arXiv subjects

Jasmina Blecic

Publications and source records attributed to Jasmina Blecic.

At least 19 recordsLinked to original sources

arXiv2026

Pyrat Bay 2.0: an Upgraded Framework for Exoplanet Atmosphere Modeling in the JWST Era

This article presents a major update to the open-source \textsc{Pyrat Bay} modeling framework (version 2.0), tailored for the characterization of exoplanet atmospheres with the observational capabilities of current facilities, such as the James Webb Space Telescope (JWST), and future missions. The upgraded framework introduces a standalone chemistry package, \textsc{chemcat}, enabling the modeling of exoplanet atmospheres via thermochemical-equilibrium calculations with custom compositions, self-consistent radiative-equilibrium thermal profiles, and equilibrium-chemistry retrievals. Other key implementations include nested sampling via MultiNest, isotopic-ratio fitting, transit light source modeling, and free-chemistry parameterization allowing vertical variations in volume mixing ratios. We validated the thermochemical- and radiative-equilibrium modules via comparisons with the \textsc{GGchem}, \textsc{FastChem}, and \textsc{HELIOS} codes. We present an application of the new modeling framework by conducting an atmospheric characterization study using simulated transmission spectra of high signal-to-noise observations for a gas-giant exoplanet. We found that vertical abundance variations in planetary atmospheres can be accurately recovered using data of JWST quality. In such cases, retrievals that neglect these variations may result in biased abundance constraints, e.g., when employing the commonly used free-chemistry approach assuming constant abundance profiles. The results highlight the potential of JWST to study the multi-dimensional nature of exoplanetary atmospheres and their underlying physical processes.

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arXiv2026

Phase-dependent chemistry of WASP-43 b revealed with a suite of one-, two-, and three-dimensional models

Our goal is to investigate the chemistry of the hot Jupiter WASP-43 b in detail using theoretical models, considering the constraints of the James Webb Space Telescope MIRI phase curve. With a suite of pseudo-two-dimensional and three-dimensional photochemical models, we simulate the composition of WASP-43 b in various configurations, and compare them with atmospheric retrieval models. We confirm that disequilibrium chemistry in our theoretical models reduces the methane concentration on the planet night side for wind jet speeds > 500 m/s. Varying the metallicity in the models induces large changes in the CO$_2$ and SO$_2$ concentrations, with SO$_2$ producing mid-infrared absorption features in synthetic emission spectra of the night side at atmospheric metallicities > 10x solar. Our models provide evidence for pole-to-equator circulation enhancing the CH$_4$, NH$_3$, and HCN abundances, which is nonetheless insufficient for detectable spectral features. Finally, we show that H$_2$O, CO, and CO$_2$ are robustly modeled, but species affected by photochemistry are more sensitive to model-specific assumptions and pathways. We conclude that horizontal quenching is the prime mechanism that explains the non-detection of methane in the MIRI phase-curve of WASP-43 b. This mechanism requires only moderate wind speeds and is operative at various thermal structures and atmospheric metallicities. Furthermore, coupled carbon-sulfur chemistry leads to an additional decrease in methane compared to previous models in the literature that did not contain sulfur chemistry. We do not favor a high metallicity as it would have led to observable SO$_2$ features in the MIRI spectra. Our study shows that phase-dependent photochemistry models are essential tools in the interpretation of hot-Jupiter phase curves, but benchmarking is needed to improve the accuracy of photochemical models in the future.

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arXiv2026

Super-Solar Metallicity and Tentative Evidence for Photochemistry on WASP-96b from JWST and Ground-Based VLT Transmission Spectroscopy

