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J. E. Méndez-Delgado

Publications and source records attributed to J. E. Méndez-Delgado.

At least 19 recordsLinked to original sources

The DESIRED strong-line calibrations: I. New empirical metallicity relations for the local and high-redshift universe

We present the most comprehensive set of empirical optical strong-line metallicity calibrations to date, based on the DEep Spectra of Ionised REgions Database (DESIRED), the largest compilation of HII regions and galaxies with direct electron-temperature determinations. We construct a high-quality calibration sample of 2392 spectra: 1029 extragalactic HII regions, 1296 local star-forming galaxies, and 67 high-redshift ($z > 2$) galaxies, drawn from 201 independent literature references, spanning $12+\log({\rm O/H}) \in [6.79, 9.07]$. Physical conditions and chemical abundances are derived homogeneously using up-to-date atomic data. We derive 27 strong-line calibrations covering oxygen-, nitrogen-, sulphur-, argon-, and neon-based line ratios, including 4 previously uncalibrated diagnostics, with reported validity ranges and intrinsic dispersions (typically $\sim0.15-0.35$~dex). For the first time in a systematic calibration framework, all relations are presented for both the homogeneous temperature case ($t^2 = 0$) and a scenario including temperature inhomogeneities ($t^2 > 0$), thereby reconciling abundances from recombination lines (RLs) and collisionally excited lines (CELs) and directly tackling the abundance discrepancy problem. A comparison with previous calibrations shows that the DESIRED relations span the broadest validity intervals while remaining anchored to the empirical data. Comparisons with $z>2$ galaxies show that several DESIRED calibrations remain consistent with independent high-redshift relations within their intrinsic scatter, whereas others display systematic offsets associated with elevated N/O or harder ionising conditions. Thus, DESIRED calibrations can provide reliable metallicity estimates at high redshift for a subset of diagnostics, while highlighting the need to account for diagnostic-specific redshift evolution.

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Investigating the electron temperature of [Ar IV] in planetary nebulae using the DESIRED database

(Abridged) We investigate the behaviour of the electron temperature derived from [Ar IV] lines, Te([Ar IV]), in a sample of PNe to characterize the thermal structure of high-excitation gas and compare it with the predictions of standard photoionisation models. Using the DEep Spectra of ionised REgions Data Base Extended (DESIRED-E), we selected a sample of 57 PNe for which Te([Ar IV]), Te([O III]), and ne([Ar IV]) could be determined simultaneously and homogeneously. We performed a detailed comparison between these observational diagnostics and a suite of over 160000 photoionisation models from the Mexican Million Models Database (3MdB). We find that the observed Te([Ar IV]) values are systematically higher than those predicted by pure photoionisation models for a given Te([O III]), i.e. approximately 31 percent of the PNe sample exhibits a Te([Ar IV]) more than 2sigma higher than photoionization model predictions. This discrepancy persists regardless of the specific set of auroral lines used for the diagnostic or the choice of atomic data (transition probabilities and collision strengths) adopted in the calculations. Other high-ionisation Te diagnostics, compiled from the DESIRED database or from the literature, however, do not show such behaviour, though the statistics for these are much more limited. The fact that models succeed for the highest-ionisation species but fail specifically for [Ar IV] suggests that the discrepancy is not due to a global inner-nebula heating mechanism. Instead, it points toward a localized physical effect or a limitation in the current understanding of the ionisation stratification and atomic physics specific to the Argon ion stages. This "[Ar IV] anomaly" must be resolved to ensure the reliability of abundance determinations in high-excitation nebulae.

