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J. V. Sengers

Publications and source records attributed to J. V. Sengers.

24 records · Page 2Linked to original sources
arXiv2002

Dynamic Crossover to Tricriticality and Anomalous Slowdown of Critical Fluctuations by Entanglements in Polymer Solutions

We have performed accurate dynamic light-scattering measurements near critical demixing points of solutions of polystyrene in cyclohexane with polymer molecular weight ranging from 200,000 to 11.4 million. Two dynamic modes have been observed, ''slow'' and ''fast'', that result from a coupling between diffusive relaxation of critical fluctuations of the concentration and visco-elastic relaxation associated with the entanglement network of the polymer chains. The coupling with the visco-elastic mode causes an additional slowdown of the critical mode on top of the uncoupled diffusion mode. By implementing crossover from critical to theta-point tricritical behavior for both static and dynamic properties, we are able to present a quantitative description of the phenomenon and to obtain a scaling of the visco-elastic parameters as a function of the molecular weight.

cond-mat.soft↗
arXiv2002

Competition of Mesoscales and Crossover to Tricriticality in Polymer Solutions

We show that the approach to asymptotic fluctuation-induced critical behavior in polymer solutions is governed by a competition between a correlation length diverging at the critical point and an additional mesoscopic length-scale, the radius of gyration. Accurate light-scattering experiments on polystyrene solutions in cyclohexane with polymer molecular weights ranging from 200,000 up to 11.4 million clearly demonstrate a crossover between two universal regimes: a regime with Ising asymptotic critical behavior, where the correlation length prevails, and a regime with tricritical theta-point behavior determined by a mesoscopic polymer-chain length.

cond-mat.soft↗
arXiv2001

Long-Time Tails, Weak Localization, and Classical and Quantum Critical Behavior

An overview is given of the long-time and long-distance behavior of correlation functions in both classical and quantum statistical mechanics. After a simple derivation of the classical long-time tails in equilibrium time correlation functions, we discuss analogous long-distance phenomena in nonequilibrium classical systems. The paper then draws analogies between these phenomena and similar effects in quantum statistical mechanics, with emphasis on the soft modes that underly long-time tails and related phenomena. We also elucidate the interplay between critical phenomena and long-time tails, using the classical liquid-gas critical point and the quantum ferromagnetic transition as examples.

cond-mat.stat-mech↗
arXiv2001

Fluctuations in fluids in thermal nonequilibrium states below the convective Rayleigh-Benard instability

Starting from the linearized fluctuating Boussinesq equations we derive an expression for the structure factor of fluids in stationary convection-free thermal nonequilibrium states, taking into account both gravity and finite-size effects. It is demonstrated how the combined effects of gravity and finite size causes the structure factor to go through a maximum value as a function of the wave number $q$. The appearance of this maximum is associated with a crossover from a $q^{-4}$ dependence for larger $q$ to a $q^2$ dependence for very small $q$. The relevance of this theoretical result for the interpretation of light scattering and shadowgraph experiments is elucidated. The relationship with studies on various aspects of the problem by other investigators is discussed. The paper thus provides a unified treatment for dealing with fluctuations in fluid layers subjected to a stationary temperature gradient regardless of the sign of the Rayleigh number $R$, provided that $R$ is smaller than the critical value $R_\mathrm{c}$ associated with the appearance of Rayleigh-Bénard convection.

cond-mat.stat-mech↗
arXiv2000

Light Scattering from Nonequilibrium Concentration Fluctuations in a Polymer solution

We have performed light-scattering measurements in dilute and semidilute polymer solutions of polystyrene in toluene when subjected to stationary temperature gradients. Five solutions with concentrations below and one solution with a concentration above the overlap concentration were investigated. The experiments confirm the presence of long-range nonequilibrium concentration fluctuations which are proportional to $(\nabla T)^2/k^4$, where $\nabla T$ is the applied temperature gradient and $k$ is the wave number of the fluctuations. In addition, we demonstrate that the strength of the nonequilibrium concentration fluctuations, observed in the dilute and semidilute solution regime, agrees with theoretical values calculated from fluctuating hydrodynamics. Further theoretical and experimental work will be needed to understand nonequilibrium fluctuations in polymer solutions at higher concentrations.

cond-mat.soft↗