arXiv subjects

J. K. Jørgensen

Publications and source records attributed to J. K. Jørgensen.

At least 37 records · Page 2Linked to original sources

arXiv2022

Millimetre-wave spectroscopy of 2-hydroxyprop-2-enal and an astronomical search with ALMA

The molecule studied in this work, 2-hydroxyprop-2-enal, is among the candidates to be searched for in the interstellar medium (ISM), as it is a dehydration product of C3 sugars and contains structural motifs typical for some interstellar molecules. The aim of this work is to deepen knowledge about the millimetre-wave spectrum of 2-hydroxyprop-2-enal in the region enabling its search towards astronomical objects. We target the solar-type protostar IRAS16293-2422 and star-forming region Sagittarius (Sgr) B2(N). The rotational spectrum of 2-hydroxyprop-2-enal was measured and analysed in the frequency regions of 128-166 GHz and 285-329 GHz. The interstellar exploration towards IRAS16293-2422 was based on the Atacama Large Millimeter/submillimeter Array (ALMA) data of the Protostellar Interferometric Line Survey. We also used the imaging spectral line survey ReMoCA performed with ALMA toward Sgr B2(N). We modelled the astronomical spectra under the assumption of local thermodynamic equilibrium. We provide analysis of hundreds of rotational transitions of 2-hydroxyprop-2-enal in the ground state and the lowest lying excited vibrational state. We report its nondetection towards IRAS16293 B. The 2-hydroxyprop-2-enal/3-hydroxypropenal abundance ratio is estimated to be less-than or similar to 0.9-1.3 in agreement with the predicted value of 1.4. We also report the nondetection of 2-hydroxyprop-2-enal toward the hot molecular core Sgr B2(N1). We did not detect the related aldehydes 2-hydroxypropanal and 3-hydroxypropenal either. We find that these three molecules are at least 9, 4, and 10 times less abundant than acetaldehyde in this source, respectively. Despite the nondetections, the results of this work represent a significant improvement on previous investigations in the microwave region and meets the requirements for further searches of this molecule in the ISM.

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arXiv2022

Physical properties of accretion shocks toward the Class I protostellar system Oph-IRS 44

(Abridged) Physical processes such as accretion shocks are thought to be common in the protostellar phase, where the envelope component is still present, and they can release molecules from the dust to the gas phase, altering the original chemical composition of the disk. Consequently, the study of accretion shocks is essential for a better understanding of the physical processes at disk scales and their chemical output. The purpose of this work is to assess the characteristics of accretion shocks traced by sulfur-related species. We present ALMA high angular resolution observations (0.1") of the Class I protostar Oph-IRS 44. The continuum emission at 0.87 mm is observed, together with sulfur-related species such as SO, SO$_{2}$, and $^{34}$SO$_{2}$. Six lines of SO$_{2}$, two lines of $^{34}$SO$_{2}$, and one line of SO are detected toward IRS 44. The emission of all the detected lines peaks at ~0.1" (~14 au) from the continuum peak and we find infalling-rotating motions inside 30 au. However, only redshifted emission is seen between 50 and 30 au. Colder and more quiescent material is seen toward an offset region located at a distance of ~400 au from the protostar, and we do not find evidence of a Keplerian profile in these data. Accretion shocks are the most plausible explanation for the high temperatures, high densities, and velocities found for the SO$_{2}$ emission. When material enters the disk--envelope system, it generates accretion shocks that increase the dust temperature and desorb SO$_{2}$ molecules from dust grains. High-energy SO$_{2}$ transitions (~200 K) seem to be the best tracers of accretion shocks that can be followed up by future higher angular resolution ALMA observations and compared to other species to assess their importance in releasing molecules from the dust to the gas phase.

