arXiv subjects

J. K. Jørgensen

Publications and source records attributed to J. K. Jørgensen.

At least 73 records · Page 4Linked to original sources

arXiv2016

The ALMA Protostellar Interferometric Line Survey (PILS): First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA

The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. This paper introduces a systematic survey, "Protostellar Interferometric Line Survey (PILS)" of the Class 0 protostellar binary IRAS 16293-2422 using the Atacama Large Millimeter/submillimeter Array (ALMA). The survey covers the full frequency range from 329 to 363 GHz (0.8 mm) with additional targeted observations at 3.0 and 1.3 mm. More than 10,000 features are detected toward one component in the protostellar binary. Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center, these two species are over-abundant relative to methanol, possibly an indication of formation at low temperatures in CO-rich ices. Both 13C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximately 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde. Measurements of the 13C-species lead to a 12C:13C ratio of approximately 30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12CO and 13CO ices sublimate. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle.

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arXiv2016

The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium

Formamide (NH$_2$CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293-2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). We detect for the first time the three singly deuterated forms of NH$_2$CHO (NH$_2$CDO, cis- and trans-NHDCHO) as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the $^{13}$C isotopologues of formamide and a standard $^{12}$C/$^{13}$C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide ($\sim$1%). These results are in agreement with the hypothesis that NH$_2$CHO and HNCO are chemically related through grain surface formation.

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arXiv2016

Constraining the physical structure of the inner few 100 AU scales of deeply embedded low-mass protostars

(Abridged) The physical structure of deeply-embedded low-mass protostars (Class 0) on scales of less than 300 AU is still poorly constrained. Determining this is crucial for understanding the physical and chemical evolution from cores to disks. In this study two models of the emission, a Gaussian disk intensity distribution and a parametrized power-law disk model, are fitted to sub-arcsecond resolution interferometric continuum observations of five Class 0 sources, including one source with a confirmed Keplerian disk. For reference, a spherically symmetric single power-law envelope is fitted to the larger scale ($\sim$1000 AU) emission and investigated further for one of the sources on smaller scales. A thin disk model can approximate the emission and physical structure in the inner few 100 AU scales of the studied deeply-embedded low-mass protostars and paves the way for analysis of a larger sample with ALMA. While the disk radii agree with previous estimates the masses are different for some of the sources studied. Assuming a typical temperature distribution, the fractional amount of mass in the disk above 100 K varies in between 7% to 30%. Kinematic data are needed to determine the presence of any Keplerian disk. Using previous observations of p-H$_2^{18}$O, we estimate the relative gas phase water abundances roughly an order of magnitude higher than previously inferred when both warm and cold H$_2$ was used as reference. A spherically symmetric single power-law envelope model fails to simultaneously reproduce both the small and large scale emission.

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arXiv2016

A young bipolar outflow from IRAS 15398-3359

Changing physical conditions in the vicinity of protostars allow for a rich and interesting chemistry to occur. Heating and cooling of the gas allows molecules to be released from and frozen out on dust grains. These changes in physics, traced by chemistry, as well as the kinematical information allows us to distinguish between different scenarios describing the infall of matter and the launching of molecular outflows and jets. We aim at determining the spatial distribution of different species, of different chemical origin. This is to examine the physical processes in play in the observed region. From the kinematical information of the emission lines we aim at determining the nature of the infalling and outflowing gas in the system. We also aim at determining the physical properties of the outflow. Maps from the Sub-Millimeter Array reveal the spatial distribution of the gaseous emission toward IRAS15398-3359. The line radiative transfer code LIME is used to construct a full 3D model of the system taking all relevant components and scales into account. CO, HCO+ and N2H+ are detected and are shown to trace the motions of the outflow. For CO, also the circumstellar envelope and the surrounding cloud have a profound impact on the observed line profiles. N2H+ is detected in the outflow, but is suppressed towards the central region, perhaps due to the competing reaction between CO and H3+ in the densest regions as well as destruction of N2H+ by CO. N2D+ is detected in a ridge south-west from the protostellar condensation. The morphology and kinematics of the CO emission suggests that the source is younger than 1000 years. The mass, momentum, momentum rate, mechanical luminosity, kinetic energy and mass-loss rate are also all estimated to be low. A full 3D radiative transfer model of the system can explain all the kinematical and morphological features in the system.

