arXiv subjects

J. Crovisier

Publications and source records attributed to J. Crovisier.

At least 19 recordsLinked to original sources

arXiv2026

Perihelion observations of interstellar comet 3I/ATLAS with the IRAM 30-m telescope

3I/ATLAS is the third interstellar comet identified as passing through the Solar System. Its high outgassing activity and favourable perihelion passage on October 29, 2025 UT provided an excellent opportunity to investigate the composition of its coma gases through millimeter spectroscopy. We present observations undertaken with the IRAM 30-m telescope on November 1--3, 2025 at an heliocentric distance of 1.36--1.37 au. Lines of HCN, CH$_3$OH, CO, and H$_2$CO are well detected, and $\sim$4$\sigma$ detections are obtained for CS and CH$_3$CN. The search for H$_2$S was unsuccessful. Abundances of CO, H$_2$CO, CH$_3$OH, and CH$_3$CN relative to HCN are in the upper ranges of values measured in Solar System comets. The sulfur-to-carbon abundance ratio in 3I/ATLAS's coma is at most the minimum value observed in comets. The unusually low expansion velocity of coma gases suggests a near-nucleus gas flow driven by heavy molecules such as CO$_2$, and/or a large fraction of the gaseous production coming from subliming icy grains.

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arXiv2026

A Multi-Wavelength Study of Comet C/2022 E3 (ZTF): Complementary ALMA and JWST Investigations of Water and Methanol in Cometary Comae

Long-period comets, which are often considered to be representative of material in the protoplanetary disk that formed the Solar System, are ideal to investigate the question of chemical inheritance in astronomy. Determining the chemistry of comets, both individually and as a population, has become of great importance in comparative studies against sources representative of evolutionary precursors to planetary systems. Contemporaneous observations of long-period comet C/2022 E3 (ZTF) were obtained with the JWST and the Atacama Large Millimeter/submillimeter Array (ALMA) in early 2023 March. This work focuses on \ce{CH3OH} measurements from both ALMA and JWST as well as \ce{H2O} measurements from JWST. Radiative transfer modeling of \ce{CH3OH} and \ce{H2O} was performed to investigate spatial variations in rotational temperature, column density, and production rates, as well as a comparison of derived values between the two telescopes. Most of the spatial distributions of the modeled values are centrally peaked, and the modeled values from JWST are all within the error bars of the average values from ALMA. C/2022 E3 (ZTF) also displays an enhancement in modeled rotational temperature in the anti-Sunward direction that is shown to be statistically significant. Based on non-LTE radiative transfer modeling, the declining \ce{H2O} rotational temperatures as a function of nucleocentric distance observed by JWST can be explained primarily as a result of rotational line cooling. The values derived in this work are in general agreement with single-dish millimeter-wave observations.

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arXiv2025

A D/H Ratio Consistent with Earth's Water in Halley-type Comet 12P from ALMA HDO Mapping

Isotopic measurements of Solar System bodies provide a primary paradigm within which to understand the origins and histories of planetary materials. The D/H ratio in particular, helps reveal the relationship between (and heritage of) different H$_2$O reservoirs within the Solar System. Here we present interferometric maps of water (H$_2$O) and semiheavy water (HDO) in the gas-phase coma of a comet (Halley-type comet 12P/Pons-Brooks), obtained using the Atacama Large Millimeter/submillimeter Array (ALMA). The maps are consistent with outgassing of both H$_2$O and HDO directly from the nucleus, and imply a coma D/H ratio (for water) of $(1.71 \pm 0.44)\times10^{-4}$. This is at the lower end of the range of previously-observed values in comets, and is consistent with D/H in Earth's ocean water. Our results suggest a possible common heritage between a component of the Oort cloud's water ice reservoir, and the water that was delivered to the young Earth during the early history of the Solar System.

