arXiv subjects

J. F. Zasadzinski

Publications and source records attributed to J. F. Zasadzinski.

At least 19 recordsLinked to original sources

arXiv2025

Signatures of Enhanced Superconducting Properties in Niobium Cavities

Superconducting radio-frequency (SRF) niobium cavities are critical for modern particle accelerators, as well as for advancing superconducting quantum systems and enabling ultra-sensitive searches for new physics. In this work, we report a systematic observation of an anomalous frequency dip in Nb cavities, which occurs at temperatures just below the critical temperature ($T_\mathrm{c}$), indicative of enhanced superconducting properties at $T \ll T_c$. The magnitude of this dip is strongly correlated with the RF surface resistance, impurity distribution near the surface, and $T_\mathrm{c}$. Additionally, we report measurements of the coherence peak in the AC conductivity of two Nb SRF cavities processed using distinct methods. By comparing recent theories developed to model this experimental data, we show that the frequency dip feature, larger coherence peak height, and reduction in the temperature-dependent surface resistance with RF current occur at minimal but finite levels of disorder.

physics.acc-ph↗

arXiv2018

Insight into bulk niobium superconducting RF cavities performances by tunneling spectroscopy

Point contact tunneling (PCT) spectroscopy measurements are reported over wide areas of cm-sized cut outs from niobium superconducting RF cavities. A comparison is made between a high-quality, conventionally processed (CP) cavity with a high field Q drop for acceleration field E $>$ 20 MV/m and a nitrogen doped (N-doped) cavity that exhibits an increasing Q up to fields approaching 15 MV/m. The CP cavity displays hot spot regions at high RF fields where Q-drop occurs as well as unaffected regions (cold spots). PCT data on cold spots reveals a near ideal BCS density of states (DOS) with gap parameters, $Δ$ as high as 1.62 meV, that are among the highest values ever reported for Nb. Hot spot regions exhibit a wide distribution of gap values down to $Δ\sim$ 1.0 meV and DOS broadening characterized by a relatively large value of pair-breaking rate, $Γ$, indicating surface regions of significantly reduced superconductivity. In addition, hot spots commonly exhibit Kondo tunneling peaks indicative of surface magnetic moments attributed to a defective oxide. N-doped cavities reveal a more homoegeneous gap distribution centered at $Δ\sim$ 1.5 meV and relatively small values of $Γ/Δ$. The absence of regions of significantly reduced superconductivity indicates that the N interstitials are playing an important role in preventing the formation of hydride phases and other macroscopic defects which might otherwise severely affect the local, surface superconductivity that lead to hot spot formation. The N-doped cavities also display a significantly improved surface oxide, i.e., increased thickness and tunnel barrier height, compared to CP cavities. These results help explain the improved performance of N-doped cavities and give insights into the origin of the initial increasing Q with RF amplitude.

cond-mat.supr-con↗

arXiv2016

Effect of interstitial impurities on the field dependent microwave surface resistance of niobium

Previous work has demonstrated that the radio frequency surface resistance of niobium resonators is dramatically reduced when nitrogen impurities are dissolved as interstitial in the material. The origin of this effect is attributed to the lowering of the Mattis and Bardeen surface resistance contribution with increasing accelerating field. Meanwhile, an enhancement of the sensitivity to trapped magnetic field is typically observed for such cavities. In this paper we conduct the first systematic study on these different components contributing to the total surface resistance as a function of different levels of dissolved nitrogen, in comparison with standard surface treatments for niobium resonators. Adding these results together we are able to show for the first time which is the optimum surface treatment that maximizes the Q-factor of superconducting niobium resonators as a function of expected trapped magnetic field in the cavity walls. These results also provide new insights on the physics behind the change in the field dependence of the Mattis and Bardeen surface resistance, and of the trapped magnetic vortex induced losses in superconducting niobium resonators.

physics.acc-ph↗

arXiv2016

Quench-Induced Degradation of the Quality Factor in Superconducting Resonators

Quench of superconducting radio-frequency cavities frequently leads to the lowered quality factor Q0, which had been attributed to the additional trapped magnetic flux. Here we demonstrate that the origin of this magnetic flux is purely extrinsic to the cavity by showing no extra dissipation (unchanged Q0) after quenching in zero magnetic field, which allows us to rule out intrinsic mechanisms of flux trapping such as generation of thermal currents or trapping of the rf field. We also show the clear relation of dissipation introduced by quenching to the orientation of the applied magnetic field and the possibility to fully recover the quality factor by requenching in the compensated field. We discover that for larger values of the ambient field, the Q-factor degradation may become irreversible by this technique, likely due to the outward flux migration beyond the normal zone opening during quench. Our findings are of special practical importance for accelerators based on low- and medium-beta accelerating structures residing close to focusing magnets, as well as for all high-Q cavity-based accelerators.

