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J. R. Dorfman

Publications and source records attributed to J. R. Dorfman.

At least 37 records · Page 2Linked to original sources

Entropy Production, Fractals, and Relaxation to Equilibrium

The theory of entropy production in nonequilibrium, Hamiltonian systems, previously described for steady states using partitions of phase space, is here extended to time dependent systems relaxing to equilibrium. We illustrate the main ideas by using a simple multibaker model, with some nonequilibrium initial state, and we study its progress toward equilibrium. The central results are (i) the entropy production is governed by an underlying, exponentially decaying fractal structure in phase space, (ii) the rate of entropy production is largely independent of the scale of resolution used in the partitions, and (iii) the rate of entropy production is in agreement with the predictions of nonequilibrium thermodynamics.

nlin.CD↗

Chaotic Properties of Dilute Two and Three Dimensional Random Lorentz Gases II: Open Systems

We calculate the spectrum of Lyapunov exponents for a point particle moving in a random array of fixed hard disk or hard sphere scatterers, i.e. the disordered Lorentz gas, in a generic nonequilibrium situation. In a large system which is finite in at least some directions, and with absorbing boundary conditions, the moving particle escapes the system with probability one. However, there is a set of zero Lebesgue measure of initial phase points for the moving particle, such that escape never occurs. Typically, this set of points forms a fractal repeller, and the Lyapunov spectrum is calculated here for trajectories on this repeller. For this calculation, we need the solution of the recently introduced extended Boltzmann equation for the nonequilibrium distribution of the radius of curvature matrix and the solution of the standard Boltzmann equation. The escape-rate formalism then gives an explicit result for the Kolmogorov Sinai entropy on the repeller.

nlin.CD↗

Fractal Dimensions of the Hydrodynamic Modes of Diffusion

We consider the time-dependent statistical distributions of diffusive processes in relaxation to a stationary state for simple, two dimensional chaotic models based upon random walks on a line. We show that the cumulative functions of the hydrodynamic modes of diffusion form fractal curves in the complex plane, with a Hausdorff dimension larger than one. In the limit of vanishing wavenumber, we derive a simple expression of the diffusion coefficient in terms of this Hausdorff dimension and the positive Lyapunov exponent of the chaotic model.

nlin.CD↗

On thermostats and entropy production

The connection between the rate of entropy production and the rate of phase space contraction for thermostatted systems in nonequilibrium steady states is discussed for a simple model of heat flow in a Lorentz gas, previously described by Spohn and Lebowitz. It is easy to show that for the model discussed here the two rates are not connected, since the rate of entropy production is non-zero and positive, while the overall rate of phase space contraction is zero. This is consistent with conclusions reached by other workers. Fractal structures appear in the phase space for this model and their properties are discussed. We conclude with a discussion of the implications of this and related work for understanding the role of chaotic dynamics and special initial conditions for an explanation of the Second Law of Thermodynamics.

nlin.CD↗

Entropy Production in a Persistent Random Walk

We consider a one-dimensional persisent random walk viewed as a deterministic process with a form of time reversal symmetry. Particle reservoirs placed at both ends of the system induce a density current which drives the system out of equilibrium. The phase space distribution is singular in the stationary state and has a cumulative form expressed in terms of generalized Takagi functions. The entropy production rate is computed using the coarse-graining formalism of Gaspard, Gilbert and Dorfman. In the continuum limit, we show that the value of the entropy production rate is independent of the coarse-graining and agrees with the phenomenological entropy production rate of irreversible thermodynamics.

nlin.CD↗

Kinetic Theory Estimates for the Kolmogorov-Sinai Entropy and the Largest Lyapunov Exponents for Dilute, Hard-Ball Gases and for Dilute, Random Lorentz Gases

