arXiv subjects

J. Hakl

Publications and source records attributed to J. Hakl.

4 recordsLinked to original sources

arXiv2015

Nanoscale characterization of thin immersion silver coatings on copper substrates

Microelectronic-grade copper foils were immersion silver plated in a home-made non-cyanide alkaline silver nitrate - thiosulfate solution and in two commercially available industrial baths via contact reductive precipitation. The concentration depth profiles of the freshly deposited silver layers were afterwards analyzed at nanoscale resolution by means of Secondary Neutral Mass Spectrometry (SNMS) and Glow Discharge Optical Emission Spectroscopy (GDOES). The thickness of deposited silver layers obtained with 30-60 s immersion time were in the range of 50-150 nm, depending on the parameters of the immersion procedure. Slight contamination of sulfur from the thiosulfate bath was detectable. Traces of Cr and Na could be observed as well around the interface between the copper substrate and silver deposit. Results also indicate that storage for longer time in air especially at higher than ambient temperatures induces a kind of ageing effect in the deposited layer, changing its composition. In case of samples prepared from home-made solution increasing amounts of copper together with its corrosion products became detectable.

cond-mat.mtrl-sci↗

arXiv2014

Larmor precession and Debye relaxation of single-domain magnetic nanoparticles

The numerous phenomenological equations used in the study of the behaviour of single-domain magnetic nanoparticles are described and some issues clarified by means of qualitative comparison. To enable a quantitative \textit{application} of the model based on the Debye (exponential) relaxation and the torque driving the Larmor precession, we present analytical solutions for the steady states in presence of circularly and linearly polarized AC magnetic fields. Using the exact analytical solutions, we can confirm the insight that underlies Rosensweig's introduction of the "chord" susceptibility for an approximate calculation of the losses. As an important consequence, it can also explain experiments, where power dissipation for both fields were found to be identical in "root mean square" sense. We also find that this approximation provides satisfactory numerical accuracy only up to magnetic fields for which the argument of the Langevin function reaches the value 2.8.

cond-mat.mes-hall↗

arXiv2009

Magnetic particle hyperthermia: Neel relaxation in magnetic nanoparticles under circularly polarized field

The mechanism of magnetization reversal in single-domain ferromagnetic particles is of interest in many applications, in most of which losses must be minimized. In cancer therapy by hyperthermia the opposite requirement prevails: the specific loss power should be maximized. Of the mechanisms of dissipation, here we study the effect of Neel relaxation on magnetic nanoparticles unable to move or rotate and compare the losses in linearly and circularly polarized field. We present exact analytical solutions of the Landau-Lifshitz equation as derived from the Gilbert equation and use the calculated time-dependent magnetizations to find the energy loss per cycle. In frequencies lower than the Larmor frequency linear polarization is found to be the better source of heat power, at high frequencies (beyond the Larmor frequency) circular polarization is preferable.

cond-mat.other↗

arXiv2009

Application of Secondary Neutral Mass Spectrometry in the investigation of doped perovskites

Electromagnetic properties of doped perovskites depend sensitively on the doping level. Both the superconducting transition temperature of Bi2Sr2Ca(Pr)Cu2O8+d compounds and the magnetic and electronic transport properties of La(Sr)Co(Fe)O3 perovskites change dramatically with the doping level. Apart from doping, oxygen deficiency is influenced by the details of preparation processes such as calcination and sintering. Simultaneous determination of constituents is of crucial importance from sample characterization point of view. Quantitative analysis of perovskite oxides can be performed by Secondary Neutral Mass Spectrometry (SNMS) which is a suitable technique to measure the chemical composition of almost any sample because the flux of atoms sputtered from the sample is representative of the stoichiometry of the top-most layers. The composition and oxygen content of Bi2Sr2Ca0.86Pr0.14Cu2O8.4 and La1-xSrxCo0.975Fe0.025O3-d, where 0<x<0.5, were determined by SNMS. The results show that the method is equally applicable for insulating and conducting compounds. The observed electromagnetic properties reflect well the compositions obtained experimentally.

cond-mat.mtrl-sci↗