physics.acc-ph↗

arXiv2015

Nanostructural features degrading the performance of superconducting radio frequency niobium cavities revealed by TEM and EELS

Nanoscale defect structure within the magnetic penetration depth of ~100nm is key to the performance limitations of niobium superconducting radio frequency (SRF) cavities. Using a unique combination of advanced thermometry during cavity RF measurements, and TEM structural and compositional characterization of the samples extracted from cavity walls, we discover the existence of nanoscale hydrides in electropolished cavities limited by the high field Q slope, and show the decreased hydride formation in the electropolished cavity after 120C baking. Furthermore, we demonstrate that adding 800C hydrogen degassing followed by light buffered chemical polishing restores the hydride formation to the pre-120C bake level. We also show absence of niobium oxides along the grain boundaries and the modifications of the surface oxide upon 120C bake.

physics.acc-ph↗

arXiv2015

Giant two-phonon Raman scattering from nanoscale NbC precipitates in Nb

High purity niobium (Nb), subjected to the processing methods used in the fabrication of superconducting RF cavities, displays micron-sized surface patches containing excess carbon. High-resolution transmission electron microscopy and electron energy-loss spectroscopy measurements are presented which reveal the presence of nanoscale NbC coherent precipitates in such regions. Raman backscatter spectroscopy on similar surface regions exhibit spectra consistent with the literature results on bulk NbC but with significantly enhanced two-phonon scattering. The unprecedented strength and sharpness of the two-phonon signal has prompted a theoretical analysis, using density functional theory (DFT), of phonon modes in NbC for two different interface models of the coherent precipitate. One model leads to overall compressive strain and a comparison to ab-initio calculations of phonon dispersion curves under uniform compression of the NbC shows that the measured two-phonon peaks are linked directly to phonon anomalies arising from strong electron-phonon interaction. Another model of the extended interface between Nb and NbC, studied by DFT, gives insight into the frequency shifts of the acoustic and optical mode density of states measured by first order Raman. The exact origin of the stronger two-phonon response is not known at present but it suggests the possibility of enhanced electron-phonon coupling in transition metal carbides under strain found either in the bulk NbC inclusions or at their interfaces with Nb metal. Preliminary tunneling studies using a point contact method show some energy gaps larger than expected for bulk NbC.

cond-mat.supr-con↗

arXiv2010

Rebuttal to "Comment by V.M. Krasnov on 'Counterintuitive consequence of heating in strongly-driven intrinsic junctions of Bi2Sr2CaCu2O8+d Mesas' "

In our article [1], we found that with increasing dissipation there is a clear, systematic shift and sharpening of the conductance peak along with the disappearance of the higher-bias dip/hump features (DHF), for a stack of intrinsic Josephson junctions (IJJs) of intercalated Bi2Sr2CaCu2O8+δ (Bi2212). Our work agrees with Zhu et al [2] on unintercalated, pristine Bi2212, as both studies show the same systematic changes with dissipation. The broader peaks found with reduced dissipation [1,2] are consistent with broad peaks in the density-of-states (DOS) found among scanning tunneling spectroscopy [3] (STS), mechanical contact tunneling [4] (MCT) and inferred from angle (momentum) resolved photoemission spectroscopy [5] (ARPES); results that could not be ignored. Thus, sharp peaks are extrinsic and cannot correspond to the superconducting DOS. We suggested that the commonality of the sharp peaks in our conductance data, which is demonstrably shown to be heating-dominated, and the peaks of previous intrinsic tunneling spectroscopy (ITS) data implies that these ITS reports might need reinterpretation.

cond-mat.supr-con↗

arXiv2009

Counterintuitive Consequence of Heating in Strongly-Driven Intrinsic-Junctions of Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ Mesas

Anomalously high and sharp peaks in the conductance of intrinsic Josephson junctions in Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ (Bi2212) mesas have been universally interpreted as superconducting energy gaps, but here we show they are a result of heating. This interpretation follows from a direct comparison to the equilibrium gap, $\mathit Δ$, measured in break junctions on similar Bi2212 crystals. As the dissipated power increases with a greater number of junctions in the mesa, the conductance peak abruptly sharpens and its voltage decreases to well below 2$\mathit Δ$. This sharpening, found in our experimental data, defies conventional intuition of heating effects on tunneling spectra, but it can be understood as an instability into a nonequilibrium two-phase coexistent state. The measured peak positions occur accurately within the voltage range that an S-shaped backbending is found in the {\it calculated} current-voltage curves for spatially {\it uniform} self-heating and that S-shape implies the potential for the uniform state to be unstable.

