arXiv subjects

J. Le Bourlot

Publications and source records attributed to J. Le Bourlot.

At least 19 recordsLinked to original sources

arXiv2025

Interstellar medium phases and abundances in the central parsec: A JWST MIRI/MRS view of the Galactic center

We used newly obtained observations from the Mid-Infrared Instrument (MIRI) equipped with the Medium Resolution Spectrometer (MRS) aboard the James Webb Space Telescope (JWST) to extract spectra covering the entire spectral range from 5 to 27~$μ$m in the CND and in the CC. We used the photoionization code CLOUDY to generate synthetic spectra with the same spectral range and resolution, simulating a wide range of gas phases and abundances. We then determined the contribution of each phase to the spectra. Once the abundances and contribution from each phase of the gas were determined, we identified four dominant phases and performed a spatial analysis to determine their contribution to each spaxel of the datacubes. We find that in both the CND and the CC, the bulk of the emission originates from warm ionized gas with temperatures of between $10^4$ and $10^{4.8}$~K. In the CND, molecular gas contributes significantly to the flux and is spatially structured, while the CC shows minimal molecular gas content, as is expected from these regions. Coronal gas is detected in both regions at the interface between molecular and warm ionized gas. The observed abundance pattern (enhanced CNO and $α$ elements with suppressed Fe) indicates a chemically young environment, recently enriched by core-collapse supernovae and stellar winds, with a limited contribution from older Type Ia supernovae. This favors a scenario of massive, recent star formation rather than cumulative long-term enrichment.

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arXiv2025

JWST observations of photodissociation regions: II. Warm molecular Hydrogen spectroscopy in the Horsehead nebula

H2 is the most abundant molecule in the interstellar medium and is a useful tool to study photodissociation regions, where radiative feedback from massive stars on molecular clouds is dominant. The James Webb Space Telescope, with its high spatial resolution, sensitivity, and wavelength coverage provides unique access to the detection of most of H2 lines and the analysis of its spatial morphology. Our goal is to use H2 line emission detected with the JWST in the Horsehead nebula to constrain the physical parameters (e.g., extinction, gas temperature, thermal pressure) throughout the PDR and its geometry. The study of H2 morphology reveals that FUV-pumped lines peak closer to the edge of the PDR than thermalized lines. From H2 lines, we estimate the value of extinction throughout the PDR. We find that AV is increasing from the edge of the PDR to the second and third H2 filaments. Then, we study the H2 excitation in different regions across the PDR. The temperature profile shows that the observed gas temperature is quite constant throughout the PDR, with a slight decline in each of the dissociation fronts. This study also reveals that the OPR is far from equilibrium. We observe a spatial separation of para and ortho rovibrational levels, indicating that efficient ortho-para conversion and preferential ortho self-shielding are driving the spatial variations of the OPR. Finally, we derive a thermal pressure in the first filament around P > 6x10$^6$ K cm$^{-3}$, about ten times higher than that of the ionized gas. We highlight that template stationary 1D PDR models cannot account for the intrinsic 2D structure and the very high temperature observed in the Horsehead nebula. We argue the highly excited, over-pressurized H2 gas at the edge of the PDR interface could originate from the mixing between the cold and hot phase induced by the photo-evaporation of the cloud.

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arXiv2025

Rotational equilibrium of C$_2$ in diffuse interstellar clouds

Context. Recent spectroscopic measurements have revealed absorption from higher rotational levels in C$_2$ than previous observations. These improvements are accompanied by the availability of updated radiative and collisional data. Aims. We revisit the density and radiation field intensity diagnostics provided by the observations of many rotational levels of inter- stellar C$_2$ and extensive molecular information. Methods. We built an excitation model of C2 without spatial structure, including levels up to J= 34 where updated radiative and collisional excitation data are introduced as well as excitation by chemical formation. Results. We confirm the importance of the recent collisional excitation rate coefficients of C$_2$ by molecular H$_2$. We show that the new higher level observations cannot be explained by the standard balance between collisional excitation and radiative transitions. We propose that chemical excitation at formation provides a plausible mechanism to explain the observed high excitation of C$_2$. In addition, it allows us to lift the degeneracy of the density over radiation field strength parameter in the excitation model. Conclusions. A 0D model remains limited and it is highly desirable to use a full Photon Dominated Region (PDR) model, which includes all excitation processes introduced here and full chemical and thermal balance.

