arXiv subjects

Javier Alonso

Publications and source records attributed to Javier Alonso.

8 recordsLinked to original sources

arXiv2026

Some results on the Dunkl-Williams constant

This paper presents a compilation of various formulas for calculating the Dunkl-Williams constant $DW(X)$ of a real normed linear space. The constant $DW_B(X)$ related to Birkhoff orthogonality is also considered. The value of $DW(X)$ is calculated for several two-dimensional spaces. In particular, it is shown that the Dunk-Williams constant for $\ell_2-\ell_1$ is equal to $2\sqrt{2}$, and that it is equal to $8(2-\sqrt3)$ for the two dimensional normed linear space whose unit sphere is a dodecahedron.

math.FA↗

arXiv2026

Maximum spanning trees in normed planes

Extending some properties from the Euclidean plane to any normed plane, we show the validity of the Monma-Paterson-Suri-Yao algorithm for finding the maximum-weighted spanning tree of a set of $n$ points, where the weight of an edge is the distance between the end points measured by the norm and there are not repeated distances. For strictly convex normed planes, we expose an strategy for moving slightly the points of the set in order to obtain distinct distances.

math.CO↗

arXiv2025

Micromagnetic structure of oxidized magnetite nanoparticles: sharp structural versus diffuse magnetic interface

The oxidation of magnetite to maghemite is a naturally occurring process that leads to the degradation of the magnetic properties of magnetite nanoparticles. Despite being systematically observed with traditional macroscopic magnetization measurement techniques, a detailed understanding of this process at the microscale is still missing. In this study, we track the evolution of the magnetic structure of magnetite nanoparticles during their oxidation to maghemite through numerical micromagnetic simulations. To capture realistic interparticle effects, we incorporate dipolar interactions by modeling the nanoparticles arranged in chains. Our computational results are benchmarked against experimental data from magnetotactic bacteria, studied over a time scale of years. To resolve the magnetization at the interface between both oxide phases, we propose spin-polarized small-angle neutron scattering (SANS), an experimental technique capable of probing magnetization textures at nanometer length scales. By analyzing the pair-distance distribution function extracted from SANS, we identify distinct signatures of magnetic disorder. Specifically, our findings suggest that the magnetization from the non-oxidized core region varies smoothly across the (structurally sharp) interface into the oxidized shell. The existence of such a diffuse magnetic interface may account for the superior magnetic properties of partially oxidized magnetite nanoparticles compared to fully converted maghemite samples.

cond-mat.mes-hall↗

arXiv2024

Superparamagnetic Superparticles for Magnetic Hyperthermia Therapy: Overcoming the Particle Size Limit

Iron oxide (e.g., Fe$_3$O$_4$ or Fe$_2$O$_3$) nanoparticles are promising candidates for a variety of biomedical applications ranging from magnetic hyperthermia therapy to drug delivery and bio-detection, due to their superparamagnetism, non-toxicity, and biodegradability. While particles of small size (below a critical size, ~20 nm) display superparamagnetic behavior at room temperature, these particles tend to penetrate highly sensitive areas of the body such as the Blood-Brain Barrier (BBB), leading to undesired effects. In addition, these particles possess a high probability of retention, which can lead to genotoxicity and biochemical toxicity. Increasing particle size is a means for addressing these problems but also suppresses the superparamagnetism. We have overcome this particle size limit by synthesizing unique polycrystalline iron oxide nanoparticles composed of multiple nanocrystals of 10 to 15 nm size while tuning particle size from 160 to 400 nm. These so-called superparticles preserve superparamagnetic characteristics and exhibit excellent hyperthermia responses. The specific absorption rates (SAR) exceed 250 W/g (HAC = 800 Oe, f = 310 kHz) at a low concentration of 0.5 mg/mL, indicating their capability in cancer treatment with minimum dose. Our study underscores the potential of size-tunable polycrystalline iron oxide superparticles with superparamagnetic properties for advanced biomedical applications and sensing technologies.

physics.app-ph↗

arXiv2024

Exploring the complex interplay of anisotropies in magnetosomes of magnetotactic bacteria