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arXiv2024

Evidence for Surprising Heavy Nitrogen Isotopic Enrichment in Comet 46P/Wirtanen's Hydrogen Cyanide

46P/Wirtanen is a Jupiter-family comet, probably originating from the Solar System's Kuiper belt, that now resides on a 5.4 year elliptical orbit. During its 2018 apparition, comet 46P passed unusually close to the Earth (within 0.08 au), presenting an outstanding opportunity for close-up observations of its inner coma. Here we present observations of HCN, H$^{13}$CN and HC$^{15}$N emission from 46P using the Atacama Compact Array (ACA). The data were analyzed using the SUBLIME non-LTE radiative transfer code to derive $^{12}$C/$^{13}$C and $^{14}$N/$^{15}$N ratios. The HCN/H$^{13}$CN ratio is found to be consistent with a lack of significant $^{13}$C fractionation, whereas the HCN/HC$^{15}$N ratio of $68\pm27$ (using our most conservative $1σ$ uncertainties), indicates a strong enhancement in $^{15}$N compared with the solar and terrestrial values. The observed $^{14}$N/$^{15}$N ratio is also significantly lower than the values of $\sim140$ found in previous comets, implying a strong $^{15}$N enrichment in 46P's HCN. This indicates that the nitrogen in Jupiter-family comets could reach larger isotopic enrichments than previously thought, with implications for the diversity of $^{14}$N/$^{15}$N ratios imprinted into icy bodies at the birth of the Solar System.

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arXiv2024

Chemical composition of comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF) from radio spectroscopy and the abundance of HCOOH and HNCO in comets

We present the results of a molecular survey of long period comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF). Comet C/2021 A1 was observed with the IRAM 30-m radio telescope in November-December 2021 before perihelion when it was closest to the Earth. We observed C/2022 E3 in January-February 2023 with the Odin 1-m space telescope and IRAM 30-m, shortly after its perihelion, and when it was closest to the Earth. Snapshots were obtained during 12-16 November 2021 period for comet C/2021 A1. Spectral surveys were undertaken over the 8-13 December 2021 period for comet C/2021 A1 (8, 16, and 61 GHz bandwidth in the 3 mm, 2 mm, and 1 mm window) and over the 3-7 February 2023 period for comet C/2022 E3 (25 and 61 GHz at 2 and 1mm). We report detections of 14 molecular species (HCN, HNC, CH3CN, HNCO, NH2CHO, CH3OH, H2CO, HCOOH, CH3CHO, H2S, CS, OCS, C2H5OH and aGg-(CH2OH)2 ) in both comets plus HC3N and CH2OHCHO marginally detected in C/2021 A1 and CO and H2O (with Odin detected in C/2022 E3. The spatial distribution of several species is investigated. Significant upper limits on the abundances of other molecules and isotopic ratios are also presented. The activity of comet C/2021 A1 did not vary significantly between 13 November and 13 December 2021. Short-term variability in the outgassing of comet C/2022 E3 on the order of +-20% is present and possibly linked to its 8h rotation period. Both comets exhibit rather low abundances relative to water for volatiles species such as CO (< 2%) and H2S (0.15%). Methanol is also rather depleted in comet C/2021 A1 (0.9%). Following their revised photo-destruction rates, HNCO and HCOOH abundances in comets have been reevaluated. Both molecules are relatively enriched in these two comets (0.2% relative to water). We cannot exclude that these species could be produced by the dissociation of ammonium salts.

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arXiv2023

Gas Sources from the Coma and Nucleus of Comet 46P/Wirtanen Observed Using ALMA

Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo-)chemical processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species towards comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) during the comet's unusually close (~0.1 au) approach to Earth in December 2018. Interferometric maps of HCN, CH3OH, CH3CN, H2CO, CS and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH3OH and CH3CN spatial distributions are consistent with production by direct outgassing from (or very near to) the nucleus, with a significant proportion of the observed CH3OH originating from sublimation of icy grains in the near-nucleus coma (at a scale-length $L_p=36\pm7$ km). On the other hand, H2CO, CS and HNC originate primarily from distributed coma sources (with $L_p$ values in the range 550-16,000 km), the identities of which remain to be established. The HCN, CH3OH and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H2CO, CH3CN and CS abundances are relatively low.