The kinetic theory of gases provides methods for calculating Lyapunov exponents and other quantities, such as Kolmogorov-Sinai entropies, that characterize the chaotic behavior of hard-ball gases. Here we illustrate the use of these methods for calculating the Kolmogorov-Sinai entropy, and the largest positive Lyapunov exponent, for dilute hard-ball gases in equilibrium. The calculation of the largest Lyapunov exponent makes interesting connections with the theory of propagation of hydrodynamic fronts. Calculations are also presented for the Lyapunov spectrum of dilute, random Lorentz gases in two and three dimensions, which are considerably simpler than the corresponding calculations for hard-ball gases. The article concludes with a brief discussion of some interesting open problems.

chao-dyn↗

Long-time-tail Effects on Lyapunov Exponents of a Random, Two-dimensional Field-driven Lorentz Gas

We study the Lyapunov exponents for a moving, charged particle in a two-dimensional Lorentz gas with randomly placed, non-overlapping hard disk scatterers placed in a thermostatted electric field, $\vec{E}$. The low density values of the Lyapunov exponents have been calculated with the use of an extended Lorentz-Boltzmann equation. In this paper we develop a method to extend these results to higher density, using the BBGKY hierarchy equations and extending them to include the additional variables needed for calculation of Lyapunov exponents. We then consider the effects of correlated collision sequences, due to the so-called ring events, on the Lyapunov exponents. For small values of the applied electric field, the ring terms lead to non-analytic, field dependent, contributions to both the positive and negative Lyapunov exponents which are of the form ${\tildeε}^{2} \ln\tildeε$, where $\tildeε$ is a dimensionless parameter proportional to the strength of the applied field. We show that these non-analytic terms can be understood as resulting from the change in the collision frequency from its equilibrium value, due to the presence of the thermostatted field, and that the collision frequency also contains such non-analytic terms.

cond-mat.stat-mech↗

Kinetic Theory of Dynamical Systems

It is generally believed that the dynamics of simple fluids can be considered to be chaotic, at least to the extent that they can be modeled as classical systems of particles interacting with short range, repulsive forces. Here we give a brief introduction to those parts of chaos theory that are relevant for understanding some features of non-equilibrium processes in fluids. We introduce the notions of Lyapunov exponents, Kolmogorov-Sinai entropy and related quantities using some simple low-dimensional systems as "toy" models of the more complicated systems encountered in the study of fluids. We then show how familiar methods used in the kinetic theory of gases can be employed for explicit, analytical calculations of the largest Lyapunov exponent and KS entropy for dilute gases composed of hard spheres in d dimensions. We conclude with a brief discussion of interesting, open problems.

chao-dyn↗

Entropy Production : From Open Volume Preserving to Dissipative Systems

We generalize Gaspard's method for computing the ε-entropy production rate in Hamiltonian systems to dissipative systems with attractors considered earlier by Tél, Vollmer, and Breymann. This approach leads to a natural definition of a coarse grained Gibbs entropy which is extensive, and which can be expressed in terms of the SRB measures and volumes of the coarse graining sets which cover the attractor. One can also study the entropy and entropy production as functions of the degree of resolution of the coarse graining process, and examine the limit as the coarse graining size approaches zero. We show that this definition of the Gibbs entropy leads to a positive rate of irreversible entropy production for reversible dissipative systems. We apply the method to the case of a two dimensional map, based upon a model considered by Vollmer, Tél and Breymann, that is a deterministic version of a biased-random walk. We treat both volume preserving and dissipative versions of the basic map, and make a comparison between the two cases. We discuss the ε-entropy production rate as a function of the size of the coarse graining cells for these biased-random walks and, for an open system with flux boundary conditions, show regions of exponential growth and decay of the rate of entropy production as the size of the cells decreases. This work describes in some detail the relation between the results of Gaspard, those of Tél, Vollmer and Breymann, and those of Ruelle, on entropy production in various systems described by Anosov or Anosov-like maps.

chao-dyn↗

Field Driven Thermostated System : A Non-Linear Multi-Baker Map

In this paper, we discuss a simple model for a field driven, thermostated random walk that is constructed by a suitable generalization of a multi-baker map. The map is a usual multi-baker, but perturbed by a thermostated external field that has many of the properties of the fields used in systems with Gaussian thermostats. For small values of the driving field, the map is hyperbolic and has a unique SRB measure that we solve analytically to first order in the field parameter. We then compute the positive and negative Lyapunov exponents to second order and discuss their relation to the transport properties. For higher values of the parameter, this system becomes non-hyperbolic and posseses an attractive fixed point.