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arXiv2022

The ALMA-PILS survey: First tentative detection of 3-hydroxypropenal (HOCHCHCHO) in the interstellar medium and chemical modeling of the C$_3$H$_4$O$_2$ isomers

Characterizing the molecular composition of solar-type protostars is useful for improving our understanding of the physico-chemical conditions under which the Sun and its planets formed. In this work, we analyzed the Atacama Large Millimeter/submillimeter Array (ALMA) data of the Protostellar Interferometric Line Survey (PILS), an unbiased spectral survey of the solar-type protostar IRAS~16293--2422, and we tentatively detected 3-hydroxypropenal (HOCHCHCHO) for the first time in the interstellar medium towards source B. Based on the observed line intensities and assuming local thermodynamic equilibrium, its column density is constrained to be $\sim$10$^{15}$ cm$^{-2}$, corresponding to an abundance of 10$^{-4}$ relative to methanol, CH$_3$OH. Additional spectroscopic studies are needed to constrain the excitation temperature of this molecule. We included HOCHCHCHO and five of its isomers in the chemical network presented in Manigand et al. (2021) and we predicted their chemical evolution with the Nautilus code. The model reproduces the abundance of HOCHCHCHO within the uncertainties. This species is mainly formed through the grain surface reaction CH$_2$CHO + HCO $\rightarrow$ HCOCH$_2$CHO, followed by the tautomerization of HCOCH$_2$CHO into HOCHCHCHO. Two isomers, CH$_3$COCHO and CH$_2$COHCHO, are predicted to be even more abundant than HOCHCHCHO. Spectroscopic studies of these molecules are essential in searching for them in IRAS~16293--2422 and other astrophysical sources.

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arXiv2021

Rotational and rovibrational spectroscopy of CD$_3$OH with an account of CD$_3$OH toward IRAS 16293$-$2422

Solar-type protostars harbor highly deuterated complex organics. While this degree of deuteration may provide important clues in studying the formation of these species, spectroscopic information on multiply deuterated isotopologs is often insufficient. In particular, searches for triply deuterated methanol, CD$_3$OH, are hampered by the lack of intensity information from a spectroscopic model. The aim of the present study is to develop such a model of CD$_3$OH in low-lying torsional states that is sufficiently accurate to facilitate further searches for CD$_3$OH in space. We performed a new measurement campaign for CD$_3$OH involving three spectroscopic laboratories that covers the 34 GHz-1.1 THz and the 20-900 cm$^{-1}$ ranges. The analysis was performed using the torsion-rotation Hamiltonian model based on the rho-axis method. We determined a model that describes the ground and first excited torsional states of CD$_3$OH, up to quantum numbers $J \leqslant 55$ and $K_a \leqslant 23$, and we derived a line list for radio-astronomical observations. This list is accurate up to at least 1.1 THz and should be sufficient for all types of radio-astronomical searches for this methanol isotopolog. It was used to search for CD$_3$OH in data from the Protostellar Interferometric Line Survey of IRAS 16293-2422 using ALMA. CD$_3$OH is securely detected in the data, with a large number of clearly separated and well-reproduced lines. We detected lines belonging to the ground and the first excited torsional states. The derived abundance of CD$_3$OH relative to non-deuterated isotopolog confirm the significant enhancement of this multiply deuterated variant. This finding is in line with other observations of multiply deuterated complex organic molecules and may serve as an important constraint on their formation models.

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arXiv2021

Linking High- and Low-Mass Star Formation: Observation-Based Continuum Modelling and Physical Conditions

