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J. Margalef-Roig

Publications and source records attributed to J. Margalef-Roig.

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Analysis of a three-component model phase diagram by Catastrophe Theory: Potentials with two Order Parameters

In this work we classify the singularities obtained from the Gibbs potential of a lattice gas model with three components, two order parameters and five control parameters applying the general theorems provided by Catastrophe Theory. In particular, we clearly establish the existence of Landau potentials in two variables or, in other words, corank 2 canonical forms that are associated to the hyperbolic umbilic, D_{+4}, its dual the elliptic umbilic, D_{-4}, and the parabolic umbilic, D_5, catastrophes. The transversality of the potential with two order parameters is explicitely shown for each case. Thus we complete the Catastrophe Theory analysis of the three-component lattice model, initiated in a previous paper.

cond-mat.stat-mech

Analysis of a three-component model phase diagram by Catastrophe Theory

We analyze the thermodynamical potential of a lattice gas model with three components and five parameters using the methods of Catastrophe Theory. We find the highest singularity, which has codimension five, and establish its transversality. Hence the corresponding seven-degree Landau potential, the canonical form Wigwam or $A_6$, constitutes the adequate starting point to study the overall phase diagram of this model.

cond-mat.stat-mech