arXiv subjects

Jai Singh

Publications and source records attributed to Jai Singh.

5 recordsLinked to original sources

arXiv2026

Spinel Ferrite-Based Materials for Electrochemical Applications: Synthesis, Applications, and Future Perspectives

Spinel ferrites have shown wide range of applications in various fields, including supercapacitors, Li-ion batteries, water splitting, chemical sensors, catalytic activity, high-frequency magnetic devices, and biomedical, hyperthermia, drug delivery applications., etc. This review focuses on the latest progress and trends on design of spinel ferrites (MFe2O4; M = Divalent transition metal ion) based materials for electrochemical applications. Spinel ferrites exhibit good chemical stability, high surface area and excellent electrochemical behaviour with their multiple oxidation states, making them suitable for the detection of a wide range of gaseous analytes including volatile organic compounds, heavy metal ions, biomolecules, and environmental pollutants. It also makes spinel ferrites a great choice for efficient energy storage and utility in supercapacitors. The electrochemical performance of spinel ferrite-based electrode materials can be effectively tuned via morphology control, incorporation of carbon-based materials, compositional substitution, doping and forming composition systems, especially in nanostructured form. This review will serve as a comprehensive resource for researchers interested in the synthesis and various enhancement techniques for electrode material composition of electrochemical device applications specifically, gas sensors and supercapacitors, which are two of the highest emerging functional applications for the new sustainability directed world, utilizing these advanced materials.

cond-mat.mtrl-sci↗

arXiv2025

TeamCMU at Touché: Adversarial Co-Evolution for Advertisement Integration and Detection in Conversational Search

As conversational search engines increasingly adopt generation-based paradigms powered by Large Language Models (LLMs) and Retrieval-Augmented Generation (RAG), the integration of advertisements into generated responses presents both commercial opportunities and challenges for user experience. Unlike traditional search, where advertisements are clearly delineated, generative systems blur the boundary between informational content and promotional material, raising concerns around transparency and trust. In this work, we propose a modular pipeline for advertisement management in RAG-based conversational systems, consisting of an ad-rewriter for seamless ad integration and a robust ad-classifier for detection. We leverage synthetic data to train high-performing classifiers, which are then used to guide two complementary ad-integration strategies: supervised fine-tuning of the ad-rewriter and a best-of-N sampling approach that selects the least detectable ad-integrated response among multiple candidates. Our evaluation focuses on two core questions: the effectiveness of ad classifiers in detecting diverse ad integration strategies, and the training methods that best support coherent, minimally intrusive ad insertion. Experimental results show that our ad-classifier, trained on synthetic advertisement data inspired by marketing strategies and enhanced through curriculum learning, achieves robust detection performance. Additionally, we demonstrate that classifier-guided optimization, through both fine-tuning and best-of-N sampling, significantly improves ad stealth, enabling more seamless integration. These findings contribute an adversarial co-evolution framework for developing more sophisticated ad-aware generative search systems and robust ad classifiers.

cs.CL↗

arXiv2005

Theory of the colossal Van-der-Waals binding in soft and hard condensed matter

A simple theory is proposed for the dispersive molecular binding of unusually high magnitude due to an enhanced polarizability. Two alternative ways have so far been considered in the literature leading to the polarizability enhancement: (i) a vibronic energy level gap narrowing, as proposed by us with regard to a hypothetical exciton matter, and (ii) a giant electric dipole in a Rydberg state of constituent atoms, as proposed by Gilman with regard to an enigmatic substance building the ball lightning. We now combine the two mechanisms to obtain concrete expressions for the colossal binding energy. The problem is exemplified for a three-level system coupled to the umbrella mode of an ammonia molecule. Other possibilities for the design of enhanced-polarizability molecules are also discussed. The colossal Van-der-Waals binding is most likely to materialize in hard condensed matter and perhaps less so in soft condensed matter.

cond-mat.soft↗

arXiv2005

Exciton matter sustained by colossal dispersive interactions due to enhanced polarizability: Possible clue to ball lightning

Recently Gilman has pointed out that the material state of a ball lightning is both highly cohesive and flexible. He makes a specific proposal for a cohesive state arising from (colossal) Van-der-Waals attraction between highly polarizable Rydberg atoms produced under a linear lightning. We accept his general suggestions but propose that the colossal Van-der-Waals coupling may also arise from the enhanced polarizability of surrogate molecular clusters, due to the polaron gap narrowing effect. We consider a few illuminating cases and present calculations for the ammonia molecule. Although being unable to identify the exact nature of the surrogate molecules at least for the time-being, we suggest a general scenario of photoexcited vibronic excitons forming a supersaturated surrogate gas phase in which a ball arises as a result of condensation. The orange color of the luminous ball is due to radiative exciton deexcitation and suggests that there may be a unique surrogate material for ball lightning.

physics.ao-ph↗

arXiv2005

Nucleation and growth of catalyst-free ZnO nanostructures

This paper deals with the investigations on the nucleation and growth of ZnO nanostructures in a catalyst free synthesis. The ZnO nanostructures have been formed by evaporation of Zn (99.99%) in O_2 and Ar atmosphere in single zone furnace under two temperature regions, region A (~1173-1073K) and region B (~873-773K). Through application of XRD and TEM techniques, it has been shown that first ZnO is formed which changes to ZnOx through creation of oxygen vacancies. The ZnOx acts as self-catalyst and leads to formation of various nanostructures. Those observed in the present investigation are nanotetrapods (1D, diameter ~ 70-450nm, length ~ 2-4.5mm) nanorods (1D, diameter ~ 45-95nm, length ~ 2.5-4.5mm), nanoflowers(2D,central core diameter ~ 90-185nm, length of petals/nanorod ~ 1.0-3.5mm) and nanoparticles (3D, size ~ 0.85-2.5mm). These nanostructures have been revealed by SEM explorations. Attempts have been made to explain the formation of the various nanostructures in terms of the creation and distribution of the ZnOx, the temperature as well as oxygenation conditions.

cond-mat.mtrl-sci↗