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SDSS-V LVM: Revealing the Physical and Chemical Structure of the Helix Nebula

We present the first spatially contiguous study of the physical and chemical structure of the Helix Nebula (NGC~7293, PNG 036.1-57.1) based on integral-field spectroscopy from the SDSS-V Local Volume Mapper (LVM). The wide-field observations provide nearly complete spectroscopic coverage of the nebula, enabling a spaxel-by-spaxel analysis of extinction, electron density and temperature, ionisation structure, and chemical abundances. We reconstruct calibrated datacubes from the LVM row-stacked spectra and measure 41 optical emission lines, including hydrogen, helium, and collisionally excited metal lines. The resulting maps reveal a strongly stratified nebula, with highly ionised gas traced by \heii~concentrated toward the central cavity, low-ionisation material dominating the bright shell, and neutral or transition-zone gas enhanced in the outer regions. The Helix is a low-density object, with typical electron densities of $\sim10^{2}\mathrm{cm^{-3}}$, and exhibits a non-uniform temperature structure, with variations of several thousand Kelvin across different ionisation zones. We derive a near-solar oxygen abundance, $12+\log(\mathrm{O/H})\simeq8.7$, consistent with spatially complete sampling. The central abundance pattern indicates a significant contribution from unobserved O$^{3+}$, suggesting that apparent abundance variations are primarily driven by ionisation effects rather than true chemical inhomogeneities. We also find evidence for a sulfur deficit of $\sim$1 dex, consistent with the planetary-nebula sulfur anomaly. The helium and nitrogen abundances place the Helix near the classical boundary of Type~I planetary nebulae, suggesting moderate chemical enrichment by its progenitor star.

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The DESIRED electron temperature relations in star-forming regions of the local Universe

(Abridged) Aims. We present a homogeneous observational study of electron temperature ($T_{\rm e}$) relations between ionic species: $T_{\rm e}$([N II]), $T_{\rm e}$([O II]), $T_{\rm e}$([O III]), $T_{\rm e}$([S II]), $T_{\rm e}$([S III]) and $T_{\rm e}$([Ar III]), using 699 spectra of Galactic and extragalactic H II regions and local star-forming galaxies (SFGs). Methods. We use the DEep Spectra of Ionised REgions Database Extended (DESIRED-E), comprising more than 3000 spectra with direct $T_{\rm e}$ determinations, selecting those with at least two $T_{\rm e}$ diagnostics. We recompute electron density ($n_{\rm e}$) and $T_{\rm e}$ using updated atomic data and a consistent methodology. The resulting $T_{\rm e}$--$T_{\rm e}$ relations are analysed using orthogonal distance regression, quantifying total and intrinsic dispersions and comparing slopes with previous works and photoionisation models. Results. Relations involving low-ionisation $T_{\rm e}$ diagnostics show large intrinsic dispersions, especially for $T_{\rm e}$([O II]) and $T_{\rm e}$([S II]), likely due to sensitivity to $n_{\rm e}$ inhomogeneities, recombination contributions, and uncertainties. In contrast, relations using $T_{\rm e}$([N II]) show lower dispersions, indicating that this diagnostic provides a more reliable estimate of the low-ionisation zone temperature when only higher-ionisation $T_{\rm e}$ diagnostics are available, despite observational difficulties at low metallicity. Overall, slopes agree with model predictions, particularly for relations with low intrinsic dispersion, such as those involving $T_{\rm e}$([N II]) and $T_{\rm e}$([S III]). These results provide a robust empirical basis for estimating $T_{\rm e}$ when limited diagnostics are available.

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SDSS-V LVM: A spatially resolved study of the physical conditions and the chemical abundance discrepancy in the Lagoon Nebula (M 8)

The abundance discrepancy problem refers to the systematic differences observed between chemical abundances derived from collisionally excited lines (CELs) and recombination lines (RLs) of heavy ions. It remains a major unsolved problem in the study of ionized nebulae and is quantified by the abundance discrepancy factor (ADF). In this work, we present a deep integral field spectroscopic dataset covering the entire Lagoon Nebula (M 8), obtained by the SDSS-V Local Volume Mapper project, at a spatial resolution of 0.21 pc per spaxel. This unique dataset allows us, for the first time, to investigate spatially resolved maps of oxygen RL intensities (O II V1), together with maps of H I RLs, heavy-ion CELs, and dust attenuation across a whole H II region. We map the electron temperature using CELs and RLs of $O^{2+}$, CELs of $N^{+}$, and the electron density using CELs of $S^{+}$. We derive CEL-based ionic and elemental oxygen abundances and, for the first time, a spatially resolved map of the RL-based $O^{2+}$ abundance in an H II region. These measurements enable the construction of the first spatially resolved ADF($O^{2+}$) map of an H II region and yield a global mean ADF of ~0.47 +/- 0.02 dex. Focusing on the central region of M 8, where ionization is dominated by the O-type star Her 36, we find radial variations in the ADF ranging between ~0.35-0.50 dex. Our findings provide novel constraints on the spatial behavior and origin of the abundance discrepancy in H II regions.

