arXiv subjects

J. L. López-Picón

Publications and source records attributed to J. L. López-Picón.

4 recordsLinked to original sources

arXiv2026

The quantum square-well fluid: a thermodynamic geometric view

We investigate several aspects of the thermodynamic geometry for a quantum fluid with square-well interactions using a third-order perturbation theory framework based on the path-integral-necklace analogy. A comparison is made between the thermodynamic and geometric properties of the quantum fluid and its classical counterpart for the interaction ranges $λ^{*}= 1.3$, 1.5, and 1.7. In particular, we analyze the scalar curvature behavior, criticality, and the corresponding Widom lines derived from curvature and several thermodynamic response functions. Quantum effects are shown to smooth supercritical anomalies of the scalar curvature and to shift its extrema for short-range interactions, while leaving the critical exponents of both the curvature and its heat capacity consistent with mean-field predictions. Widom lines associated with temperature-dependent response functions and with the curvature scalar exhibit pronounced classical-quantum differences for short interaction ranges; in contrast, those derived from the isothermal compressibility exhibit only minor variations. Overall, these results highlight the sensitivity of geometric information of thermodynamic systems due to quantum effects and the crucial role of the interaction range in shaping supercritical thermodynamic behavior.

cond-mat.stat-mech↗

arXiv2025

Constructing allowed complex metrics from black holes

We use diffeomorphic mappings to connect black hole metrics with complex solutions allowed by the Kontsevich-Segal criterion. By swapping radial and time-like coordinates and applying complex mappings, we derive dynamic metrics suitable for a Quantum Field Theory. This is shown for static and rotating black holes, mapping their interiors into the Kantowski-Sachs and a specific Gowdy-type cosmological model. We offer interpretations of the period during which the Kontsevich-Segal criterion holds.

gr-qc↗

arXiv2024

Quantum Fluids in Thermodynamic Geometry

In this work, the Thermodynamic Geometry (TG) of quantum fluids (QF) is analyzed. We present results for two models. The first one is a quantum hard-sphere fluid (QHS) whose Helmholtz free energy is obtained from Path Integrals Monte Carlo simulations (PIMC). It is found that due to quantum contributions in the thermodynamic potential, the anomaly found in TG for the classical hard-sphere fluid related to the sign of the scalar curvature, is now avoided in a considerable region of the thermodynamic space. The second model is a semi-classical square-well fluid (QSW), described by a quantum hard-sphere repulsive interaction coupled with a classical attractive square-well contribution. Behavior of the semi-classical curvature scalar as a function of the thermal de Broglie wavelength $λ_B$ is analyzed for several attractive-potential ranges, and description of the semi-classical R-Widom lines defined by the maxima of the curvature scalar, are also obtained and compared with classical results for different square-well ranges.

cond-mat.stat-mech↗

arXiv2022

The square-well fluid: a thermodynamic geometric view

The square-well fluid with hard-sphere diameters is studied within the framework of Thermodynamic Geometry (TG). Coexistence and spinodal curves, as well as the Widom line for ranges $λ^{*} = 1.25, 1.5, 2.0, 3.0$ for this fluid are carefully studied using geometric methods. We are able to show that, unlike coexistence curves, an exact result can be given along all the thermodynamic space and for all potential ranges for spinodal curves. Additionally, $R$-Widom line which is defined as the locus of extrema of the curvature scalar is calculated as a function of the potential range, satisfying near the critical point a kind of Clausius-Clapeyron equation. It is argued that this relation could be a signature of certain type of characteristic phase transition when crossing the boundary of the Widom line.

cond-mat.stat-mech↗