Astronomers have yet to establish whether high-mass protostars form from high-mass prestellar cores, similar to their lower-mass counterparts, or from lower-mass fragments at the heart of a pre-protostellar cluster undergoing large-scale collapse. Part of the uncertainty is due to a shortage of envelope structure data on protostars of a few tens of solar masses, where we expect to see a transition from intermediate-mass star formation to the high-mass process. We sought to derive the masses, luminosities, and envelope density profiles for eight sources in Cygnus-X, whose mass estimates in the literature placed them in the sampling gap. Combining these sources with similarly evolved sources in the literature enabled us to perform a meta-analysis of protostellar envelope parameters over six decades in source luminosity. We performed spectral energy distribution (SED) fitting on archival broadband photometric continuum data from 1.2 to 850 $μ$m, to derive bolometric luminosities for our eight sources plus initial mass and radius estimates for modelling density and temperature profiles with the radiative transfer package Transphere. The envelope masses, densities at 1000 AU, outer envelope radii, and density power law indices as functions of bolometric luminosity all follow established trends in the literature spanning six decades in luminosity. Most of our sources occupy an intermediate to moderately high range of masses and luminosities, which helps to more firmly establish the continuity between low- and high-mass star formation mechanisms. Our density power law indices are consistent with observed values in literature, which show no discernible trends with luminosity. Finally, we show that the trends in all of the envelope parameters for high-mass protostars are statistically indistinguishable from trends in the same variables for low- and intermediate-mass protostars.

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arXiv2021

Protostellar Interferometric Line Survey of the Cygnus X region (PILS-Cygnus) -- First results: observations of CygX-N30

(Abridged) Complex organic molecules (COMs) are commonly detected in and near star-forming regions. However, the dominant process in the release of these COMs from the icy grains - where they predominately form - to the gas phase is still an open question. We investigate the origin of COM emission in a protostellar source, CygX-N30, through high-angular-resolution interferometric observations over a continuous broad frequency range. We used 32 GHz Submillimeter Array observations with continuous frequency coverage from 329 to 361 GHz at an angular resolution of ~1" to do a line survey and obtain a chemical inventory of the source. The line emission was used to determine column densities and excitation temperatures for the COMs. We mapped out the intensity distribution of the different species and identified approximately 400 lines that can be attributed to 29 different molecular species and their isotopologues. We find that the molecular peak emission is along a linear gradient, coinciding with the axis of red- and blueshifted H2CO and CS emission. Chemical differentiation is detected along this gradient, with the O-bearing molecular species peaking towards one component of the system and the N- and S-bearing species peaking towards the other. The inferred column densities and excitation temperatures are compared to other sources where COMs are abundant. The origin of the observed COM emission is probably a combination of the young stellar sources along with accretion of infalling material onto a disc-like structure surrounding a young protostar. The low D/H ratio observed (<0.1%) likely reflects a pre-stellar phase where COMs formed on the ices at warm temperatures (~ 30 K), with inefficient deuterium fractionation. The observations and results presented here demonstrate the importance of good frequency coverage and high angular resolution when disentangling the origin of COM emission.

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arXiv2021

ALMA observations of doubly deuterated water: Inheritance of water from the prestellar environment

Establishing the origin of the water D/H ratio in the Solar System is central to our understanding of the chemical trail of water during the star and planet formation process. Recent modeling suggests that comparisons of the D$_2$O/HDO and HDO/H$_2$O ratios are a powerful way to trace the chemical evolution of water and, in particular, determine whether the D/H ratio is inherited from the molecular cloud or established locally. We seek to determine the D$_2$O column density and derive the D$_2$O/HDO ratios in the warm region toward the low-mass Class 0 sources B335 and L483. The results are compared with astrochemical models and previous observations to determine their implications for the chemical evolution of water. We present ALMA observations of the D$_2$O transition at 316.8 GHz toward B335 and L483 at $<$0.5" ($<$ 100 au) resolution, probing the inner warm envelope gas. The column densities of D$_2$O, HDO, and H$_{2}^{18}$O are determined by synthetic spectrum modeling and direct Gaussian fitting, under the assumption of a single excitation temperature and similar spatial extent for the three water isotopologs. D$_2$O is detected toward both sources in the inner warm envelope. The derived D$_2$O/HDO ratios is $(1.0\pm0.2)\times10^{-2}$ for L483 and $(1.4\pm0.1)\times10^{-2}$ for B335. The high D$_2$O/HDO ratios are a strong indication of chemical inheritance of water from the prestellar phase down to the inner warm envelope. This implies that the local cloud conditions in the prestellar phase, such as temperatures and timescales, determine the water chemistry at later stages and could provide a source of chemical differentiation in young systems. In addition, the observed D$_2$O/H$_2$O ratios support an observed dichotomy in the deuterium fractionation of water toward isolated and clustered protostars, namely, a higher D/H ratio toward isolated sources

