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J. E. Hirsch

Publications and source records attributed to J. E. Hirsch.

142 records · Page 8Linked to original sources

Electron-Phonon or Hole Superconductivity in $MgB_2$?

The BCS electron-phonon mechanism and the unconventional 'hole mechanism' have been proposed as explanations for the high temperature superconductivity observed in $MgB_2$. It is proposed that a critical test of which theory is correct is the dependence of $T_c$ on hole doping: the hole mechanism predicts that $T_c$ will drop rapidly to zero as holes are added, while the electron-phonon mechanism appears to predict increasing $T_c$ for a substantial range of hole doping. Furthermore, the hole mechanism and electron-phonon mechanism differ qualitatively in their predictions of the effect on $T_c$ of change in the $B-B$ distances. We discuss predictions of the hole mechanism for a variety of observables as a function of doping, emphasizing the expected differences and similarities with the electron-phonon explanation. The hole mechanism predicts coherence length and penetration depth to increase and decrease monotonically with hole doping respectively.

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Hole Superconductivity in $Mg B_2$: a high $T_c$ cuprate without Cu

The theory of hole superconductivity explains high temperature superconductivity in cuprates as driven by pairing of hole carriers in oxygen $pπ$ orbitals in the highly negatively charged $Cu-O$ planes. The pairing mechanism is hole undressing and is Coulomb-interaction driven. We propose that the planes of $B$ atoms in $Mg B_2$ are akin to the $Cu-O$ planes without $Cu$, and that the recently observed high temperature superconductivity in $Mg B_2$ arises similarly from undressing of hole carriers in the planar boron $p_{x,y}$ orbitals in the negatively charged $B^-$ planes. Doping $Mg B_2$ with electrons and with holes should mirror the behavior of underdoped and overdoped high $T_c$ cuprates respectively. We discuss possible ways to achieve higher transition temperatures in boron compounds based on this theory.

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Superconductivity from Hole Undressing

Photoemission and optical experiments indicate that the transition to superconductivity in cuprates is an 'undressing' transition . In photoemission this is seen as a coherent quasiparticle peak emerging from an incoherent background, in optics as violation of the Ferrell-Glover-Tinkham sum rule indicating effective mass reduction of superconducting carriers. We propose that this is a manifestation of the fundamental electron-hole asymmetry of condensed matter described by the theory of hole superconductivity. The theory asserts that electrons in nearly empty bands and holes in nearly full bands are fundamentally different : the former yield high conductivity and normal metals, the latter yield low normal state conductivity and high temperature superconductivity. This is because the normal state transport of electrons is coherent and that of holes is incoherent. We explain how this asymmetry arises from the Coulomb interaction between electrons in atoms and the nature of atomic orbitals, and propose a simple Hamiltonian to describe it. A $universal$ mechanism for superconductivity follows from this physics, whereby dressed hole carriers undress by pairing, turning (partially) into electrons and becoming more mobile in the superconducting state.

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Consequences of charge imbalance in superconductors within the theory of hole superconductivity

The theory of hole superconductivity proposes that the fundamental asymmetry between electrons and holes in solids is responsible for superconductivity. Here we point out a remarkable consequence of this theory: a tendency for negative charge to be expelled from the bulk of the superconductor towards the surface. Experimentally observable consequences of this physics are discussed.

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Superconductivity from Undressing. II. Single Particle Green's Function and Photoemission in Cuprates

Experimental evidence indicates that the superconducting transition in high $T_c$ cuprates is an 'undressing' transition. Microscopic mechanisms giving rise to this physics were discussed in the first paper of this series. Here we discuss the calculation of the single particle Green's function and spectral function for Hamiltonians describing undressing transitions in the normal and superconducting states. A single parameter, $Υ$, describes the strength of the undressing process and drives the transition to superconductivity. In the normal state, the spectral function evolves from predominantly incoherent to partly coherent as the hole concentration increases. In the superconducting state, the 'normal' Green's function acquires a contribution from the anomalous Green's function when $ Υ$ is non-zero; the resulting contribution to the spectral function is $positive$ for hole extraction and $negative$ for hole injection. It is proposed that these results explain the observation of sharp quasiparticle states in the superconducting state of cuprates along the $(π,0)$ direction and their absence along the $(π,π)$ direction.