With its expanded wavelength coverage and increased precision compared to previous space-based observatories, JWST provides the opportunity to revisit benchmark planets and view them in a new light. Here, we conduct an in-depth study of the atmosphere of the hot-Saturn WASP-96b combining a new JWST NIRSpec/G395H transit with archival NIRISS/SOSS and VLT/FORS2 transmission spectra. The combined spectrum shows clearly-visible features from H2O, CO2, and Na. CO, though, remains unconstrained, precluding a firm metallicity derivation from free retrievals alone. However, self-consistent grids yield a broadly super-stellar atmospheric metallicity of 2-6x stellar. When combined with a roughly stellar C/O ratio ($0.41^{+0.10}_{-0.09}$ from self-consistent grids), we find that WASP-96b potentially formed via core-accretion beyond the H2O snowline and subsequently accreted volatile-rich material. Free retrievals also find a moderate preference (ln B=2.69) for models with SO2 versus without. WASP-96b falls directly on the proposed "SO2 shoreline" and the retrieved SO2 abundance is well-matched to predictions from photochemical models. Our combined spectrum displays an optical slope, which our models fit with opacity from scattering aerosols -- either small-particle condensate clouds or photochemical hazes -- though we cannot completely rule out the broad wings of Na or the effects of stellar contamination. Future observations are necessary to disentangle these effects. Finally, we explore the possibility for limb asymmetry in WASP-96b's transmission spectrum and provide several tests to identify asymmetries in our data. We encourage the community to prioritize the development of a robust pathway to quantify the presence of limb asymmetry -- particularly for low signal-to-noise cases.

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arXiv2025

Horizontal and vertical exoplanet thermal structure from a JWST spectroscopic eclipse map

Highly-irradiated giant exoplanets known as "ultra-hot Jupiters" are anticipated to exhibit large variations of atmospheric temperature and chemistry as a function of longitude, latitude, and altitude. Previous observations have hinted at these variations, but the existing data have been fundamentally restricted to probing hemisphere-integrated spectra, thereby providing only coarse information on atmospheric gradients. Here we present a spectroscopic eclipse map of an extrasolar planet, resolving the atmosphere in multiple dimensions simultaneously. We analyze a secondary eclipse of the ultra-hot Jupiter WASP-18b observed with the NIRISS instrument on JWST. The mapping reveals weaker longitudinal temperature gradients than were predicted by theoretical models, indicating the importance of hydrogen dissociation and/or nightside clouds in shaping global thermal emission. Additionally, we identify two thermally distinct regions of the planet's atmosphere: a "hotspot" surrounding the substellar point and a "ring" near the dayside limbs. The hotspot region shows a strongly inverted thermal structure due to the presence of optical absorbers and a water abundance marginally lower than the hemispheric average, in accordance with theoretical predictions. The ring region shows colder temperatures and poorly constrained chemical abundances. Similar future analyses will reveal three-dimensional thermal, chemical, and dynamical properties of a broad range of exoplanet atmospheres.

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arXiv2025

The SPACE Program. I. The featureless spectrum of HD 86226 c challenges sub-Neptune atmosphere trends

Sub-Neptune exoplanets are the most abundant type of planet known today. As they do not have a Solar System counterpart, many open questions exist about their composition and formation. Previous spectroscopic studies rule out aerosol-free hydrogen-helium-dominated atmospheres for many characterized sub-Neptunes but are inconclusive about their exact atmospheric compositions. Here we characterize the hot (Teq=1311K) sub-Neptune HD 86226 c, which orbits its G-type host star. Its high equilibrium temperature prohibits methane-based haze formation, increasing the chances for a clear atmosphere on this planet. We use HST data taken with WFC3 and STIS from the Sub-neptune Planetary Atmosphere Characterization Experiment (SPACE) Program to perform near-infrared 1.1-1.7micrometer transmission spectroscopy and UV characterization of the host star. We report a featureless transmission spectrum that is consistent within 0.4 sigma with a constant transit depth of 418+-14ppm. The amplitude of this spectrum is only 0.01 scale heights for a H/He-dominated atmosphere, excluding a cloud-free solar-metallicity atmosphere on HD 86226 c with a confidence of 6.5 sigma. Based on an atmospheric retrieval analysis and forward models of cloud and haze formation, we find that the featureless spectrum could be due to a metal enrichment [M/H] above 2.3 (3 sigma confidence lower limit) of a cloudless atmosphere, or silicate (MgSiO3), iron (Fe), or manganese sulfide (MnS) clouds. For these species, we perform an investigation of cloud formation in high-metallicity, high-temperature atmospheres. Our results highlight that HD 86226c does not follow the aerosol trend of sub-Neptunes found by previous studies. Follow-up observations with the JWST could determine whether this planet aligns with the recent detections of metal-enriched atmospheres or if it harbors a cloud species otherwise atypical for sub-Neptunes.

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arXiv2024

Inhomogeneous terminators on the exoplanet WASP-39 b

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ μ$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.