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arXiv2022

Water, hydrogen cyanide, carbon monoxide, and dust production from distant comet 29P/Schwassmann-Wachmann 1

29P/Schwassmann-Wachmann 1 is a distant Centaur/comet, showing persistent CO-driven activity and frequent outbursts. We used the Herschel space observatory in 2010, 2011, and 2013 to observe H$_2$O and NH$_3$ and to image the dust coma. Observations with the IRAM 30 m were undertaken in 2007, 2010, 2011, and 2021 to monitor the CO production rate and to search for HCN. Modeling was performed to constrain the size of the sublimating icy grains and to derive the dust production rate. HCN is detected for the first time in comet 29P (at 5$σ$ in the line area). H$_2$O is detected as well, but not NH$_3$. H$_2$O and HCN line shapes differ strongly from the CO line shape, indicating that these two species are released from icy grains. CO production rates are in the range (2.9-5.6) $\times$ 10$^{28}$ s$^{-1}$ (1400--2600 kg s$^{-1}$). A correlation between the CO production rate and coma brightness is observed, as is a correlation between CO and H$_2$O production. The correlation obtained between the excess of CO production and excess of dust brightness with respect to the quiescent state is similar to that established for the continuous activity of comet Hale-Bopp. The measured $Q$(H$_2$O)/$Q$(CO) and $Q$(HCN)/$Q$(CO) production rate ratios are 10.0 $\pm$ 1.5 % and 0.12 $\pm$ 0.03 %, respectively, averaging the April-May 2010 measurements ($Q$(H$_2$O) = (4.1 $\pm$ 0.6) $\times$ 10$^{27}$ s$^{-1}$, $Q$(HCN) = (4.8 $\pm$ 1.1) $\times$ 10$^{25}$ s$^{-1}$). We derive three independent and similar values of the effective radius of the nucleus, $\sim$ 31 $\pm$ 3 km. The inferred dust mass-loss rates during quiescent phases are in the range 30-120 kg s$^{-1}$, indicating a dust-to-gas mass ratio $<$ 0.1 during quiescent activity. We conclude that strong local heterogeneities exist on the surface of 29P, with quenched dust activity from most of the surface, but not in outbursting regions.

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arXiv2022

Water Ortho-to-Para ratio in the coma of comet 67P/Churyumov-Gerasimenko

Abundance ratios of the nuclear-spin isomers of H$_2$O and NH$_3$ have been measured in about two dozen comets, with a mean value corresponding to a nuclear-spin temperature of $\sim$ 30 K. The real meaning of these unequilibrated nuclear-spin abundance ratios is still debated. However, an equilibrated water ortho-to-para ratio (OPR) of 3 is also commonly observed. The H channel of VIRTIS (VIRTIS-H) on board Rosetta provided high-resolution 2.5--2.9 $μ$m spectra of H$_2$O vapour in the coma of comet 67P/Churyumov-Gerasimenko (67P), which are suitable for the determination of the OPR of water in this comet. A large dataset of VIRTIS-H spectra obtained in limb-sounding viewing geometry was analysed, covering heliocentric distances from 1.24 to 2.73 au and altitudes from a few hundred metres to $>$ 100 km. The OPR, together with the H$_2$O rotational temperature and column density, were derived for each spectra. The weak lines of the $ν_1$, $ν_1+ν_3-ν_1$ and $ν_2+ν_3-ν_2$ bands in the 2.774--2.910 $μ$m range were used to calculate by how much the strong $ν_3$ band centred at 2.67 $μ$m is attenuated due to optical depth effects, expressed by the attenuation factor $f_{\rm atten}$. Most OPR determinations are strongly affected by opacity effects, as demonstrated by the observed anti-correlation between the OPR and the column density, and the correlation between the OPR and attenuation factor $f_{\rm atten}$. Based on both radiative transfer calculations and OPR values obtained in low-opacity conditions, we derive an OPR of 2.94 $\pm$ 0.06 for comet 67P. The water OPR measured in the coma of 67P is consistent with laboratory experiments showing that water vapour that has thermally desorbed from water ice has a statistical value of 3, regardless of the past formation process of water ice.

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arXiv2021

Molecular composition of comet 46P/Wirtanen from millimetre-wave spectroscopy

We present the results of a molecular survey of comet 46P/Wirtanen undertaken with the IRAM 30-m and NOEMA radio telescopes in December 2018. Observations at IRAM 30-m during the 12-18 Dec. period comprise a 2 mm spectral survey covering 25 GHz and a 1 mm survey covering 62 GHz. The gas outflow velocity and kinetic temperature have been accurately constrained by the observations. We derive abundances of 11 molecules, some being identified remotely for the first time in a Jupiter-family comet, including complex organic molecules such as formamide, ethylene glycol, acetaldehyde, or ethanol. Sensitive upper limits on the abundances of 24 other molecules are obtained. The comet is found to be relatively rich in methanol (3.4 percent relative to water), but relatively depleted in CO, CS, HNC, HNCO, and HCOOH.

