arXiv subjects

Jayesh Goyal

Publications and source records attributed to Jayesh Goyal.

At least 19 recordsLinked to original sources

arXiv2026

A Clearer View of HAT-P-1 b: JWST NIRSpec G395H Reveals Water, Carbon Dioxide, and Possibly Hydrogen Sulfide

As part of JWST's Exoplanet Grand Tour Survey, we use panchromatic transmission spectroscopy to connect HAT-P-1 b's previously studied optical and near-infrared atmosphere to the longer-wavelength molecular bands accessible with JWST. We present JWST NIRSpec G395H transmission spectroscopy of the hot Jupiter HAT-P-1 b over 2.7--5.3~$\mu$m, and combine the new spectrum with archival HST STIS and WFC3 observations for a 0.3--5.3~$\mu$m atmospheric analysis. We independently reduce the JWST data with the Eureka!, FIREFLy, and Tswift pipelines, finding mutually consistent transmission spectra across the G395H bandpass. Atmospheric retrievals yield strong evidence for H$_2$O and CO$_2$ with Bayes factors of $\log_{10}B_{\mathrm{H_2O}}=8.9$ and $\log_{10}B_{\mathrm{CO_2}}=52.3$, while providing tentative evidence for H$_2$S ($\log_{10}B_{\mathrm{H_2S}}=1.4$). The joint H$_2$O and CO$_2$ constraints favor an atmosphere near chemical equilibrium, with $\log_{10} \text{M/H}=0.99^{+0.19}_{-0.14}$, corresponding to $\sim10\times$ Solar or $\sim9\times$ relative to the near-solar metallicity host star, and a 3$\sigma$ upper limit of C/O $<0.52$. Because H$_2$O and CO$_2$ provide a metallicity comparatively insensitive to vertical mixing in this temperature regime, their combined detection suggests the composition is dominated by bulk enrichment rather than strong disequilibrium transport. We find no significant evidence for clouds; instead, the persistence of molecular structure across the spectrum argues against strong cloud muting. The tentative H$_2$S signal, if confirmed, would further suggest limited photochemical processing at the pressures probed. Together, the molecular inventory, enriched metallicity, and low C/O ratio point to an oxygen-rich atmosphere and establish HAT-P-1 b as a benchmark for comparative studies of hot-Jupiter atmospheric composition.

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arXiv2025

JWST-TST DREAMS: The Nightside Emission and Chemistry of WASP-17b

Theoretical studies have suggested using planetary infrared excess (PIE) to detect and characterize the thermal emission of transiting and non-transiting exoplanets, however the PIE technique requires empirical validation. Here we apply the PIE technique to a combination of JWST NIRSpec G395H transit and eclipse measurements of WASP-17b, a hot Jupiter orbiting an F-type star, obtained consecutively (0.5 phase or 1.8 days apart) as part of the JWST-TST program to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS). Using the in-eclipse measured stellar spectrum to circumvent the need for ultra-precise stellar models, we extract the first JWST nightside emission spectrum of WASP-17b using only transit and eclipse data thereby performing a controlled test of the PIE technique. From the WASP-17b nightside spectrum, we measure a nightside equilibrium temperature of $1005 \pm 256$ K and find tentative evidence for nightside SO2 absorption ($\ln B = 1.45$, $2.3\sigma$). In context with the dayside, the temperature of the nightside is consistent with (1) previous eclipse mapping findings that suggest relatively inefficient day-night heat transport, and (2) a non-zero bond albedo of $0.42^{+0.06}_{-0.10}$. SO2 on the nightside, if confirmed, would represent the first direct evidence for transport-induced chemistry, matching previous model predictions, and opening a new door into the 3D nature of giant exoplanets. Our results suggest that PIE is feasible with JWST/NIRSpec for two epochs separated in time by significantly less than the rotation period of the host star.