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arXiv2015

Classifying the embedded young stellar population in Perseus and Taurus & the LOMASS database

Context. The classification of young stellar objects (YSOs) is typically done using the infrared spectral slope or bolometric temperature, but either can result in contamination of samples. More accurate methods to determine the evolutionary stage of YSOs will improve the reliability of statistics for the embedded YSO population and provide more robust stage lifetimes. Aims. We aim to separate the truly embedded YSOs from more evolved sources. Methods. Maps of HCO+ J=4-3 and C18O J=3-2 were observed with HARP on the James Clerk Maxwell Telescope (JCMT) for a sample of 56 candidate YSOs in Perseus and Taurus in order to characterize emission from high (column) density gas. These are supplemented with archival dust continuum maps observed with SCUBA on the JCMT and Herschel PACS to compare the morphology of the gas and dust in the protostellar envelopes. The spatial concentration of HCO+ J=4-3 and 850 micron dust emission are used to classify the embedded nature of YSOs. Results. Approximately 30% of Class 0+I sources in Perseus and Taurus are not Stage I, but are likely to be more evolved Stage II pre-main sequence (PMS) stars with disks. An additional 16% are confused sources with an uncertain evolutionary stage. Conclusions. Separating classifications by cloud reveals that a high percentage of the Class 0+I sources in the Perseus star forming region are truly embedded Stage I sources (71%), while the Taurus cloud hosts a majority of evolved PMS stars with disks (68%). The concentration factor method is useful to correct misidentified embedded YSOs, yielding higher accuracy for YSO population statistics and Stage timescales. Current estimates (0.54 Myr) may overpredict the Stage I lifetime on the order of 30%, resulting in timescales of 0.38 Myr for the embedded phase.

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arXiv2015

The VISTA Orion mini-survey: star formation in the Lynds 1630 North cloud

The Orion cloud complex presents a variety of star formation mechanisms and properties and it is still one of the most intriguing targets for star formation studies. We present VISTA/VIRCAM near-infrared observations of the L1630N star forming region, including the stellar clusters NGC 2068 and NGC 2071, in the Orion molecular cloud B and discuss them in combination with Spitzer data. We select 186 young stellar object (YSO) candidates in the region on the basis of multi-colour criteria, confirm the YSO nature of the majority of them using published spectroscopy from the literature, and use this sample to investigate the overall star formation properties in L1630N. The K-band luminosity function of L1630N is remarkably similar to that of the Trapezium cluster, i.e., it presents a broad peak in the range 0.3-0.7 M$_\odot$ and a fraction of sub-stellar objects of $\sim$20%. The fraction of YSOs still surrounded by disk/envelopes is very high ($\sim$85%) compared to other star forming regions of similar age (1-2 Myr), but includes some uncertain corrections for diskless YSOs. Yet, a possibly high disk fraction together with the fact that 1/3 of the cloud mass has a gas surface density above the threshold for star formation ($\sim$129 M$_\odot$ pc$^{-2}$), points towards a still on-going star formation activity in L1630N. The star formation efficiency (SFE), star formation rate (SFR) and density of star formation of L1630N are within the ranges estimated for galactic star forming regions by the Spitzer "core to disk" and "Gould's Belt" surveys. However, the SFE and SFR are lower than the average value measured in the Orion A cloud and, in particular, lower than that in the southern regions of L1630. This might suggest different star formation mechanisms within the L1630 cloud complex.