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arXiv2024

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

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arXiv2024

Simultaneous retrieval of orbital phase resolved JWST/MIRI emission spectra of the hot Jupiter WASP-43b: evidence of water, ammonia and carbon monoxide

Spectroscopic phase curves of hot Jupiters measure their emission spectra at multiple orbital phases, thus enabling detailed characterisation of their atmospheres. Precise constraints on the atmospheric composition of these exoplanets offer insights into their formation and evolution. We analyse four phase-resolved emission spectra of the hot Jupiter WASP-43b, generated from a phase curve observed with the MIRI/LRS onboard the JWST, to retrieve its atmospheric properties. Using a parametric 2D temperature model and assuming a chemically homogeneous atmosphere within the observed pressure region, we simultaneously fit the four spectra to constrain the abundances of atmospheric constituents, thereby yielding more precise constraints than previous work that analysed each spectrum independently. Our analysis reveals statistically significant evidence of NH3 (4$σ$) in a hot Jupiter's emission spectra for the first time, along with evidence of H2O (6.5$σ$), CO (3.1$σ$), and a non-detection of CH4. With our abundance constraints, we tentatively estimate the metallicity of WASP-43b at 0.6-6.5$\times$solar and its C/O ratio at 0.6-0.9. Our findings offer vital insights into the atmospheric conditions and formation history of WASP-43b by simultaneously constraining the abundances of carbon, oxygen, and nitrogen-bearing species.

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arXiv2024

Debris Disks can Contaminate Mid-Infrared Exoplanet Spectra: Evidence for a Circumstellar Debris Disk around Exoplanet Host WASP-39

The signal from a transiting planet can be diluted by astrophysical contamination. In the case of circumstellar debris disks, this contamination could start in the mid-infrared and vary as a function of wavelength, which would then change the observed transmission spectrum for any planet in the system. The MIRI/LRS WASP-39b transmission spectrum shows an unexplained dip starting at $\sim$10 $μ$m that could be caused by astrophysical contamination. The spectral energy distribution displays excess flux at similar levels to that which are needed to create the dip in the transmission spectrum. In this article, we show that this dip is consistent with the presence of a bright circumstellar debris disk, at a distance of $>$2 au. We discuss how a circumstellar debris disk like that could affect the atmosphere of WASP-39b. We also show that even faint debris disks can be a source of contamination in MIRI exoplanet spectra.

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arXiv2024

Two-Dimensional Eclipse Mapping of the Hot Jupiter WASP-43b with JWST MIRI/LRS

We present eclipse maps of the two-dimensional thermal emission from the dayside of the hot Jupiter WASP-43b, derived from an observation of a phase curve with the JWST MIRI/LRS instrument. The observed eclipse shapes deviate significantly from those expected for a planet emitting uniformly over its surface. We fit a map to this deviation, constructed from spherical harmonics up to order $\ell_{\rm max}=2$, alongside the planetary, orbital, stellar, and systematic parameters. This yields a map with a meridionally-averaged eastward hot-spot shift of $(7.75 \pm 0.36)^{\circ}$, with no significant degeneracy between the map and the additional parameters. We show the latitudinal and longitudinal contributions of the day-side emission structure to the eclipse shape, finding a latitudinal signal of $\sim$200 ppm and a longitudinal signal of $\sim$250 ppm. To investigate the sensitivity of the map to the method, we fix the non-mapping parameters and derive an "eigenmap" fitted with an optimised number of orthogonal phase curves, which yields a similar map to the $\ell_{\rm max}=2$ map. We also fit a map up to $\ell_{\rm max}=3$, which shows a smaller hot-spot shift, with a larger uncertainty. These maps are similar to those produced by atmospheric simulations. We conclude that there is a significant mapping signal which constrains the spherical harmonic components of our model up to $\ell_{\rm max}=2$. Alternative mapping models may derive different structures with smaller-scale features; we suggest that further observations of WASP-43b and other planets will drive the development of more robust methods and more accurate maps.