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arXiv2025

Revisiting the Atmosphere of HD 149026b: The Role of Stellar Abundances and Choice of Opacities in Exoplanet Atmosphere Modeling

Planet formation occurs within the same molecular cloud as the host star, suggesting a link between the elemental abundances of star and the planet. Exoplanet atmosphere studies often assume solar abundances for host stars, however, specific host star abundances might lead to more accurate constraints. In this work, we perform sensitivity studies for a metal rich stellar host HD 149026 and its exoplanet HD 149026b, to understand the effect of solar versus stellar abundance choice on the $P$-$T$ profiles, equilibrium chemical abundances and emission spectra, using self-consistent atmosphere models. We find that the differences are dependent on the model parameters, particularly C/O ratio, and for HD 149026b the difference in the eclipse depth is maximum $\sim$80 ppm, for C/O between 0.75-0.85. Recent JWST NIRCam observations of HD 149026b have yielded widely varying metallicity ranges, highly super-solar (59-275$\times$) using chemical equilibrium retrievals and 12-31$\times$ solar using self-consistent models, both using solar abundances. In this work, we constrain the metallicity of HD 149026b to be 53-113$\times$ solar, with solar abundances and 39-78$\times$ stellar, with stellar abundances. We constrain the self-consistent $P$-$T$ profile of HD 149026b to be substantially cooler (upto 500 K) than the self-consistent best-fit model in the previous work, in the emission spectra probed region, thus requiring higher CO$_2$ abundance to explain the observations, leading to comparatively higher metallicity constraint. We find that the inclusion of Fe opacity in computing self-consistent $P$-$T$ profiles for HD 149026b in our models is the major reason for these differences. We constrain the C/O ratio to 0.47-0.68 and the heat redistribution factor to 0.70-0.76, indicating higher heat redistribution than previously estimated.

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arXiv2025

Cloudy mornings and clear evenings on a gas giant exoplanet

The spectra of exoplanet atmospheres are affected by aerosols (clouds and hazes) of uncertain origin. Proposed aerosol formation mechanisms include gas condensation or photochemical reactions. We measure the transmission spectrum of the tidally locked gas giant exoplanet WASP-94A b and identify asymmetry in its atmosphere. The morning limb is cooler and cloudy, while the evening limb is hotter and exhibits gaseous H$_2$O absorption features. We interpret this difference as due to the formation of cloud droplets near the morning limb, which evaporate during circulation to the evening limb. The dominant aerosols are clouds cycling between the day and night sides of the atmosphere, not photochemical hazes. The resulting asymmetry can severely bias chemical abundance measurements, unless limb-resolved spectroscopy is available.

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arXiv2025

A Detailed Investigation of HD 209458 b HST & JWST Transmission Spectra with SANSAR

HD 209458 b is the first exoplanet on which an atmosphere was detected. Since then, its atmosphere has been investigated using multiple telescopes and instruments. However, many of its atmospheric constraints remain debatable. While HST observations suggested a highly sub-solar metallicity, recent JWST NIRCam observations by Xue et al. 2024 constrained a super-solar metallicity with highly sub-solar C/O. In this work, we show a detailed investigation of HD 209458 b transmission spectra observations from JWST and HST using SANSAR, a newly developed planetary atmosphere modeling framework, with free, equilibrium chemistry and self-consistent grid retrievals. The overall best-fitting model with free retrievals ($\chi^2_{\rm{red}}$=1.21) constrains its metallicity and C/O to be highly sub-solar, while equilibrium chemistry and grid retrievals ($\chi^2_{\rm{red}}$=1.27 and 1.30, respectively) are consistent with solar values using STIS+WFC3+NIRCam observations. The retrieved abundances of H$_2$O and CO$_2$ are almost three orders of magnitude lower (highly sub-solar) with STIS+WFC3+NIRCam compared to just NIRCam, using free retrievals. NIRCam observations alone also result in misleading constraints on metallicity and C/O, with equilibrium chemistry and grid retrieval. We find that the model choice of varying C/H or O/H to vary the C/O in equilibrium chemistry retrievals leads to different metallicity constraints with NIRCam, but similar constraints with STIS+WFC3+NIRCam. We conclude that NIRCam observations alone can lead to overestimation of abundances for exoplanet atmospheres and, therefore, should be used in combination with UV/Optical and near-infrared observations to obtain robust constraints on abundances, C/O, and metallicity. In particular, even though we can detect the CO$_2$ feature with just NIRCam, we cannot constrain its abundances robustly without the optical baseline.