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arXiv2024

PDRs4All. X. ALMA and JWST detection of neutral carbon in the externally irradiated disk d203-506: Undepleted gas-phase carbon

The gas-phase abundance of carbon, x_C = C/H, and its depletion factors are essential parameters for understanding the gas and solid compositions that are ultimately incorporated into planets. The majority of protoplanetary disks are born in clusters and, as a result, are exposed to external FUV radiation. These FUV photons potentially affect the disk's evolution, chemical composition, and line excitation. We present the first detection of the [CI]609um fine-structure line of neutral carbon (CI), achieved with ALMA, toward one of these disks, d203-506, in the Orion Nebula Cluster. We also report the detection of CI forbidden and permitted lines (from electronically excited states up to 10 eV) observed with JWST in the IR. These lines trace the irradiated outer disk and photo-evaporative wind. Contrary to the common belief that these IR lines are C+ recombination lines, we find that they are dominated by FUV-pumping of CI followed by fluorescence cascades. They trace the transition from atomic to molecular gas, and their intensities scale with G0. The lack of outstanding IR OI fluorescent emission, however, implies a sharper attenuation of external FUV radiation with E > 12 eV (~Lyman-beta). This is related to a lower effective FUV dust absorption cross section compared to that of interstellar grains, implying a more prominent role for FUV shielding by the CI photoionization continuum. The [CI]609um intensity is proportional to N(CI) and can be used to infer x_C. We derive x_C ~ 1.4E-4. This implies that there is no major depletion of volatile carbon compared to x_C measured in the natal cloud, hinting at a young disk. We also show that external FUV radiation impacts the outer disk and wind by vertically shifting the water freeze-out depth, which results in less efficient grain growth and settling. This shift leads to nearly solar gas-phase C/O abundance ratios in these irradiated layers.

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arXiv2023

HCN emission from translucent gas and UV-illuminated cloud edges revealed by wide-field IRAM 30m maps of Orion B GMC: Revisiting its role as tracer of the dense gas reservoir for star formation

We present 5 deg^2 (~250 pc^2) HCN, HNC, HCO+, and CO J=1-0 maps of the Orion B GMC, complemented with existing wide-field [CI] 492 GHz maps, as well as new pointed observations of rotationally excited HCN, HNC, H13CN, and HN13C lines. We detect anomalous HCN J=1-0 hyperfine structure line emission almost everywhere in the cloud. About 70% of the total HCN J=1-0 luminosity arises from gas at A_V < 8 mag. The HCN/CO J=1-0 line intensity ratio shows a bimodal behavior with an inflection point at A_V < 3 mag typical of translucent gas and UV-illuminated cloud edges. We find that most of the HCN J=1-0 emission arises from extended gas with n(H2) ~< 10^4 cm^-3, even lower density gas if the ionization fraction is > 10^-5 and electron excitation dominates. This result explains the low-A_V branch of the HCN/CO J=1-0 intensity ratio distribution. Indeed, the highest HCN/CO ratios (~0.1) at A_V < 3 mag correspond to regions of high [CI] 492 GHz/CO J=1-0 intensity ratios (>1) characteristic of low-density PDRs. Enhanced FUV radiation favors the formation and excitation of HCN on large scales, not only in dense star-forming clumps. The low surface brightness HCN and HCO+ J=1-0 emission scale with I_FIR (a proxy of the stellar FUV radiation field) in a similar way. Together with CO J=1-0, these lines respond to increasing I_FIR up to G0~20. On the other hand, the bright HCN J=1-0 emission from dense gas in star-forming clumps weakly responds to I_FIR once the FUV radiation field becomes too intense (G0>1500). The different power law scalings (produced by different chemistries, densities, and line excitation regimes) in a single but spatially resolved GMC resemble the variety of Kennicutt-Schmidt law indexes found in galaxy averages. As a corollary for extragalactic studies, we conclude that high HCN/CO J=1-0 line intensity ratios do not always imply the presence of dense gas.