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arXiv2021

Torsional-rotational spectrum of doubly-deuterated dimethyl ether (CH$_3$OCHD$_2$) -- First ALMA detection in the interstellar medium

In 2013, we have published the first rotational analysis and detection of mono-deuterated dimethyl ether in the solar-type protostar IRAS 16293-2422 with the IRAM 30m telescope. Dimethyl ether is one of the most abundant complex organic molecules (COMs) in star-forming regions and their D-to-H (D/H) ratios is important to understand its chemistry and trace the source history. We present the first analysis of doubly-deuterated dimethyl ether (methoxy-d2-methane, 1,1-dideuteromethylether) in its ground-vibrational state, based on an effective Hamiltonian for an asymmetric rotor molecules with internal rotors. The analysis covers the frequency range 0.15-1.5THz. The laboratory rotational spectrum of this species was measured between 150 and 1500 GHz with the Lille's submillimeter spectrometer. For the astronomical detection, we used the Atacama Large Millimeter/submillimeter Array (ALMA) observations from the Protostellar Interferometric Line Survey, PILS. New sets of spectroscopic parameters have been determined by a least squares fit with the ERHAM code for both symmetric and asymmetric conformers. As for the mono-deuterated species, these parameters have permitted the first identification in space of both conformers of a doubly-deuterated dimethyl ether via detection near the B component of the Class 0 protostar IRAS 16293-2422.

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arXiv2021

Linking ice and gas in the Lambda Orionis Barnard 35A cloud

Dust grains play an important role in the synthesis of molecules in the interstellar medium, from the simplest species to complex organic molecules. How some of these solid-state molecules are converted into gas-phase species is still a matter of debate. Our aim is to directly compare ice and gas abundances of methanol (CH$_3$OH) and CO, and to investigate the relationship between ice and gas in low-mass protostellar envelopes. We present Submillimeter Array and Atacama Pathfinder EXperiment observations of gas-phase CH$_3$OH and CO towards the multiple protostellar system IRAS05417+0907 located in the B35A cloud. We use archival AKARI ice data toward the same target to calculate CH$_3$OH and CO gas-to-ice ratios. The CO isotopologues emissions are extended, whereas the CH$_3$OH emission is compact and traces the giant outflow emanating from IRAS05417+0907. A discrepancy between submillimeter dust emission and H$_2$O ice column density is found for B35A$-$4 and B35A$-$5, similar to what has previously been reported. B35A$-$2 and B35A$-$3 are located where the submillimeter dust emission peaks and show H$_2$O column densities lower than for B35A$-$4. The difference between the submillimeter continuum emission and the infrared H$_2$O ice observations suggests that the distributions of dust and H$_2$O ice differ around the young stellar objects in this dense cloud. The reason for this may be that the sources are located in different environments resolved by the interferometric observations: B35A$-$2, B35A$-$3 and in particular B35A$-$5 are situated in a shocked region plausibly affected by sputtering and heating impacting the submillimeter dust emission pattern, while B35A$-$4 is situated in a more quiescent part of the cloud. Gas and ice maps are essential to connect small-scale variations in the ice composition with large-scale astrophysical phenomena probed by gas observations.

