arXiv subjects

J. P. Fonfría

Publications and source records attributed to J. P. Fonfría.

At least 19 recordsLinked to original sources

arXiv2026

The formation radius of HCN in O-rich asymptotic giant branch stars

Molecules detected in circumstellar envelopes around asymptotic giant branch (AGB) stars are generally well explained in terms of formation under chemical equilibrium in the stellar atmosphere or photochemistry in the outer expanding layers. However, several molecules are detected in the inner circumstellar regions with abundances orders of magnitude above the predictions of chemical equilibrium. Anomalously abundant molecules comprise H2O, NH3, SiH4, and PH3 in C-rich envelopes and HCN, CS, and NH3 in O-rich sources. These molecules are formed by some yet unknown nonequilibrium processes. Aims: We aim to shed light on the nonequilibrium process that enhances the abundance of anomalously abundant molecules in the inner regions of circumstellar envelopes. Here, we focus on HCN in O-rich stars to constrain its formation radius. Method: We observed the O-rich AGB stars RCrt and IKTau with ALMA at high angular resolution (HPBW=~0.05") in the J=4-3 line of HCN in both the ground and the ν_2=1 vibrational states. The radial distribution of the emission was modeled using a large velocity gradient radiative transfer code in which we considered an abundance profile with a central hole. Results: The models with a hole in the abundance distribution of HCN reproduce the specific shape of the radial emission distribution around the two studied O-rich stars. The best models locate the formation radius of HCN at 4-6 Rstar in RCrt and 3-5 Rstar in IKTau. Conclusion: The formation radius of HCN inferred from observations is consistent with models that invoke shocked-induced chemistry but also with models where photochemistry acts as the solely disequilibrium process. High angular resolution observations of more O-rich stars and tailored shocked-induced and/or photochemical models are needed to unambiguously unveil the underlying mechanism behind anomalously abundant molecules in AGB envelopes.

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arXiv2026

Detection of unidentified molecular pure rotational lines in C-rich PNe I. The fullerene-containing PN IC 418

Molecular emission is observed in a wide variety of astrophysical environments, yet a substantial fraction of spectral features detected at mm wavelengths remains unidentified. Identifying these features is essential for constraining the inventory of interstellar and circumstellar molecules and for understanding the chemical pathways operating in evolved stars. In this study, we investigate a set of weak unidentified molecular features detected in the C-rich PN IC 418. We aim to constrain the nature of their molecular carriers and assess their possible connection to fullerene-related chemistry. High-sensitivity observations at 2, 3, and 7 mm were carried out using the RT40m and IRAM 30m radio telescopes. The spectral features found in these data sets were compared with public molecular spectroscopic databases. Spectral-pattern searches and line fits were performed under linear, symmetric, and asymmetric rotor approximations to estimate rotational constants of potential molecular carriers. We report the detection of 20 weak (SNR~2-13) unidentified features (UFs), none of which can be attributed to mm radio recombination lines, instrumental artifacts, or known molecular species. The observed features are inconsistent with the regular line spacing expected from linear molecules or symmetric rotors, although a recurrent doublet-like pattern is identified. The estimated rotational constants (B~2 500-3 660 MHz) suggest carriers with 4-13 atoms and are incompatible with those expected from C60 derivatives (B~100 MHz). Non-planar carbonaceous molecules produced during the destruction/processing of hydrogenated amorphous carbon (HAC) grains are suggested as promising candidates. The catalog of UFs presented here is made publicly available to facilitate future comparisons with laboratory measurements and theoretical calculations aimed at identifying their molecular carriers.

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arXiv2026

Chemistry in the High expansion-velocity C-rich evolved star AFGL2233. Isotopic ratios, peculiarities and evolutionary status

