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Jake D. Koralek

Publications and source records attributed to Jake D. Koralek.

7 recordsLinked to original sources

Selective strain tuning of nonequilibrium multiferroic dynamics in BiFeO$_\text3$

Quantum materials are characterized by intertwined orders, and a fundamental goal in condensed matter physics is to achieve their selective control in such a way that one order parameter can be tuned while leaving others largely unaffected. Although significant progress has been made in thermal equilibrium, realizing such control out of equilibrium remains highly challenging. Here we employed \textit{in situ} tensile strain to selectively manipulate the photoinduced lattice dynamics associated with ferroelectric and magnetic orders in multiferroic BiFeO$_3$. By applying MeV ultrafast electron diffraction to freestanding BiFeO$_3$ membranes under tunable strain, we showed that tensile strain markedly suppresses the ultrafast photoinduced reduction of the ferroelectric displacement. By contrast, the photoinduced dynamics of the antiferrodistortive rotation of the oxygen octahedra, which modulates the magnetic order, remains insensitive to strain. Not only do these findings reveal distinct microscopic pathways underlying nonequilibrium multiferroic dynamics, they also establish tunable strain as an effective route for engineering ultrafast phase control in correlated materials.

cond-mat.mtrl-sci↗

The chemRIXS Instrument for the LCLS-II X-Ray Free Electron Laser

The chemRIXS instrument at the Linac Coherent Light Source offers new opportunities for studying solution-phase systems with time-resolved soft X-ray spectroscopy through the recently commissioned high-repetition-rate LCLS-II X-ray free electron laser. The orders-of-magnitude X-ray flux improvement provided by the superconducting accelerator, combined with corresponding advances in the optical laser system and the liquid jet recirculation system, enables studies on dilute systems with high signal-to-noise compared to what was possible with the LCLS-I copper accelerator. These capabilities open up time-resolved X-ray absorption spectroscopy and resonant inelastic X-ray scattering to entirely new classes of samples, as well as enabling the development of new soft X-ray spectroscopies on liquid samples. An overview of the beamline components and the first LCLS-II commissioning results are presented.

physics.ins-det↗

Terahertz field-induced giant symmetry modulations in a van der Waals antiferromagnet

Strong-field terahertz (THz) excitations enable dynamic control over electronic, lattice and symmetry degrees of freedom in quantum materials. Here, we uncover pronounced terahertz-induced symmetry modulations and coherent phonon dynamics in the van der Waals antiferromagnet MnPS3, in which inversion symmetry is broken by its antiferromagnetic spin configuration. Time-resolved second harmonic generation measurements reveal long-lived giant oscillations in the antiferromagnetic phase, with amplitudes comparable to the equilibrium signal, driven by phonons involving percent-level atomic displacements relative to the equilibrium bond lengths. The temporal evolution of the rotational anisotropy patterns indicate a dynamic breaking of mirror symmetry, modulated by two vibrational modes at 1.7 THz and 4.5 THz, with the former corresponding to a hidden mode not observed in equilibrium spectroscopy. We show that these effects arise in part from a field-induced charge rearrangement mechanism that lowers the local crystal symmetry, and couples to the phonon modes. A long-lived field-driven response was uncovered with a complex THz polarization dependence which, in comparison to theory, indicates evidence for an antiferromagnetic-to-ferrimagnetic transition. Our results establish an effective field-tunable pathway for driving excitations otherwise weak in equilibrium, and for manipulating magnetism in low-dimensional materials via dynamical modulation of symmetry.

cond-mat.str-el↗

Liquid Heterostructures: Generation of Liquid-Liquid Interfaces in Free-Flowing Liquid Sheets

Chemical reactions and biological processes are often governed by the structure and transport dynamics of the interface between two liquid phases. Despite their importance, our microscopic understanding of liquid-liquid interfaces has been severely hindered by difficulty in accessing the interface through the bulk liquid. Here we demonstrate a method for generating large-area liquid-liquid interfaces within free-flowing liquid sheets, which we call liquid heterostructures. These sheets can be made thin enough to transmit photons from across the spectrum, which also minimizes the amount of bulk liquid relative to the interface and makes them ideal targets for a wide range of spectroscopies and scattering experiments. The sheets are produced with a microfluidic nozzle that impinges two converging jets of one liquid onto two sides of a third jet of another liquid. The hydrodynamic forces provided by the colliding jets both produce a multilayered laminar liquid sheet with the central jet is flattened in the middle. Infrared microscopy, white light reflectivity, and imaging ellipsometry measurements demonstrate that the buried layer has a tunable thickness and displays well-defined liquid-liquid interfaces, and that the inner layer can be thinner than 100 nm.