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arXiv2021

Modeling chemistry during star formation: Water deuteration in dynamic star-forming regions

Recent observations of the HDO/H$_2$O ratio toward protostars in isolated and clustered environments show an apparent dichotomy, where isolated sources show higher D/H ratios than clustered counterparts. Establishing which physical and chemical processes create this differentiation can provide insights into the chemical evolution of water during star formation and the chemical diversity during the star formation process and in young planetary systems. Methods: The evolution of water is modeled using 3D physicochemical models of a dynamic star-forming environment. The physical evolution during the protostellar collapse is described by tracer particles from a 3D MHD simulation of a molecular cloud region. Each particle trajectory is post-processed using RADMC-3D to calculate the temperature and radiation field. The chemical evolution is simulated using a three-phase grain-surface chemistry model and the results are compared with interferometric observations of H$_2$O, HDO, and D$_2$O in hot corinos toward low-mass protostars. Results: The physicochemical model reproduces the observed HDO/H$_2$O and D$_2$O/HDO ratios in hot corinos, but shows no correlation with cloud environment for similar identical conditions. The observed dichotomy in water D/H ratios requires variation in the initial conditions (e.g., the duration and temperature of the prestellar phase). Reproducing the observed D/H ratios in hot corinos requires a prestellar phase duration $t\sim$1-3 Myr and temperatures in the range $T \sim$ 10-20 K prior to collapse. This work demonstrates that the observed differentiation between clustered and isolated protostars stems from differences in the molecular cloud or prestellar core conditions and does not arise during the protostellar collapse itself.

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arXiv2020

The prebiotic molecular inventory of Serpens SMM1 I. An investigation of the isomers CH$_{3}$NCO and HOCH$_{2}$CN

Methyl isocyanate (CH$_{3}$NCO) and glycolonitrile (HOCH$_{2}$CN) are isomers and prebiotic molecules that are involved in the formation of peptide structures and the nucleobase adenine, respectively. ALMA observations of the intermediate-mass Class 0 protostar Serpens SMM1-a and ALMA-PILS data of the low-mass Class 0 protostar IRAS~16293B are used. Spectra are analysed with the CASSIS line analysis software package in order to identify and characterise molecules. CH$_{3}$NCO, HOCH$_{2}$CN, and various other molecules are detected towards SMM1-a. HOCH$_{2}$CN is identified in the PILS data towards IRAS~16293B in a spectrum extracted at a half-beam offset position from the peak continuum. CH$_{3}$NCO and HOCH$_{2}$CN are equally abundant in SMM1-a at [X]/[CH$_{3}$OH] of 5.3$\times$10$^{-4}$ and 6.2$\times$10$^{-4}$, respectively. A comparison between SMM1-a and IRAS~16293B shows that HOCH$_{2}$CN and HNCO are more abundant in the former source, but CH$_{3}$NCO abundances do not differ significantly. Data from other sources are used to show that the [CH$_{3}$NCO]/[HNCO] ratio is similar in all these sources within $\sim$10\%. The new detections of CH$_{3}$NCO and HOCH$_{2}$CN are additional evidence for a large interstellar reservoir of prebiotic molecules that can contribute to the formation of biomolecules on terrestrial planets. A plausible formation pathway for HOCH$_{2}$CN is the thermal Strecker-like reaction of CN$^{-}$ with H$_{2}$CO. The similar [CH$_{3}$NCO]/[HNCO] ratios indicate that these two species either are chemically related or their formation is affected by physical conditions in the same way. The relatively high abundances of HOCH$_{2}$CN and HNCO in SMM1-a may be explained by a prolonged stage of relatively warm ice mantles, where thermal and energetic processing of HCN in the ice results in the efficient formation of both species.