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arXiv2014

Revealing H2D+ depletion and compact structure in starless and protostellar cores with ALMA

We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of the submillimeter dust continuum and H2D+ 1_{10}-1_{11} emission toward two evolved, potentially protostellar cores within the Ophiuchus molecular cloud, Oph A SM1 and SM1N. The data reveal small-scale condensations within both cores, with mass upper limits of M <~ 0.02M_Sun (~ 20 M_Jup). The SM1 condensation is consistent with a nearly-symmetric Gaussian source with a width of only 37 AU. The SM1N condensation is elongated, and extends 500 AU along its major axis. No evidence for substructure is seen in either source. A Jeans analysis indicates these sources are unlikely to fragment, suggesting that both will form single stars. H2D+ is only detected toward SM1N, offset from the continuum peak by ~150-200 AU. This offset may be due to either heating from an undetected, young, low luminosity protostellar source or first hydrostatic core, or HD (and consequently H2D+) depletion in the cold centre of the condensation. We propose that SM1 is protostellar, and that the condensation detected by ALMA is a warm (T ~ 30-50 K) accretion disk. The less concentrated emission of the SM1N condensation suggests that it is still starless, but we cannot rule out the presence of a low-luminosity source, perhaps surrounded by a pseudodisk. These data reveal observationally the earliest stages of the formation of circumstellar accretion regions, and agree with theoretical predictions that disk formation can occur very early in the star formation process, coeval with or just after the formation of a first hydrostatic core or protostar.

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arXiv2014

The deuterium fractionation of water on solar-system scales in deeply-embedded low-mass protostars

(Abridged) The water deuterium fractionation (HDO/H$_2$O abundance ratio) has traditionally been used to infer the amount of water brought to Earth by comets. Measuring this ratio in deeply-embedded low-mass protostars makes it possible to probe the critical stage when water is transported from clouds to disks in which icy bodies are formed. We present sub-arcsecond resolution observations of HDO in combination with H$_2^{18}$O from the PdBI toward the three low-mass protostars NGC 1333-IRAS 2A, IRAS 4A-NW, and IRAS 4B. The resulting HDO/H$_2$O ratio is $7.4\pm2.1\times10^{-4}$ for IRAS 2A, $19.1\pm5.4\times10^{-4}$ for IRAS 4A-NW, and $5.9\pm1.7\times10^{-4}$ for IRAS 4B. Derived ratios agree with radiative transfer models within a factor of 2-4 depending on the source. Our HDO/H$_2$O ratios for the inner regions (where $T>100$ K) of four young protostars are only a factor of 2 higher than those found for pristine, solar system comets. These small differences suggest that little processing of water occurs between the deeply embedded stage and the formation of planetesimals and comets.

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arXiv2014

Atomic jet from SMM1 (FIRS1) in Serpens uncovers non-coeval binary companion

We report on the detection of an atomic jet associated with the protostellar source SMM1 (FIRS1) in Serpens. The jet is revealed in [FeII] and [NeII] line maps observed with Spitzer/IRS, and further confirmed in HiRes IRAC and MIPS images. It is traced very close to SMM1 and peaks at ~5 arcsec" from the source at a position angle of $\sim 125 degrees. In contrast, molecular hydrogen emission becomes prominent at distances > 5" from the protostar and extends at a position angle of 160 degrees. The morphological differences suggest that the atomic emission arises from a companion source, lying in the foreground of the envelope surrounding the embedded protostar SMM1. In addition the molecular and atomic Spitzer maps disentangle the large scale CO (3-2) emission observed in the region into two distinct bipolar outflows, giving further support to a proto-binary source setup. Analysis at the peaks of the [FeII] jet show that emission arises from warm and dense gas (T ~1000 K, n(electron) 10^5 - 10^6 cm^-3). The mass flux of the jet derived independently for the [FeII] and [NeII] lines is 10^7 M(sun)/yr, pointing to a more evolved Class~I/II protostar as the driving source. All existing evidence converge to the conclusion that SMM1 is a non-coeval proto-binary source.