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arXiv2025

Superhabitable Planets Around Mid-Type K Dwarf Stars Enhance Simulated JWST Observability and Surface Habitability

In our search for life beyond the Solar System, certain planetary bodies may be more conducive to life than Earth. However, the observability of these `superhabitable' planets in the habitable zones around K dwarf stars has not been fully modeled. This study addresses this gap by modeling the atmospheres of superhabitable exoplanets. We employed the 1D model $\texttt{Atmos}$ to define the superhabitable parameter space, $\texttt{POSEIDON}$ to calculate synthetic transmission spectra, and $\texttt{PandExo}$ to simulate $\text{JWST}$ observations. Our results indicate that planets orbiting mid-type K dwarfs, receiving $80\%$ of Earth's solar flux, are optimal for life. These planets sustain temperate surfaces with moderate $CO_2$ levels, unlike those receiving $60\%$ flux, where necessarily higher $CO_2$ levels could hinder biosphere development. Moreover, they are easier to observe, requiring significantly fewer transits for biosignature detection compared to Earth-like planets around Sun-like stars. For instance, detecting biosignature pairs like oxygen and methane from $30$ parsecs would require $150$ transits ($43$ years) for a superhabitable planet, versus over $1700$ transits ($\sim 1700$ years) for Earth-like planets. While such observation times lie outside of $\text{JWST}$ mission timescales, our study underscores the necessity of next-generation telescopes and provides valuable targets for future observations with, for example, the $\text{ELT}$.

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arXiv2024

JWST-TST DREAMS: A Precise Water Abundance for Hot Jupiter WASP-17b from the NIRISS SOSS Transmission Spectrum

Water has proven to be ubiquitously detected in near-infrared (NIR) transmission spectroscopy observations of hot Jupiter atmospheres, including WASP-17b. However, previous analyses of WASP-17b's atmosphere based upon Hubble Space Telescope (HST) and Spitzer data could not constrain the water abundance, finding that sub-solar, super-solar and bimodal posterior distributions were all statistically valid. In this work, we observe one transit of the hot Jupiter WASP-17b using JWST's Near Infrared Imager and Slitless Spectrograph Single Object Slitless Spectroscopy (NIRISS SOSS) mode. We analyze our data using three independent data analysis pipelines, finding excellent agreement between results. Our transmission spectrum shows multiple H$_2$O absorption features and a flatter slope towards the optical than seen in previous HST observations. We analyze our spectrum using both PICASO+Virga forward models and free retrievals. POSEIDON retrievals provide a well-constrained super-solar $\log$(H$_2$O) abundance (-2.96$^{+0.31}_{-0.24}$), breaking the degeneracy from the previous HST/Spitzer analysis. We verify our POSEIDON results with petitRADTRANS retrievals. Additionally, we constrain the abundance of $\log$(H$^-$), -10.19$^{+0.30}_{-0.23}$, finding that our model including H$^-$ is preferred over our model without H$^-$ to 5.1 $\sigma$. Furthermore, we constrain the $\log$(K) abundance (-8.07$^{+0.58}_{-0.52}$) in WASP-17b's atmosphere for the first time using space-based observations. Our abundance constraints demonstrate the power of NIRISS SOSS's increased resolution, precision, and wavelength range to improve upon previous NIR space-based results. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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arXiv2024

Low-resolution Transit Spectroscopy of Three Hot Jupiters Using the 2m Himalayan Chandra Telescope

Here, we present the low-resolution transmission spectroscopy of three giant planets using the Himalayan Faint Object Spectrograph Camera (HFOSC) on the 2m Himalayan Chandra Telescope (HCT) in Hanle, India. It is the first application of transmission spectroscopy with HCT. This study presents results from a single transit, each for three planets: HAT-P-1b, KELT- 18b and WASP-127b. The selection of suitable reference stars assisted in accurately tracking slit losses for the long cadence observations that are needed to achieve the required Signal to Noise Ratio (SNR). We employ the Common Mode Correction (CMC) technique, utilizing a white light transit curve to minimize time dependent systematic errors. The observed spectra for WASP-127b and HAT-P-1b agree with previous low-resolution transit spectroscopic observations using other observing facilities. We confirm the presence of Rayleigh scattering in the atmosphere of WASP-127b. In addition, we provide the first low-resolution transmission spectrum for KELT-18b. Modeling the exoplanet atmosphere with HFOSC and available IR observations from HST and SPITZER for WASP-127b and HAT-P-1b shows that HFOSC can be an alternative optical instrument to use in conjunction with IR observations to constrain the atmospheric parameters better.

