arXiv subjects

Jakob Yngvason

Publications and source records attributed to Jakob Yngvason.

53 records · Page 3Linked to original sources

arXiv2003

The Mathematical Structure of the Second Law of Thermodynamics

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose increase characterizes the possible state changes under adiabatic conditions. It is one of the few really fundamental physical laws (in the sense that no deviation, however tiny, is permitted) and its consequences are far reaching. This principle is independent of models, statistical mechanical or otherwise, and can be understood without recourse to Carnot cycles, ideal gases and other assumptions about such things as `heat', `temperature', `reversible processes', etc., as is usually done. Also the well known formula of statistical mechanics, S = -\sum p log p, is not needed for the derivation of the entropy principle. This contribution is partly a summary of our joint work (Physics Reports, Vol. 310, 1--96 (1999)) where the existence and uniqueness of S is proved to be a consequence of certain basic properties of the relation of adiabatic accessibility among equilibrium states. We also present some open problems and suggest directions for further study.

math-ph↗

arXiv2003

The Ground State of the Bose Gas

Now that the low temperature properties of quantum-mechanical many-body systems (bosons) at low density, $ρ$, can be examined experimentally it is appropriate to revisit some of the formulas deduced by many authors 4-5 decades ago. For systems with repulsive (i.e. positive) interaction potentials the experimental low temperature state and the ground state are effectively synonymous -- and this fact is used in all modeling. In such cases, the leading term in the energy/particle is $2π\hbar^2 a ρ/m$ where $a$ is the scattering length of the two-body potential. Owing to the delicate and peculiar nature of bosonic correlations (such as the strange $N^{7/5}$ law for charged bosons), four decades of research failed to establish this plausible formula rigorously. The only previous lower bound for the energy was found by Dyson in 1957, but it was 14 times too small. The correct asymptotic formula has recently been obtained by us and this work will be presented. The reason behind the mathematical difficulties will be emphasized. A different formula, postulated as late as 1971 by Schick, holds in two-dimensions and this, too, will be shown to be correct. With the aid of the methodology developed to prove the lower bound for the homogeneous gas, two other problems have been successfully addressed. One is the proof by us that the Gross-Pitaevskii equation correctly describes the ground state in the `traps' actually used in the experiments. For this system it is also possible to prove complete Bose condensation, as we have shown. Another topic is a proof that Foldy's 1961 theory of a high density Bose gas of charged particles correctly describes its ground state energy.

math-ph↗

arXiv2002

Superfluidity in Dilute Trapped Bose Gases

A commonly used theoretical definition of superfluidity in the ground state of a Bose gas is based on the response of the system to an imposed velocity field or, equivalently, to twisted boundary conditions in a box. We are able to carry out this program in the case of a dilute interacting Bose gas in a trap. We prove that a gas with repulsive interactions is 100% superfluid in the dilute limit in which the Gross-Pitaevskii equation is exact. This is the first example in an experimentally realistic continuum model in which superfluidity is rigorously verified.

cond-mat↗

arXiv2000

A Rigorous Derivation of the Gross-Pitaevskii Energy Functional for a Two-Dimensional Bose Gas

We consider the ground state properties of an inhomogeneous two-dimensional Bose gas with a repulsive, short range pair interaction and an external confining potential. In the limit when the particle number $N$ is large but $\barρa^2$ is small, where $\barρ$ is the average particle density and $a$ the scattering length, the ground state energy and density are rigorously shown to be given to leading order by a Gross-Pitaevskii (GP) energy functional with a coupling constant $g\sim 1/|\ln(\barρa^2)|$. In contrast to the 3D case the coupling constant depends on $N$ through the mean density. The GP energy per particle depends only on $Ng$. In 2D this parameter is typically so large that the gradient term in the GP energy functional is negligible and the simpler description by a Thomas-Fermi type functional is adequate.

cond-mat.stat-mech↗

arXiv2000

The Ground State Energy of a Dilute Bose Gas

According to a formula that was put forward many decades ago the ground state energy per particle of an interacting, dilute Bose gas at density $ρ$ is $2π\hbar^2ρa/m$ to leading order in $ρa^3\ll 1$, where $a$ is the scattering length of the interaction potential and $m$ the particle mass. This result, which is important for the theoretical description of current experiments on Bose-Einstein condensation, has recently been established rigorously for the first time. We give here an account of the proof that applies to nonnegative, spherically symmetric potentials decreasing faster than $1/r^3$ at infinity.

math-ph↗

arXiv2000

A Fresh Look at Entropy and the Second Law of Thermodynamics

This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic processes for macroscopic systems. It is not necessary to assume a-priori concepts such as "heat", "hot and cold", "temperature". These are derivable from entropy, whose existence we derive from the basic assumptions. See cond-mat/9708200 and math-ph/9805005.

math-ph↗

arXiv2000

The Ground State Energy of a Dilute Two-dimensional Bose Gas

The ground state energy per particle of a dilute, homogeneous, two-dimensional Bose gas, in the thermodynamic limit is shown rigorously to be $E_0/N = (2π\hbar^2ρ/m){|\ln (ρa^2)|^{-1}}$, to leading order, with a relative error at most ${\rm O} (|\ln (ρa^2)|^{-1/5})$. Here $N$ is the number of particles, $ρ=N/V$ is the particle density and $a$ is the scattering length of the two-body potential. We assume that the two-body potential is short range and nonnegative. The amusing feature of this result is that, in contrast to the three-dimensional case, the energy, $E_0$ is not simply $N(N-1)/2$ times the energy of two particles in a large box of volume (area, really) $V$. It is much larger.