High expansion velocity carbon stars (HVCs) are a rare class of evolved stars whose circumstellar envelopes (CSEs) combine C-rich chemistry with unusually high expansion velocities typical of O-rich massive evolved stars. AFGL2233 has been proposed as a high-mass evolved object that exhausted hot-bottom burning. Studying its chemistry is essential to understand the nature and evolution of these objects. We characterize the chemical composition and isotopic ratios of the CSE of AFGL2233 and investigate chemical peculiarities, including the presence of N- and O-bearing species in a C-rich environment. We carried out a complete line survey at 3 mm and 1 mm using the IRAM 30m telescope, complemented by Herschel/HIFI FIR observations and interferometric maps of SiO, C2H, and HCN. Molecular emission was analyzed using rotational diagrams and radiative transfer modeling under the LVG approximation. Column densities and fractional abundances were derived for more than 30 molecular species, including isotopologues, and compared with other evolved stars. The Gaia DR3 distance of 1.236 kpc implies a luminosity of ~2 Lsun, consistent with an initial mass of 4.5-9 Msun. The molecular inventory confirms C-rich chemistry but reveals unusually high abundances of NH3, H2O, and SiN. The isotopic ratios vary among species, with 12C/13C ranging from 7 to 55. The C2H/C4H ratio is abnormally high compared with C-rich AGB stars. The presence of SiN and high NH3 may indicate N-enrichment or the influence of a companion. AFGL2233 is likely a high-mass AGB or super-AGB star with a complex evolutionary history involving nucleosynthesis, shocks, and possible binary interaction.

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arXiv2025

Exploring circumstellar chemistry in X-ray emitting AGB stars

Aims. Our goal is to characterize the chemistry and physical conditions of the circumstellar envelopes (CSEs) of Asymptotic Giant Branch (AGB) binary candidate stars with UV-excess and X-ray emission, in particular, to identify the effects of the internal X-ray emission in the abundance of certain key molecules. Methods. We observed the 86.0-94.0 and 260.0-272.5 GHz spectral ranges searching for rotational transitions of the X-ray sensitive molecule $HCO^{+}$ in four AGB stars, two of them detected in both UV and X-ray emission and the other two detected only in UV. We derived the CSEs's physical parameters from previous CO observations and determined the molecular abundances of the detected species using radiative transfer models. We developed chemical kinetics models that account for the effects of internal X-ray emission (as well as UV radiation) and compared our predictions with observations. Results. We report the detection of $HCO^{+}$ in the X-ray emitting C-rich AGB T\,Dra, while it remains undetected in the spectra of the other three sources. In T\,Dra we also detect SiO, HCN, HNC, $HC_{3}N$, $SiC_{2}$, $C_{2}H$ and SiS. For the other targets only HCN and SiO are detected. The high fractional abundance of $HCO^{+}$ derived for T\,Dra ($[1.5-3.0]\times 10^{-8}$) is in good agreement with the predictions from our chemical kinetics models including the effects of internal X-ray emission, and one order of magnitude higher than the values expected for C-rich AGB stars. Additionally, we identify abundance enhancements for HNC, and $HC_{3}N$ alongside a depletion of CO in the innermost regions of T\,Dra's envelope. Conclusions. An internal X-ray source can significantly alter molecular abundances in AGB CSEs, enhancing $HCO^{+}$, $N_{2}H^{+}$, HNC, and $HC_{3}N$ while depleting parent species like CO. UV radiation has a weaker effect unless the envelope is optically thin or porous.

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arXiv2024

Atmospheric molecular blobs shape up circumstellar envelopes of AGB stars

During their thermally pulsing phase, Asymptotic Giant Branch (AGB) stars eject material that forms extended dusty envelopes. Visible polarimetric imaging found clumpy dust clouds within two stellar radii of several oxygen-rich stars. Inhomogeneous molecular gas has also been observed in multiple emission lines within several stellar radii of different oxygen rich stars, including W Hya and Mira. At the stellar surface level, infrared images have revealed intricate structures around the carbon semi-regular variable R Scl and in the S-type star $π^{\mathrm{1}}$ Gru. Infrared images have also shown clumpy dust structures within a few stellar radii of the prototypical carbon AGB star IRC+10216, and studies of the molecular gas distribution beyond the dust formation zone have also shown complex circumstellar structures. Because of the lack of sufficient spatial resolution, however, the distribution of molecular gas in the stellar atmosphere and the dust formation zone of AGB carbon stars is not known, nor is how it is subsequently expelled. Here we report observations with a resolution of one stellar radius of the recently formed dust and molecular gas in the atmosphere of IRC+10216. Lines of HCN, SiS, and SiC$_2$ appear at different radii and in different clumps, which we interpret as large convective cells in the photosphere, as seen in Betelgeuse. The convective cells coalesce with pulsation causing anisotropies that, together with companions, shape its circumstellar envelope.