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arXiv2013

DIGIT: Herschel and Spitzer spectro-imaging of SMM3 and SMM4 in Serpens

We report on spectro-imaging observations employing Spitzer IRS and Herschel PACS, aiming to constrain the physical conditions around SMM3 and SMM4 in Serpens. The combined power of both instruments provides an almost complete wavelength coverage between 5 and 200 micron at an angular resolution of 10". We detect line emission from all major molecular (H2, CO, H2O and OH) and many atomic ([OI], [CII], [FeII], [SiII] and [SI]) coolants. Line emission tends to peak at distances of 10 - 20" from the protostellar sources, at positions of known outflow shocks. The only exception is [CII] which likely traces a PDR excited from the neighboring source SMM6. Excitation analysis indicates that H2 and CO originate from gas at two distinct rotational temperatures of 300 K and 1000 K, while H2O and OH emission corresponds to rotational temperatures of 100 - 200 K. The morphological and physical association between CO and H2 suggests a common excitation mechanism which allows direct comparisons between the two molecules. The CO/H2 abundance ratio varies from 10^-5 in the warm gas up to 10^-4 in the hotter regions. The occurrence of J-shocks is suggested by the strong atomic/ionic (except for [CII]) emission as well as a number of line ratio diagnostics. Both C- and J-shocks can account for the observed molecular emission, however J-shocks are strongly advocated by the atomic emission and provide simpler and more homogeneous solutions for CO and H2. C-shocks describe better the emission from H2O and OH. The variations in the CO/H2 abundance ratio for gas at different temperatures can be interpreted by their reformation rates in dissociative J-type shocks, or the simultaneous influence of both C and J shocks.

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arXiv2012

Strong irradiation of protostellar cores in Corona Australis

The importance of the physical environment in the evolution of newly formed low-mass stars remains an open question. In particular, radiation from nearby more massive stars may affect both the physical and chemical structure of these kinds of young stars. Aims: To constrain the physical characteristics of a group of embedded low-mass protostars in Corona Australis in the vicinity of the young luminous Herbig Be star R CrA. Methods: Millimetre wavelength maps of molecular line and continuum emission towards the low-mass star forming region IRS7 near R CrA from the SMA and APEX are presented. The maps show the distribution of 18 lines from 7 species (H2CO, CH3OH, HC3N, c-C3H2, HCN, CN and SiO) on scales from 3" to 60" (400-8000 AU). Using a set of H2CO lines, we estimate the temperatures and column densities in the region using LTE and non-LTE methods. The results are compared with 1-D radiative transfer modelling of the protostellar cores. These models constrain which properties of the central source, envelope, and environment can give rise to the observed line and continuum emission. Results: Most of the H2CO emission from the regions emerges from two elongated narrow ridges dominating the emission picked up in both interferometric and single-dish measurements. The temperatures inferred from the H2CO lines are no less than ~30 K and more likely 50-60 K, and the line emission peaks are offset by ~2500 AU from the location of the embedded protostars. The temperatures can not be explained by the heating from the young stellar objects themselves. Irradiation by the nearby Herbig Be star R CrA could, however, explain the high temperatures. The elevated temperatures can in turn impact the physical and chemical characteristics of protostars and lead to enhanced abundances of typical tracers of photon dominated regions seen in single-dish line surveys of embedded protostars in the region.

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arXiv2012

Adaptable Radiative Transfer Innovations for Submillimetre Telescopes (ARTIST) - Dust polarisation module (DustPol)

We present a new publicly available tool (DustPol) aimed to model the polarised thermal dust emission. The module DustPol, which is publicly available, is part of the ARTIST (Adaptable Radiative Transfer Innovations for Submillimetre Telescopes) package, which also offers tools for modelling the polarisation of line emission together with a model library and a Python-based user interface. DustPol can easily manage analytical as well as pre-gridded models to generate synthetic maps of the Stokes I, Q, and U parameters. These maps are stored in FITS format which is straightforwardly read by the data reduction software used, e.g., by the Atacama Large Millimeter Array (ALMA). This turns DustPol into a powerful engine for the prediction of the expected polarisation features of a source observed with ALMA or the Planck satellite as well as for the interpretation of existing submillimetre observations obtained with other telescopes. DustPol allows the parameterisation of the maximum degree of polarisation and we find that, in a prestellar core, if there is depolarisation, this effect should happen at densities of 10^6 cm-3 or larger. We compare a model generated by DustPol with the observational polarisation data of the low-mass Class 0 object NGC 1333 IRAS 4A, finding that the total and the polarised emission are consistent.