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arXiv2021

Influence of the nano-grain depletion in photon-dominated regions: Application to the gas physics and chemistry in the Horsehead

The large disparity in physical conditions from the diffuse interstellar medium (ISM) to denser clouds such as photon-dominated regions (PDRs) triggers an evolution of the dust properties (i.e. composition, size, and shape). The gas physics and chemistry are tightly connected to these dust properties and are therefore affected by dust evolution and especially the nano-grain depletion in the outer irradiated part of PDRs. We highlight the influence of nano-grain depletion on the gas physics and chemistry in the Horsehead nebula, a prototypical PDR. We used a model for atomic and molecular gas in PDRs, the Meudon PDR code, using diffuse ISM-like dust and Horsehead-like dust to study the influence of nano-grain depletion on the gas physics and chemistry, focusing on the impact on photoelectric heating and H2 formation and, therefore, on the H2 gas lines. We find that nano-grain depletion in the Horsehead strongly affects gas heating through the photoelectric effect and thus the gas temperature and the H2 formation, hence the H -> H2 position. Consequently, the first four pure rotational lines of H2 (e.g. 0-0 S(0), S(1), S(2), and S(3)) vary by a factor of 2 to 14. The 0-0 S(3) line that is often underestimated in models is underestimated even more when taking nano-grain depletion into account due to the decrease in gas heating through the photoelectric effect. This strongly suggests that our understanding of the excitation of H2 and/or of heating processes in the Horsehead, and more generally in PDRs, is still incomplete. Nano-grain depletion in the outer part of the Horsehead has a strong influence on several gas tracers that will be prominent in JWST observations of irradiated clouds. We therefore need to take this depletion into account in order to improve our understanding of the Horsehead, and more generally PDRs, and to contribute to the optimal scientific return of the mission.

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arXiv2019

ESA Voyage 2050 white paper: A complete census of the gas phases in and around galaxies, far-UV spectropolarimetry as a prime tool for understanding galaxy evolution and star formation

(abridged) The far-UV wavelength range (912-2000A) provides access to atomic and molecular transitions of many species the interstellar medium (ISM), circumgalactic medium (CGM), and intergalactic medium, within phases spanning a wide range of ionization, density, temperature, and molecular gas fraction. Far-UV space telescopes have enabled detailed studies of the ISM in the Milky Way thanks to absorption features appearing in the UV spectra of hot stars and yielding fundamental insights into the composition and physical characteristics of all phases of the ISM along with the processes that influence them. However, we have yet to design a spectrometer able to observe the full UV domain at resolving power R>10^5 with a signal-to-noise ratio SNR>500. Such a resolution is necessary to resolve lines from both the cold molecular hydrogen and the warm metal ions with a turbulent velocity of about 1 km s-1, and to differentiate distinct velocity components. Future UV spectroscopic studies of the Milky Way ISM must revolutionize our understanding of the ISM as a dynamical, unstable, and magnetized medium, and rise to the challenge brought forward by current theories. Another interesting prospect is to transpose the same level of details that has been reached for the Milky Way to the ISM in external galaxies, in particular in metal-poor galaxies, where the ISM chemical composition, physical conditions, and topology change dramatically, with significant consequences on the star-formation properties. Finally, we need to be able to perform statistical analyses of background quasar lines of sight intersecting the CGM of galaxies at various redshifts and to comprehend the role of gas exchanges and flows for galaxy evolution.

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arXiv2018

Structure of photodissociation fronts in star-forming regions revealed by observations of high-J CO emission lines with Herschel

In bright photodissociation regions (PDRs) associated to massive star formation, the presence of dense "clumps" that are immersed in a less dense interclump medium is often proposed to explain the difficulty of models to account for the observed gas emission in high-excitation lines. We aim at presenting a comprehensive view of the modeling of the CO rotational ladder in PDRs, including the high-J lines that trace warm molecular gas at PDR interfaces. We observed the 12CO and 13CO ladders in two prototypical PDRs, the Orion Bar and NGC 7023 NW using the instruments onboard Herschel. We also considered line emission from key species in the gas cooling of PDRs (C+, O, H2) and other tracers of PDR edges such as OH and CH+. All the intensities are collected from Herschel observations, the literature and the Spitzer archive and are analyzed using the Meudon PDR code. A grid of models was run to explore the parameter space of only two parameters: thermal gas pressure and a global scaling factor that corrects for approximations in the assumed geometry. We conclude that the emission in the high-J CO lines, which were observed up to Jup=23 in the Orion Bar (Jup=19 in NGC7023), can only originate from small structures of typical thickness of a few 1e-3 pc and at high thermal pressures (Pth~1e8 K cm-3). Compiling data from the literature, we found that the gas thermal pressure increases with the intensity of the UV radiation field given by G0, following a trend in line with recent simulations of the photoevaporation of illuminated edges of molecular clouds. This relation can help rationalising the analysis of high-J CO emission in massive star formation and provides an observational constraint for models that study stellar feedback on molecular clouds.