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arXiv2023

Zooming on the emerging ionized regions of pPNe with ALMA

We report on recent results from our successful and pioneering observational program with ALMA to study emerging ultracom pact HII regions of pre-Planetary Nebulae (pPNe) using mm-wavelength recombination lines (mRRLs) as new optimal tracers. We focus on our study of two poster-child pPNe, namely, M2-9 and CRL618. We reveal the structure and kinematics of the en igmatic inner nebular regions of these objects with an unprecedented angular resolution down to 20-30mas (~15-30AU). For both targets, the ionized central regions are elongated along the main symmetry axis of the large-scale nebulae, consiste nt with bipolar winds, and show notable axial velocity gradients with expansion velocities of up to ~100km/s. The H30a pr ofiles exhibit time variability, reflecting changes in the physical properties and kinematics on scales of a few years. O ur ongoing analysis employs 3D, non-LTE radiative transfer modeling, providing a detailed description of the innermost la yers of these well known pPNe with exceptional clarity.

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arXiv2022

History of two mass loss processes in VY CMa. Fast outflows carving older ejecta

Red supergiant stars (RSGs, Minit = 10-40Msun) are known to eject large amounts of material, as much as half of their initial mass during this evolutionary phase. However, the processes powering the mass ejection in low- and intermediate-mass stars do not work for RSGs and the mechanism that drives the ejection remains unknown. Different mechanisms have been proposed as responsible for this mass ejection but so far little is known about the actual processes taking place in these objects. Here we present high angular resolution interferometric ALMA maps of VY CMa continuum and molecular emission, which resolve the structure of the ejecta with unprecedented detail. The study of the molecular emission from the ejecta around evolved stars has been shown to be an essential tool in determining the characteristics of the mass loss ejections. Our aim is thus to use the information provided by these observations to understand the ejections undergone by VY CMa and to determine their possible origins. We inspected the kinematics of molecular emission observed. We obtained position-velocity diagrams and reconstructed the 3D structure of the gas traced by the different species. It allowed us to study the morphology and kinematics of the gas traced by the different species surrounding VY CMa. Two types of ejecta are clearly observed: extended, irregular, and vast ejecta surrounding the star that are carved by localized fast outflows. The structure of the outflows is found to be particularly flat. We present a 3D reconstruction of these outflows and proof of the carving. This indicates that two different mass loss processes take place in this massive star. We tentatively propose the physical cause for the formation of both types of structures. These results provide essential information on the mass loss processes of RSGs and thus of their further evolution.

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arXiv2022

First detection of AlF line emission towards M-type AGB stars

The nucleosynthesis production of fluorine (F) is still a matter of debate. Asymptotic giant branch (AGB) stars are one of the main candidates for F production. However, their contribution to the total F budget is not fully known due to the lack of observations. In this paper, we report the detection of AlF line emission, one of the two main carriers of F in the gas-phase in the outflow of evolved stars, towards five nearby oxygen-rich AGB stars, $o$ Ceti, R Leo, IK Tau, R Dor, and W Hya. From spatially resolved observations, we estimated the AlF emitting region with a radius $\sim11R_{\star}$ for $o$ Ceti and $\sim9R_{\star}$ for R Leo. From population diagram analysis, we report the AlF column densities of $\sim 5.8\times10^{15}$ cm$^{-2}$ and $\sim 3\times10^{15}$ cm$^{-2}$ for $o$ Ceti and R Leo, respectively, within these regions. For $o$ Ceti, we used the C$^{18}$O ($v=0$, $J=3-2$) observations to estimate the H$_2$ column density of the emitting region. We found a fractional abundance of $f_{\rm AlF/H_2}\sim(2.5\pm1.7)\times10^{-8}$. This gives a lower limit on the F budget in $o$ Ceti and is compatible with the solar F budget $f_{\rm F/H_2}=(5\pm2)\times10^{-8}$. For R Leo, a fractional abundance $f_{\rm AlF/H_2}=(1.2\pm0.5)\times10^{-8}$ is estimated. For other sources, we cannot precisely determine the emitting region based on the available data. Assuming an emitting region with a radius of $\sim 11R_{\star}$ and the rotational temperatures derived for $o$ Ceti and R Leo, we crudely approximated the AlF column density to be $\sim(1.2-1.5)\times10^{15}$ cm$^{-2}$ in W Hya, $\sim(2.5-3.0)\times10^{14}$ cm$^{-2}$ in R Dor, and $\sim(0.6-1.0)\times10^{16}$ cm$^{-2}$ in IK Tau. These result in fractional abundances within a range of $f_{\rm AlF/H_2}\sim(0.1-4)\times10^{-8}$ in W Hya, R Dor, and IK Tau.

