CH3O, although it cannot be fully neglected, remains controversial.

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arXiv2016

Constraints on the H2O formation mechanism in the wind of carbon-rich AGB stars

Context. The recent detection of warm H$_2$O vapor emission from the outflows of carbon-rich asymptotic giant branch (AGB) stars challenges the current understanding of circumstellar chemistry. Two mechanisms have been invoked to explain warm H$_2$O vapor formation. In the first, periodic shocks passing through the medium immediately above the stellar surface lead to H$_2$O formation. In the second, penetration of ultraviolet interstellar radiation through a clumpy circumstellar medium leads to the formation of H$_2$O molecules in the intermediate wind. Aims. We aim to determine the properties of H$_2$O emission for a sample of 18 carbon-rich AGB stars and subsequently constrain which of the above mechanisms provides the most likely warm H$_2$O formation pathway. Methods, Results, and Conclusions. See paper.

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arXiv2015

Polycyclic aromatic hydrocarbons and molecular hydrogen in oxygen-rich planetary nebulae: the case of NGC6720

Evolved stars are primary sources for the formation of polycyclic aromatic hydrocarbons (PAHs) and dust grains. Their circumstellar chemistry is usually designated as either oxygen-rich or carbon-rich, although dual-dust chemistry objects, whose infrared spectra reveal both silicate- and carbon-dust features, are also known. The exact origin and nature of this dual-dust chemistry is not yet understood. Spitzer-IRS mid-infrared spectroscopic imaging of the nearby, oxygen-rich planetary nebula NGC6720 reveals the presence of the 11.3 micron aromatic (PAH) emission band. It is attributed to emission from neutral PAHs, since no band is observed in the 7 to 8 micron range. The spatial distribution of PAHs is found to closely follow that of the warm clumpy molecular hydrogen emission. Emission from both neutral PAHs and warm H2 is likely to arise from photo-dissociation regions associated with dense knots that are located within the main ring. The presence of PAHs together with the previously derived high abundance of free carbon (relative to CO) suggest that the local conditions in an oxygen-rich environment can also become conducive to in-situ formation of large carbonaceous molecules, such as PAHs, via a bottom-up chemical pathway. In this scenario, the same stellar source can enrich the interstellar medium with both oxygen-rich dust and large carbonaceous molecules.

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arXiv2015

The peculiar distribution of CH3CN in IRC+10216 seen by ALMA

IRC+10216 is a circumstellar envelope around a carbon-rich evolved star which contains a large variety of molecules. According to interferometric observations, molecules are distributed either concentrated around the central star or as a hollow shell with a radius of 15". We present ALMA Cycle 0 band 6 observations of the J=14-13 rotational transition of CH3CN in IRC+10216, obtained with an angular resolution of 0.76x0.61". The bulk of the emission is distributed as a hollow shell located at just 2" from the star, with a void of emission in the central region up to a radius of 1". This spatial distribution is markedly different from those found to date in this source for other molecules. Our analysis indicate that methyl cyanide is not formed neither in the stellar photosphere nor far in the outer envelope, but at radial distances as short as 1-2", reaching a maximum abundance of 0.02 molecules cm-3 at 2" from the star. Standard chemical models of IRC+10216 predict that the bulk of CH3CN molecules should be present at a radius of 15", where other species such as polyyne radicals and cyanopolyynes are observed, with an additional inner component within 1" from the star. The non-uniform structure of the circumstellar envelope and grain surface processes are discussed as possible causes of the peculiar distribution of methyl cyanide in IRC+10216.