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arXiv2011

The end of star formation in Chamaeleon I ? A LABOCA census of starless and protostellar cores

Chamaeleon I is the most active region in terms of star formation in the Chamaeleon molecular cloud complex. Its population of prestellar and protostellar cores is not known and a controversy exists concerning its history of star formation. Our goal is to characterize the earliest stages of star formation in this cloud. We used the bolometer array LABOCA at APEX to map the cloud in dust continuum emission at 870 micron. The detected sources are analysed by carefully taking into account the spatial filtering inherent in the data reduction process. A search for associations with YSOs is performed using Spitzer data and the SIMBAD database. Most of the detected 870 micron emission is distributed in 5 filaments. We identify 59 starless cores, one candidate first hydrostatic core, and 21 sources associated with more evolved YSOs. The starless cores are only found above a visual extinction threshold of 5 mag. They are less dense than those detected in other nearby molecular clouds by a factor of a few on average. The core mass distribution is consistent with the IMF at the high-mass end but is overpopulated at the low-mass end. In addition, at most 17% of the cores have a mass larger than the critical Bonnor-Ebert mass. Both results suggest that a large fraction of the starless cores may not be prestellar. Based on the census of prestellar cores, Class 0 protostars, and more evolved YSOs, we conclude that the star formation rate has decreased with time in this cloud. The low fraction of candidate prestellar cores among the population of starless cores, the small number of Class 0 protostars, the high global star formation efficiency, the decrease of the star formation rate with time, and the low mass per unit length of the detected filaments all suggest that we may be witnessing the end of the star formation process in Cha I {abridged}.

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arXiv2010

Water in massive star-forming regions: HIFI observations of W3 IRS5

We present Herschel observations of the water molecule in the massive star-forming region W3 IRS5. The o-H17O 110-101, p-H18O 111-000, p-H2O 22 202-111, p-H2O 111-000, o-H2O 221-212, and o-H2O 212-101 lines, covering a frequency range from 552 up to 1669 GHz, have been detected at high spectral resolution with HIFI. The water lines in W3 IRS5 show well-defined high-velocity wings that indicate a clear contribution by outflows. Moreover, the systematically blue-shifted absorption in the H2O lines suggests expansion, presumably driven by the outflow. No infall signatures are detected. The p-H2O 111-000 and o-H2O 212-101 lines show absorption from the cold material (T ~ 10 K) in which the high-mass protostellar envelope is embedded. One-dimensional radiative transfer models are used to estimate water abundances and to further study the kinematics of the region. We show that the emission in the rare isotopologues comes directly from the inner parts of the envelope (T > 100 K) where water ices in the dust mantles evaporate and the gas-phase abundance increases. The resulting jump in the water abundance (with a constant inner abundance of 10^{-4}) is needed to reproduce the o-H17O 110-101 and p-H18O 111-000 spectra in our models. We estimate water abundances of 10^{-8} to 10^{-9} in the outer parts of the envelope (T < 100 K). The possibility of two protostellar objects contributing to the emission is discussed.