physics.chem-ph↗

Magnon-spinon dichotomy in the Kitaev hyperhoneycomb $β$-Li$_2$IrO$_3$

The family of edge-sharing tri-coordinated iridates and ruthenates has emerged in recent years as a major platform for Kitaev spin liquid physics, where spins fractionalize into emergent magnetic fluxes and Majorana fermions with Dirac-like dispersions. While such exotic states are usually pre-empted by long-range magnetic order at low temperatures, signatures of Majorana fermions with long coherent times have been predicted to manifest at intermediate and higher energy scales, similar to the observation of spinons in quasi-1D spin chains. Here we present a Resonant Inelastic X-ray Scattering study of the magnetic excitations of the hyperhoneycomb iridate $β$-Li$_2$IrO$_3$ under a magnetic field with a record-high-resolution spectrometer. At low-temperatures, dispersing spin waves can be resolved around the predicted intertwined incommensurate spiral and field-induced zigzag orders, whose excitation energy reaches a maximum of 16meV. A 2T magnetic field softens the dispersion around ${\bf Q}=0$. The behavior of the spin waves under magnetic field is consistent with our semiclassical calculations for the ground state and the dynamical spin structure factor, which further predicts that the ensued intertwined uniform states remain robust up to very high fields (100 T). Most saliently, the low-energy magnon-like mode is superimposed by a broad continuum of excitations, centered around 35meV and extending up to 100meV. This high-energy continuum survives up to at least 300K -- well above the ordering temperature of 38K -- and gives evidence for pairs of long-lived Majorana fermions of the proximate Kitaev spin liquid.

cond-mat.str-el↗

Tracking Cooper Pairs in a Cuprate Superconductor by Ultrafast Angle-Resolved Photoemission

In high-temperature superconductivity, the process that leads to the formation of Cooper pairs, the fundamental charge carriers in any superconductor, remains mysterious. We use a femtosecond laser pump pulse to perturb superconducting Bi2Sr2CaCu2O8+δ, and study subsequent dynamics using time- and angle-resolved photoemission and infrared reflectivity probes. Gap and quasiparticle population dynamics reveal marked dependencies on both excitation density and crystal momentum. Close to the d-wave nodes, the superconducting gap is sensitive to the pump intensity and Cooper pairs recombine slowly. Far from the nodes pumping affects the gap only weakly and recombination processes are faster. These results demonstrate a new window into the dynamical processes that govern quasiparticle recombination and gap formation in cuprates.

cond-mat.supr-con↗

Emergence of the persistent spin helix in semiconductor quantum wells

According to Noethers theorem, for every symmetry in nature there is a corresponding conservation law. For example, invariance with respect to spatial translation corresponds to conservation of momentum. In another well-known example, invariance with respect to rotation of the electrons spin, or SU(2) symmetry, leads to conservation of spin polarization. For electrons in a solid, this symmetry is ordinarily broken by spin-orbit coupling, allowing spin angular momentum to flow to orbital angular momentum. However, it has recently been predicted that SU(2) can be achieved in a two-dimensional electron gas, despite the presence of spin-orbit coupling. The corresponding conserved quantities include the amplitude and phase of a helical spin density wave termed the persistent spin helix. SU(2) is realized, in principle, when the strength of two dominant spin-orbit interactions, the Rashba (strength parameterized by α) and linear Dresselhaus (β_1), are equal. This symmetry is predicted to be robust against all forms of spin-independent scattering, including electron-electron interactions, but is broken by the cubic Dresselhaus term (β_3) and spin-dependent scattering. When these terms are negligible, the distance over which spin information can propagate is predicted to diverge as αapproaches β_1. Here we observe experimentally the emergence of the persistent spin helix in GaAs quantum wells by independently tuning αand β_1. Using transient spin-grating spectroscopy, we find a spin-lifetime enhancement of two orders of magnitude near the symmetry point.........

cond-mat.mtrl-sci↗