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SDSS-V Local Volume Mapper (LVM): Helix Nebula public data, Data Analysis Pipeline data products

We present a spatially resolved spectroscopic analysis of the Helix Nebula (NGC 7293) using data from the SDSS-V Local Volume Mapper (LVM), by applying the recently developed LVM Data Analysis Pipeline (LVM-DAP). Covering the full optical range (3600-9800 Å) over a contiguous ~ 0.5 degree field, the LVM data provide the first hexagonally sampled, wide-field emission-line maps of all major ionic species in this archetypal planetary nebula. The resulting flux, kinematic, and line-ratio maps reveal the well-known ionization stratification of the nebula, from the compact He++ core to the bright [O III] ring and the extended low-ionization envelope, enabling a detailed comparison with classical aperture spectroscopy. Owing to the sensitivity and uniform spatial sampling of the LVM, numerous faint auroral and diagnostic lines are detected across the nebula, including [O III] 4363, [N II] 5755, and He I lines, allowing precise measurements of weak-line morphology. The derived radial trends confirm the remarkably low dust content and the overall homogeneity of electron temperature and density across the main ring. Ionized-gas kinematics traced by Hα further support the scenario of a slowly expanding, limb-brightened shell consistent with previous studies. This work demonstrates the diagnostic power of LVM spectroscopy for extended nebulae and highlights its capability to recover both global and spatially resolved physical conditions across complex ionized structures.

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First direct electron temperature measurement in [O II] zone in I Zw 18

We present new precise measurements of electron temperatures and oxygen abundances in the southeast knot of I Zw 18, one of the most metal-poor blue compact dwarf galaxies known, using spectroscopic data from the Dark Energy Spectroscopic Instrument Data Release 1 (DESI DR1). For the first time in I Zw 18, we directly measure electron temperature in the low-ionization zone using the rarely detected [O II] $λ\lambda7320,7330$ doublet. We also detect the auroral lines [O III] $\lambda4363$ and [S III] $\lambda6312$, associated with high and intermediate ionization zones, respectively. We derive $T_{\mathrm{e}}([\mathrm{O}\,\mathrm{III}])=21\,200\pm860\ \mathrm{K}$, $T_{\mathrm{e}}([\mathrm{O}\,\mathrm{II}])=16\,170\pm950\ \mathrm{K}$, and $T_{\mathrm{e}}([\mathrm{S}\,\mathrm{III}])=17\,290\pm1750\ \mathrm{K}$, highlighting a significant temperature difference between ionization zones. Using these direct temperature measurements, we determine a total oxygen abundance of $12+\log(\mathrm{O}/\mathrm{H})=7.066\pm0.046$, $\log(\mathrm{N}/\mathrm{O})=-1.509\pm0.097$, and $\log(\mathrm{S}/\mathrm{O})=-1.558\pm0.041$. Our results extend the calibration of $t_2$--$t_3$ relations to the highest temperatures, providing important anchor points for the temperature structure of extremely metal-poor H II regions, including high-redshift galaxies where direct temperature measurements are especially challenging.

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Why the Northern Hemisphere Needs a 30-40 m Telescope and the Science at Stake: Northern Local Star-forming Dwarf Galaxies. Analogues of the First Galaxies and Probes of the Cosmic Metallicity Scale

Star-forming dwarf galaxies in the local Universe, especially extremely metal-poor ones, can be considered analogous to early galaxies of the Epoch of Reionization (z >= 6). Currently available telescopes cannot adequately detect and measure heavy element recombination lines and certain faint collisionally excited lines, which are essential for exploring the effects and biases that potential inhomogeneities in electron temperature and density of the ionized gas may have on determining the chemical composition of these galaxies. On the other hand, the origin of very high-ionization lines (e.g. He II, [Ne V], C IV]) measured in the spectra of an important fraction of these objects remains unknown and a challenge to current stellar models, suggesting the presence of Population III-like stars and/or the existence of non-conventional ionizing sources. Obtaining very deep spectra for a selected sample of local star-forming dwarf galaxies would provide unprecedented constraints on their nature, ionization and true chemical abundances, and could change the metallicity scale we assume to understand the chemical evolution of galaxies over cosmic time.

