arXiv subjects

J. I. Lunine

Publications and source records attributed to J. I. Lunine.

At least 19 recordsLinked to original sources

arXiv2026

An unidentified absorption feature at 5.11 $μ$m on the surface of Titan and Pluto from JWST spectroscopy

Titan possesses a thick N$_2$-CH$_4$ atmosphere that makes it difficult to study its surface spectroscopically. The chemical composition of the solid surface of Titan thus remains very uncertain. By leveraging JWST's high sensitivity and large spectral coverage, we searched for any signature from Titan's surface in the broad and less explored 5-$μ$m atmospheric window. We also investigated the JWST spectrum of Pluto which has a thin Titan-like atmosphere. We made selections of JWST NIRSpec and MIRI spectra around Titan's disk center and compared the NIRSpec average spectrum with a radiative transfer model including gas and haze opacity. We detected an unidentified absorption in both NIRSpec and MIRI spectra of Titan centered at 5.113 $μ$m (1956 cm$^{-1}$) and 6-7% deep. The width of the feature is 0.024$\pm$0.0008 $μ$m (9.2$\pm$0.3 cm$^{-1}$) in the NIRSpec spectrum recorded on the trailing side and is possibly 25% narrower in the MIRI spectrum of the leading side. This absorption most likely originates from the surface. We could not identify this signature among published laboratory spectra of ices relevant to Titan's atmospheric compounds but present a few plausible candidates. A 4-5% deep absorption is also present in the MIRI spectrum of Pluto but is about 3 times broader than on Titan's trailing side.

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arXiv2024

Unveiling the ice and gas nature of active centaur (2060) Chiron using the James Webb Space Telescope

(2060) Chiron is a large centaur that has been reported active on multiple occasions including during aphelion passage. Studies of Chirons coma during active periods have resulted in the detection of C(triple)N and CO outgassing. Significant work remains to be undertaken to comprehend the activation mechanisms on Chiron and the parent molecules of the gas phases detected. This work reports the study of the ices on Chirons surface and coma and seeks spectral indicators of volatiles associated with the activity. Additionally, we discuss how these detections could be related to the activation mechanism for Chiron and, potentially, other centaurs. In July 2023, the James Webb Space Telescope (JWST) observed Chiron when it was active near its aphelion. We present JWST/NIRSpec spectra from 0.97 to 5.27 microns with a resolving power of 1000, and compare them with laboratory data for identification of the spectral bands. We report the first detections on Chiron of absorption bands of several volatile ices, including CO2, CO, C2H6, C3H8, and C2H2. We also confirm the presence of water ice in its amorphous state. A key discovery arising from these data is the detection of fluorescence emissions of CH4, revealing the presence of a gas coma rich in this hyper-volatile molecule, which we also identify to be in non-local thermal equilibrium (nonLTE). CO2 gas emission is also detected in the fundamental stretching band at 4.27 microns. We argue that the presence of CH4 emission is the first proof of the desorption of CH4 due to a density phase transition of amorphous water ice at low temperature in agreement with the estimated temperature of Chiron during the JWST observations (61 K). Detection of photolytic and proton irradiation products of CH4 and CO2 on the surface, in the coma ice grains, or in the ring material is also detected via a forest of absorption features from 3.5 to 5.3 microns.

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arXiv2024

A Tale of 3 Dwarf Planets: Ices and Organics on Sedna, Gonggong, and Quaoar from JWST Spectroscopy