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arXiv2020

Unusually High CO Abundance of the First Active Interstellar Comet

Comets spend most of their lives at large distances from any star, during which time their interior compositions remain relatively unaltered. Cometary observations can therefore provide direct insight into the chemistry that occurred during their birth at the time of planet formation. To-date, there have been no confirmed observations of parent volatiles (gases released directly from the nucleus) of a comet from any planetary system other than our own. Here we present high-resolution, interferometric observations of 2I/Borisov, the first confirmed interstellar comet, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 15th-16th December 2019. Our observations reveal emission from hydrogen cyanide (HCN), and carbon monoxide (CO), coincident with the expected position of 2I/Borisov's nucleus, with production rates Q(HCN)=$(7.0\pm1.1)\times10^{23}$ s$^{-1}$ and Q(CO)=$(4.4\pm0.7)\times10^{26}$ s$^{-1}$. While the HCN abundance relative to water (0.06-0.16%) appears similar to that of typical, previously observed comets in our Solar System, the abundance of CO (35-105%) is among the highest observed in any comet within 2 au of the Sun. This shows that 2I/Borisov must have formed in a relatively CO-rich environment - probably beyond the CO ice-line in the very cold, outer regions of a distant protoplanetary accretion disk, as part of a population of small, icy bodies analogous to our Solar System's own proto-Kuiper Belt.

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arXiv2019

Diurnal variation of dust and gas production in comet 67P/Churyumov-Gerasimenko at the inbound equinox as seen by OSIRIS and VIRTIS-M on board Rosetta

On 27 Apr 2015, when 67P/C-G was at 1.76 au from the Sun and moving towards perihelion, the OSIRIS and VIRTIS-M instruments on Rosetta observed the evolving dust and gas coma during a complete rotation of the comet. We aim to characterize the dust, H2O and CO2 gas spatial distribution in the inner coma. To do this we performed a quantitative analysis of the release of dust and gas and compared the observed H2O production rate with the one calculated using a thermo-physical model. For this study we selected OSIRIS WAC images at 612 nm (dust) and VIRTIS-M image cubes at 612 nm, 2700 nm (H2O) and 4200 nm (CO2). We measured the average signal in a circular annulus, to study spatial variation around the comet, and in a sector of the annulus, to study temporal variation in the sunward direction with comet rotation, both at a fixed distance of 3.1 km from the comet centre. The spatial correlation between dust and water, both coming from the sun-lit side of the comet, shows that water is the main driver of dust activity in this time period. The spatial distribution of CO2 is not correlated with water and dust. There is no strong temporal correlation between the dust brightness and water production rate as the comet rotates. The dust brightness shows a peak at 0deg sub-solar longitude, which is not pronounced in the water production. At the same epoch, there is also a maximum in CO2 production. An excess of measured water production, with respect to the value calculated using a simple thermo-physical model, is observed when the head lobe and regions of the Southern hemisphere with strong seasonal variations are illuminated. A drastic decrease in dust production, when the water production (both measured and from the model) displays a maximum, happens when typical Northern consolidated regions are illuminated and the Southern hemisphere regions with strong seasonal variations are instead in shadow.

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arXiv2019

ALMA Autocorrelation Spectroscopy of Comets: The HCN/H^13CN ratio in C/2012 S1 (ISON)

The Atacama Large Millimeter/submillimeter Array (ALMA) is a powerful tool for high-resolution mapping of comets, but the main interferometer (comprised of 50x12-m antennas) is insensitive to the largest coma scales due to a lack of very short baselines. In this work, we present a new technique employing ALMA autocorrelation data (obtained simultaneously with the interferometric observations), effectively treating the entire 12-m array as a collection of single-dish telescopes. Using combined autocorrelation spectra from 28 active antennas, we recovered extended HCN coma emission from comet C/2012 S1 (ISON), resulting in a fourteen-fold increase in detected line brightness compared with the interferometer. This resulted in the first detection of rotational emission from H^13CN in this comet. Using a detailed coma radiative transfer model accounting for optical depth and non-LTE excitation effects, we obtained an H^12CN/H^13CN ratio of 88+-18, which matches the terrestrial value of 89, consistent with a lack of isotopic fractionation in HCN during comet formation in the protosolar accretion disk. The possibility of future discoveries in extended sources using autocorrelation spectroscopy from the main ALMA array is thus demonstrated.