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The PHANGS-MUSE/HST-Halpha Nebulae Catalogue

We present the PHANGS-MUSE/HST-Halpha nebulae catalogue, comprising 5177 spatially resolved nebulae across 19 nearby star-forming galaxies (< 20 Mpc), based on high-resolution Halpha imaging from HST, homogenised to a fixed 10 pc resolution and sensitivity. Combined with MUSE spectroscopy, this enables robust classification of 4882 H II regions and separation of planetary nebulae and supernova remnants. Electron densities for 2544 H II regions are derived using [S II] diagnostics, and nebular sizes measured via circularised radii and second moments yield a median of 20 pc, extending to sub-parsec scales. A structural complexity score traces substructure, showing that about a third of regions are H II complexes, with a higher fraction in galaxy centres. A luminosity-size relation calibrated from the HST sample is applied to 30,790 MUSE nebulae, recovering sizes down to 1 pc. Observed sizes exceed classical Stromgren radii, implying typical volume filling factors of 0.22. We associate 3349 H II regions with stellar populations from PHANGS-HST, finding median ages of 3 Myr and masses of 4-5 log(Msun). The dataset provides a detailed, spatially resolved link between nebular structure and ionising sources, serving as a benchmark for future studies of feedback, diffuse ionised gas, and star formation regulation in the interstellar medium. The full catalogue is made publicly available in machine-readable format.

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Unified Spectrospatial Forward Models: Spatially Continuous Maps of Weak Emission Lines in the Rosette Nebula with SDSS-V LVM

Analyses of IFU data are typically performed on a per-spaxel basis, with each spectrum modelled independently. For low signal-to-noise (S/N) features such as weak emission lines, estimating properties is difficult and imprecise. Arbitrary binning schemes boost S/N at the cost of resolution, and risk introducing biases. We present a general forward-modelling approach that assumes spectra close on the sky are more similar than distant ones, and so can be modelled jointly. These "spectrospatial" models exploit spatial correlation to provide robust inferences, while simultaneously providing continuous predictions of line properties like strength and kinematics across the sky. Instrumental and calibration systematics are straightforward to include and infer. The model provides a natural trade-off between spatial resolution and S/N in a data-driven way. We apply this to Sloan Digital Sky Survey V (SDSS-V) Local Volume Mapper (LVM) data of the Rosette Nebula, producing continuous maps of fluxes and kinematics for Balmer, nebular, and auroral lines, as well as weak C II and N II recombination lines, demonstrating the approach across three orders of magnitude in S/N, including in the very low-S/N regime. The method recovers identical morphologies across different lines tracing similar ionisation volumes, at varying resolutions set by the S/N. We additionally provide a general framework for building and fitting such models in JAX, suitable for many applications. The implementation is fast and memory efficient, scales to large data volumes as in LVM, and can be deployed on hardware accelerators.

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Atmospheric parameters and chemical abundances of young stars with APOGEE. I. Orion star-forming region