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arXiv2024

JWST-TST DREAMS: A Super-Solar Metallicity in WASP-17 b Dayside Atmosphere from NIRISS SOSS Eclipse Spectroscopy

We present the first emission spectrum of the hot Jupiter WASP-17 b using one eclipse observation from the JWST Near Infrared Imager and Slitless Spectrograph (NIRISS) Single Object Slitless Spectroscopy (SOSS) mode. Covering a wavelength range of 0.6 to 2.8 microns, our retrieval analysis reveals a strong detection of H2O in WASP-17b dayside atmosphere (6.4sigma). Our retrievals consistently favor a super-solar dayside H2O abundance and a non-inverted temperature-pressure profile over a large pressure range. Additionally, our examination of the brightness temperature reveals excess emission below 1 microns, suggesting the possibility of a high internal temperature (600 to 700 K) and/or contributions from reflected light. We highlight that JWST emission spectroscopy retrieval results can be sensitive to whether negative eclipse depths are allowed at optical wavelengths during light curve fitting. Our findings deepen our understanding of WASP-17b atmospheric composition while also highlighting the sensitivity of our results to pressure-temperature profile parameterizations. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we will use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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arXiv2024

JWST-TST DREAMS: Non-Uniform Dayside Emission for WASP-17b from MIRI/LRS

We present the first spectroscopic characterisation of the dayside atmosphere of WASP-17b in the mid-infrared using a single JWST MIRI/LRS eclipse observation. From forward-model fits to the 5-12 $\mu$m emission spectrum, we tightly constrain the heat redistribution factor of WASP-17b to be 0.92$\pm$0.02 at the pressures probed by this data, indicative of inefficient global heat redistribution. We also marginally detect a supersolar abundance of water, consistent with previous findings for WASP-17b, but note our weak constraints on this parameter. These results reflect the thermodynamically rich but chemically poor information content of MIRI/LRS emission data for high-temperature hot Jupiters. Using the eclipse mapping method, which utilises the signals that the spatial emission profile of an exoplanet imprints on the eclipse light curve during ingress/egress due to its partial occultation by the host star, we also construct the first eclipse map of WASP-17b, allowing us to diagnose its multidimensional atmospheric dynamics for the first time. We find a day-night temperature contrast of order 1000 K at the pressures probed by this data, consistent with our derived heat redistribution factor, along with an eastward longitudinal hotspot offset of $18.7^{+11.1\deg}_{-3.8}$, indicative of the presence of an equatorial jet induced by day-night thermal forcing being the dominant redistributor of heat from the substellar point. These dynamics are consistent with general circulation model predictions for WASP-17b. This work is part of a series of studies by the JWST Telescope Scientist Team (JWST-TST), in which we use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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arXiv2024

Constraining Planetary Albedo of JWST Targets in the TESS bandpass, using TESS, HST and Spitzer Eclipse Depth Observations

Albedo is one of the important characteristics of hot Jupiter exoplanets. However, albedo constraints have been obtained for very few exoplanets. In this work, we present the TESS Phase Curve observations of WASP-18b, WASP-19b, WASP-121b, WASP-43b, WASP-17b, and WASP-77b, all JWST targets for atmospheric characterization and constrain their occultation depth as well as geometric albedo (A$_g$). We use a grid of self-consistent model atmospheres to constrain the metallicity, C/O ratio, and heat re-distribution for these six targets by fitting to their HST and/or Spitzer observations and also compute the thermal contribution to total occultation depth in the TESS bandpass. We report the first value of TESS occultation depth for WASP-17b ($151_{-66}^{+83}$) and updated value for WASP-77Ab ($94_{-62}^{+53}$). We find self-consistent models constrain high values of thermal contribution to total occultation compared to Planck models. We find very low A$_g$ values for WASP-18b (< 0.089), WASP-19b (< 0.022), WASP-121b ($0.0^{+0.055}_{-0.104}$), WASP-77Ab ($0.017^{+0.126}_{-0.147}$) and significantly higher value for WASP-43b ($0.109^{+0.086}_{-0.088}$) and WASP-17b ($0.401^{+0.526}_{-0.307}$). We find WASP-17b lies in the ideal spot of low gravity and low equilibrium temperature, conducive for cloud formation, leading to high A$_g$. With the best-fit models, we constrain low heat re-distribution for all planets, with WASP-18b having the least. We also constrain sub-solar metallicity for all planets except WASP-17b and WASP-19b. We find a highly sub-solar C/O ratio for WASP-77Ab and WASP-43b, solar for WASP-18b, and super-solar for WASP-121b. The best-fit $P$-$T$ profiles show thermal inversion for WASP-18b and WASP-121b and none for WASP-77b and WASP-43b, which is in agreement with previous works.