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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arXiv2023

Detection of Carbon Monoxide in the Atmosphere of WASP-39b Applying Standard Cross-Correlation Techniques to JWST NIRSpec G395H Data

Carbon monoxide was recently reported in the atmosphere of the hot Jupiter WASP-39b using the NIRSpec PRISM transit observation of this planet, collected as part of the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) Program. This detection, however, could not be confidently confirmed in the initial analysis of the higher resolution observations with NIRSpec G395H disperser. Here we confirm the detection of CO in the atmosphere of WASP-39b using the NIRSpec G395H data and cross-correlation techniques. We do this by searching for the CO signal in the unbinned transmission spectrum of the planet between 4.6 and 5.0 $μ$m, where the contribution of CO is expected to be higher than that of other anticipated molecules in the planet's atmosphere. Our search results in a detection of CO with a cross-correlation function (CCF) significance of $6.6 σ$ when using a template with only ${\rm ^{12}C^{16}O}$ lines. The CCF significance of the CO signal increases to $7.5 σ$ when including in the template lines from additional CO isotopologues, with the largest contribution being from ${\rm ^{13}C^{16}O}$. Our results highlight how cross-correlation techniques can be a powerful tool for unveiling the chemical composition of exoplanetary atmospheres from medium-resolution transmission spectra, including the detection of isotopologues.

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arXiv2023

Awesome SOSS: Transmission Spectroscopy of WASP-96b with NIRISS/SOSS

The future is now - after its long-awaited launch in December 2021, JWST began science operations in July 2022 and is already revolutionizing exoplanet astronomy. The Early Release Observations (ERO) program was designed to provide the first images and spectra from JWST, covering a multitude of science cases and using multiple modes of each on-board instrument. Here, we present transmission spectroscopy observations of the hot-Saturn WASP-96b with the Single Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph, observed as part of the ERO program. As the SOSS mode presents some unique data reduction challenges, we provide an in-depth walk-through of the major steps necessary for the reduction of SOSS data: including background subtraction, correction of 1/f noise, and treatment of the trace order overlap. We furthermore offer potential routes to correct for field star contamination, which can occur due to the SOSS mode's slitless nature. By comparing our extracted transmission spectrum with grids of atmosphere models, we find an atmosphere metallicity between 1x and 5x solar, and a solar carbon-to-oxygen ratio. Moreover, our models indicate that no grey cloud deck is required to fit WASP-96b's transmission spectrum, but find evidence for a slope shortward of 0.9$μ$m, which could either be caused by enhanced Rayleigh scattering or the red wing of a pressure-broadened Na feature. Our work demonstrates the unique capabilities of the SOSS mode for exoplanet transmission spectroscopy and presents a step-by-step reduction guide for this new and exciting instrument.

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arXiv2023

Awesome SOSS: Atmospheric Characterisation of WASP-96 b using the JWST Early Release Observations

The newly operational JWST offers the potential to study the atmospheres of distant worlds with precision that has not been achieved before. One of the first exoplanets observed by JWST in the summer of 2022 was WASP-96 b, a hot-Saturn orbiting a G8 star. As part of the Early Release Observations program, one transit of WASP-96 b was observed with NIRISS/SOSS to capture its transmission spectrum from 0.6-2.85 microns. In this work, we utilise four retrieval frameworks to report precise and robust measurements of WASP-96 b's atmospheric composition. We constrain the logarithmic volume mixing ratios of multiple chemical species in its atmosphere, including: H$_2$O = $-3.59 ^{+ 0.35 }_{- 0.35 }$, CO$_2$ = $-4.38 ^{+ 0.47 }_{- 0.57 }$ and K = $-8.04 ^{+ 1.22 }_{- 1.71 }$. Notably, our results offer a first abundance constraint on potassium in WASP-96 b's atmosphere, and important inferences on carbon-bearing species such as CO$_2$ and CO. Our short wavelength NIRISS/SOSS data are best explained by the presence of an enhanced Rayleigh scattering slope, despite previous inferences of a clear atmosphere - although we find no evidence for a grey cloud deck. Finally, we explore the data resolution required to appropriately interpret observations using NIRISS/SOSS. We find that our inferences are robust against different binning schemes. That is, from low $R = 125$ to the native resolution of the instrument, the bulk atmospheric properties of the planet are consistent. Our systematic analysis of these exquisite observations demonstrates the power of NIRISS/SOSS to detect and constrain multiple molecular and atomic species in the atmospheres of hot giant planets.

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arXiv2023

Photochemically-produced SO$_2$ in the atmosphere of WASP-39b

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $μ$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $μ$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$σ$) and G395H (4.5$σ$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

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arXiv2023

A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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arXiv2022

Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $μ$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $μ$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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arXiv2022

Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $μ$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$σ$) and H$_2$O (21.5$σ$), and identify SO$_2$ as the source of absorption at 4.1 $μ$m (4.8$σ$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

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