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arXiv2022

Detection of the S(1) Rotational Line of H2 toward IRC+10216: A Simultaneous Measurement of Mass-Loss Rate and CO Abundance

We report the first detection of the S(1) pure rotational line of ortho-H2 at 17.04 um in an asymptotic giant branch star, using observations of IRC+10216 with the Echelon-cross-echelle Spectrograph (EXES) mounted on the Stratospheric Observatory for Infrared Astronomy (SOFIA). This line, which was observed in a very high sensitivity spectrum (RMS noise ~0.04% of the continuum), was detected in the wing of a strong telluric line and displayed a P Cygni profile. The spectral ranges around the frequencies of the S(5) and S(7) ortho-H2 transitions were observed as well but no feature was detected in spectra with sensitivities of 0.12% and 0.09% regarding the continuum emission, respectively. We used a radiation transfer code to model these three lines and derived a mass-loss rate of 2.43(0.21)E-05 M_sun/yr without using the CO abundance. The comparison of this rate with previous estimates derived from CO observations suggests that the CO abundance relative to H2 is 6.7(1.4)E-04. From this quantity and previously reported molecular abundances, we estimate the O/H and C/H ratios to be 3.3(0.7)E-04 and >5.2(0.9)E-04, respectively. The C/O ratio is >1.5(0.4). The absence of the S(5) and S(7) lines of ortho-H2 in our observations can be explained by the opacity of hot dust within 5R* from the center of the star. We estimate the intensity of the S(0) and S(2) lines of para-H2 to be ~0.1% and 0.2% of the continuum, respectively, which are below the detection limit of EXES.

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arXiv2021

Magnesium radicals MgC$_5$N and MgC$_6$H in IRC+10216

After the previous discovery of MgC$_3$N and MgC$_4$H in IRC+10216, a deeper Q-band (31.0-50.3 GHz) integration on this source had revealed two additional series of harmonically related doublets that we assigned on the basis of quantum mechanical calculations to the larger radicals MgC$_5$N and MgC$_6$H. The results presented here extend and confirm previous results on magnesium-bearing molecules in IRC\,+10216. We derived column densities of (4.7$\pm$1.3)$\times$10$^{12}$ for MgC$_5$N and (2.0$\pm$0.9)$\times$10$^{13}$ for MgC$_6$H, which imply that MgC$_5$N/MgC$_3$N=0.5 and MgC$_6$H/MgC$_4$H = 0.9. Therefore, MgC$_5$N and MgC$_6$H are present with column densities not so different from those of the immediately shorter analogs. The synthesis of these large magnesium cyanides and acetylides in IRC+10216 can be explained for their shorter counterparts by a two-step process initiated by the radiative association of Mg$^+$ with large cyanopolyynes and polyynes, which are still quite abundant in this source, followed by the dissociative recombination of the ionic complexes.

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arXiv2021

Multi-frequency high spectral resolution observations of HCN toward the circumstellar envelope of Y CVn

High spectral resolution observations toward the low mass-loss rate C-rich, J-type AGB star Y CVn have been carried out at 7.5, 13.1 and 14.0 um with SOFIA/EXES and IRTF/TEXES. Around 130 HCN and H13CN lines of bands v2, 2v2, 2v2-v2, 3v2-2v2, 3v2-v2, and 4v2-2v2 have been identified involving lower levels with energies up to ~3900 K. These lines have been complemented with the pure rotational lines J=1-0 and 3-2 of the vibrational states up to 2v2 acquired with the IRAM 30 m telescope, and with the continuum taken with ISO. We have analyzed the data with a ro-vibrational diagram and a code which models the absorption and emission of the circumstellar envelope of an AGB star. The continuum is produced by the star with a small contribution from dust grains comprising warm to hot SiC and cold amorphous carbon. The HCN abundance distribution seems to be anisotropic. The ejected gas is accelerated up to the terminal velocity (~8 km/s) from the photosphere to ~3R* but there is evidence of higher velocities (>9-10 km/s) beyond this region. In the vicinity of Y CVn, the line widths are as high as ~10 km/s, which implies a maximum turbulent velocity of 6 km/s or the existence of other physical mechanisms probably related to matter ejection that involve higher gas expansion velocities than expected. HCN is rotationally and vibrationally out of LTE throughout the whole envelope. A difference of about 1500 K in the rotational temperature at the photosphere is needed to explain the observations at 7.5 and 13-14 um. Our analysis finds a total HCN column density that ranges from ~2.1E+18 to 3.5E+18 cm^{-2}, an abundance with respect to H2 of 3.5E-05 to 1.3E-04, and a 12C/13C isotopic ratio of ~2.5 throughout the whole envelope.