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arXiv2010

Herschel-HIFI observations of high-J CO lines in the NGC 1333 low-mass star-forming region

Herschel-HIFI observations of high-J lines (up to J_u=10) of 12CO, 13CO and C18O are presented toward three deeply embedded low-mass protostars, NGC 1333 IRAS 2A, IRAS 4A, and IRAS 4B, obtained as part of the Water In Star-forming regions with Herschel (WISH) key program. The spectrally-resolved HIFI data are complemented by ground-based observations of lower-J CO and isotopologue lines. The 12CO 10-9 profiles are dominated by broad (FWHM 25-30 km s^-1) emission. Radiative transfer models are used to constrain the temperature of this shocked gas to 100-200 K. Several CO and 13CO line profiles also reveal a medium-broad component (FWHM 5-10 km s^-1), seen prominently in H2O lines. Column densities for both components are presented, providing a reference for determining abundances of other molecules in the same gas. The narrow C18O 9-8 lines probe the warmer part of the quiescent envelope. Their intensities require a jump in the CO abundance at an evaporation temperature around 25 K, thus providing new direct evidence for a CO ice evaporation zone around low-mass protostars.

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arXiv2010

HERSCHEL-HIFI spectroscopy of the intermediate mass protostar NGC7129 FIRS 2

HERSCHEL-HIFI observations of water from the intermediate mass protostar NGC7129 FIRS 2 provide a powerful diagnostic of the physical conditions in this star formation environment. Six spectral settings, covering four H216O and two H218O lines, were observed and all but one H218O line were detected. The four H2 16 O lines discussed here share a similar morphology: a narrower, \approx 6 km/s, component centered slightly redward of the systemic velocity of NGC7129 FIRS 2 and a much broader, \approx 25 km/s component centered blueward and likely associated with powerful outflows. The narrower components are consistent with emission from water arising in the envelope around the intermediate mass protostar, and the abundance of H2O is constrained to \approx 10-7 for the outer envelope. Additionally, the presence of a narrow self-absorption component for the lowest energy lines is likely due to self-absorption from colder water in the outer envelope. The broader component, where the H2O/CO relative abundance is found to be \approx 0.2, appears to be tracing the same energetic region that produces strong CO emission at high J.

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arXiv2010

Variations in H2O+/H2O ratios toward massive star-forming regions

Early results from the Herschel Space Observatory revealed the water cation H2O+ to be an abundant ingredient of the interstellar medium. Here we present new observations of the H2O and H2O+ lines at 1113.3 and 1115.2 GHz using the Herschel Space Observatory toward a sample of high-mass star-forming regions to observationally study the relation between H2O and H2O+ . Nine out of ten sources show absorption from H2O+ in a range of environments: the molecular clumps surrounding the forming and newly formed massive stars, bright high-velocity outflows associated with the massive protostars, and unrelated low-density clouds along the line of sight. Column densities per velocity component of H2 O+ are found in the range of 10^12 to a few 10^13 cm-2 . The highest N(H2O+) column densities are found in the outflows of the sources. The ratios of H2O+/H2O are determined in a range from 0.01 to a few and are found to differ strongly between the observed environments with much lower ratios in the massive (proto)cluster envelopes (0.01-0.1) than in outflows and diffuse clouds. Remarkably, even for source components detected in H2O in emission, H2O+ is still seen in absorption.

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arXiv2010

Herschel-HIFI detections of hydrides towards AFGL 2591 (Envelope emission versus tenuous cloud absorption)

The Heterodyne Instrument for the Far Infrared (HIFI) onboard the Herschel Space Observatory allows the first observations of light diatomic molecules at high spectral resolution and in multiple transitions. Here, we report deep integrations using HIFI in different lines of hydrides towards the high-mass star forming region AFGL 2591. Detected are CH, CH+, NH, OH+, H2O+, while NH+ and SH+ have not been detected. All molecules except for CH and CH+ are seen in absorption with low excitation temperatures and at velocities different from the systemic velocity of the protostellar envelope. Surprisingly, the CH(JF,P = 3/2_2,- - 1/2_1,+) and CH+(J = 1 - 0, J = 2 - 1) lines are detected in emission at the systemic velocity. We can assign the absorption features to a foreground cloud and an outflow lobe, while the CH and CH+ emission stems from the envelope. The observed abundance and excitation of CH and CH+ can be explained in the scenario of FUV irradiated outflow walls, where a cavity etched out by the outflow allows protostellar FUV photons to irradiate and heat the envelope at larger distances driving the chemical reactions that produce these molecules.

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