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arXiv2017

The onset of energetic particle irradiation in Class 0 protostars

The early stages of low-mass star formation are likely to be subject to intense ionization by protostellar energetic MeV particles. As a result, the surrounding gas is enriched in molecular ions, such as HCO$^{+}$ and N$_{2}$H$^{+}$. Nonetheless, this phenomenon remains poorly understood for Class 0 objects. Recently, based on Herschel observations taken as part of the key program Chemical HErschel Surveys of Star forming regions (CHESS), a very low HCO$^{+}$/N$_{2}$H$^{+}$ abundance ratio of about 3-4, has been reported toward the protocluster OMC-2 FIR4. This finding suggests a cosmic-ray ionization rate in excess of 10$^{-14}$ s$^{-1}$, much higher than the canonical value of $ζ$ = 3$\times$10$^{-17}$ s$^{-1}$ (value expected in quiescent dense clouds). To assess the specificity of OMC-2 FIR4, we have extended this study to a sample of sources in low- and intermediate mass. More specifically, we seek to measure the HCO$^{+}$/N$_2$H$^{+}$ abundance ratio from high energy lines (J $\ge$ 6) toward this source sample in order to infer the flux of energetic particles in the warm and dense gas surrounding the protostars. We use observations performed with the Heterodyne Instrument for the FarInfrared spectrometer on board the Herschel Space Observatory toward a sample of 9 protostars. We report HCO$^{+}$/N$_2$H$^{+}$ abundance ratios in the range of 5 up to 73 toward our source sample. The large error bars do not allow us to conclude whether OMC-2~FIR4 is a peculiar source. Nonetheless, an important result is that the measured HCO$^{+}$/N$_2$H$^{+}$ ratio does not vary with the source luminosity. At the present time, OMC-2 FIR4 remains the only source where a high flux of energetic particles is clearly evident. More sensitive and higher angular resolution observations are required to further investigate this process.

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arXiv2016

A milestone toward understanding PDR properties in the extreme environment of LMC-30Dor

More complete knowledge of galaxy evolution requires understanding the process of star formation and interaction between the interstellar radiation field and the interstellar medium in galactic environments traversing a wide range of physical parameter space. Here we focus on the impact of massive star formation on the surrounding low metallicity ISM in 30 Doradus in the Large Magellanic Cloud. A low metal abundance, as is the case of some galaxies of the early universe, results in less ultra-violet shielding for the formation of the molecular gas necessary for star formation to proceed. The half-solar metallicity gas in this region is strongly irradiated by the super star cluster R136, making it an ideal laboratory to study the structure of the ISM in an extreme environment. Our spatially resolved study investigates the gas heating and cooling mechanisms, particularly in the photo-dissociation regions where the chemistry and thermal balance are regulated by far-ultraviolet photons (6 eV< hν<13.6 eV). We present Herschel observations of far-infrared fine-structure lines obtained with PACS and SPIRE/FTS. We have combined atomic fine-structure lines from Herschel and Spitzer observations with ground-based CO data to provide diagnostics on the properties and the structure of the gas by modeling it with the Meudon PDR code. We derive the spatial distribution of the radiation field, the pressure, the size, and the filling factor of the photodissociated gas and molecular clouds. We find a range of pressure of ~ 10^5 - 1.7x10^6 cm^{-3} K and a range of incident radiation field G_UV ~ 10^2 - 2.5x10^4 through PDR modeling. Assuming a plane-parallel geometry and a uniform medium, we find a total extinction of 1-3 mag , which correspond to a PDR cloud size of 0.2 to 3pc, with small CO depth scale of 0.06 to 0.5pc. We also determine the three dimensional structure of the gas. (Abridged)