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arXiv2015

Velocity-resolved [CII] emission and [CII]/FIR Mapping along Orion with Herschel

We present the first 7.5'x11.5' velocity-resolved map of the [CII]158um line toward the Orion molecular cloud-1 (OMC-1) taken with the Herschel/HIFI instrument. In combination with far-infrared (FIR) photometric images and velocity-resolved maps of the H41alpha hydrogen recombination and CO J=2-1 lines, this data set provides an unprecedented view of the intricate small-scale kinematics of the ionized/PDR/molecular gas interfaces and of the radiative feedback from massive stars. The main contribution to the [CII] luminosity (~85%) is from the extended, FUV-illuminated face of the cloud G_0>500, n_H>5x10^3 cm^-3) and from dense PDRs (G_0~10^4, n_H~10^5 cm^-3) at the interface between OMC-1 and the HII region surrounding the Trapezium cluster. Around 15% of the [CII] emission arises from a different gas component without CO counterpart. The [CII] excitation, PDR gas turbulence, line opacity (from [13CII]) and role of the geometry of the illuminating stars with respect to the cloud are investigated. We construct maps of the [CII]/FIR and FIR/M_Gas ratios and show that [CII]/FIR decreases from the extended cloud component (10^-2-10^-3) to the more opaque star-forming cores (10^-3-10^-4). The lowest values are reminiscent of the "[CII] deficit" seen in local ultra-luminous IR galaxies hosting vigorous star formation. Spatial correlation analysis shows that the decreasing [CII]/FIR ratio correlates better with the column density of dust through the molecular cloud than with FIR/M_Gas. We conclude that the [CII] emitting column relative to the total dust column along each line of sight is responsible for the observed [CII]/FIR variations through the cloud.

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arXiv2015

Searching for Trans Ethyl Methyl Ether in Orion KL

We report on the tentative detection of $trans$ Ethyl Methyl Ether (tEME), $t-CH_3CH_2OCH_3$, through the identification of a large number of rotational lines from each one of the spin states of the molecule towards Orion KL. We also search for $gauche$-$trans$-n-propanol, $Gt-n-CH_3CH_2CH_2OH$, an isomer of tEME in the same source. We have identified lines of both species in the IRAM 30m line survey and in the ALMA Science Verification data. We have obtained ALMA maps to establish the spatial distribution of these species. Whereas tEME mainly arises from the compact ridge component of Orion, Gt-n-propanol appears at the emission peak of ethanol (south hot core). The derived column densities of these species at the location of their emission peaks are $\leq(4.0\pm0.8)\times10^{15} cm^{-2}$ and $\leq(1.0\pm0.2)\times10^{15} cm^{-2}$ for tEME and Gt-n-propanol, respectively. The rotational temperature is $\sim100 K$ for both molecules. We also provide maps of $CH_3OCOH$, $CH_3CH_2OCOH$, $CH_3OCH_3$, $CH_3OH$, and $CH_3CH_2OH$ to compare the distribution of these organic saturated O-bearing species containing methyl and ethyl groups in this region. Abundance ratios of related species and upper limits to the abundances of non-detected ethers are provided. We derive an abundance ratio $N(CH_3OCH_3)/N(tEME)\geq150$ in the compact ridge of Orion.

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arXiv2015

Probing highly obscured, self-absorbed galaxy nuclei with vibrationally excited HCN

We present high resolution (0."4) IRAM PdBI and ALMA mm and submm observations of the (ultra) luminous infrared galaxies ((U)LIRGs) IRAS17208-0014, Arp220, IC860 and Zw049.057 that reveal intense line emission from vibrationally excited ($ν_2$=1) J=3-2 and 4-3 HCN. The emission is emerging from buried, compact (r<17-70 pc) nuclei that have very high implied mid-infrared surface brightness $>$$5\times 10^{13}$ L$_{\odot}$ kpc$^{-2}$. These nuclei are likely powered by accreting supermassive black holes (SMBHs) and/or hot (>200 K) extreme starbursts. Vibrational, $ν_2$=1, lines of HCN are excited by intense 14 micron mid-infrared emission and are excellent probes of the dynamics, masses, and physical conditions of (U)LIRG nuclei when H$_2$ column densities exceed $10^{24}$ cm$^{-2}$. It is clear that these lines open up a new interesting avenue to gain access to the most obscured AGNs and starbursts. Vibrationally excited HCN acts as a proxy for the absorbed mid-infrared emission from the embedded nuclei, which allows for reconstruction of the intrinsic, hotter dust SED. In contrast, we show strong evidence that the ground vibrational state ($ν$=0), J=3-2 and 4-3 rotational lines of HCN and HCO$^+$ fail to probe the highly enshrouded, compact nuclear regions owing to strong self- and continuum absorption. The HCN and HCO$^+$ line profiles are double-peaked because of the absorption and show evidence of non-circular motions - possibly in the form of in- or outflows. Detections of vibrationally excited HCN in external galaxies are so far limited to ULIRGs and early-type spiral LIRGs, and we discuss possible causes for this. We tentatively suggest that the peak of vibrationally excited HCN emission is connected to a rapid stage of nuclear growth, before the phase of strong feedback.

