arXiv subjects

J. H. Neethling

Publications and source records attributed to J. H. Neethling.

4 recordsLinked to original sources

arXiv2026

High-temperature behavior of amorphous alumina coatings: Insights from in-situ nanoindentation and X-ray diffraction studies

Further development of nuclear power plant technology relies heavily on materials durability under operating conditions. Estimating the materials performance in the operando tests is crucial. In this paper, the mechanical behavior of thin amorphous nuclear-dedicated Al2O3 coatings deposited by pulsed laser deposition was investigated by nanoindentation over the temperature range of 25-650C. Experimental nanomechanical analysis was supported by MD simulations. The results indicate that the hardness of the amorphous coating experiences a gradual, constant decrease with temperature, while the Young modulus value remains constant in the whole temperature range. Observed phenomena confirm the increasing plasticity of the material and it is postulated to be related to the bond-switching mechanism that accelerates at high temperatures. The post-mortem transmission electron microscopy characterization confirmed that the loaded material was non-crystalline over the entire range of the indentation temperatures. The thermal stability of the structure was further studied in-situ up to 1050C by X-ray diffraction. The implemented methodology allowed us to follow the dynamic process of phase transitions occurring in the material above 650C. First, thermally activated crystallization was observed at 700C. Intermediate alumina phases were present up to 950C, while above this temperature, exclusively the thermodynamically stable alpha-Al2O3 was observed. The in-situ high-temperature characterization of the evolution of thin films boosts the understanding of the application limits of the coating systems at elevated temperatures. The added value is that the paper demonstrates the potential usefulness of combining high-temperature techniques to characterize the complete behavior of thin films at elevated temperatures.

cond-mat.mtrl-sci↗

arXiv2025

Nanoindentation responses of Fe-Cr alloys from room temperature to 600 {\deg}C

In this work, the evolution of nanomechanical properties was studied systematically as a function of temperature, chemical, and microstructural complexity of different Fe-based alloys. Experiments were performed at different temperatures (room temperature, 200 C, 400 C, 600 C) using the nanoindentation technique on low activation Fe9Cr-1WVTa (Eurofer97), model Fe-9Cr-NiSiP, Fe-9Cr alloys, and pure iron samples, followed by microstructural observations. The results show varying softening and hardening effects depending on the experimental temperature, demonstrating Portevin-Le-Chatelier effect, i.e., dynamic strain aging phenomenon in model alloys. Sources of the dynamic strain aging instabilities were traced back to the interaction between dislocations and alloying elements such as interstitial carbon and substitutional chromium. The materials undergo dynamic recovery and recrystallization below the regions of high-temperature indentation depending on the pre-indentation dislocation density and the alloy composition. Our findings help in the understanding of the structure and mechanical property relationship in complex Eurofer97 alloy at high-temperatures for potential nuclear applications as structural materials.

cond-mat.mtrl-sci↗

arXiv2023

Absolute radiation tolerance of amorphous alumina coatings at room temperature

In this study structural and mechanical properties of a 1 um thick Al2O3 coating, deposited on 316L stainless steel by Pulsed Laser Deposition (PLD), subjected to high energy ion irradiation were assessed. Mechanical properties of pristine and ion-modified specimens were investigated using the nanoindentation technique. A comprehensive characterization combining Transmission Electron Microscopy and Grazing-Incidence X-ray Diffraction provided deep insight into the structure of the tested material at the nano- and micro- scale. Variation in the local atomic ordering of the irradiated zone at different doses was investigated using a reduced distribution function analysis obtained from electron diffraction data. Findings from nanoindentation measurements revealed a slight reduction in hardness of all irradiated layers. At the same time TEM examination indicated that the irradiated layer remained amorphous over the whole dpa range. No evidence of crystallization, void formation or element segregation was observed up to the highest implanted dose. Reported mechanical and structural findings were critically compared with each other pointing to the conclusion that under given irradiation conditions, over the whole range of doses used, alumina coatings exhibit excellent radiation resistance. Obtained data strongly suggest that investigated material may be considered as a promising candidate for next-generation nuclear reactors, especially LFR-type, where high corrosion protection is one of the highest prerogatives to be met.

cond-mat.mtrl-sci↗

arXiv2021

Iron-silica interaction during reduction of precipitated silica-promoted iron oxides using in situ XRD and TEM

The effect of silica-promotion on the reduction of iron oxides in hydrogen was investigated using in situ X-ray diffraction and aberration-corrected transmission electron microscopy to understand the mechanism of reduction and the identity of the iron(II) silicate phase that has historically been designated as the cause of the iron-silica interaction in such materials. In the absence of a silica promoter the reduction of hematite to α-Fe proceeds via magnetite. Silica promoted amorphous iron oxide is reduced to α-Fe via stable magnetite and wüstite phases. During reduction of silica-promoted iron oxide, Fe0 diffuses out of the amorphous silica-promoted iron oxide matrix upon reduction from Fe2+ and coexists with an amorphous Fe-O-Si matrix. Certain portions of wüstite remain difficult to reduce to α-Fe owing to the formation of a protective silica-containing layer covering the remaining iron oxide regions. Given sufficient energy, this amorphous Fe-O-Si material forms ordered, crystalline fayalite.

cond-mat.mtrl-sci↗