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arXiv2015

$Herschel$ SPIRE-FTS observations of RCW 120

The expansion of Galactic HII regions can trigger the formation of a new generation of stars. However, little is know about the physical conditions that prevail in these regions. We study the physical conditions that prevail in specific zones towards expanding HII regions that trace representative media such as the photodissociation region, the ionized region, and condensations with and without ongoing star formation. We use the SPIRE Fourier Transform Spectrometer (FTS) on board $Herschel$ to observe the HII region RCW 120. Continuum and lines are observed in the $190-670\,μ$m range. Line intensities and line ratios are obtained and used as physical diagnostics of the gas. We used the Meudon PDR code and the RADEX code to derive the gas density and the radiation field at nine distinct positions including the PDR surface and regions with and without star-formation activity. For the different regions we detect the atomic lines [NII] at $205\,μ$m and [CI] at $370$ and $609\,μ$m, the $^{12}{\rm CO}$ ladder between the $J=4$ and $J=13$ levels and the $^{13}{\rm CO}$ ladder between the $J=5$ and $J=14$ levels, as well as CH$ ^{+} $ in absorption. We find gas temperatures in the range $45-250\,$K for densities of $10^4-10^6\,{\rm cm}^{-3}$, and a high column density on the order of $N_{\rm H}\sim10^{22}\,{\rm cm}^{-2}$ that is in agreement with dust analysis. The ubiquitousness of the atomic and CH$ ^{+} $ emission suggests the presence of a low-density PDR throughout RCW 120. High-excitation lines of CO indicate the presence of irradiated dense structures or small dense clumps containing young stellar objects, while we also find a less dense medium ($N_{\rm H}\sim10^{20}\,{\rm cm}^{-2}$) with high temperatures ($80-200\,$K).

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arXiv2014

Photodissociation of interstellar ArH+

Aims. Following the recent detection of 36ArH+ in the Crab nebula spectrum, we have computed the photodissociation rate of ArH+ in order to constrain the physical processes at work in this environment. Methods. Photodissociation cross sections of ArH+ are computed in an ab initio approach including explicit account of spin-orbit coupling. Results. We report the photodissociation cross section of ArH+ as a function of wavelength. Photodissociation probabilities are derived for different impinging radiation fields.The photodissociation probability of for a very small unshielded cloud surrounded on all sides by the unshielded InterStellar Radiation Field (ISRF) model described by Draine (1978) is equal to 9.9e-12 s-1 and 1.9e-9 s-1 in the Crab nebula conditions. The dependence on the visual extinction is obtained by using the Meudon Photon Dominated Region (PDR) code and corresponding analytical fits are provided. Conclusions. These data will help to produce a realistic chemical network to interpret the observations. Photodissociation of ArH+ is found to be moderate and the presence of this molecular ion is mainly dependent on the molecular fraction

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arXiv2013

The IRAM-30m line survey of the Horsehead PDR: IV. Comparative chemistry of H2CO and CH3OH

Aims. We investigate the dominant formation mechanism of H2CO and CH3OH in the Horsehead PDR and its associated dense core. Methods. We performed deep integrations of several H2CO and CH3OH lines at two positions in the Horsehead, namely the PDR and dense core, with the IRAM-30m telescope. In addition, we observed one H2CO higher frequency line with the CSO telescope at both positions. We determine the H2CO and CH3OH column densities and abundances from the single-dish observations complemented with IRAM-PdBI high-angular resolution maps (6") of both species. We compare the observed abundances with PDR models including either pure gas-phase chemistry or both gas-phase and grain surface chemistry. Results. We derive CH3OH abundances relative to total number of hydrogen atoms of ~1.2e-10 and ~2.3e-10 in the PDR and dense core positions, respectively. These abundances are similar to the inferred H2CO abundance in both positions (~2e-10). We find an abundance ratio H2CO/CH3OH of ~2 in the PDR and ~1 in the dense core. Pure gas-phase models cannot reproduce the observed abundances of either H2CO or CH3OH at the PDR position. Both species are therefore formed on the surface of dust grains and are subsequently photodesorbed into the gas-phase at this position. At the dense core, on the other hand, photodesorption of ices is needed to explain the observed abundance of CH3OH, while a pure gas-phase model can reproduce the observed H2CO abundance. The high-resolution observations show that CH3OH is depleted onto grains at the dense core. CH3OH is thus present in an envelope around this position, while H2CO is present in both the envelope and the dense core itself. Conclusions. Photodesorption is an efficient mechanism to release complex molecules in low FUV-illuminated PDRs, where thermal desorption of ice mantles is ineffective.