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arXiv2020

Detection of infrared fluorescence of carbon dioxide in R Leonis with SOFIA/EXES

We report on the detection of hot CO2 in the O-rich AGB star R Leo based on high spectral resolution observations in the range 12.8-14.3 um carried out with the Echelon-cross-Echelle Spectrograph (EXES) mounted on the Stratospheric Observatory for Infrared Astronomy (SOFIA). We have found ~240 CO2 emission lines in several vibrational bands. These detections were possible thanks to a favorable Doppler shift that allowed us to avoid contamination by telluric CO2 features. The highest excitation lines involve levels at an energy of ~7000 K. The detected lines are narrow (average deconvolved width ~2.5 km/s) and weak (usually <10% the continuum). A ro-vibrational diagram shows that there are three different populations, warm, hot, and very hot, with rotational temperatures of ~550, 1150, and 1600 K, respectively. From this diagram, we derive a lower limit for the column density of ~2.2E+16 cm^{-2}. Further calculations based on a model of the R Leo envelope suggest that the total column density can be as large as 7.0E+17 cm^{-2} and the abundance with respect to H2 ~2.5E-05. The detected lines are probably formed due to de-excitation of CO2 molecules from high energy vibrational states, which are essentially populated by the strong R Leo continuum at 2.7 and 4.2 um.

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arXiv2019

IRC+10216 mass loss properties through the study of $λ$3mm emission: Large spatial scale distribution of SiO, SiS, and CS

The study of the gas in the envelopes surrounding asymptotic giant branch (AGB) stars through observations in the millimetre wavelength range provides information about the history and nature of these molecular factories. Here we present ALMA observations at subarsecond resolution, complemented with IRAM-30m data, of several lines of SiO, SiS, and CS towards the best-studied AGB circumstellar envelope, IRC+10216. We aim to characterise their spatial distribution and determine their fractional abundances mainly through radiative transfer and chemical modelling. The three species display extended emission with several enhanced emission shells. CS displays the most extended distribution reaching distances up to approximately 20''. SiS and SiO emission have similar sizes of approximately 11'', but SiS emission is slightly more compact. We have estimated fractional abundances relative to H$_2$, which on average are equal to f(SiO)$\sim$10$^{-7}$, f(SiS)$\sim$10$^{-6}$, and f(CS)$\sim$10$^{-6}$ up to the photo-dissociation region. The observations and analysis presented here show evidence that the circumstellar material displays clear deviations from an homogeneous spherical wind, with clumps and low density shells that may allow UV photons from the interstellar medium (ISM) to penetrate deep into the envelope, shifting the photo-dissociation radius inwards. Our chemical model predicts photo-dissociation radii compatible with those derived from the observations, although it is unable to predict abundance variations from the starting radius of the calculations ($\sim$10$R_{*}$), which may reflect the simplicity of the model. We conclude that the spatial distribution of the gas proves the episodic and variable nature of the mass loss mechanism of IRC+10216, on timescales of hundreds of years.

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arXiv2019

Discovery of the first Ca-bearing molecule in space: CaNC

We report on the detection of calcium isocyanide, CaNC, in the carbon-rich evolved star IRC+10216. We derived a column density for this species of (2.0$\pm$0.5)$\times$10$^{11}$ cm$^{-2}$. Based on the observed line profiles and the modelling of its emission through the envelope, the molecule has to be produced in the intermediate and outer layers of the circumstellar envelope where other metal-isocyanides have previously been found in this source. The abundance ratio of CaNC relative to MgNC and FeCN is $\simeq$1/60 and $\simeq$1, respectively. We searched for the species CaF, CaCl, CaC, CaCCH, and CaCH$_3$ for which accurate frequency predictions are available. Only upper limits have been obtained for these molecules.