math-ph↗

arXiv1999

The Ground State Energy and density of Interacting Bosons in a Trap

In the theoretical description of recent experiments with dilute Bose gases confined in external potentials the Gross-Pitaevskii equation plays an important role. Its status as an approximation for the quantum mechanical many-body ground state problem has recently been rigorously clarified. A summary of this work is presented here.

math-ph↗

arXiv1999

Atoms in strong magnetic fields: The high field limit at fixed nuclear charge

Let E(B,Z,N) denote the ground state energy of an atom with N electrons and nuclear charge Z in a homogeneous magnetic field B. We study the asymptotics of E(B,Z,N) as $B\to \infty$ with N and Z fixed but arbitrary. It is shown that the leading term has the form $(\ln B)^2 e(Z,N)$, where e(Z,N) is the ground state energy of a system of N {\em bosons} with delta interactions in {\em one} dimension. This extends and refines previously known results for N=1 on the one hand, and $N,Z\to\infty$ with $B/Z^3\to\infty$ on the other hand.

math-ph↗

arXiv1999

Geometric Modular Action, Wedge Duality and Lorentz Covariance are Equivalent for Generalized Free Fields

The Tomita-Takesaki modular groups and conjugations for the observable algebras of space-like wedges and the vacuum state are computed for translationally covariant, but possibly not Lorentz covariant, generalized free quantum fields in arbitrary space-time dimension d. It is shown that for $d\geq 4$ the condition of geometric modular action (CGMA) of Buchholz, Dreyer, Florig and Summers \cite{BDFS}, Lorentz covariance and wedge duality are all equivalent in these models. The same holds for d=3 if there is a mass gap. For massless fields in d=3, and for d=2 and arbitrary mass, CGMA does not imply Lorentz covariance of the field itself, but only of the maximal local net generated by the field.

math-ph↗

arXiv1999

Bosons in a Trap: A Rigorous Derivation of the Gross-Pitaevskii Energy Functional

The ground state properties of interacting Bose gases in external potentials, as considered in recent experiments, are usually described by means of the Gross-Pitaevskii energy functional. We present here the first proof of the asymptotic exactness of this approximation for the ground state energy and particle density of a dilute Bose gas with a positive interaction.

math-ph↗

arXiv1999

The Physics and Mathematics of the Second Law of Thermodynamics

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy constructed here is defined only for equilibrium states and no attempt is made to define it otherwise. Statistical mechanics does not enter these considerations. One of the main concepts that makes everything work is the comparison principle (which, in essence, states that given any two states of the same chemical composition at least one is adiabatically accessible from the other) and we show that it can be derived from some assumptions about the pressure and thermal equilibrium. Temperature is derived from entropy, but at the start not even the concept of `hotness' is assumed. Our formulation offers a certain clarity and rigor that goes beyond most textbook discussions of the second law.

cond-mat.soft↗

arXiv1998

Quantum dots. A survey of rigorous results

The paper reviews rigorous results about quantum dots, in particular exact solutions for few electron dots and limit theorems for high magnetic fields and/or high electron number.

math-ph↗

arXiv1998

A Guide to Entropy and the Second Law of Thermodynamics

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy constructed here is defined only for equilibrium states and no attempt is made to define it otherwise. Statistical mechanics does not enter these considerations. One of the main concepts that makes everything work is the comparison principle (which, in essence, states that any two states of the same chemical composition can be connected by an adiabatic process) and we show that it can be derived from some assumptions about the pressure and thermal equilibrium. Temperature is derived from entropy, but at the start not even the concept of `hotness' is assumed. Our formulation offers a certain clarity and rigor that goes beyond most textbook discussions of the second law.

math-ph↗

arXiv1998

Ground State Energy of the Low Density Bose Gas

Now that the properties of low temperature Bose gases at low density, $ρ$, can be examined experimentally it is appropriate to revisit some of the formulas deduced by many authors 4-5 decades ago. One of these is that the leading term in the energy/particle is $2π\hbar^2 ρa/m$, where $a$ is the scattering length. Owing to the delicate and peculiar nature of bosonic correlations, four decades of research have failed to establish this plausible formula rigorously. The only known lower bound for the energy was found by Dyson in 1957, but it was 14 times too small. The correct bound is proved here.

cond-mat.soft↗

arXiv1996

Density Matrix Functional Calculations for Matter in Strong Magnetic Fields: I. Atomic Properties

We report on a numerical study of the density matrix functional introduced by Lieb, Solovej and Yngvason for the investigation of heavy atoms in high magnetic fields. This functional describes {\em exactly} the quantum mechanical ground state of atoms and ions in the limit when the nuclear charge $Z$ and the electron number $N$ tend to infinity with $N/Z$ fixed, and the magnetic field $B$ tends to infinity in such a way that $B/Z^{4/3}\to\infty$. We have calculated electronic density profiles and ground state energies for values of the parameters that prevail on neutron star surfaces and compared them with results obtained by other methods. For iron at $B=10^{12}$ G the ground state energy differs by less than 2 \% from the Hartree-Fock value. We have also studied the maximal negative ionization of heavy atoms in this model at various field strengths. In contrast to Thomas-Fermi type theories atoms can bind excess negative charge in the density matrix model. For iron at $B=10^{12}$ G the maximal excess charge in this model corresponds to about one electron.

atom-ph↗

arXiv1994

There are No Causality Problems for Fermi's Two Atom System

A repeatedly discussed gedanken experiment, proposed by Fermi to check Einstein causality, is reconsidered. It is shown that, contrary to a recent statement made by Hegerfeldt, there appears no causality paradoxon in a proper theoretical description of the experiment.

hep-th↗