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Ferromagnetism from Undressing

We have recently proposed that superconductivity may be understood as driven by the undressing of quasiparticles as the superconducting state develops. Similarly we propose here that ferromagnetism in metals may be understood as driven by the undressing of quasiparticles as the ferromagnetic state develops. In ferromagnets, the undressing is proposed to occur due to the reduction in $bond$ $charge$ caused by spin polarization, in contrast to superconductors where the undressing is proposed to occur due to the reduction in $site$ $charge$ caused by (hole) pairing. The undressing process manifests itself in the one and two-particle Green's functions as a transfer of spectral weight from high to low frequencies. Hence it should have universal observable consequences in one- and two-particle spectroscopies such as photoemission and optical absorption.

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Superconductivity and Ferromagnetism from Effective Mass Reduction

Within a simple model Hamiltonian, both superconductivity and metallic ferromagnetism can be understood as arising from lowering of kinetic energy as the ordered state develops, due to a reduction in the carriers effective mass, or equivalently, a bandwidth expansion. Experimental manifestation of this physics has been detected in both high Tc superconductors and large magnetoresistance ferromagnets, as an anomalous transfer of spectral weight in optical absorption from high to low frequencies as the ordered state develops. It is proposed that this general principle is common to the essential physics of superconductivity and ferromagnetism in nature, and hence that these effects in optical properties, although often smaller in magnitude, should exist in all superconductors and metallic ferromagnets.

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Superconductivity from Undressing

Photoemission experiments in high $T_c$ cuprates indicate that quasiparticles are heavily 'dressed' in the normal state, particularly in the low doping regime. Furthermore these experiments show that a gradual undressing occurs both in the normal state as the system is doped and the carrier concentration increases, as well as at fixed carrier concentration as the temperature is lowered and the system becomes superconducting. A similar picture can be inferred from optical experiments. It is argued that these experiments can be simply understood with the single assumption that the quasiparticle dressing is a function of the local carrier concentration. Microscopic Hamiltonians describing this physics are discussed. The undressing process manifests itself in both the one-particle and two-particle Green's functions, hence leads to observable consequences in photoemission and optical experiments respectively. An essential consequence of this phenomenology is that the microscopic Hamiltonians describing it break electron-hole symmetry: these Hamiltonians predict that superconductivity will only occur for carriers with hole-like character, as proposed in the theory of hole superconductivity.

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Hole superconductivity from kinetic energy gain

The apparently unrelated experimental observations of optical sum rule violation[1] and of tunneling asymmetry in NIS tunneling[2] find a simple explanation within the theory of hole superconductivity. In fact, both phenomena were predicted by the theory long before they were experimentally observed[3,4]. Other experimental predictions of the theory, in particular a novel feature expected in photoemission experiments, are discussed.

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Anisotropic penetration depth and optical sum rule violation in La_(2-x)Sr_xCuO_4

We calculate the doping dependence of the penetration depths and optical sum rule violation in La_(2-x)Sr_xCuO_4 within the model of hole superconductivity. In the clean limit the predicted in-plane sum rule violation is larger than the c-axis one, however in the presence of disorder the latter one becomes very substantially enhanced.

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Optical sum rule violation, superfluid weight and condensation energy in the cuprates

The model of hole superconductivity predicts that the superfluid weight in the zero-frequency $δ$-function in the optical conductivity has an anomalous contribution from high frequencies, due to lowering of the system's kinetic energy upon entering the superconducting state. The lowering of kinetic energy, mainly in-plane in origin, accounts for both the condensation energy of the superconductor as well as an increased potential energy due to larger Coulomb repulsion in the paired state. It leads to an apparent violation of the conductivity sum rule, which in the clean limit we predict to be substantially larger for in-plane than for c-axis conductivity. However, because cuprates are in the dirty limit for c-axis transport, the sum rule violation is found to be greatly enhanced in the c-direction. The model predicts the sum rule violation to be largest in the underdoped regime and to decrease with doping, more rapidly in the c-direction that in the plane. So far, experiments have detected sum rule violation in c-axis transport in several cuprates, as well as a decrease and disappearance of this violation for increasing doping, but no violation in-plane. We explore the predictions of the model for a wide range of parameters, both in the absence and in the presence of disorder, and the relation with current experimental knowledge.