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arXiv2019

VIRTIS-H observations of comet 67P's dust coma: spectral properties and color temperature variability with phase and elevation

We analyze 2-5 micrometre spectroscopic observations of the dust coma of comet 67P/Churyumov-Gerasimenko obtained with the VIRTIS-H instrument onboard Rosetta from 3 June to 29 October 2015 at heliocentric distances r_h = 1.24-1.55 AU. The 2-2.5 micrometre color, bolometric albedo, and color temperature are measured using spectral fitting. Data obtained at alpha = 90° solar phase angle show an increase of the bolometric albedo (0.05 to 0.14) with increasing altitude (0.5 to 8 km), accompanied by a possible marginal decrease of the color and color temperature. Possible explanations include the presence in the inner coma of dark particles on ballistic trajectories, and radial changes in particle composition. In the phase angle range 50-120°, phase reddening is significant (0.031 %/100 nm/°), for a mean color of 2 %/100 nm at alpha = 90°, that can be related to the roughness of the dust particles. Moreover, a decrease of the color temperature with decreasing phase angle is also observed at a rate of ~ 0.3 K/°, consistent with the presence of large porous particles, with low thermal inertia, and showing a significant day-to-night temperature contrast. Comparing data acquired at fixed phase angle (alpha = 90°), a 20% increase of the bolometric albedo is observed near perihelion. Heliocentric variations of the dust color are not significant in the analyzed time period. Measured color temperatures are varying from 260 to 320 K, and follow a r^0.6 variation in the r_h = 1.24-1.5 AU range, close to the expected r_h^0.5 value.

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arXiv2018

The extraordinary composition of the "blue comet" C/2016 R2 (PanSTARRS)

We present a multi-wavelength study of comet C/2016 R2 (PanSTARRS). This comet was observed on 23-24 January 2018 with the IRAM 30m telescope, and in January to March 2018 with the Nançay radio telescope. Visible spectroscopy was performed in December 2017 and February 2018 with small amateur telescopes. We report on measurements of CO, CH3OH, H2CO and HCN production rates, and on the determination of the N2/CO abundance ratio. Several other species, especially OH, were searched for but not detected. The inferred relative abundances, including upper limits for sulfur species, are compared to those measured in other comets at about the same heliocentric distance of about 2.8 AU. The coma composition of comet C/2016 R2 is very different from all other comets observed so far, being rich in N2 and CO and dust poor. This suggests that this comet might belong to a very rare group of comets formed beyond the N2 ice line. Alternatively, comet C/2016 R2 (PanSTARRS) could be the fragment of a large and differentiated transneptunian object, with properties characteristic of volatile-enriched layers.

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arXiv2018

Rosetta et après: le futur de l'exploration des comètes

This article reviews the results obtained by the Rosetta space probe on comet 67P/Churyumov-Gerasimenko and the expectations of future space exploration of comets. -------------- Cet article présente une synthèse des résultats obtenus par la sonde Rosetta sur la comète 67P/Churyumov-Gerasimenko et envisage le futur de l'exploration spatiale des comètes.

