arXiv subjects

J. Vollmer

Publications and source records attributed to J. Vollmer.

9 recordsLinked to original sources

arXiv2021

Universality of breath figures on two-dimensional surfaces: an experimental study

Droplet condensation on surfaces produces patterns, called breath figures. Their evolution into self-similar structures is a classical example of self-organization. It is described by a scaling theory with scaling functions whose universality has recently been challenged by numerical work. Here, we provide a thorough experimental testing, where we inspect substrates with vastly different chemical properties, stiffness, and condensation rates. We critically survey the size distributions, and the related time-asymptotic scaling of droplet number and surface coverage. In the time-asymptotic regime they admit a data collapse: the data for all substrates and condensation rates lie on universal scaling functions.

cond-mat.soft↗

arXiv2018

Characterizing the Nature of the Yielding Transition

Particulate matter, such as foams, emulsions, and granular materials, attain rigidity in a dense regime: the rigid phase can yield when a threshold force is applied. The rigidity transition in particulate matter exhibits {\it bona fide} scaling behavior near the transition point. However, a precise determination of exponents describing the rigidity transition has raised much controversy. Here, we pinpoint the causes of the controversies. We then establish a conceptual framework to quantify the critical nature of the yielding transition. Our results demonstrate that there is a spectrum of possible values for the critical exponents for which, without a robust framework, one cannot distinguish the genuine values of the exponents. Our approach is two-fold: ({\it i}) a precise determination of the transition density using rheological measurements and ({\it ii}) a matching rule that selects the critical exponents and rules out all other possibilities from the spectrum. This enables us to determine exponents with unprecedented accuracy and resolve the long-standing controversy over exponents of jamming. The generality of the approach paves the way to quantify the critical nature of many other types of rheological phase transitions such as those in oscillatory shearing.

cond-mat.soft↗

arXiv2017

Characterizing rare fluctuations in soft particulate flows

Soft particulate media include a wide range of systems involving athermal dissipative particles both in non-living and biological materials. Characterization of flows of particulate media is of great practical and theoretical importance. A fascinating feature of these systems is the existence of a critical rigidity transition in the dense regime dominated by highly intermittent fluctuations that severely affects the flow properties. Here, we unveil the underlying mechanisms of rare fluctuations in soft particulate flows. We find that rare fluctuations have different origins above and below the critical jamming density and become suppressed near the jamming transition. We then conjecture a time-independent local fluctuation relation, which we verify numerically, and that gives rise to an effective temperature. We discuss similarities and differences between our proposed effective temperature with the conventional kinetic temperature in the system by means of a universal scaling collapse.

cond-mat.stat-mech↗

arXiv2015

Impact of microphysics on the growth of one-dimensional breath figures

Droplet patterns condensing on solid substrates (breath figures) tend to evolve into a self-similar regime, characterized by a bimodal droplet size distribution. The distributions comprise a bell-shaped peak of monodisperse large droplets, and a broad range of smaller droplets. The size distribution of the latter follows a scaling law characterized by a non-trivial polydispersity exponent. We present here a numerical model for three-dimensional droplets on a one-dimensional substrate (fiber) that accounts for droplet nucleation, growth and merging. The polydispersity exponent retrieved using this model is not universal. Rather it depends on the thickness of the fiber and on details of the droplet interaction leading to merging. In addition, its values consistently differ from the theoretical prediction by Blackman (Phys. Rev. Lett., 2000). Possible causes of this discrepancy are pointed out.