We observed Sedna, Gonggong, and Quaoar with the NIRSpec instrument on the James Webb Space Telescope (JWST). All three bodies were observed in the low-resolution prism mode at wavelengths spanning 0.7 to 5.2 $μ$m. Quaoar was also observed at 10x higher spectral resolution from 0.97 to 3.16 $μ$m using medium-resolution gratings. Sedna's spectrum shows a large number of absorption features due to ethane (C$_2$H$_6$), as well as acetylene (C$_2$H$_2$), ethylene (C$_2$H$_4$), H$_2$O, and possibly minor CO$_2$. Gonggong's spectrum also shows several, but fewer and weaker, ethane features, along with stronger and cleaner H$_2$O features and CO$_2$ complexed with other molecules. Quaoar's prism spectrum shows even fewer and weaker ethane features, the deepest and cleanest H$_2$O features, a feature at 3.2 $μ$m possibly due to HCN, and CO$_2$ ice. The higher-resolution medium grating spectrum of Quaoar reveals several overtone and combination bands of ethane and methane (CH$_4$). Spectra of all three objects show steep red spectral slopes and strong, broad absorptions between 2.7 and 3.6 $μ$m indicative of complex organic molecules. The suite of light hydrocarbons and complex organic molecules are interpreted as the products of irradiation of methane. We infer that the differences in apparent abundances of irradiation products are likely due to their distinctive orbits, which lead to different timescales of methane retention and to different charged particle irradiation environments. In all cases, however, the continued presence of light hydrocarbons implies a resupply of methane to the surface. We suggest that these three bodies have undergone internal melting and geochemical evolution similar to the larger dwarf planets and distinct from all smaller KBOs.

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arXiv2023

Measurement of D/H and 13C/12C Ratios in Methane Ice on Eris and Makemake: Evidence for Internal Activity

James Webb Space Telescope's NIRSpec infrared imaging spectrometer observed the outer solar system dwarf planets Eris and Makemake in reflected sunlight at wavelengths spanning 1 through 5 microns. Both objects have high albedo surfaces that are rich in methane ice, with a texture that permits long optical path lengths through the ice for solar photons. There is evidence for N2 ice absorption around 4.2 um on Eris, though not on Makemake. No CO ice absorption is seen at 4.67 um on either body. For the first time, absorption bands of two heavy isotopologues of methane are observed at 2.615 um (13CH4), 4.33 um (12CH3D), and 4.57 um (12CH3D). These bands enable us to measure D/H ratios of (2.5 +/- 0.5) x 10-4 and (2.9 +/- 0.6) x 10-4, along with 13C/12C ratios of 0.012 +/- 0.002 and 0.010 +/- 0.003 in the surface methane ices of Eris and Makemake, respectively. The measured D/H ratios are much lower than that of presumably primordial methane in comet 67P/Churyumov-Gerasimenko, but they are similar to D/H ratios in water in many comets and larger outer solar system objects. This similarity suggests that the hydrogen atoms in methane on Eris and Makemake originated from water, indicative of geochemical processes in past or even ongoing hot environments in their deep interiors. The 13C/12C ratios are consistent with commonly observed solar system values, suggesting no substantial enrichment in 13C as could happen if the methane currently on their surfaces was the residue of a much larger inventory that had mostly been lost to space. Possible explanations include geologically recent outgassing from the interiors as well as processes that cycle the surface methane inventory to keep the uppermost surfaces refreshed.

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arXiv2022

Moonraker -- Enceladus Multiple Flyby Mission

Enceladus, an icy moon of Saturn, possesses an internal water ocean and jets expelling ocean material into space. Cassini investigations indicated that the subsurface ocean could be a habitable environment having a complex interaction with the rocky core. Further investigation of the composition of the plume formed by the jets is necessary to fully understand the ocean, its potential habitability, and what it tells us about Enceladus' origin. Moonraker has been proposed as an ESA M-class mission designed to orbit Saturn and perform multiple flybys of Enceladus, focusing on traversals of the plume. The proposed Moonraker mission consists of an ESA-provided platform, with strong heritage from JUICE and Mars Sample Return, and carrying a suite of instruments dedicated to plume and surface analysis. The nominal Moonraker mission has a duration of 13.5 years. It includes a 23-flyby segment with 189 days allocated for the science phase, and can be expanded with additional segments if resources allow. The mission concept consists in investigating: i) the habitability conditions of present-day Enceladus and its internal ocean, ii) the mechanisms at play for the communication between the internal ocean and the surface of the South Polar Terrain, and iii) the formation conditions of the moon. Moonraker, thanks to state-of-the-art instruments representing a significant improvement over Cassini's payload, would quantify the abundance of key species in the plume, isotopic ratios, and physical parameters of the plume and the surface. Such a mission would pave the way for a possible future landed mission.