cond-mat.supr-con↗

arXiv2009

Thermal Management in Large Bi2212 Mesas used for Terahertz Sources

We present a thermal analysis of a patterned mesa on a Bi2Sr2CaCu2O8 (Bi2212) single crystal that is based on tunneling characteristics of the c-axis stack of ~800 intrinsic Josephson junctions in the mesa. Despite the large mesa volume (e.g., 40x300x1.2 micron3) and power dissipation that result in selfheating and backbending of the current-voltage curve (I-V), there are accessible bias conditions for which significant polarized THz-wave emission can be observed. We estimate the mesa temperature by equating the quasiparticle resistance, Rqp(T), to the ratio V/I over the entire I-V including the backbending region. These temperatures are used to predict the unpolarized black-body radiation reaching our bolometer and there is substantial agreement over the entire I-V. As such, backbending results from the particular Rqp(T) for Bi2212, as first discussed by Fenton, rather than a significant suppression of the energy gap. This model also correctly predicts the observed disappearance of backbending above ~60 K.

cond-mat.supr-con↗

arXiv2008

Tunneling study of cavity grade Nb: possible magnetic scattering at the surface

Tunneling spectroscopy was performed on Nb pieces prepared by the same processes used to etch and clean superconducting radio frequency (SRF) cavities. Air exposed, electropolished Nb exhibited a surface superconducting gap delta=1.55 meV, characteristic of clean, bulk Nb. However the tunneling density of states (DOS) was broadened significantly. The Nb pieces treated with the same mild baking used to improve the Q-slope in SRF cavities, reveal a sharper DOS. Good fits to the DOS were obtained using Shiba theory, suggesting that magnetic scattering of quasiparticles is the origin of the gapless surface superconductivity and a heretofore unrecognized contributor to the Q-slope problem of Nb SRF cavities.

cond-mat.supr-con↗

arXiv2007

Characteristic Energy of the Coulomb Interactions and the Pileup of States

Tunneling data on $\mathrm{La_{1.28}Sr_{1.72}Mn_2O_7}$ crystals confirm Coulomb interaction effects through the $\sqrt{\mathrm{E}}$ dependence of the density of states. Importantly, the data and analysis at high energy, E, show a pileup of states: most of the states removed from near the Fermi level are found between ~40 and 130 meV, from which we infer the possibility of universal behavior. The agreement of our tunneling data with recent photoemission results further confirms our analysis.

cond-mat.str-el↗

arXiv2007

Evidence of Strong-Coupled Superconductivity in CaC6 from Tunneling Spectroscopy

Point-contact tunneling on CaC$_6$ crystals reproducibly reveals superconducting gaps, $Δ$, of 2.3$\pm$0.2 meV which are $\sim$~40% larger than earlier reports. That puts CaC$_6$ into the class of very strong-coupled superconductors since 2$Δ$/kT$_c\sim$~4.6. Thus soft Ca phonons will be primarily involved in the superconductivity, a conclusion that explains the large Ca isotope effect found recently for CaC$_6$. Consistency among superconductor-insulator-normal metal (SIN), SIS and Andreev reflection (SN) junctions reinforces the intrinsic nature of this result.

cond-mat.supr-con↗

arXiv2006

Tunneling spectroscopy of Tl2Ba2CaCu2O8 single crystals and thin films

Early electron tunneling experiments with the Tl2Ba2CaCu2O8 measured Δ= 16-28 meV, while bulk optical experiments measured Δ= 43-45 meV. We report new tunneling measurements of Tl2Ba2CaCu2O8 single crystals and c-axis oriented thin films, where the measured Δvalues on both sample types cover the range of 24-50 meV, with more than 70% of the junctions displaying Δ> 30 meV. This work resolves the inconsistency between previously published results of tunneling and optical experiments. New tunneling conductances reveal improved superconducting gap region characteristics consistent with d-wave symmetry. The tunneling spectra also display features similar to the dip feature observed in Bi2Sr2CaCu2O8. We discuss our results in context of experiments reported previously on related materials.

cond-mat.supr-con↗

arXiv2006

Modeling Study of the Dip/Hump Feature in Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ Tunneling Spectroscopy

