arXiv subjects

J. Pérez-Ríos

Publications and source records attributed to J. Pérez-Ríos.

11 recordsLinked to original sources

arXiv2026

Precision Positronium Spectroscopy as a Test of the Helium Ionization Energy Anomaly

Precise measurements of the metastable helium (1s)(2s)$\,^3S_1$ ionization energy have revealed a 9$σ$ discrepancy with QED theory that persists in isotopic measurements, suggesting a leptophilic bosonic interaction as a possible explanation. A subsequent investigation of such interactions has concluded that only a scalar boson interaction is consistent with the He observations. Taking this as a starting point, we derive the response of positronium energy levels to the corresponding finite-range Yukawa potential, using exact hydrogenic matrix elements and a numerical helium calculation. Across the viable mediator-mass range of 0-800 eV, the He anomaly interpreted in this way implies a positronium 1$^3$S$_1 \rightarrow 2^3$S$_1$ shift ranging from 0.250-0.850 MHz, and a 2S-ionization shift of 0.14-0.21 MHz. We discuss the feasibility of observing these shifts experimentally.

physics.atom-ph↗

arXiv2024

Collisional alignment and molecular rotation control chemi-ionization of individual conformers

The relationship between the shape of a molecule and its chemical reactivity is a central tenet in chemistry. However, the influence of the molecular geometry on reactivity can be subtle and result from several opposing effects. Using a novel crossed-molecular-beam experiment in which individual rotational quantum states of specific conformers of a molecule are separated, we study the chemi-ionization reaction of hydroquinone with metastable neon atoms. We show that collision-induced alignment of the reaction partners caused by geometry-dependent long-range forces crucially influences reaction pathways for distinct conformers which is, however, countered by molecular rotation. We demonstrate how the interplay between molecular geometry, chemical steering forces and rotational dynamics govern the outcome of reactions and illustrate the capability of advanced molecule-control techniques to unravel these effects.

physics.chem-ph↗

arXiv2023

Spectroscopic constants from atomic properties: a machine learning approach

We present a machine-learning approach toward predicting spectroscopic constants based on atomic properties. After collecting spectroscopic information on diatomics and generating an extensive database, we employ Gaussian process regression to identify the most efficient characterization of molecules to predict the equilibrium distance, vibrational harmonic frequency, and dissociation energy. As a result, we show that it is possible to predict the equilibrium distance with an absolute error of 0.04 Å and vibrational harmonic frequency with an absolute error of 36 $\text{cm}^{-1}$, including only atomic properties. These results can be improved by including prior information on molecular properties leading to an absolute error of 0.02 Å and 28 $\text{cm}^{-1}$ for the equilibrium distance and vibrational harmonic frequency, respectively. In contrast, the dissociation energy is predicted with an absolute error $\lesssim 0.4$ eV. Alongside these results, we prove that it is possible to predict spectroscopic constants of homonuclear molecules from the atomic and molecular properties of heteronuclear. Finally, based on our results, we present a new way to classify diatomic molecules beyond chemical bond properties.

physics.chem-ph↗

arXiv2022

Trap-assisted complexes in cold atom-ion collisions

We theoretically investigate the trap-assisted formation of complexes in atom-ion collisions and their impact on the stability of the trapped ion. The time-dependent potential of the Paul trap facilitates the formation of temporary complexes by reducing the energy of the atom, which gets temporarily stuck in the atom-ion potential. As a result, those complexes significantly impact termolecular reactions leading to molecular ion formation via three-body recombination. We find that complex formation is more pronounced in systems with heavy atoms, but the mass has no influence on the lifetime of the transient state. Instead, the complex formation rate strongly depends on the amplitude of the ion's micromotion. We also show that complex formation persists even in the case of a time-independent harmonic trap. In this case, we find higher formation rates and longer lifetimes than the Paul trap, indicating that the atom-ion complex plays an essential role in atom-ion mixtures in optical traps.

physics.atom-ph↗

arXiv2022

The chemistry of AlF and CaF production in buffer gas sources

In this work, we explore the role of chemical reactions on the properties of buffer gas-cooled molecular beams. In particular, we focus on scenarios relevant to the formation of AlF and CaF via chemical reactions between the Ca and Al atoms ablated from a solid target in an atmosphere of a fluorine-containing gas, in this case, SF6 and NF3. Reactions are studied following an ab initio molecular dynamics approach, and the results are rationalized following a tree-shaped reaction model based on Bayesian inference. We find that NF3 reacts more efficiently with hot metal atoms to form monofluoride molecules than SF6. In addition, when using NF3, the reaction products have lower kinetic energy, requiring fewer collisions to thermalize with the cryogenic helium. Furthermore, we find that the reaction probability for AlF formation is much higher than for CaF across a broad range of temperatures.