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arXiv2022

Airfall on Comet 67P/Churyumov-Gerasimenko

We here study the transfer process of material from one hemisphere to the other (deposition of airfall material) on an active comet nucleus, specifically 67P/Churyumov-Gerasimenko. Our goals are to: 1) quantify the thickness of the airfall debris layers and how it depends on the location of the target area, 2) determine the amount of $\mathrm{H_2O}$ and $\mathrm{CO_2}$ ice that are lost from icy dust assemblages of different sizes during transfer through the coma, and 3) estimate the relative amount of vapor loss in airfall material after deposition in order to understand what locations are expected to be more active than others on the following perihelion approach. We use various numerical simulations, that include orbit dynamics, thermophysics of the nucleus and of individual coma aggregates, coma gas kinetics and hydrodynamics, as well as dust dynamics due to gas drag, to address these questions. We find that the thickness of accumulated airfall material varies substantially with location, and typically is of the order $0.1$-$1\,\mathrm{m}$. The airfall material preserves substantial amounts of water ice even in relatively small (cm-sized) coma aggregates after a rather long ($12\,\mathrm{h}$) residence in the coma. However, $\mathrm{CO_2}$ is lost within a couple of hours even in relatively large (dm-sized) aggregates, and is not expected to be an important component in airfall deposits. We introduce reachability and survivability indices to measure the relative capacity of different regions to simultaneously collect airfall and to preserve its water ice until the next perihelion passage, thereby grading their potential of contributing to comet activity during the next perihelion passage.

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arXiv2022

Jupiter's inhomogeneous envelope

While Jupiter's massive gas envelope consists mainly of hydrogen and helium, the key to understanding Jupiter's formation and evolution lies in the distribution of the remaining (heavy) elements. Before the Juno mission, the lack of high-precision gravity harmonics precluded the use of statistical analyses in a robust determination of the heavy-elements distribution in Jupiter's envelope. In this paper, we assemble the most comprehensive and diverse collection of Jupiter interior models to date and use it to study the distribution of heavy elements in the planet's envelope. We apply a Bayesian statistical approach to our interior model calculations, reproducing the Juno gravitational and atmospheric measurements and constraints from the deep zonal flows. Our results show that the gravity constraints lead to a deep entropy of Jupiter corresponding to a 1 bar temperature 5-15 K higher than traditionally assumed. We also find that uncertainties in the equation of state are crucial when determining the amount of heavy elements in Jupiter's interior. Our models put an upper limit to the inner compact core of Jupiter of 7 Earth masses, independently on the structure model (with or without dilute core) and the equation of state considered. Furthermore, we robustly demonstrate that Jupiter's envelope is inhomogenous, with a heavy-element enrichment in the interior relative to the outer envelope. This implies that heavy element enrichment continued through the gas accretion phase, with important implications for the formation of giant planets in our solar system and beyond.

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arXiv2020

Key Atmospheric Signatures for Identifying the Source Reservoirs of Volatiles in Uranus and Neptune

We investigate the enrichment patterns of several delivery scenarios of the volatiles to the atmospheres of ice giants, having in mind that the only well constrained determination made remotely, i.e. the carbon abundance measurement, suggests that their envelopes possess highly supersolar metallicities, i.e. close to two orders of magnitude above that of the protosolar nebula. In the framework of the core accretion model, only the delivery of volatiles in solid forms (amorphous ice, clathrates, pure condensates) to these planets can account for the apparent supersolar metallicity of their envelopes. In contrast, because of the inward drift of icy particles through various snowlines, all mechanisms invoking the delivery of volatiles in vapor forms predict subsolar abundances in the envelopes of Uranus and Neptune. Alternatively, even if the disk instability mechanism remains questionable in our solar system, it might be consistent with the supersolar metallicities observed in Uranus and Neptune, assuming the two planets suffered subsequent erosion of their H-He envelopes. The enrichment patterns derived for each delivery scenario considered should be useful to interpret future in situ measurements by atmospheric entry probes.