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arXiv2020

Linking ice and gas in the Serpens low-mass star-forming region

The interaction between dust, ice, and gas during the formation of stars produces complex organic molecules. While observations indicate that several species are formed on ice-covered dust grains and are released into the gas phase, the exact chemical interplay between solid and gas phases and their relative importance remain unclear. Our goal is to study the interplay in regions of low-mass star formation through ice- and gas-mapping and by directly measuring gas-to-ice ratios. This provides constraints on the routes that lead to the chemical complexity that is observed in both phases. We present observations of gas-phase methanol (CH$_3$OH) and carbon monoxide at 1.3 mm towards ten low-mass young protostars in the Serpens SVS4 cluster from the SubMillimeter Array and the Atacama Pathfinder EXperiment telescope. We used archival data from the Very Large Telescope to derive abundances of ice H$_2$O, CO, and CH$_3$OH towards the same region. Finally, we constructed gas-ice maps of SVS4 and directly measured CO and CH$_3$OH gas-to-ice ratios. The CH$_3$OH gas-to-ice ratio agrees with values that were previously reported for embedded Class 0/I low-mass protostars. The CO gas-maps trace an extended gaseous component that is not sensitive to the effect of freeze-out. We find that there is no straightforward correlation between CO and CH$_3$OH gas with their ice counterparts in the cluster. This is likely related to the complex morphology of SVS4: the Class 0 protostar SMM4 and its envelope lie in the vicinity, and the outflow associated with SMM4 intersects the cluster. This study serves as a pathfinder for future observations with ALMA and the James Webb Space Telescope that will provide high-sensitivity gas-ice maps of molecules more complex than methanol. Such comparative maps will be essential to constrain the chemical routes that regulate the chemical complexity in star-forming regions.

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arXiv2020

The ALMA-PILS survey: First detection of the unsaturated 3-carbon molecules Propenal (C$_2$H$_3$CHO) and Propylene (C$_3$H$_6$) towards IRAS 16293$-$2422 B

Complex organic molecules with three carbon atoms are found in the earliest stages of star formation. In particular, propenal (C$_2$H$_3$CHO) is a species of interest due to its implication in the formation of more complex species and even biotic molecules. This study aims to search for the presence of C$_2$H$_3$CHO and other three-carbon species such as propylene (C$_3$H$_6$) in the hot corino region of the low-mass protostellar binary IRAS 16293--2422 to understand their formation pathways. We use ALMA observations in Band 6 and 7 from various surveys to search for the presence of C$_3$H$_6$ and C$_2$H$_3$CHO towards the protostar IRAS 16293--2422 B (IRAS 16293B). We report the detection of both C$_3$H$_6$ and C$_2$H$_3$CHO towards IRAS 16293B, however, no unblended lines were found towards the other component of the binary system, IRAS 16293A. We derive column density upper limits for C$_3$H$_8$, HCCCHO, n-C$_3$H$_7$OH, i-C$_3$H$_7$OH, C$_3$O, and cis-HC(O)CHO towards IRAS 16293B. We then use a three-phase chemical model to simulate the formation of these species in a typical prestellar environment followed by its hydrodynamical collapse until the birth of the central protostar. Different formation paths, such as successive hydrogenation and radical-radical additions on grain surfaces, are tested and compared to the observational results. The simulations reproduce the abundances within one order of magnitude from those observed towards IRAS 16293B, with the best agreement found for a rate of $10^{-12}$ cm$^3$ s$^{-1}$ for the gas-phase reaction C$_3$ + O $\rightarrow$ C$_2$ + CO. Successive hydrogenations of C$_3$, HC(O)CHO, and CH$_3$OCHO on grain surfaces are a major and crucial formation route of complex organics molecules, whereas both successive hydrogenation pathways and radical-radical addition reactions contribute to the formation of C$_2$H$_5$CHO.

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arXiv2020

The ALMA-PILS survey: Inventory of complex organic molecules towards IRAS 16293-2422 A