physics.flu-dyn↗

arXiv2015

Arrest stress of uniformly sheared wet granular matter

We conduct extensive independent numerical experiments considering frictionless disks without internal degrees of freedom (rotation etc.) in two dimensions. We report here that for a large range of the packing fractions below random-close packing, all components of the stress tensor of wet granular materials remain finite in the limit of zero shear rate. This is direct evidence for a fluid-to-solid arrest transition. The offset value of the shear stress characterizes plastic deformation of the arrested state {which corresponds to {\em dynamic yield stress} of the system}. {Based on an analytical line of argument, we propose that the mean number of capillary bridges per particle, $ν$, follows a non-trivial dependence on the packing fraction, $ϕ$, and the capillary energy, $\vareps$. Most noticeably, we show that $ν$ is a generic and universal quantity which does not depend on the driving protocol.} Using this universal quantity, we calculate the arrest stress, $σ_a$, analytically based on a balance of the energy injection rate due to the external force driving the flow and the dissipation rate accounting for the rupture of capillary bridges. The resulting prediction of $σ_a$ is a non-linear function of the packing fraction $ϕ$, and the capillary energy $\vareps$. This formula provides an excellent, parameter-free prediction of the numerical data. Corrections to the theory for small and large packing fractions are connected to the emergence of shear bands and of contributions to the stress from repulsive particle interactions, respectively.

cond-mat.soft↗

arXiv2014

Ripening and Focusing of Aggregate Size Distributions with Overall Volume Growth

We explore the evolution of the aggregate size distribution in systems where aggregates grow by diffusive accretion of mass. Supersaturation is controlled in such a way that the overall aggregate volume grows linearly in time. Classical Ostwald ripening, which is recovered in the limit of vanishing overall growth, constitutes an unstable solution of the dynamics. In the presence of overall growth evaporation of aggregates always drives the dynamics into a new, qualitatively different growth regime where ripening ceases, and growth proceeds at a constant number density of aggregates. We provide a comprehensive description of the evolution of the aggregate size distribution in the constant density regime: the size distribution does not approach a universal shape, and even for moderate overall growth rates the standard deviation of the aggregate radius decays monotonically. The implications of this theory for the focusing of aggregate size distributions are discussed for a range of different settings including the growth of tiny rain droplets in clouds, as long as they do not yet feel gravity, and the synthesis of nano-particles and quantum dots.

cond-mat.stat-mech↗

arXiv2012

Direct measurement of yield stress of discrete materials

We present a novel computational method for direct measurement of yield stress of discrete materials. The method is well-suited for the measurement of jamming phase diagram of a wide range of discrete particle systems such as granular materials, foams, and colloids. We further successfully apply the method to evaluate the jamming phase diagram of wet granular material in order to demonstrates the applicability of the model.

cond-mat.soft↗

arXiv2008

Basin boundary, edge of chaos, and edge state in a two-dimensional model

In shear flows like pipe flow and plane Couette flow there is an extended range of parameters where linearly stable laminar flow coexists with a transient turbulent dynamics. When increasing the amplitude of a perturbation on top of the laminar flow, one notes a a qualitative change in its lifetime, from smoothly varying and short one on the laminar side to sensitively dependent on initial conditions and long on the turbulent side. The point of transition defines a point on the edge of chaos. Since it is defined via the lifetimes, the edge of chaos can also be used in situations when the turbulence is not persistent. It then generalises the concept of basin boundaries, which separate two coexisting attractors, to cases where the dynamics on one side shows transient chaos and almost all trajectories eventually end up on the other side. In this paper we analyse a two-dimensional map which captures many of the features identified in laboratory experiments and direct numerical simulations of hydrodynamic flows. The analysis of the map shows that different dynamical situations in the edge of chaos can be combined with different dynamical situations in the turbulent region. Consequently, the model can be used to develop and test further characterisations that are also applicable to realistic flows.

nlin.CD↗

arXiv2003

Phase Separation in Binary Fluid Mixtures with Continuously Ramped Temperature

We consider the demixing of a binary fluid mixture, under gravity, which is steadily driven into a two phase region by slowly ramping the temperature. We assume, as a first approximation, that the system remains spatially isothermal, and examine the interplay of two competing nonlinearities. One of these arises because the supersaturation is greatest far from the meniscus, creating inversion of the density which can lead to fluid motion; although isothermal, this is somewhat like the Benard problem (a single-phase fluid heated from below). The other is the intrinsic diffusive instability which results either in nucleation or in spinodal decomposition at large supersaturations. Experimental results on a simple binary mixture show interesting oscillations in heat capacity and optical properties for a wide range of ramp parameters. We argue that these oscillations arise under conditions where both nonlinearities are important.

cond-mat.soft↗