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arXiv2019

Comparing key compositional indicators in Jupiter with those in extra-solar giant planets

Spectroscopic transiting observations of the atmospheres of hot Jupiters around other stars, first with Hubble Space Telescope and then Spitzer, opened the door to compositional studies of exoplanets. The James Webb Space Telescope will provide such a profound improvement in signal-to-noise ratio that it will enable detailed analysis of molecular abundances, including but not limited to determining abundances of all the major carbon- and oxygen-bearing species in hot Jupiter atmospheres. This will allow determination of the carbon-to-oxygen ratio, an essential number for planet formation models and a motivating goal of the Juno mission currently around Jupiter

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arXiv2018

Synthesis of molecular oxygen via irradiation of ice grains in the protosolar nebula

Molecular oxygen has been detected in the coma of comet 67P/Churyumov--Gerasimenko with a mean abundance of 3.80 $\pm$ 0.85\% by the ROSINA mass spectrometer on board the Rosetta spacecraft. To account for the presence of this species in comet 67P/Churyumov--Gerasimenko, it has been shown that the radiolysis of ice grains precursors of comets is a viable mechanism in low-density environments, such as molecular clouds. Here, we investigate the alternative possibility that the icy grains present in the midplane of the protosolar nebula were irradiated during their vertical transport between the midplane and the upper layers over a large number of cycles, as a result of turbulent mixing. Consequently, these grains spent a non-negligible fraction of their lifetime in the disk's upper regions, where the irradiation by cosmic rays was strong. To do so, we used a coupled disk-transport-irradiation model to calculate the time evolution of the molecular oxygen abundance radiolytically produced in ice grains. Our computations show that, even if a significant fraction of the icy particles have followed a back and forth cycle towards the upper layers of the disk over 10 million of years, a timespan far exceeding the formation timescale of comet 67P/Churyumov--Gerasimenko, the amount of produced molecular oxygen is at least two orders of magnitude lower than the Rosetta observations. We conclude that the most likely scenario remains the formation of molecular oxygen in low-density environments, such as the presolar cloud, prior to the genesis of the protosolar nebula.

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arXiv2017

Impact of radiogenic heating on the formation conditions of comet 67P/Churyumov-Gerasimenko

Because of the high fraction of refractory material present in comets, the heat produced by the radiogenic decay of elements such as aluminium and iron can be high enough to induce the loss of ultravolatile species such as nitrogen, argon or carbon monoxide during their accretion phase in the protosolar nebula. Here, we investigate how heat generated by the radioactive decay of 26Al and 60Fe influences the formation of comet 67P/Churyumov-Gerasimenko, as a function of its accretion time and size of parent body. We use an existing thermal evolution model that includes various phase transitions, heat transfer in the ice-dust matrix, and gas diffusion throughout the porous material, based on thermodynamic parameters derived from Rosetta observations. Two possibilities are considered: either, to account for its bilobate shape, 67P/Churyumov-Gerasimenko was assembled from two primordial ~2 kilometer-sized planetesimals, or it resulted from the disruption of a larger parent body with a size corresponding to that of comet Hale-Bopp (~70 km). To fully preserve its volatile content, we find that either 67P/Churyumov-Gerasimenko's formation was delayed between ~2.2 and 7.7 Myr after that of Ca-Al-rich Inclusions in the protosolar nebula or the comet's accretion phase took place over the entire time interval, depending on the primordial size of its parent body and the composition of the icy material considered. Our calculations suggest that the formation of 67P/Churyumov-Gerasimenko is consistent with both its accretion from primordial building blocks formed in the nebula or from debris issued from the disruption of a Hale-Bopp-like body.

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arXiv2016

Possible Internal Structures and Compositions of Proxima Centauri b

We explore the possible Proxima Centauri b's interiors assuming the planet belongs to the class of dense solid planets (rocky with possible addition of water) and derive the corresponding radii. To do so, we use an internal structure model that computes the radius of the planet along with the locations of the different layers of materials, assuming that its mass and bulk composition are known. Lacking detailed elementary abundances of the host star to constrain the planet's composition, we base our model on solar system values. We restrained the simulations to the case of solid planets without massive atmospheres. With these assumptions, the possible radius of Proxima Centauri b spans the 0.94--1.40 $R_\oplus$ range. The minimum value is obtained considering a 1.10 $M_\oplus$ Mercury-like planet with a 65% core mass fraction, whereas the highest radius is reached for 1.46 $M_\oplus$ with 50% water in mass, constituting an ocean planet. Although this range of radii still allows very different planet compositions, it helps characterizing many aspects of Proxima Centauri b, such as the formation conditions of the system or the current amount of water on the planet. This work can also help ruling out future measurements of the planet's radius that would be physically incompatible with a solid planetary body.