Complex organic molecules (COM) are detected in many sources in the warm inner regions of envelopes surrounding deeply embedded protostars. Exactly how these COM form remains an open question. This study aims to constrain the formation of complex organic molecules through comparisons of their abundances towards the Class 0 protostellar binary IRAS 16293-2422 (IRAS16293). We utilised observations from the ALMA Protostellar Interferometric Line Survey of IRAS16293. The species identification and the rotational temperature and column density estimation were derived by fitting the extracted spectra towards IRAS16293 A and IRAS16293 B with synthetic spectra. The majority of the work in this paper pertains to the analysis of IRAS16293 A for a comparison with the results from the other binary component, which have already been published. We detect 15 different COM, as well as 16 isotopologues towards the most luminous companion protostar IRAS16293 A. Tentative detections of an additional 11 isotopologues are reported. We also searched for and report on the first detections of CH3OCH2OH and t-C2H5OCH3 towards IRAS16293 B and the follow-up detection of CH2DCHO and CH3CDO. Twenty-four lines of CHD2OH are also identified. The comparison between the two protostars of the binary system shows significant differences in abundance for some of the species, which are partially correlated to their spatial distribution. The spatial distribution is consistent with the sublimation temperature of the species; those with higher expected sublimation temperatures are located in the most compact region of the hot corino towards IRAS16293 A. This spatial differentiation is not resolved in IRAS16293 B and will require observations at a higher angular resolution. In parallel, the list of identified CHD2OH lines shows the need of accurate spectroscopic data including their line strength.

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arXiv2019

The ALMA-PILS survey: propyne (CH$_3$CCH) in IRAS 16293$-$2422

Context. Propyne (CH$_3$CCH) has been detected in a variety of environments, from Galactic star-forming regions to extragalactic sources. Such molecules are excellent tracers of the physical conditions in star-forming regions. Aims. This study explores the emission of CH$_3$CCH in the low-mass protostellar binary, IRAS 16293$-$2422, examining the spatial scales traced by this molecule, as well as its formation and destruction pathways. Methods. ALMA observations from the Protostellar Interferometric Line Survey (PILS) are used to determine the abundances and excitation temperatures of CH$_3$CCH towards both protostars, exploring spatial scales from 70 to 2400 au. The three-phase chemical kinetics model MAGICKAL is also used, to explore the chemical reactions of this molecule. Results. CH$_3$CCH is detected towards both IRAS 16293A and IRAS 16293B and is found to trace the hot corino component around each source in the PILS dataset. Eighteen transitions above 3$σ$ are detected, enabling robust excitation temperatures and column densities to be determined in each source. In IRAS 16293A, an excitation temperature of 90 K and a column density of 7.8$\times$10$^{15}$ cm$^{-2}$ best fits the spectra. In IRAS 16293B, an excitation temperature of 100 K and 6.8$\times$10$^{15}$ cm$^{-2}$ best fits the spectra. The chemical modelling finds that in order to reproduce the observed abundances, both gas-phase and grain-surface reactions are needed. Conclusions. CH$_3$CCH is a molecule whose brightness and abundance in many different regions can be utilised to provide a benchmark of molecular variation with the physical properties of star-forming regions. It is essential when making such comparisons, that the abundances are determined with a good understanding of the spatial scale of the emitting region, to ensure that accurate abundances are derived.

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arXiv2019

ALMA observations of water deuteration: A physical diagnostic of the formation of protostars

The deuterium fractionation of water can serve as a tracer for the chemical and physical evolution of water during star formation and can constrain the origin of water in Solar System bodies. We determine the HDO/H$_2$O ratio in the inner warm gas toward three low-mass Class 0 protostars selected to be in isolated cores, i.e., not associated with any cloud complexes. Previous sources for which the HDO/H$_2$O ratio have been established were all part of larger star-forming complexes. Targeting these isolated protostars allows comparison of the water chemistry in isolated and clustered regions to determine the influence of local cloud environment. We present ALMA observations of the HDO $3_{1,2}$-$2_{2,1}$ and $2_{1,1}$-$2_{1,2}$ transitions at 225.897 GHz and 241.562 GHz along with the H$_2^{18}$O $3_{1,3}$-$2_{2,0}$ transition at 203.407 GHz. The high angular resolution (0\farcs3-1\farcs3) allow the study of the inner warm envelope gas. Model-independent estimates for the HDO/H$_2$O ratios are obtained and compared with previous determinations in the warm gas toward low-mass protostars. We detect the targeted water transitions toward the three sources with S/N > 5. We determine the HDO/H$_2$O ratio toward L483, B335 and BHR71-IRS1 to be ($2.2\pm0.4$)$\times 10^{-3}$, ($1.7\pm0.3$)$\times 10^{-3}$, and ($1.8\pm0.4$)$\times 10^{-3}$, respectively, assuming $T_\mathrm{ex} = 124$ K. The degree of water deuteration of these isolated protostars are a factor of 2-4 higher relative to Class 0 protostars that are members of known nearby clustered star-forming regions. The results indicate that the water deuterium fractionation is influenced by the local cloud environment. This effect can be explained by variations in either collapse timescales or temperatures, which depends on local cloud dynamics and could provide a new method to decipher the history of young stars.