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Where is 99% of the condensation energy of Tl_2Ba_2CuO_y coming from?

Anderson's interlayer tunneling model can account for up to 1% of the condensation energy of Tl_2Ba_2CuO_y. Here we account for the remaining 99%. We predict an in-plane kinetic energy gain of 1 to 3 meV per planar oxygen in the optimally doped material when it goes superconducting. It is suggested that the effect may be most easily detected in underdoped dirty samples.

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Overlooked Contribution to the Hall Effect in Ferromagnetic Metals

It is pointed out that in ferromagnetic metals a contribution to the Hall voltage arises when a non-zero spin current exists, which is generally the case in the presence of a charge current. This contribution is independent of any scattering effects and exists down to zero temperature. The sign of the resulting Hall coefficient may be either equal or opposite to the one of the ordinary Hall coefficient depending on the band filling. This effect seems to have been left out in previous analyses of the Hall effect in ferromagnetic metals.

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Spin Hall effect

It is proposed that when a charge current circulates in a paramagnetic metal a transverse spin imbalance will be generated, giving rise to a 'spin Hall voltage'. Similarly, that when a spin current circulates a transverse charge imbalance will be generated, hence a Hall voltage, in the absence of charge current and magnetic field. Based on these principles we propose an experiment to generate and detect a spin current in a paramagnetic metal.

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Slope of the superconducting gap function in $Bi_2Sr_2CaCu_2O_{8+δ}$ measured by vacuum tunneling spectroscopy

Reproducible scanning tunneling microscope (STM) spectra of $Bi_2Sr_2CaCu_2O_{8+δ}$ consistently exhibit asymmetric tunneling characteristics, with the higher peak conductance corresponding to a negatively biased sample. We consider various possible sources of this asymmetry that are not intrinsic to the superconducting state, including energy dependence of the normal state densities of states of sample and/or tip, existence of bandwidth cutoffs, unequal work functions of tip and sample, and energy-dependent transmission probability. None of these effects can explain the sign and temperature dependence of the observed asymmetry. This indicates that the observed asymmetry reflects an intrinsic property of the superconducting state: an energy-dependent superconducting gap function with non-zero slope at the Fermi energy. Such a sloped gap function will also give rise to a thermoelectric effect in STM experiments, resulting in a $positive$ thermopower. We discuss the feasibility of observing this thermoelectric effect with an STM and conclude that it is easily observable. An analysis of thermoelectric currents and voltages together with the tunneling spectra as function of temperature and tip- sample distance would allow for accurate determination of the slope of the gap function. It is suggested that it would be very worthwhile to perform these experiments, because the slope of the gap function reflects a fundamental property of the superconducting state. The theory of hole superconductivity has predicted the existence of such a slope, of universal sign, in all superconductors. It is furthermore argued that recent experimental results on vortex lattice imaging provide further strong evidence for the existence of the gap slope discussed here.

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Metallic ferromagnetism without exchange splitting

In the band theory of ferromagnetism there is a relative shift in the position of majority and minority spin bands due to the self-consistent field due to opposite spin electrons. In the simplest realization, the Stoner model, the majority and minority spin bands are rigidly shifted with respect to each other. Here we consider models at the opposite extreme, where there is no overall shift of the energy bands. Instead, upon spin polarization one of the bands broadens relative to the other. Ferromagnetism is driven by the resulting gain in kinetic energy. A signature of this class of mechanisms is that a transfer of spectral weight in optical absorption from high to low frequencies occurs upon spin polarization. We show that such models arise from generalized tight binding models that include off-diagonal matrix elements of the Coulomb interaction. For certain parameter ranges it is also found that reentrant ferromagnetism occurs. We examine properties of these models at zero and finite temperatures, and discuss their possible relevance to real materials.

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