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arXiv2023

JWST-TST DREAMS: Quartz Clouds in the Atmosphere of WASP-17b

Clouds are prevalent in many of the exoplanet atmospheres that have been observed to date. For transiting exoplanets, we know if clouds are present because they mute spectral features and cause wavelength-dependent scattering. While the exact composition of these clouds is largely unknown, this information is vital to understanding the chemistry and energy budget of planetary atmospheres. In this work, we observe one transit of the hot Jupiter WASP-17b with JWST's MIRI LRS and generate a transmission spectrum from 5-12 $\rm{\mu}$m. These wavelengths allow us to probe absorption due to the vibrational modes of various predicted cloud species. Our transmission spectrum shows additional opacity centered at 8.6 $\rm{\mu}$m, and detailed atmospheric modeling and retrievals identify this feature as SiO$_2$(s) (quartz) clouds. The SiO$_2$(s) clouds model is preferred at 3.5-4.2$\sigma$ versus a cloud-free model and at 2.6$\sigma$ versus a generic aerosol prescription. We find the SiO$_2$(s) clouds are comprised of small ${\sim}0.01$ $\rm{\mu}$m particles, which extend to high altitudes in the atmosphere. The atmosphere also shows a depletion of H$_2$O, a finding consistent with the formation of high-temperature aerosols from oxygen-rich species. This work is part of a series of studies by our JWST Telescope Scientist Team (JWST-TST), in which we will use Guaranteed Time Observations to perform Deep Reconnaissance of Exoplanet Atmospheres through Multi-instrument Spectroscopy (DREAMS).

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arXiv2023

Awesome SOSS: Transmission Spectroscopy of WASP-96b with NIRISS/SOSS

The future is now - after its long-awaited launch in December 2021, JWST began science operations in July 2022 and is already revolutionizing exoplanet astronomy. The Early Release Observations (ERO) program was designed to provide the first images and spectra from JWST, covering a multitude of science cases and using multiple modes of each on-board instrument. Here, we present transmission spectroscopy observations of the hot-Saturn WASP-96b with the Single Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph, observed as part of the ERO program. As the SOSS mode presents some unique data reduction challenges, we provide an in-depth walk-through of the major steps necessary for the reduction of SOSS data: including background subtraction, correction of 1/f noise, and treatment of the trace order overlap. We furthermore offer potential routes to correct for field star contamination, which can occur due to the SOSS mode's slitless nature. By comparing our extracted transmission spectrum with grids of atmosphere models, we find an atmosphere metallicity between 1x and 5x solar, and a solar carbon-to-oxygen ratio. Moreover, our models indicate that no grey cloud deck is required to fit WASP-96b's transmission spectrum, but find evidence for a slope shortward of 0.9$\mu$m, which could either be caused by enhanced Rayleigh scattering or the red wing of a pressure-broadened Na feature. Our work demonstrates the unique capabilities of the SOSS mode for exoplanet transmission spectroscopy and presents a step-by-step reduction guide for this new and exciting instrument.

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arXiv2022

Diurnal variations in the stratosphere of the ultrahot giant exoplanet WASP-121b

The temperature profile of a planetary atmosphere is a key diagnostic of radiative and dynamical processes governing the absorption, redistribution, and emission of energy. Observations have revealed dayside stratospheres that either cool or warm with altitude for a small number of gas giant exoplanets, while other dayside stratospheres are consistent with constant temperatures. Here we report spectroscopic phase curve measurements for the gas giant WASP-121b, which constrain stratospheric temperatures throughout the diurnal cycle. Variations measured for a water vapour spectral feature reveal a temperature profile that transitions from warming with altitude on the dayside hemisphere to cooling with altitude on the nightside hemisphere. The data are well explained by models assuming chemical equilibrium, with water molecules thermally dissociating at low pressures on the dayside and recombining on the nightside. Nightside temperatures are low enough for perovskite (CaTiO3) to condense, which could deplete titanium from the gas phase and explain recent non-detections at the day-night terminator. Nightside temperatures are also consistent with the condensation of refractory species such as magnesium, iron, and vanadium. Detections of these metals at the day-night terminator suggest, however, that if they do form nightside clouds, cold trapping does not efficiently remove them from the upper atmosphere. Horizontal winds and vertical mixing could keep these refractory condensates aloft in the upper atmosphere of the nightside hemisphere until they are recirculated to the hotter dayside hemisphere and vaporised.