The tunneling spectra of high temperature superconductors on Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ (Bi-2212) reproducibly show a high bias structure in the form of a dip-hump at voltages higher than the gap voltage. Of central concern is whether this feature originates from the normal state background or is intrinsic to the superconducting mechanism. We address this issue by generating a set of model conductance curves - a ''normal state'' conductance that takes into account effects such as the band structure and a possible pseudogap, and a pure superconducting state conductance. When combined, the result shows that the dip-hump feature present in the experimental conductance curves cannot be naively attributed to a normal state effect. In particular, strong dip features found in superconductor-insulator-superconductor data on optimally-doped Bi-2212, including negative dI/dV, cannot be a consequence of an extrinsic pseudogap. However, such features can easily arise from states-conserving deviations in the superconducting density of states, e.g., from strong-coupling effects.

cond-mat.supr-con↗

arXiv2005

Persistence of Strong Electron Coupling to a Narrow Boson Spectrum in Overdoped BiSrCaCuO (Bi2212) Tunneling Data

A d-wave, Eliashberg analysis of break junction and STM tunneling spectra on BiSrCaCuO (Bi2212) reveals that a spectral dip feature is directly linked to strong electronic coupling to a narrow boson spectrum, evidenced by a large peak in the boson spectral weight. The tunneling dip feature remains robust in the overdoped regime of Bi2212 with bulk Tc values of 56 K-62 K. This is contrary to recent optical conductivity measurements of the self-energy that suggest the narrow boson spectrum disappears in overdoped Bi2212 and therefore cannot be essential for the pairing mechanism. The discrepancy is resolved by considering the way each technique probes the electron self-energy, in particular, the unique sensitivity of tunneling to the off-diagonal or pairing part of the self-energy.

cond-mat.supr-con↗

arXiv2004

Single Junction and Intrinsic Josephson Junction Tunneling Spectroscopies of Bi2Sr2CaCu2O8+d

Tunneling spectroscopy measurements are reported on optimally-doped and overdoped Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ single crystals. A novel point contact method is used to obtain superconductor-insulator-normal metal (SIN) and SIS break junctions as well as intrinsic Josephson junctions (IJJ) from nanoscale crystals. Three junction types are obtained on the same crystal to compare the quasiparticle peaks and higher bias dip/hump structures which have also been found in other surface probes such as scanning tunneling spectroscopy and angle-resolved photoemission spectroscopy. However, our IJJ quasiparticle spectra consistently reveal very sharp conductance peaks and no higher bias dip structures. The IJJ conductance peak voltage divided by the number of junctions in the stack consistently leads to a significant underestimate of $Δ$ when compared to the single junction values. The comparison of the three methods suggests that the markedly different characteristics of IJJ are a consequence of nonequilibrium effects and are not intrinsic quasiparticle features.

cond-mat.supr-con↗

arXiv2003

Retention of Two-Band Superconductivity in Highly Carbon-Doped MgB2

Tunneling data on MgB_{1.8}C_{0.2} show a reduction in the energy gap of the pi-bands by a factor of two from undoped MgB2 that is consistent with the Tc reduction, but inconsistent with the expectations of the dirty limit. Dirty-limit theory for undoped MgB2 predicts a single gap about three times larger than measured and a reduced Tc comparable to that measured. Our heavily-doped samples exhibit a uniform dispersion of C suggestive of significantly enhanced scattering, and we conclude that the retention of two-band superconductivity in these samples is caused by a selective suppression of interband scattering.

cond-mat.supr-con↗

arXiv2003

Probing the Phase Diagram of Bi2Sr2CaCu2O8+d with Tunneling Spectroscopy

Tunneling measurements are performed on Ca-rich single crystals of Bi2Sr2CaCu2O8+d (Bi2212), with various oxygen doping levels, using a novel point contact method. At 4.2 K, SIN and SIS tunnel junctions are obtained with well-defined quasiparticle peaks, robust dip and hump features and in some cases Josephson currents. The doping dependence of tunneling conductances of Ca-rich Bi2212 are analyzed and compared to stoichiometric Bi2212. A similar profile of energy gap vs. doping concentration is found although the Ca-rich samples have a slighly smaller optimum Tc and therefore smaller gap values for any doping level. The evolution of tunneling conductance peak height to background ratios with hole concentration are compared. For a given doping level, the Ca-rich spectra showed more broadened features compared to the stoichiometric counterparts, most likely due to increased disorder from the excess Ca. Comparison of the dip and hump features has provided some potential insights into their origins.

cond-mat.supr-con↗