We derive atmospheric parameters and chemical abundances in young G-, K-, and M-type stars (temperatures between 6500 and 3100 K) using infrared APOGEE-2 spectra. Atmospheric parameters were determined for 548 young stars in the Orion complex (Orion A, B, OB1, and $λ$ Ori) using the TONALLI code. For 340 slow rotators v sini $\leq$ 30 km s$^{-1}$), we derived C, Mg, Si, K, Ti, and Fe abundances using 19 atomic lines, MARCS model atmospheres, and BACCHUS. To mitigate the impact of circumstellar material, we excluded stars with infrared excess identified via 2MASS and WISE photometry. We find sub-solar [X/H] abundance ratios, consistent across elements and among all four groups, suggesting a chemically homogeneous Orion complex. We computed [$α$/Fe] from [Mg/Fe], [Si/Fe], and [Ti/Fe], obtaining a median of $-0.14 \pm 0.04$, about 0.10 dex lower than the value for nearby main-sequence stars ($-0.04 \pm 0.04$) at similar [Fe/H]. This result aligns with predictions from Galactic chemical evolution models. Furthermore, the median [C/H] abundance we derived for Orion agrees with previous estimations based on the analysis of the ionized gas of the Orion nebula. This work sets the stage for extending the analysis to stars with circumstellar material and higher rotational velocities, which will not only improve our understanding of Orion, but also provide critical insight into the formation and evolution of young stars, as well as the chemical evolution of the Milky Way.

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Surveying the Whirlpool at Arcseconds with NOEMA (SWAN): III. $^{13}$CO/C$^{18}$O ratio variations across the M51 galaxy

CO isotopologues are common tracers of the bulk molecular gas in extragalactic studies, providing insights into the physical and chemical conditions of the cold molecular gas, a reservoir for star formation. Since star formation occurs within molecular clouds, mapping CO isotopologues at cloud-scale is important to understanding the processes driving star formation. However, achieving this mapping at such scales is challenging and time-intensive. The Surveying the Whirlpool Galaxy at Arcseconds with NOEMA (SWAN) survey addresses this by using the Institut de radioastronomie millimétrique (IRAM) NOrthern Extended Millimeter Array (NOEMA) to map the $^{13}$CO(1-0) and C$^{18}$O(1-0) isotopologues, alongside several dense gas tracers, in the nearby star-forming galaxy M51 at high sensitivity and spatial resolution ($\approx$ 125 pc).We examine the $^{13}$CO(1-0) to C$^{18}$O(1-0) line emission ratio as a function of galactocentric radius and star formation rate surface density to infer how different chemical and physical processes affect this ratio at cloud scales across different galactic environments: nuclear bar, molecular ring, northern and southern spiral arms. In line with previous studies conducted at kiloparsec scales for nearby star-forming galaxies, we find a moderate positive correlation with galactocentric radius and a moderate negative correlation with star formation rate surface density across the field-of-view (FoV), with slight variations depending on the galactic environment. We propose that selective nucleosynthesis and changes in the opacity of the gas are the primary drivers of the observed variations in the ratio.

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Temperature based radial metallicity gradients in nearby galaxies

Gas-phase abundances provide insights into the baryon cycle, with radial gradients and 2D metallicity distributions tracking how metals build up and redistribute within galaxy disks over cosmic time. We use a catalog of 22,958 HII regions across 19 nearby spiral galaxies to examine how precisely the radial abundance gradients can be traced using only the [NII]5755 electron temperature as a proxy for `direct method' metallicities. Using 534 direct detections of the temperature sensitive [NII]5755 auroral line, we measure gradients in 15 of the galaxies. Leveraging our large catalog of individual HII regions, we stack in bins of HII region [NII]6583 luminosity and radius to recover stacked radial gradients. We find good agreement between the metallicity gradients from the stacked spectra, those gradients from individual regions and those from strong line methods. In addition, particularly in the stacked Te([NII]) measurements, some galaxies show very low (<0.05 dex) scatter in metallicities, indicative of a well-mixed ISM. We examine individual high confidence (S/N > 5) outliers and identify 13 regions across 9 galaxies with anomalously low metallicity, although this is not strongly reflected in the strong line method metallicities. By stacking arm and interarm regions, we find no systematic evidence for offsets in metallicity between these environments, suggesting enrichment within spiral arms is due to very localized processes. This work demonstrates the potential to systematically exploit the single [NII]5755 auroral line for detailed gas-phase abundance studies of galaxies. It provides strong validation of previous results, based on the strong line calibrations, of a well-mixed ISM across typical star-forming spiral galaxies.