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arXiv2015

The abundance of 28Si32S, 29Si32S, 28Si34S, and 30Si32S in the inner layers of the envelope of IRC+10216

We present high spectral resolution mid-IR observations of SiS towards the C-rich AGB star IRC+10216 carried out with the Texas Echelon-cross-Echelle Spectrograph mounted on the NASA Infrared Telescope Facility. We have identified 204 ro-vibrational lines of 28Si32S, 26 of 29Si32S, 20 of 28Si34S, and 15 of 30Si32S in the frequency range 720-790 cm-1. These lines belong to bands v=1-0, 2-1, 3-2, 4-3, and 5-4, and involve rotational levels with Jlow<90. About 30 per cent of these lines are unblended or weakly blended and can be partially or entirely fitted with a code developed to model the mid-IR emission of a spherically symmetric circumstellar envelope composed of expanding gas and dust. The observed lines trace the envelope at distances to the star <35R* (~0.7 arcsec). The fits are compatible with an expansion velocity of 1+2.5(r/R*-1) km/s between 1 and 5R*, 11 km/s between 5 and 20R*, and 14.5 km/s outwards. The derived abundance profile of 28Si32S with respect to H2 is 4.9e-6 between the stellar photosphere and 5R*, decreasing linearly to 1.6e-6 at 20R* and to 1.3e-6 at 50R*. 28Si32S seems to be rotationally under LTE in the region of the envelope probed with our observations and vibrationally out of LTE in most of it. There is a red-shifted emission excess in the 28Si32S lines of band v=1-0 that cannot be found in the lines of bands v=2-1, 3-2, 4-3, and 5-4. This excess could be explained by an enhancement of the vibrational temperature around 20R* behind the star. The derived isotopic ratios 28Si/29Si, and 32S/34S are 17 and 14, compatible with previous estimates.

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arXiv2015

New observations and models of circumstellar CO line emission of AGB stars in the Herschel SUCCESS programme

CONTEXT: Asymptotic giant branch (AGB) stars are in one of the latest evolutionary stages of low to intermediate-mass stars. Their vigorous mass loss has a significant effect on the stellar evolution, and is a significant source of heavy elements and dust grains for the interstellar medium. The mass-loss rate can be well traced by carbon monoxide (CO) line emission. AIMS: We present new Herschel HIFI and IRAM 30m telescope CO line data for a sample of 53 galactic AGB stars. The lines cover a fairly large range of excitation energy from the $J=1\to0$ line to the $J=9\to8$ line, and even the $J=14\to13$ line in a few cases. We perform radiative transfer modelling for 38 of these sources to estimate their mass-loss rates. METHODS: We used a radiative transfer code based on the Monte Carlo method to model the CO line emission. We assume spherically symmetric circumstellar envelopes that are formed by a constant mass-loss rate through a smoothly accelerating wind. RESULTS: We find models that are consistent across a broad range of CO lines for most of the stars in our sample, i.e., a large number of the circumstellar envelopes can be described with a constant mass-loss rate. We also find that an accelerating wind is required to fit, in particular, the higher-J lines and that a velocity law will have a significant effect on the model line intensities. The results cover a wide range of mass-loss rates ($\sim 10^{-8}$ to $2\times 10^{-5}~\mathrm{M}_\odot~\mathrm{ yr}^{-1}$) and gas expansion velocities (2 to $21.5$ km s$^{-1}$), and include M-, S-, and C-type AGB stars. Our results generally agree with those of earlier studies, although we tend to find slightly lower mass-loss rates by about 40%, on average. We also present "bonus" lines detected during our CO observations.

