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J. Kaiser

Publications and source records attributed to J. Kaiser.

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Comparison of two laser wavelengths for LIBS bioimaging of plants grown in lunar regolith

The colonisation of extraterrestrial planets requires sustainable food production independent of Earth-based supplies. Due to the high costs and complicated logistics of food transport, in-situ cultivation will be essential. Growing plants directly in regolith offers a practical approach to achieve sustainable long-term human habitation beyond Earth. In this study, Laser-Induced Breakdown Spectroscopy (LIBS) technique was employed for bioimaging of broccoli (Brassica oleracea) and salad (Lactuca sativa) plants grown in Lunar regolith simulant and control substrate. For this purpose, the potential of the 2090 nm laser wavelength for bioimaging of plant tissue was studied compared to the conventional 1064 nm. The signal-to-noise ratio (SNR), total emissivity ($\epsilon_{\mathrm{tot}}$), and Mg II / Mg I intensity ratio (ionisation degree) were all higher when using the 2090 nm laser wavelength compared to 1064 nm. These findings indicate that the 2090 nm laser produces a hotter and more efficiently ionised plasma, supporting its feasibility for bioimaging of plant tissues. Additionally, bioimaging with both laser wavelengths confirmed higher uptake of key plant nutrients such as magnesium (Mg) and calcium (Ca) from Lunar regolith simulant. These results support the potential of LIBS as a diagnostic tool for plant growth monitoring in extraterrestrial environments.

physics.optics

Library transfer between distinct Laser-Induced Breakdown Spectroscopy systems with shared standards

The mutual incompatibility of distinct spectroscopic systems is among the most limiting factors in Laser-Induced Breakdown Spectroscopy (LIBS). The cost related to setting up a new LIBS system is increased, as its extensive calibration is required. Solving the problem would enable inter-laboratory reference measurements and shared spectral libraries, which are fundamental for other spectroscopic techniques. In this work, we study a simplified version of this challenge where LIBS systems differ only in used spectrometers and collection optics but share all other parts of the apparatus, and collect spectra simultaneously from the same plasma plume. Extensive datasets measured as hyperspectral images of heterogeneous specimens are used to train machine learning models that can transfer spectra between systems. The transfer is realized by a pipeline that consists of a variational autoencoder (VAE) and a fully-connected artificial neural network (ANN). In the first step, we obtain a latent representation of the spectra which were measured on the Primary system (by using the VAE). In the second step, we map spectra from the Secondary system to corresponding locations in the latent space (by the ANN). Finally, Secondary system spectra are reconstructed from the latent space to the space of the Primary system. The transfer is evaluated by several figures of merit (Euclidean and cosine distances, both spatially resolved; k-means clustering of transferred spectra). The methodology is compared to several baseline approaches.

physics.data-an

Magnetic phase diagram, magnetoelastic coupling and Gr\"uneisen scaling in CoTiO$_3$

High-quality single crystals of CoTiO$_3$ are grown and used to elucidate in detail structural and magnetostructural effects by means of high-resolution capacitance dilatometry studies in fields up to 15 T which are complemented by specific heat and magnetization measurements. In addition, we refine the single-crystal structure of the ilmenite ($R\bar{3}$) phase. At the antiferromagnetic ordering temperature $T_\mathrm{N}$, pronounced $\lambda$-shaped anomaly in the thermal expansion coefficients signals shrinking of both the $c$ and $b$ axes, indicating strong magnetoelastic coupling with uniaxial pressure along $c$ yielding six times larger effect on $T_\mathrm{N}$ than the pressure applied in-plane. The hydrostatic pressure dependency derived by means of Gr\"uneisen analysis amounts to $\partial T_\mathrm{N}/ \partial p\approx 2.7(4)$~K/GPa. The high-field magnetization studies in static and pulsed magnetic fields up to 60~T along with high-field thermal expansion measurements facilitate in constructing the complete anisotropic magnetic phase diagram of CoTiO$_3$. While the results confirm the presence of significant magnetodielectric coupling, our data show that magnetism drives the observed structural, dielectric, and magnetic changes both in the short-range ordered regime well-above $T_\mathrm{N}$ as well as in the long-range magnetically ordered phase.

cond-mat.str-el