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arXiv2016

Stability of sulphur dimers S2 in cometary ices

S2 has been observed for decades in comets, including comet 67P/Churyumov-Gerasimenko. Despite the fact that this molecule appears ubiquitous in these bodies, the nature of its source remains unknown. In this study, we assume that S2 is formed by irradiation (photolysis and/or radiolysis) of S-bearing molecules embedded in the icy grain precursors of comets, and that the cosmic ray flux simultaneously creates voids in ices within which the produced molecules can accumulate. We investigate the stability of S2 molecules in such cavities, assuming that the surrounding ice is made of H2S or H2O. We show that the stabilization energy of S2 molecules in such voids is close to that of the H2O ice binding energy, implying that they can only leave the icy matrix when this latter sublimates. Because S2 has a short lifetime in the vapor phase, we derive that its formation in grains via irradiation must occur only in low density environments such as the ISM or the upper layers of the protosolar nebula, where the local temperature is extremely low. In the first case, comets would have agglomerated from icy grains that remained pristine when entering the nebula. In the second case, comets would have agglomerated from icy grains condensed in the protosolar nebula and that would have been efficiently irradiated during their turbulent transport towards the upper layers of the disk. Both scenarios are found consistent with the presence of molecular oxygen in comets.

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arXiv2016

A protosolar nebula origin for the ices agglomerated by Comet 67P/Churyumov-Gerasimenko

The nature of the icy material accreted by comets during their formation in the outer regions of the protosolar nebula is a major open question in planetary science. Some scenarios of comet formation predict that these bodies agglomerated from crystalline ices condensed in the protosolar nebula. Concurrently, alternative scenarios suggest that comets accreted amorphous ice originating from the interstellar cloud or from the very distant regions of the protosolar nebula. On the basis of existing laboratory and modeling data, we find that the N$_2$/CO and Ar/CO ratios measured in the coma of the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA instrument aboard the European Space Agency's Rosetta spacecraft match those predicted for gases trapped in clathrates. If these measurements are representative of the bulk N$_2$/CO and Ar/CO ratios in 67P/Churyumov-Gerasimenko, it implies that the ices accreted by the comet formed in the nebula and do not originate from the interstellar medium, supporting the idea that the building blocks of outer solar system bodies have been formed from clathrates and possibly from pure crystalline ices. Moreover, because 67P/Churyumov-Gerasimenko is impoverished in Ar and N$_2$, the volatile enrichments observed in Jupiter's atmosphere cannot be explained solely via the accretion of building blocks with similar compositions and require an additional delivery source. A potential source may be the accretion of gas from the nebula that has been progressively enriched in heavy elements due to photoevaporation.

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arXiv2016

Origin of molecular oxygen in Comet 67P/Churyumov-Gerasimenko

Molecular oxygen has been detected in the coma of comet 67P/Churyumov-Gerasimenko with abundances in the 1-10% range by the ROSINA-DFMS instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in low-density environments such as the presolar cloud may induce the production of large amounts of molecular oxygen. We also show that molecular oxygen can be efficiently trapped in clathrates formed in the protosolar nebula, and that its incorporation as crystalline ice is highly implausible because this would imply much larger abundances of Ar and N2 than those observed in the coma. Assuming that radiolysis has been the only O2 production mechanism at work, we conclude that the formation of comet 67P/Churyumov-Gerasimenko is possible in a dense and early protosolar nebula in the framework of two extreme scenarios: (1) agglomeration from pristine amorphous icy grains/particles formed in ISM and (2) agglomeration from clathrates that formed during the disk's cooling. The former scenario is found consistent with the strong correlation between O2 and H2O observed in 67P/C-G's coma while the latter scenario requires that clathrates formed from ISM icy grains that crystallized when entering the protosolar nebula.

