arXiv subjects

J. Croese

Publications and source records attributed to J. Croese.

3 recordsLinked to original sources

arXiv2024

Fully upgraded $\beta$-NMR setup at ISOLDE for high-precision high-field studies

$\beta$-NMR is an advancing technique that enables measurements relevant to various fields of research, ranging from physics to chemistry and biology. Among the recent achievements of the $\beta$-NMR setup located at the ISOLDE facility at CERN is the determination of the magnetic moment of a shortlived nucleus with a part-per-million accuracy. Presented here are major upgrades and extensions of that $\beta$-NMR setup. The most important advancement is the installation of a 4.7 T superconducting solenoidal magnet, leading to sub-ppm spatial homogeneity and temporal stability of the magnetic field. A detector array optimised for such magnetic field has also been implemented and a more powerful, time-resolved, fully-digital data acquisition system has been deployed. To commission the upgraded beamline, $\beta$-NMR resonances of short-lived 26Na were recorded in solid and liquid samples. These showed 3-fold narrower linewidths and 15-fold higher resolving power than using the previous setup. Hence, the improvements achieved here permit more accurate bio-$\beta$-NMR studies, investigating, e.g., the interaction of metal ions with biomolecules, such as DNA. They also pave the way for the first studies of the distribution of the magnetisation inside short-lived nuclei.

physics.ins-det↗

arXiv2021

High-accuracy liquid-sample $\beta$-NMR setup at ISOLDE

Recently there has been an increased interest to apply the sensitive $\beta$-decay asymmetry detected nuclear magnetic resonance ($\beta$-NMR) technique to biological studies. A liquid-sample $\beta$-NMR setup was build at ISOLDE to allow such investigations and to use the resolution gain of liquid-state NMR in nuclear physics. As part of this setup a magnetic field locking system, a set of printed circuit board shimming coils, a sample exchange system, a set of compact $\beta$-detectors and a custom experimental vacuum chamber were developed. The main magnetic field was stabilized down to the ppm level by the locking system while allowing the direct determination of the absolute magnetic field. The homogeneity of the magnetic field was improved to $\leq$~5~ppm over the sample volume by the shimming coils. Time spent on changing samples was reduced by a factor of five by the liquid sample exchange system. During experiments it was possible to continuously observe the liquid sample thanks to the custom chamber and compact $\beta$-detectors. The absolute field determination allows for a novel way to reference $\beta$-NMR measurements, removing the need for time consuming reference measurements. The improved accuracy and resolution resulting from these innovations allows the study of the distribution of nuclear magnetization and (bio)chemicals using high-accuracy liquid-sample $\beta$-NMR.

physics.ins-det↗

arXiv2020

Magnetic moments of short-lived nuclei with part-per-million accuracy: Towards novel applications of $\beta$-detected NMR in physics, chemistry and biology

We determine for the first time the magnetic dipole moment of a short-lived nucleus with part-per-million (ppm) accuracy. To achieve this two orders of magnitude improvement over previous studies, we implement a number of innovations into our $\beta$-detected Nuclear Magnetic Resonance ($\beta$-NMR) setup at ISOLDE/CERN. Using liquid samples as hosts we obtain narrow, sub-kHz linewidth, resonances, while a simultaneous in-situ $^1$H NMR measurement allows us to calibrate and stabilize the magnetic field to ppm precision, thus eliminating the need for additional $\beta$-NMR reference measurements. Furthermore, we use ab initio calculations of NMR shielding constants to improve the accuracy of the reference magnetic moment, thus removing a large systematic error. We demonstrate the potential of this combined approach with the 1.1 s half-life radioactive nucleus $^{26}$Na, which is relevant for biochemical studies. Our technique can be readily extended to other isotopic chains, providing accurate magnetic moments for many short-lived nuclei. Furthermore, we discuss how our approach can open the path towards a wide range of applications of the ultra-sensitive $\beta$-NMR in physics, chemistry, and biology.

physics.chem-ph↗