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arXiv2015

Probing non polar interstellar molecules through their protonated form: Detection of protonated cyanogen (NCCNH+)

Cyanogen (NCCN) is the simplest member of the series of dicyanopolyynes. It has been hypothesized that this family of molecules can be important constituents of interstellar and circumstellar media, although the lack of a permanent electric dipole moment prevents its detection through radioastronomical techniques. Here we present the first solid evidence of the presence of cyanogen in interstellar clouds through the detection of its protonated form toward the cold dark clouds TMC-1 and L483. Protonated cyanogen (NCCNH+) has been identified through the J=5-4 and J=10-9 rotational transitions using the 40m radiotelescope of Yebes and the IRAM 30m telescope. We derive beam averaged column densities for NCCNH+ of (8.6+/-4.4)e10 cm-2 in TMC-1 and (3.9+/-1.8)e10 cm-2 in L483, which translate to fairly low fractional abundances relative to H2, in the range (1-10)e-12. The chemistry of protonated molecules in dark clouds is discussed, and it is found that, in general terms, the abundance ratio between the protonated and non protonated forms of a molecule increases with increasing proton affinity. Our chemical model predicts an abundance ratio NCCNH+/NCCN of 1e-4, which implies that the abundance of cyanogen in dark clouds could be as high as (1-10)e-8 relative to H2, i.e., comparable to that of other abundant nitriles such as HCN, HNC, and HC3N.

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arXiv2015

Very Large Telescope observations of Gomez's Hamburger: Insights into a young protoplanet candidate

Planets are thought to form in the gas and dust disks around young stars. In particular, it has been proposed that giant planets can form through the gravitational instability of massive extended disks around intermediate-mass stars. However, we still lack direct observations to constrain this mechanism. We have spatially resolved the 8.6 and 11.2 $μ$m emission of a massive protoplanetary disk seen edge on around an A star, Gomez's Hamburger (GoHam), using VISIR at the Very Large Telescope. A compact region situated at a projected distance of $350\pm50$ AU south of the central star is found to have a reduced emission.This asymmetry is fully consistent with the presence of a cold density structure, or clump, identified in earlier CO observations, and we derive physical characteristics consistent with those observations: a mass of 0.8-11.4 Jupiter masses (for a dust-to-gas mass ratio of 0.01), a radius of about 10$^2$ astronomical units, and a local density of about $10^{7}$ cm$^{-3}$. Based on this evidence, we argue that this clump, which we call GoHam b, is a promising candidate for a young protoplanet formed by gravitational instability that might be representative of the precursors of massive planets observed around A stars, such as HR 8799 or Beta pictoris. More detailed studies at high angular resolution are needed to better constrain the physical properties of this object to confirm this proposal.

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arXiv2015

Si-bearing molecules towards IRC+10216: ALMA unveils the molecular envelope of CWLeo

We report the detection during the ALMA Cycle 0 of SiS rotational lines in high-vibrational states as well as SiO and SiC$_2$ lines in their ground vibrational state, towards IRC+10216. The spatial distribution of these molecules shows compact emission for SiS and a more extended emission for SiO and SiC$_2$, and also proves the existence of an increase in the SiC$_2$ emission at the outer shells of the circumstellar envelope. We analyze the excitation conditions of the vibrationally excited SiS using the population diagram technique and we used a large velocity gradient model to compare with the observations. We found moderate discrepancies between the observations and the models that could be explained if SiS lines detected are optically thick. Additionally, the line profiles of the detected rotational lines in the high energy vibrational states show a decreasing linewidth with increasing energy levels. This may evidence that these lines could be excited only in the inner shells, i.e. the densest and hottest, of the circumstellar envelope of IRC+10216.

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arXiv2015

Chemical composition of the circumstellar disk around AB Aurigae

Aims. Our goal is to determine the molecular composition of the circumstellar disk around AB Aurigae (hereafter, AB Aur). AB Aur is a prototypical Herbig Ae star and the understanding of its disk chemistry is of paramount importance to understand the chemical evolution of the gas in warm disks. Methods. We used the IRAM 30-m telescope to perform a sensitive search for molecular lines in AB Aur as part of the IRAM Large program ASAI (A Chemical Survey of Sun-like Star-forming Regions). These data were complemented with interferometric observations of the HCO+ 1-0 and C17O 1-0 lines using the IRAM Plateau de Bure Interferometer (PdBI). Single-dish and interferometric data were used to constrain chemical models. Results. Throughout the survey, several lines of CO and its isotopologues, HCO+, H2CO, HCN, CN and CS, were detected. In addition, we detected the SO 54-33 and 56-45 lines, confirming the previous tentative detection. Comparing to other T Tauri's and Herbig Ae disks, AB Aur presents low HCN 3-2/HCO+ 3-2 and CN 2-1/HCN 3-2 line intensity ratios, similar to other transition disks. AB Aur is the only protoplanetary disk detected in SO thus far. Conclusions. We modeled the line profiles using a chemical model and a radiative transfer 3D code. Our model assumes a flared disk in hydrostatic equilibrium. The best agreement with observations was obtained for a disk with a mass of 0.01 Msun , Rin=110 AU, Rout=550 AU, a surface density radial index of 1.5 and an inclination of 27 deg. The intensities and line profiles were reproduced within a factor of 2 for most lines. This agreement is reasonable taking into account the simplicity of our model that neglects any structure within the disk. However, the HCN 3-2 and CN 2-1 line intensities were predicted more intense by a factor of >10. We discuss several scenarios to explain this discrepancy.