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arXiv2013

Spatial distribution of small hydrocarbons in the neighborhood of the Ultra Compact HII region Monoceros R2

We study the chemistry of small hydrocarbons in the photon-dominated regions (PDRs) associated with the ultra-compact HII region Mon R2. Our goal is to determine the variations of the abundance of small hydrocarbons in a high-UV irradiated PDR and investigate their chemistry. We present an observational study of CH, CCH and c-C$_3$H$_2$ in Mon R2 combining data obtained with the IRAM 30m telescope and Herschel. We determine the column densities of these species, and compare their spatial distributions with that of polycyclic aromatic hydrocarbon (PAH). We compare the observational results with different chemical models to explore the relative importance of gas-phase, grain-surface and time-dependent chemistry in these environments. The emission of the small hydrocarbons show different patterns. The CCH emission is extended while CH and c-C$_3$H$_2$ are concentrated towards the more illuminated layers of the PDR. The ratio of the column densities of c-C$_3$H$_2$ and CCH shows spatial variations up to a factor of a few, increasing from $N(c-C$_3$H$_2$)/N(CCH)\approx0.004$ in the envelope to a maximum of $\sim0.015-0.029$ towards the 8$μ$m emission peak. Comparing these results with other galactic PDRs, we find that the abundance of CCH is quite constant over a wide range of G$_0$, whereas the abundance of c-C$_3$H$_2$ is higher in low-UV PDRs. In Mon R2, the gas-phase steady-state chemistry can account relatively well for the abundances of CH and CCH in the most exposed layers of the PDR, but falls short by a factor of 10 to reproduce c-C$_3$H$_2$. In the molecular envelope, time-dependent effects and grain surface chemistry play a dominant role in determining the hydrocarbons abundances. Our study shows that CCH and c-C$_3$H$_2$ present a complex chemistry in which UV photons, grain-surface chemistry and time dependent effects contribute to determine their abundances.

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arXiv2013

The chemistry of ions in the Orion Bar I. - CH+, SH+, and CF+: The effect of high electron density and vibrationally excited H2 in a warm PDR surface

The abundances of interstellar CH+ and SH+ are not well understood as their most likely formation channels are highly endothermic. Using data from Herschel, we study the formation of CH+ and SH+ in a typical high UV-illumination photon-dominated region (PDR), the Orion Bar. Herschel/HIFI provides velocity-resolved data of CH+ 1-0 and 2-1 and three hyperfine transitions of SH+. Herschel/PACS provides information on the excitation and spatial distribution of CH+ (up to J=6-5). The widths of the CH+ 2-1 and 1-0 transitions are of ~5 km/s, significantly broader than the typical width of dense gas tracers in the Orion Bar (2-3 km/s) and are comparable to the width of tracers of the interclump medium such as C+ and HF. The detected SH+ transitions are narrower compared to CH+ and have line widths of 3 km/s, indicating that SH+ emission mainly originates in denser condensations. Non-LTE radiative transfer models show that electron collisions affect the excitation of CH+ and SH+, and that reactive collisions need to be taken into account to calculate the excitation of CH+. Comparison to PDR models shows that CH+ and SH+ are tracers of the warm surface region (AV<1.5) of the PDR with temperatures between 500-1000 K. We have also detected the 5-4 transition of CF+ (FWHM=1.9 km/s) with an intensity that is consistent with previous observations of lower-J CF+ transitions toward the Orion Bar. A comparison to PDR models indicate that the internal vibrational energy of H2 can explain the formation of CH+ for typical physical conditions in the Orion Bar near the ionization front. H2 vibrational excitation is the most likely explanation of SH+ formation as well. The abundance ratios of CH+ and SH+ trace the destruction paths of these ions, and through that, indirectly, the ratios of H, H2 and electron abundances as a function of depth into the cloud.