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The MUSE view of the Sculptor galaxy: survey overview and the planetary nebulae luminosity function

NGC 253, the Sculptor galaxy, is the southern, massive, star-forming disk galaxy closest to the Milky Way. In this work, we present a new 103-pointing MUSE mosaic of this galaxy covering the majority of its star-forming disk up to 0.75xR25. With an area of ~20x5 arcmin2 (~20x5 kpc2, projected) and a physical resolution of ~15 pc, this mosaic constitutes one of the largest, highest physical resolution integral field spectroscopy surveys of any star-forming galaxy to date. Here, we exploit the mosaic to identify a sample of ~500 planetary nebulae (~20 times larger than in previous studies) to build the planetary nebula luminosity function (PNLF) and obtain a new estimate of the distance to NGC 253. The value obtained is 17% higher than estimates returned by other reliable measurements, mainly obtained via the top of the red giant branch method (TRGB). The PNLF also varies between the centre (r < 4 kpc) and the disk of the galaxy. The distance derived from the PNLF of the outer disk is comparable to that of the full sample, while the PNLF of the centre returns a distance ~0.9 Mpc larger. Our analysis suggests that extinction related to the dust-rich interstellar medium and edge-on view of the galaxy (the average E(B-V) across the disk is ~0.35 mag) plays a major role in explaining both the larger distance recovered from the full PNLF and the difference between the PNLFs in the centre and in the disk.

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Generalized $T_e$([OIII])-$T_e$(HeI) Discrepancies in Ionized Nebulae: Possible Evidence of Case B Deviations and Temperature Inhomogeneities

The physics of recombination lines (RLs) in the HeI singlet system is expected to be relatively simple, supported by accurate atomic models. We examine the intensities of HeI singlets $λλ$3614, 3965, 5016, 6678, 7281 and the triplet HeI $λ$5876 in various types of ionized nebulae and compare them with theoretical predictions to test the validity of the ``Case B'' recombination scenario and the assumption of thermal homogeneity. Our analysis includes 85 spectra from Galactic and extragalactic HII regions, 90 from star-forming galaxies, and 218 planetary nebulae, all compiled by the DEep Spectra of Ionized REgions Database Extended (DESIRED-E) project. By evaluating the ratios HeI $λ$7281/$λ$6678 and HeI $λ$7281/$λ$5876, we determine $T_e$(HeI) and compare it with direct measurements of $T_e$([OIII] $λ$4363/$λ$5007). We find that $T_e$(HeI) is systematically lower than $T_e$([OIII]) across most objects and nebula types. Additionally, we identify a correlation between the abundance discrepancy factor (ADF(O$^{2+}$)) and the difference $T_e$([OIII]) - $T_e$(HeI) for planetary nebulae. We explore two potential explanations: photon loss from $n^1P \rightarrow 1^1S$ transitions and temperature inhomogeneities. Deviations from ``Case B'' may indicate photon absorption by HI rather than HeI and/or generalized ionizing photon escape, highlighting the need for detailed consideration of radiative transfer effects. If temperature inhomogeneities are widespread, identifying a common physical phenomenon affecting all ionized nebulae is crucial. Our results suggest that both scenarios can contribute to the observed discrepancies.

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Alpha-element abundance patterns in star-forming regions of the local Universe

(Abridged) We reassess the alpha-element abundance ratios (Ne/O, S/O, Ar/O) with respect to metallicity in ~1000 spectra of Galactic and extragalactic HII regions and star-forming galaxies (SFGs) of the local Universe. Using the DEep Spectra of Ionised REgions Database (DESIRED) Extended project (DESIRED-E), which includes spectra with direct electron temperature determinations, we homogeneously derive physical conditions and chemical abundances for all objects. Various ionisation correction factor (ICF) schemes are analyzed for Ne, S, and Ar to identify the most reliable abundance estimates. Our findings indicate that one of the tested ICF schemes better reproduces the Ne/O, S/O, and Ar/O trends. Ne/O ratios in HII regions display large dispersion and no clear dependence on O/H, suggesting that current ICF(Ne) schemes fail for these objects. However, SFGs show consistent linear relations with slightly positive slopes for log(Ne/O) vs. 12+log(O/H) or 12+log(Ne/H), likely influenced by metallicity-dependent O dust depletion and ICF effects. The log(S/O) vs. 12+log(O/H) distribution is largely constant, especially for HII regions or combined samples (SFGs + HII regions). Conversely, log(S/O) vs. 12+log(S/H) shows a tight linear fit with a positive slope, flattening at 12+log(S/H) < 6.0, suggesting S contributions from SNe Ia. For log(Ar/O) vs. 12+log(O/H), similar trends emerge for HII regions and SFGs, independent of ionisation degree or ICF(Ar). A slight log(Ar/O) decrease with increasing 12+log(O/H) contrasts with log(Ar/O) vs. 12+log(Ar/H), which shows a small positive slope, indicating a possible minor Ar contribution from SNe Ia.