physics.comp-ph↗

arXiv2022

Observation of Chemical Reactions between a Trapped Ion and Ultracold Feshbach Dimers

We measure chemical reactions between a single trapped $^{174}$Yb$^+$ ion immersed in an ultracold bath of $^6$Li atoms containing trace amounts of Li$_2$ dimers. This produces LiYb$^+$ molecular ions that we detect via mass spectrometry. We explain the reaction rates by modelling the dimer density as a function of the magnetic field and obtain excellent agreement when we assume the reaction to follow the Langevin rate. Our results present a novel approach towards the creation of cold molecular ions and point to the exploration of ultracold chemistry in ion molecule collisions. What is more, with a detection sensitivity below molecule densities of $10^{14}\,\mathrm{m}^{-3}$, we provide a new method to detect low-density molecular gases.

physics.atom-ph↗

arXiv2019

Spectroscopic characterization of aluminum monofluoride with relevance to laser cooling and trapping

Here we report on spectroscopic measurements of the aluminum monofluoride molecule (AlF) that are relevant to laser cooling and trapping experiments. We measure the detailed energy level structure of AlF in the X$^1Σ^+$ electronic ground state, in the A$^1Π$ state, and in the metastable a$^3Π$ state. We determine the rotational, vibrational and electronic branching ratios from the A$^1Π$ state. We also study how the rotational levels split and shift in external electric and magnetic fields. We find that AlF is an excellent candidate for laser cooling on any Q-line of the A$^1Π$ - X$^1Σ^+$ transition and for trapping at high densities.

physics.atom-ph↗

arXiv2017

Ultracold Molecule Assembly with Photonic Crystals

Photoassociation (PA) is a powerful technique to synthesize molecules directly and continuously from cold and ultracold atoms into deeply bound molecular states. In freespace, however, PA efficiency is constrained by the number of spontaneous decay channels linking the initial excited molecular state to a sea of final (meta)stable rovibronic levels. Here, we propose a novel scheme based on molecules strongly coupled to a guided photonic mode in a photonic crystal waveguide that turns PA into a powerful tool for near deterministic formation of ultracold molecules in their ground rovibrational level. Our example shows a potential ground state molecule production efficiency $> 90\%$, and a saturation rate $>10^6$ molecules per second. By combining state-of-the-art cold atomic and molecular physics with nanophotonic engineering, our scheme presents a novel experimental package for trapping, cooling, and optical manipulation of ultracold molecules, opening up new possibilities in the direction of ultracold chemistry and quantum information.

physics.atom-ph↗

arXiv2017

Lifetimes of ultralong-range strontium Rydberg molecules in a dense BEC

The lifetimes and decay channels of ultralong-range Rydberg molecules created in a dense BEC are examined by monitoring the time evolution of the Rydberg population using field ionization. Studies of molecules with values of principal quantum number, $n$, in the range $n=49$ to $n=72$ that contain tens to hundreds of ground state atoms within the Rydberg electron orbit show that their presence leads to marked changes in the field ionization characteristics. The Rydberg molecules have lifetimes of $\sim1-5\,μ$s, their destruction being attributed to two main processes: formation of Sr$^+_2$ ions through associative ionization, and dissociation induced through $L$-changing collisions. The observed loss rates are consistent with a reaction model that emphasizes the interaction between the Rydberg core ion and its nearest neighbor ground-state atom. The measured lifetimes place strict limits on the time scales over which studies involving Rydberg species in cold, dense atomic gases can be undertaken and limit the coherence times for such measurements.

physics.atom-ph↗

arXiv2013

How does a magnetic trap work?

Magnetic trapping is a cornerstone for modern ultracold physics and its applications (e.g., quantum information processing, quantum metrology, quantum optics, or high-resolution spectroscopies). Here a comprehensive analysis and discussion of the basic physics behind the most commonly used magnetic traps in Bose-Einstein condensation is presented. This analysis includes the quadrupole trap, the time-averaged orbiting potential trap, and the Ioffe-Pritchard trap. It is shown how the trapping conditions and efficiency of these devices can be determined from simple derivations based on classical electromagnetism, even though they operate on quantum objects.

cond-mat.quant-gas↗

arXiv2012

Temperature-independent quantum logic for molecular spectroscopy

We propose a fast and non-destructive spectroscopic method for single molecular ions that implements quantum logic schemes between an atomic ion and the molecular ion of interest. Our proposal relies on a hybrid coherent manipulation of the two-ion system, using optical or magnetic forces depending on the types of molecular levels to be addressed (Zeeman, rotational, vibrational or electronic degrees of freedom). The method is especially suited for the non-destructive precision spectroscopy of single molecular ions, and sets a starting point for new hybrid quantum computation schemes that combine molecular and atomic ions, covering the measurement and entangling steps.

quant-ph↗