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arXiv2017

Comet 67P outbursts and quiescent coma at 1.3 AU from the Sun: dust properties from Rosetta/VIRTIS-H observations

We present 2-5 $μ$m spectroscopic observations of the dust coma of 67P/Churyumov-Gerasimenko obtained with the VIRTIS-H instrument onboard Rosetta during two outbursts that occurred on 2015, 13 September 13.6 h UT and 14 September 18.8 h UT at 1.3 AU from the Sun. Scattering and thermal properties measured before the outburst are in the mean of values measured for moderately active comets. The colour temperature excess (or superheat factor) can be attributed to submicrometre-sized particles composed of absorbing material or to porous fractal-like aggregates such as those collected by the Rosetta in situ dust instruments. The power law index of the dust size distribution is in the range 2-3. The sudden increase of infrared emission associated to the outbursts is correlated with a large increase of the colour temperature (from 300 K to up to 630 K) and a change of the dust colour at 2-2.5 $μ$m from red to blue colours, revealing the presence of very small grains ($\leq$ 100 nm) in the outburst material. In addition, the measured large bolometric albedos ($\sim$ 0.7) indicate bright grains in the ejecta, which could either be silicatic grains, implying the thermal degradation of the carbonaceous material, or icy grains. The 3-$μ$m absorption band from water ice is not detected in the spectra acquired during the outbursts, whereas signatures of organic compounds near 3.4 $μ$m are observed in emission. The H$_2$O 2.7-$μ$m and CO$_2$ 4.3-$μ$m vibrational bands do not show any enhancement during the outbursts.

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arXiv2017

ALMA mapping of rapid gas and dust variations in comet C/2012 S1 (ISON): new insights into the origin of cometary HNC

Observations of the sungrazing comet C/2012 S1 (ISON) were carried out using the Atacama Large Millimeter/submillimeter Array (ALMA) at a heliocentric distance of 0.58-0.54 AU (pre-perihelion) on 2013 November 16-17. Temporally resolved measurements of the coma distributions of HNC, CH$_3$OH, H$_2$CO and dust were obtained over the course of about an hour on each day. During the period UT 10:10-11:00 on Nov. 16, the comet displayed a remarkable drop in activity, manifested as a $>42$% decline in the molecular line and continuum fluxes. The H$_2$CO observations are consistent with an abrupt, $\approx50$% reduction in the cometary gas production rate soon after the start of our observations. On Nov. 17, the total observed fluxes remained relatively constant during a similar period, but strong variations in the morphology of the HNC distribution were detected as a function of time, indicative of a clumpy, intermittent outflow for this species. Our observations suggest that at least part of the detected HNC originated from degradation of nitrogen-rich organic refractory material, released intermittently from confined regions of the nucleus. By contrast, the distributions of CH$_3$OH and H$_2$CO during the Nov. 17 observations were relatively uniform, consistent with isotropic outflow and stable activity levels for these species. These results highlight a large degree of variability in the production of gas and dust from comet ISON during its pre-perihelion outburst, consistent with repeated disruption of the nucleus interspersed with periods of relative quiescence.

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arXiv2017

Thermal physics of the inner coma: ALMA studies of the methanol distribution and excitation in comet C/2012 K1 (PanSTARRS)

We present spatially and spectrally-resolved observations of CH$_3$OH emission from comet C/2012 K1 (PanSTARRS) using The Atacama Large Millimeter/submillimeter Array (ALMA) on 2014 June 28-29. Two-dimensional maps of the line-of-sight average rotational temperature ($T_{rot}$) were derived, covering spatial scales $0.3''-1.8''$ (corresponding to sky-projected distances $ρ\sim500$-2500 km). The CH$_3$OH column density distributions are consistent with isotropic, uniform outflow from the nucleus, with no evidence for extended sources of CH$_3$OH in the coma. The $T_{rot}(ρ)$ radial profiles show a significant drop within a few thousand kilometers of the nucleus, falling from about 60 K to 20 K between $ρ=0$ and 2500 km on June 28, whereas on June 29, $T_{rot}$ fell from about 120 K to 40 K between $ρ=$ 0 km and 1000 km. The observed $T_{rot}$ behavior is interpreted primarily as a result of variations in the coma kinetic temperature due to adiabatic cooling of the outflowing gas, as well as radiative cooling of the CH$_3$OH rotational levels. Our excitation model shows that radiative cooling is more important for the $J=7-6$ transitions (at 338 GHz) than for the $K=3-2$ transitions (at 252 GHz), resulting in a strongly sub-thermal distribution of levels in the $J=7-6$ band at $ρ\gtrsim1000$ km. For both bands, the observed temperature drop with distance is less steep than predicted by standard coma theoretical models, which suggests the presence of a significant source of heating in addition to the photolytic heat sources usually considered.

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