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Chlorine abundances in star-forming regions of the local Universe

Aims. We study the behaviour of Cl abundance and its ratios with respect to O, S and Ar abundances in a sample of more than 200 spectra of Galactic and extragalactic H ii regions and star-forming galaxies (SFGs) of the local Universe. Methods. We use the DEep Spectra of Ionised REgions Database (DESIRED) Extended project (DESIRED-E) that comprises more than 2000 spectra of H ii regions and SFGs with direct determinations of electron temperature ($T_e$). From this database we select those spectra where it is possible to determine the Cl$^{2+}$ abundance and whose line ratios meet certain observational criteria. We calculate the physical conditions and Cl, O, S and Ar abundances in an homogeneous manner for all the spectra. We compare with results of photoionisation models to carry out an analysis of which is the most appropriate $T_e$ indicator for the nebular volume where Cl$^{2+}$ lies, proposing a scheme that improves the determination of the Cl$^{2+}$ abundance. We compare the Cl/O ratios obtained using two different ionisation correction factor (ICF) schemes. We also compare the nebular Cl/O distribution with stellar determinations. Results. Our analysis indicates that the ICF scheme proposed by Izotov et al. (2006) better reproduces the observed distributions of the Cl/O ratio. We find that the log(Cl/O) vs. 12+log(O/H) and log(Cl/Ar) vs. 12+log(Ar/H) distributions are not correlated in the whole metallicity range covered by our objects indicating a lockstep evolution of those elements. In contrast, the log(Cl/S) vs. 12+log(S/H) distribution shows a weak correlation with a slight negative slope.

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Gas-phase Fe/O and Fe/N abundances in Star-Forming Regions. Relations between nucleosynthesis, metallicity and dust

In stars, metallicity is usually traced using Fe, while in nebulae, O serves as the preferred proxy. Both elements have different nucleosynthetic origins and are not directly comparable. Additionally, in ionized nebulae, Fe is heavily depleted onto dust grains. We investigate the distribution of Fe gas abundances in a sample of 452 star-forming nebulae with \feiii~$λ4658$ detections and their relationship with O and N. Additionally, we analyze the depletion of Fe onto dust grains in photoionized environments. We homogeneously determine the chemical abundances with direct determinations of electron temperature ($T_e$), considering the effect of possible internal variations of this parameter. We adopt a sample of 300 Galactic stars to interpret the nebular findings. We find a moderate linear correlation ($r=-0.59$) between Fe/O and O/H. In turn, we report a stronger correlation ($r=-0.80$) between Fe/N and N/H. We interpret the tighter correlation as evidence of Fe and N being produced on similar timescales while Fe-dust depletion scales with the Fe availability. The apparently flat distribution between Fe/N and N/H in Milky Way stars supports this interpretation. We find that when 12+log(O/H)<7.6, the nebulae seem to reach a plateau value around $\text{log(Fe/O)} \approx -1.7$. If this trend is confirmed, it would be consistent with a very small amount of Fe-dust in these systems, similar to what is observed in high-z galaxies discovered by the James Webb Space Telescope (JWST). We derive a relationship that allows us to approximate the fraction of Fe trapped into dust in ionized nebulae. If the O-dust scales in the same way, its possible contribution in low metallicity nebulae would be negligible. After analyzing the Fe/O abundances in J0811+4730 and J1631+4426, we do not see evidence of the presence of very massive stars with $M_\text{init}>300M_{\odot}$ in these systems.

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