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arXiv2019

Astro2020 Science White Paper: The fundamentals of outflows from evolved stars

Models of the chemical evolution of the interstellar medium, galaxies, and the Universe rely on our understanding of the amounts and chemical composition of the material returned by stars and supernovae. Stellar yields are obtained from stellar-evolution models, which currently lack predictive prescriptions of stellar mass loss, although it significantly affects stellar lifetimes, nucleosynthesis, and chemical ejecta. Galaxy properties are derived from observations of the integrated light of bright member stars. Stars in the late stages of their evolution are among the infrared-brightest objects in galaxies. An unrealistic treatment of the mass-loss process introduces significant uncertainties in galaxy properties derived from their integrated light. We describe current efforts and future needs and opportunities to characterize AGB outflows: driving mechanisms, outflow rates, underlying fundamental physical and chemical processes such as dust grain formation, and dependency of these on metallicity.

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arXiv2019

Gas infall and possible circumstellar rotation in R Leo

We present new interferometer molecular observations of R Leo taken at 1.2 mm with the Atacama Large Millimeter Array with an angular resolution up to ~0.026 arcsec. These observations permit us to resolve the innermost envelope of this star revealing the existence of a complex structure that involves extended continuum emission and molecular emission showing a non-radial gas velocity distribution. This molecular emission displays prominent red-shifted absorptions located right in front to the star typical of material infall and lateral gas motions compatible with the presence of a torus-like structure.

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arXiv2018

The maser emitting structure and time variability of the SiS lines J=14-13 and 15-14 in IRC+10216

We present new high angular resolution interferometer observations of the v=0 J=14-13 and 15-14 SiS lines towards IRC+10216, carried out with CARMA and ALMA. The maps, with angular resolutions of ~0.25"and 0.55", reveal (1) an extended, roughly uniform, and weak emission with a size of ~0.5", (2) a component elongated approximately along the East-West direction peaking at ~0.13" and 0.17" at both sides of the central star, and (3) two blue- and red-shifted compact components peaking around 0.07" to the NW of the star. We have modeled the emission with a 3D radiation transfer code finding that the observations cannot be explained only by thermal emission. Several maser clumps and one arc-shaped maser feature arranged from 5 to 20R* from the central star, in addition to a thin shell-like maser structure at ~13R* are required to explain the observations. This maser emitting set of structures accounts for 75% of the total emission while the other 25% is produced by thermally excited molecules. About 60% of the maser emission comes from the extended emission and the rest from the set of clumps and the arc. The analysis of a time monitoring of these and other SiS and 29SiS lines carried out with the IRAM 30m telescope from 2015 to present suggests that the intensity of some spectral components of the maser emission strongly depends on the stellar pulsation while other components show a mild variability. This monitoring evidences a significant phase lag of ~0.2 between the maser and NIR light-curves.

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arXiv2018

The Abundance of SiC2 in Carbon Star Envelopes: Evidence that SiC2 is a gas-phase precursor of SiC dust

Silicon carbide dust is ubiquitous in circumstellar envelopes around C-rich AGB stars. However, the main gas-phase precursors leading to the formation of SiC dust have not yet been identified. The most obvious candidates among the molecules containing an Si--C bond detected in C-rich AGB stars are SiC2, SiC, and Si2C. We aim to study how widespread and abundant SiC2, SiC, and Si2C are in envelopes around C-rich AGB stars and whether or not these species play an active role as gas-phase precursors of silicon carbide dust in the ejecta of carbon stars. We carried out sensitive observations with the IRAM 30m telescope of a sample of 25 C-rich AGB stars to search for emission lines of SiC2, SiC, and Si2C in the 2 mm band. We performed non-LTE excitation and radiative transfer calculations based on the LVG method to model the observed lines of SiC2 and to derive SiC2 fractional abundances in the observed envelopes. We detect SiC2 in most of the sources, SiC in about half of them, and do not detect Si2C in any source, at the exception of IRC +10216. Most of these detections are reported for the first time in this work. We find a positive correlation between the SiC and SiC2 line emission, which suggests that both species are chemically linked, the SiC radical probably being the photodissociation product of SiC2 in the external layer of the envelope. We find a clear trend in which the denser the envelope, the less abundant SiC2 is. The observed trend is interpreted as an evidence of efficient incorporation of SiC2 onto dust grains, a process which is favored at high densities owing to the higher rate at which collisions between particles take place. The observed behavior of a decline in the SiC2 abundance with increasing density strongly suggests that SiC2 is an important gas-phase precursor of SiC dust in envelopes around carbon stars.

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