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arXiv2015

Discovery of SiCSi in IRC+10216: A missing link between gas and dust carriers of SiC bonds

We report the discovery in space of a disilicon species, SiCSi, from observations between 80 and 350 GHz with the IRAM 30m radio telescope. Owing to the close coordination between laboratory experiments and astrophysics, 112 lines have now been detected in the carbon-rich star CWLeo. The derived frequencies yield improved rotational and centrifugal distortion constants up to sixth order. From the line profiles and interferometric maps with the Submillimeter Array, the bulk of the SiCSi emis- sion arises from a region of 6 arcseconds in radius. The derived abundance is comparable to that of SiC2. As expected from chemical equilibrium calculations, SiCSi and SiC2 are the most abundant species harboring a SiC bond in the dust formation zone and certainly both play a key role in the formation of SiC dust grains.

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arXiv2015

New N-bearing species towards OH231.8+4.2: HNCO, HNCS, HC$_3$N and NO

OH231.8+4.2 is a well studied O-rich CSE around an intermediate-mass evolved star that displays bipolar molecular outflows accelerated up to 400 km/s. OH231 also presents an exceptional molecular richness probably due to shock-induced chemical processes. We report the first detection in this source of HNCO, HNCS, HC3N and NO, with the IRAM-30m telescope in a sensitive mm-wavelength survey towards this target. HNCO and HNCS are also first detections in CSEs. The observed line profiles show that the emission arises in the massive central component of the envelope and at the base of the fast lobes. The NO profiles are broader than those of HNCO, HNCS, and HC3N, and most importantly, broader than the line profiles of 13CO. This indicates that the NO abundance is enhanced in the fast lobes relative to the slow, central parts. From LTE and non-LTE excitation analysis, we estimate beam-average rotational temperatures of 15-30 K (and, maybe, up to 55 K for HC3N) and fractional abundances of X(HNCO)=[0.8-1]E-7, X(HNCS)=[0.9-1]E-8, X(HC3N)=[5-7]E-9 and X(NO)=[1-2]E-6. NO is, therefore, amongst the most abundant N-bearing species in OH231. We have performed thermodynamical chemical equilibrium and chemical kinetics models to investigate the formation of these N-bearing species in OH231. The model underestimates the observed abundances for HNCO, HNCS, and HC3N by several orders of magnitude, which indicates that these molecules can hardly be products of standard UV-photon and/or cosmic-ray induced chemistry in OH231, and that other processes (e.g. shocks) play a major role in their formation. For NO, the model abundance is compatible with the observed average value. The new detections presented in this work corroborate the particularly rich chemistry of OH231, which is likely profoundly influenced by shock-induced processes, as proposed in earlier works.

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arXiv2015

Nascent bipolar outflows associated with the first hydrostatic core candidates Barnard 1b-N and 1b-S