Magnetotactic bacteria (MTB) are of significant interest for biophysical applications, particularly in cancer treatment. The biomineralized magnetosomes produced by these bacteria are high-quality magnetic nanoparticles that form chains through a highly reproducible natural process. Specifically, Magnetovibrio blakemorei and Magnetospirillum gryphiswaldense exhibit distinct magnetosome morphologies: truncated hexa-octahedral and truncated octahedral shapes, respectively. Despite having identical compositions (magnetite, Fe3O4) and comparable dimensions, their effective uniaxial anisotropies differ significantly, with M. blakemorei showing ~25 kJ/m^3 and M. gryphiswaldense ~11 kJ/m^3 at 300K. This variation presents a unique opportunity to explore the role of different anisotropy contributions in the magnetic responses of magnetite-based nanoparticles. This study systematically investigates these responses by examining static magnetization as a function of temperature (M vs. T, 5 mT) and magnetic field (M vs. H, up to 1 T). Above the Verwey transition temperature (110 K), the effective anisotropy is dominated by shape anisotropy, notably increasing coercivity for M. blakemorei by up to two-fold compared to M. gryphiswaldense. Below this temperature, the effective uniaxial anisotropy increases non-monotonically, significantly altering magnetic behavior. Our simulations based on dynamic Stoner-Wohlfarth models indicate that below the Verwey temperature, a uniaxial magnetocrystalline contribution emerges, peaking at ~22-24 kJ/m^3 at 5 K, values close to those of bulk magnetite. This demonstrates the profound impact of anisotropic properties on the magnetic behaviors and applications of magnetite-based nanoparticles and highlights the exceptional utility of magnetosomes as ideal model systems for studying the complex interplay of anisotropies in magnetite-based nanoparticles.

cond-mat.mtrl-sci↗

arXiv2023

Pedestrian and Passenger Interaction with Autonomous Vehicles: Field Study in a Crosswalk Scenario

This study presents the outcomes of empirical investigations pertaining to human-vehicle interactions involving an autonomous vehicle equipped with both internal and external Human Machine Interfaces (HMIs) within a crosswalk scenario. The internal and external HMIs were integrated with implicit communication techniques, incorporating a combination of gentle and aggressive braking maneuvers within the crosswalk. Data were collected through a combination of questionnaires and quantifiable metrics, including pedestrian decision to cross related to the vehicle distance and speed. The questionnaire responses reveal that pedestrians experience enhanced safety perceptions when the external HMI and gentle braking maneuvers are used in tandem. In contrast, the measured variables demonstrate that the external HMI proves effective when complemented by the gentle braking maneuver. Furthermore, the questionnaire results highlight that the internal HMI enhances passenger confidence only when paired with the aggressive braking maneuver.

cs.HC↗

arXiv2016

Exchange Bias Effects in Iron Oxide-Based Nanoparticle Systems

The exploration of exchange bias (EB) on the nanoscale provides a novel approach to improving the anisotropic properties of magnetic nanoparticles for prospective applications in nanospintronics and nanomedicine. However, the physical origin of EB is not fully understood. Recent advances in chemical synthesis provide a unique opportunity to explore EB in a variety of iron oxide-based nanostructures ranging from core/shell to hollow and hybrid composite nanoparticles. Experimental and atomistic Monte Carlo studies have shed light on the roles of interface and surface spins in these nanosystems. This review paper aims to provide a thorough understanding of the EB and related phenomena in iron oxide-based nanoparticle systems, knowledge of which is essential to tune the anisotropic magnetic properties of exchange-coupled nanoparticle systems for potential applications.

cond-mat.mtrl-sci↗

arXiv2015

Spin-glass-like freezing of inner and outer surface layers in hollow γFe$_2$O$_3$ nanoparticles

Disorder among surface spins largely dominates the magnetic response of ultrafine magnetic particle systems. In this work, we examine time-dependent magnetization in high-quality, monodisperse hollow maghemite nanoparticles with a 14.8 $\pm$ 0.5 nm outer diameter and enhanced surface-to-volume ratio. The nanoparticle ensemble exhibits spin-glass-like signatures in dc magnetic aging and memory protocols and ac magnetic susceptibility. The dynamics of the system slows near 50 K, and becomes frozen on experimental time scales below 20 K. Remanence curves indicate the development of magnetic irreversibility concurrent with the freezing of the spin dynamics. A strong exchange-bias effect and its training behavior point to highly frustrated surface spins that rearrange much more slowly than interior spins with bulk coordination. Monte Carlo simulations of a hollow particle reproducing the experimental morphology corroborated strongly disordered surface layers with complex energy landscapes that underlie both glass-like dynamics and magnetic irreversibility. Calculated hysteresis loops reveal that magnetic behavior is not identical at the inner and outer surfaces, with spins at the outer surface layer of the 15 nm hollow particles exhibiting a higher degree of frustration. Our study sheds light on the origin of spin-glass-like phenomena and the role of surface spins in magnetic hollow nanostructures.

cond-mat.mtrl-sci↗