chao-dyn↗

Simple deterministic dynamical systems with fractal diffusion coefficients

We analyze a simple model of deterministic diffusion. The model consists of a one-dimensional periodic array of scatterers in which point particles move from cell to cell as defined by a piecewise linear map. The microscopic chaotic scattering process of the map can be changed by a control parameter. This induces a parameter dependence for the macroscopic diffusion coefficient. We calculate the diffusion coefficent and the largest eigenmodes of the system by using Markov partitions and by solving the eigenvalue problems of respective topological transition matrices. For different boundary conditions we find that the largest eigenmodes of the map match to the ones of the simple phenomenological diffusion equation. Our main result is that the difffusion coefficient exhibits a fractal structure by varying the system parameter. To understand the origin of this fractal structure, we give qualitative and quantitative arguments. These arguments relate the sequence of oscillations in the strength of the parameter-dependent diffusion coefficient to the microscopic coupling of the single scatterers which changes by varying the control parameter.

chao-dyn↗

An Analytical Construction of the SRB Measures for Baker-type Maps

For a class of dynamical systems, called the axiom-A systems, Sinai, Ruelle and Bowen showed the existence of an invariant measure (SRB measure) weakly attracting the temporal average of any initial distribution that is absolutely continuous with respect to the Lebesgue measure. Recently, the SRB measures were found to be related to the nonequilibrium stationary state distribution functions for thermostated or open systems. Inspite of the importance of these SRB measures, it is difficult to handle them analytically because they are often singular functions. In this article, for three kinds of Baker-type maps, the SRB measures are analytically constructed with the aid of a functional equation, which was proposed by de Rham in order to deal with a class of singular functions. We first briefly review the properties of singular functions including those of de Rham. Then, the Baker-type maps are described, one of which is non-conservative but time reversible, the second has a Cantor-like invariant set, and the third is a model of a simple chemical reaction $R \leftrightarrow I \leftrightarrow P$. For the second example, the cases with and without escape are considered. For the last example, we consider the reaction processes in a closed system and in an open system under a flux boundary condition. In all cases, we show that the evolution equation of the distribution functions partially integrated over the unstable direction is very similar to de Rham's functional equation and, employing this analogy, we explicitly construct the SRB measures.

chao-dyn↗

B. B. G. K. Y. Hierarchy Methods for Sums of Lyapunov Exponents for Dilute Gases

We consider a general method for computing the sum of positive Lyapunov exponents for moderately dense gases. This method is based upon hierarchy techniques used previously to derive the generalized Boltzmann equation for the time dependent spatial and velocity distribution functions for such systems. We extend the variables in the generalized Boltzmann equation to include a new set of quantities that describe the separation of trajectories in phase space needed for a calculation of the Lyapunov exponents. The method described here is especially suitable for calculating the sum of all of the positive Lyapunov exponents for the system, and may be applied to equilibrium as well as non-equilibrium situations. For low densities we obtain an extended Boltzmann equation, from which, under a simplifying approximation, we recover the sum of positive Lyapunov exponents for hard disk and hard sphere systems, obtained before by a simpler method. In addition we indicate how to improve these results by avoiding the simplifying approximation. The restriction to hard sphere systems in $d$-dimensions is made to keep the somewhat complicated formalism as clear as possible, but the method can be easily generalized to apply to gases of particles that interact with strong short range forces.

chao-dyn↗

Deterministic Chaos and the Foundations of the Kinetic Theory of Gases

Recent work in dynamical systems theory has shown that many properties that are associated with irreversible processes in fluids can be understood in terms of the dynamical properties of reversible, Hamiltonian systems. That is, stochastic-like behavior is possible for these systems. Here we review the basic theory for this stochastic-like behavior and show how it may be used to obtain an understanding of irreversible processes in gases and fluids. Recent, closely related, work on the use of kinetic theory to calculate dynamical quantities such as Lyapunov exponents is also discussed.