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arXiv2019

Revealing the chemical structure of the Class I disc Oph-IRS 67

(Abridged) The purpose of this paper is to explore the structure of a line-rich Class I protobinary source, Oph-IRS 67, and analyse the differences and similarities with Class 0 and Class II sources. We present a systematic molecular line study of IRS 67 with the Submillimeter Array (SMA) on 1 - 2" (150 - 300 AU) scales. The wide instantaneous band-width of the SMA observations (~30 GHz) provide detections of a range of molecular transitions that trace different physics, such as CO isotopologues, sulphur-bearing species, deuterated species, and carbon-chain molecules. We see significant differences between different groups of species. For example, the CO isotopologues and sulphur-bearing species show a rotational profile and are tracing the larger-scale circumbinary disc structure, while CN, DCN, and carbon-chain molecules peak at the southern edge of the disc at blue-shifted velocities. In addition, the cold gas tracer DCO+ is seen beyond the extent of the circumbinary disc. The detected molecular transitions can be grouped into three main components: cold regions far from the system, the circumbinary disc, and a UV-irradiated region likely associated with the surface layers of the disc that are reached by the UV radiation from the sources. The different components are consistent with the temperature structure derived from the ratio of two H2CO transitions, that is, warm temperatures are seen towards the outflow direction, lukewarm temperatures are associated with the UV-radiated region, and cold temperatures are related with the circumbinary disc structure. The chemistry towards IRS 67 shares similarities with both Class 0 and Class II sources, possibly due to the high gas column density and the strong UV radiation arising from the binary system. IRS 67 is, therefore, highlighting the intermediate chemistry between deeply embedded sources and T-Tauri discs.

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arXiv2019

Physical and chemical fingerprint of protostellar disc formation

(Abridged) The purpose of this paper is to explore and compare the physical and chemical structure of Class I low-mass protostellar sources on protoplanetary disc scales. We present a study of the dust and gas emission towards a representative sample of 12 Class I protostars from the Ophiuchus molecular cloud with the Atacama Large Millimeter/submillimeter Array (ALMA). The continuum at 0.87 mm and molecular transitions from C17O, C34S, H13CO+, CH3OH, SO2 , and C2H were observed at high angular resolution (0.4", ~60 au diameter) towards each source. Disc and stellar masses are estimated from the continuum flux and position-velocity diagrams, and six of the sources show disc-like structures. Towards the more luminous sources, compact emission and large line widths are seen for transitions of SO2 that probe warm gas (Eu ~200 K). In contrast, C17O emission is detected towards the least evolved and less luminous systems. No emission of CH3OH is detected towards any of the continuum peaks, indicating an absence of warm CH3OH gas towards these sources. A power-law relation is seen between the stellar mass and the bolometric luminosity, corresponding to a mass accretion rate of (2.4 +/- 0.6) x 10^-7 Msun/year for the Class I sources. This mass accretion rate is lower than the expected value if the accretion is constant in time and rather points to a scenario of accretion occurring in bursts. The differentiation between C17O and SO2 suggests that they trace different physical components: C17O traces the densest and colder regions of the disc-envelope system, while SO2 may be associated with regions of higher temperature, such as accretion shocks. The lack of warm CH3OH emission suggests that there is no hot-core-like region around any of the sources and that the CH3OH column density averaged over the disc is low.

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