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arXiv2012

The IRAM-30m line survey of the Horsehead PDR: II. First detection of the l-C3H+ hydrocarbon cation

We present the first detection of the l-C3H+ hydrocarbon in the interstellar medium. The Horsehead WHISPER project, a millimeter unbiased line survey at two positions, namely the photo-dissociation region (PDR) and the nearby shielded core, revealed a consistent set of eight unidentified lines toward the PDR position. Six of them are detected with a signal-to-noise ratio from 6 to 19, while the two last ones are tentatively detected. Mostly noise appears at the same frequency toward the dense core, located less than 40" away. We simultaneously fit 1) the rotational and centrifugal distortion constants of a linear rotor, and 2) the Gaussian line shapes located at the eight predicted frequencies. The observed lines can be accurately fitted with a linear rotor model, implying a 1Sigma ground electronic state. The deduced rotational constant value is Be= 11244.9512 +/- 0.0015 MHz, close to that of l-C3H. We thus associate the lines to the l-C3H+ hydrocarbon cation, which enables us to constrain the chemistry of small hydrocarbons. A rotational diagram is then used to infer the excitation temperature and the column density. We finally compare the abundance to the results of the Meudon PDR photochemical model.

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arXiv2012

Herschel / HIFI observations of CO, H2O and NH3 in Mon R2

Context. Mon R2 is the only ultracompact HII region (UCHII) where the associated photon-dominated region (PDR) can be resolved with Herschel. Due to its brightness and proximity, it is the best source to investigate the chemistry and physics of highly UV-irradiated PDRs. Aims. Our goal is to estimate the abundance of H2O and NH3 in this region and investigate their origin. Methods. We present new observations obtained with HIFI and the IRAM-30m telescope. Using a large velocity gradient approach, we model the line intensities and derive an average abundance of H2O and NH3 across the region. Finally, we model the line profiles with a non-local radiative transfer model and compare these results with the abundance predicted by the Meudon PDR code. Results. The variations of the line profiles and intensities indicate complex geometrical and kinematical patterns. The H2O lines present a strong absorption at the ambient velocity and emission in high velocity wings towards the HII region. The spatial distribution of the o-H2^18O line shows that the its emission arises in the PDR surrounding the HII region. By modeling the o-H2^18O emission we derive a mean abundance of o-H2O of ~10^-8 relative to H2. The ortho-H2O abundance is however larger, ~1x10^-7, in the high velocity wings. Possible explanations for this larger abundance include an expanding hot PDR and/or an outflow. Ammonia seems to be present only in the envelope with an average abundance of ~2x10^-9 relative to H2. Conclusions. The Meudon PDR code can account for the measured water abundance in the high velocity gas as long as we assume that it originates from a <1 mag hot expanding layer of the PDR, i.e. that the outflow has only a minor contribution to this emission. To explain the abundances in the rest of the cloud the molecular freeze out and grain surface chemistry would need to be included.

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arXiv2012

Multi-line detection of O2 toward rho Oph A

Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O2, and water, H2O. Contrary to expectation, the space missions SWAS and Odin found only very small amounts of water vapour and essentially no O2 in the dense star-forming interstellar medium. Only toward rho Oph A did Odin detect a weak line of O2 at 119 GHz in a beam size of 10 arcmin. A larger telescope aperture such as that of the Herschel Space Observatory is required to resolve the O2 emission and to pinpoint its origin. We use the Heterodyne Instrument for the Far Infrared aboard Herschel to obtain high resolution O2 spectra toward selected positions in rho Oph A. These data are analysed using standard techniques for O2 excitation and compared to recent PDR-like chemical cloud models. The 487.2GHz line was clearly detected toward all three observed positions in rho Oph A. In addition, an oversampled map of the 773.8GHz transition revealed the detection of the line in only half of the observed area. Based on their ratios, the temperature of the O2 emitting gas appears to vary quite substantially, with warm gas (> 50 K) adjacent to a much colder region, where temperatures are below 30 K. The exploited models predict O2 column densities to be sensitive to the prevailing dust temperatures, but rather insensitive to the temperatures of the gas. In agreement with these model, the observationally determined O2 column densities seem not to depend strongly on the derived gas temperatures, but fall into the range N(O2) = (3 to >6)e15/cm^2. Beam averaged O2 abundances are about 5e-8 relative to H2. Combining the HIFI data with earlier Odin observations yields a source size at 119 GHz of about 4 - 5 arcmin, encompassing the entire rho Oph A core.

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