chao-dyn↗

Chaotic Properties of Dilute Two and Three Dimensional Random Lorentz Gases I: Equilibrium Systems

We compute the Lyapunov spectrum and the Kolmogorov-Sinai entropy for a moving particle placed in a dilute, random array of hard disk or hard sphere scatterers - i.e. the dilute Lorentz gas model. This is carried out in two ways: First we use simple kinetic theory arguments to compute the Lyapunov spectrum for both two and three dimensional systems. In order to provide a method that can easily be generalized to non-uniform systems we then use a method based upon extensions of the Lorentz-Boltzmann (LB) equation to include variables that characterize the chaotic behavior of the system. The extended LB equations depend upon the number of dimensions and on whether one is computing positive or negative Lyapunov exponents. In the latter case the extended LB equation is closely related to an "anti-Lorentz-Boltzmann equation" where the collision operator has the opposite sign from the ordinary LB equation. Finally we compare our results with computer simulations of Dellago and Posch and find very good agreement.

chao-dyn↗

The Kolmogorov-Sinai Entropy for Dilute Gases in Equilibrium

We use the kinetic theory of gases to compute the Kolmogorov-Sinai entropy per particle for a dilute gas in equilibrium. For an equilibrium system, the KS entropy, h_KS is the sum of all of the positive Lyapunov exponents characterizing the chaotic behavior of the gas. We compute h_KS/N, where N is the number of particles in the gas. This quantity has a density expansion of the form h_KS/N = aν[-\ln{\tilde{n}} + b + O(\tilde{n})], where νis the single-particle collision frequency and \tilde{n} is the reduced number density of the gas. The theoretical values for the coefficients a and b are compared with the results of computer simulations, with excellent agreement for a, and less than satisfactory agreement for b. Possible reasons for this difference in b are discussed.

chao-dyn↗

Thermodynamic formalism and localization in Lorentz gases and hopping models

The thermodynamic formalism expresses chaotic properties of dynamical systems in terms of the Ruelle pressure $ψ(β)$. The inverse-temperature like variable $β$ allows one to scan the structure of the probability distribution in the dynamic phase space. This formalism is applied here to a Lorentz Lattice Gas, where a particle moving on a lattice of size $L^d$ collides with fixed scatterers placed at random locations. Here we give rigorous arguments that the Ruelle pressure in the limit of infinit e systems has two branches joining with a slope discontinuity at $β= 1$. The low and high $β$--branches correspond to localization of trajectories on respectively the ``most chaotic'' (highest density) region, and the ``most deterministic'' (lowest density) region, i.e. $ψ(β)$ is completely controlled by rare fluctuations in the distribution of scatterers on the lattice, and it does not carry any information on the global structure of the static disorder. As $β$ approaches unity from either side, a localization-delocalization transition leads to a state where trajectories are extended and carry information on transport properties. At finite $L$ the narrow region around $β= 1$ where the trajectories are extended scales as $(\ln L)^{-α}$, where $α$ depends on the sign of $1-β$, if $d>1$, and as $(L\ln L)^{-1}$ if $d=1$. This result appears to be general for diffusive systems with static disorder, such as random walks in random environments or for the continuous Lorentz gas. Other models of random walks on disordered lattices, showing the same phenomenon, are discussed.

chao-dyn↗

Backscattering-Induced Crossover in Deterministic Diffusion

We study diffusion in a one-dimensional periodic array of scatterers modeled by a simple map. The chaotic scattering process for this map can be changed by a control parameter and exhibits the dynamics of a crisis in chaotic scattering. We show that the strong backscattering associated with the crisis mechanism induces a crossover which leads to different asymptotic laws for the parameter-dependent diffusion coefficient. These laws are obtained from exact diffusion coefficient results and are supported by simple random walk models. We argue that the main physical feature of the crossover should be present in many other dynamical systems with non-equilibrium transport.

chao-dyn↗