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arXiv2015

The Hera Saturn Entry Probe Mission

The Hera Saturn entry probe mission is proposed as an M--class mission led by ESA with a contribution from NASA. It consists of one atmospheric probe to be sent into the atmosphere of Saturn, and a Carrier-Relay spacecraft. In this concept, the Hera probe is composed of ESA and NASA elements, and the Carrier-Relay Spacecraft is delivered by ESA. The probe is powered by batteries, and the Carrier-Relay Spacecraft is powered by solar panels and batteries. We anticipate two major subsystems to be supplied by the United States, either by direct procurement by ESA or by contribution from NASA: the solar electric power system (including solar arrays and the power management and distribution system), and the probe entry system (including the thermal protection shield and aeroshell). Hera is designed to perform in situ measurements of the chemical and isotopic compositions as well as the dynamics of Saturn's atmosphere using a single probe, with the goal of improving our understanding of the origin, formation, and evolution of Saturn, the giant planets and their satellite systems, with extrapolation to extrasolar planets. Hera's aim is to probe well into the cloud-forming region of the troposphere, below the region accessible to remote sensing, to the locations where certain cosmogenically abundant species are expected to be well mixed. By leading to an improved understanding of the processes by which giant planets formed, including the composition and properties of the local solar nebula at the time and location of giant planet formation, Hera will extend the legacy of the Galileo and Cassini missions by further addressing the creation, formation, and chemical, dynamical, and thermal evolution of the giant planets, the entire solar system including Earth and the other terrestrial planets, and formation of other planetary systems.

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arXiv2014

The measured compositions of Uranus and Neptune from their formation on the CO iceline

The formation mechanisms of the ice giants Uranus and Neptune, and the origin of their elemental and isotopic compositions, have long been debated. The density of solids in the outer protosolar nebula is too low to explain their formation, and spectroscopic observations show that both planets are highly enriched in carbon, very poor in nitrogen, and the ices from which they originally formed might had deuterium-to-hydrogen ratios lower than the predicted cometary value, unexplained properties observed in no other planets. Here we show that all these properties can be explained naturally if Uranus and Neptune both formed at the carbon monoxide iceline. Due to the diffusive redistribution of vapors, this outer region of the protosolar nebula intrinsically has enough surface density to form both planets from carbon-rich solids but nitrogen-depleted gas, in abundances consistent with their observed values. Water rich interiors originating mostly from transformed CO ices reconcile the D/H value of Uranus and Neptune's building blocks with the cometary value. Finally, Our scenario generalizes a well known hypothesis that Jupiter formed on an iceline (water snowline) for the two ice giants, and might be a first step towards generalizing this mechanism for other giant planets.

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arXiv2014

Scientific rationale of Saturn's in situ exploration

Remote sensing observations meet some limitations when used to study the bulk atmospheric composition of the giant planets of our solar system. A remarkable example of the superiority of in situ probe measurements is illustrated by the exploration of Jupiter, where key measurements such as the determination of the noble gases abundances and the precise measurement of the helium mixing ratio have only been made available through in situ measurements by the Galileo probe. This paper describes the main scientific goals to be addressed by the future in situ exploration of Saturn placing the Galileo probe exploration of Jupiter in a broader context and before the future probe exploration of the more remote ice giants. In situ exploration of Saturn's atmosphere addresses two broad themes that are discussed throughout this paper: first, the formation history of our solar system and second, the processes at play in planetary atmospheres. In this context, we detail the reasons why measurements of Saturn's bulk elemental and isotopic composition would place important constraints on the volatile reservoirs in the protosolar nebula. We also show that the in situ measurement of CO (or any other disequilibrium species that is depleted by reaction with water) in Saturn's upper troposphere would constrain its bulk O/H ratio. We highlight the key measurements required to distinguish competing theories to shed light on giant planet formation as a common process in planetary systems with potential applications to most extrasolar systems. In situ measurements of Saturn's stratospheric and tropospheric dynamics, chemistry and cloud-forming processes will provide access to phenomena unreachable to remote sensing studies. Different mission architectures are envisaged, which would benefit from strong international collaborations.

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