In the theory of star formation, the first hydrostatic core (FHSC) phase is a critical step in which a condensed object emerges from a prestellar core. This step lasts about one thousand years, a very short time compared with the lifetime of prestellar cores, and therefore is hard to detect unambiguously. We present IRAM Plateau de Bure observations of the Barnard 1b dense molecular core, combining detections of H2CO and CH3OH spectral lines and dust continuum at 2.3" resolution (~ 500 AU). The two compact cores B1b-N and B1b-S are detected in the dust continuum at 2mm, with fluxes that agree with their spectral energy distribution. Molecular outflows associated with both cores are detected. They are inclined relative to the direction of the magnetic field, in agreement with predictions of collapse in turbulent and magnetized gas with a ratio of mass to magnetic flux somewhat higher than the critical value, μ~ 2 - 7. The outflow associated with B1b-S presents sharp spatial structures, with ejection velocities of up to ~ 7 kms from the mean velocity. Its dynamical age is estimated to be ~2000 yrs. The B1b-N outflow is smaller and slower, with a short dynamical age of ~1000 yrs. The B1b-N outflow mass, mass-loss rate, and mechanical luminosity agree well with theoretical predictions of FHSC. These observations confirm the early evolutionary stage of B1b-N and the slightly more evolved stage of B1b-S.

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arXiv2015

Molecular ions in the O-rich evolved star OH231.8+4.2: HCO$^+$,H$^{13}$CO$^+$ and first detection of SO$^+$, N$_2$H$^+$, and H$_3$O$^+$

OH 231.8+4.2, a bipolar outflow around a Mira-type variable star, displays a unique molecular richness amongst circumstellar envelopes (CSEs) around O-rich AGB and post-AGB stars. We report line observations of the HCO+ and H13CO+ molecular ions and the first detection of SO+, N2H+, and (tentatively) H3O+ in this source. SO+ and H3O+ have not been detected before in CSEs around evolved stars. These data have been obtained as part of a full mm-wave and far-IR spectral line survey carried out with the IRAM 30 m radio telescope and with Herschel/HIFI. Except for H3O+, all the molecular ions detected in this work display emission lines with broad profiles (FWHM 50-90 km/s), which indicates that these ions are abundant in the fast bipolar outflow of OH 231.8. The narrow profile (FWHM 14 km/s) and high critical densities (>1e6cm-3 ) of the H3O+ transitions observed are consistent with this ion arising from denser, inner (and presumably warmer) layers of the fossil remnant of the slow AGB CSE at the core of the nebula. From rotational diagram analysis, we deduce excitation temperatures of Tex 10-20 K for all ions except for H3O+, which is most consistent with Tex 100 K. Although uncertain, the higher excitation temperature suspected for H3O+ is similar to that recently found for H2O and a few other molecules, which selectively trace a previously unidentified, warm nebular component.The column densities of the molecular ions reported here are in the range Ntot [1-8]x1e13 cm-2, leading to beam-averaged fractional abundances relative to H2 of X(HCO+) 1e-8, X(H13CO+) 2e-9, X(SO+) 4e-9, X(N2H+) 2e-9, and X(H3O+) 7e-9 cm-2. We have performed chemical kinetics models to investigate the formation of these ions in OH 231.8 as the result of standard gas phase reactions initiated by cosmic-ray and UV-photon ionization. (abridged).

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arXiv2015

Shedding light on the formation of the pre-biotic molecule formamide with ASAI

Formamide (NH2CHO) has been proposed as a pre-biotic precursor with a key role in the emergence of life on Earth. While this molecule has been observed in space, most of its detections correspond to high-mass star-forming regions. Motivated by this lack of investigation in the low-mass regime, we searched for formamide, as well as isocyanic acid (HNCO), in 10 low- and intermediate-mass pre-stellar and protostellar objects. The present work is part of the IRAM Large Programme ASAI (Astrochemical Surveys At IRAM), which makes use of unbiased broadband spectral surveys at millimetre wavelengths. We detected HNCO in all the sources and NH2CHO in five of them. We derived their abundances and analysed them together with those reported in the literature for high-mass sources. For those sources with formamide detection, we found a tight and almost linear correlation between HNCO and NH2CHO abundances, with their ratio being roughly constant -between 3 and 10- across 6 orders of magnitude in luminosity. This suggests the two species are chemically related. The sources without formamide detection, which are also the coldest and devoid of hot corinos, fall well off the correlation, displaying a much larger amount of HNCO relative to NH2CHO. Our results suggest that, while HNCO can be formed in the gas phase during the cold stages of star formation, NH2CHO forms most efficiently on the mantles of dust grains at these temperatures, where it remains frozen until the temperature rises enough to sublimate the icy grain mantles. We propose hydrogenation of HNCO as a likely formation route leading to NH2CHO.

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