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arXiv2021

Pseudo-2D Modelling of Heat Redistribution Through H$_2$ Thermal Dissociation/Recombination: Consequences for Ultra-Hot Jupiters

Thermal dissociation and recombination of molecular hydrogen, H_2, in the atmospheres of ultra-hot Jupiters (UHJs) has been shown to play an important role in global heat redistribution. This, in turn, significantly impacts their planetary emission, yet only limited investigations on the atmospheric effects have so far been conducted. Here we investigate the heat redistribution caused by this dissociation/recombination reaction, alongside feedback mechanisms between the atmospheric chemistry and radiative transfer, for a planetary and stellar configuration typical of UHJs. To do this, we have developed a time-dependent pseudo-2D model, including a treatment of time-independent equilibrium chemical effects. As a result of the reaction heat redistribution, we find temperature changes of up to $\sim$400 K in the atmosphere. When TiO and VO are additionally considered as opacity sources, these changes in temperature increase to over $\sim$800 K in some areas. This heat redistribution is found to significantly shift the region of peak atmospheric temperature, or hotspot, towards the evening terminator in both cases. The impact of varying the longitudinal wind speed on the reaction heat distribution is also investigated. When excluding TiO/VO, increased wind speeds are shown to increase the impact of the reaction heat redistribution up to a threshold wind speed. When including TiO/VO there is no apparent wind speed threshold, due to thermal stabilisation by these species. We also construct pseudo-2D phase curves from our model, and highlight both significant spectral flux damping and increased phase offset caused by the reaction heat redistribution.

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arXiv2019

The Need for Laboratory Measurements and Ab Initio Studies to Aid Understanding of Exoplanetary Atmospheres

We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet atmospheric models capable of interpreting the upcoming observations are often limited by insufficiencies in the laboratory and theoretical data that serve as critical inputs to atmospheric physical and chemical tools. Here we provide an up-to-date and condensed description of areas where laboratory and/or ab initio investigations could fill critical gaps in our ability to model exoplanet atmospheric opacities, clouds, and chemistry, building off a larger 2016 white paper, and endorsed by the NAS Exoplanet Science Strategy report. Now is the ideal time for progress in these areas, but this progress requires better access to, understanding of, and training in the production of spectroscopic data as well as a better insight into chemical reaction kinetics both thermal and radiation-induced at a broad range of temperatures. Given that most published efforts have emphasized relatively Earth-like conditions, we can expect significant and enlightening discoveries as emphasis moves to the exotic atmospheres of exoplanets.

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arXiv2019

The carbon-to-oxygen ratio: implications for the spectra of hydrogen-dominated exoplanet atmospheres

We present results from one-dimensional atmospheric simulations investigating the effect of varying the carbon-to-oxygen (C/O) ratio on the thermal structure, chemical composition and transmission and emission spectra, for irradiated hydrogen-dominated atmospheres. We find that each of these properties of the atmosphere are strongly dependent on the individual abundances (relative to hydrogen) of carbon and oxygen. We confirm previous findings that different chemical equilibrium compositions result from different sets of element abundances but with the same C/O ratio. We investigate the effect of this difference in composition on the thermal structure and simulated spectra. We also simulate observations using the PandExo tool and show that these differences are observationally significant with current (i.e. Hubble Space Telescope) and future (i.e. James Webb Space Telescope) instruments. We conclude that it is important to consider the full set of individual element abundances, with respect to hydrogen, rather than the ratios of only two elements, such as the C/O ratio, particularly when comparing model predictions with observed transmission and emission spectra.

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arXiv2018

An optical transmission spectrum for the ultra-hot Jupiter WASP-121b measured with the Hubble Space Telescope

We present an atmospheric transmission spectrum for the ultra-hot Jupiter WASP-121b, measured using the Space Telescope Imaging Spectrograph (STIS) onboard the Hubble Space Telescope (HST). Across the 0.47-1 micron wavelength range, the data imply an atmospheric opacity comparable to - and in some spectroscopic channels exceeding - that previously measured at near-infrared wavelengths (1.15-1.65 micron). Wavelength-dependent variations in the opacity rule out a gray cloud deck at a confidence level of 3.8-sigma and may instead be explained by VO spectral bands. We find a cloud-free model assuming chemical equilibrium for a temperature of 1500K and metal enrichment of 10-30x solar matches these data well. Using a free-chemistry retrieval analysis, we estimate a VO abundance of -6.6(-0.3,+0.2) dex. We find no evidence for TiO and place a 3-sigma upper limit of -7.9 dex on its abundance, suggesting TiO may have condensed from the gas phase at the day-night limb. The opacity rises steeply at the shortest wavelengths, increasing by approximately five pressure scale heights from 0.47 to 0.3 micron in wavelength. If this feature is caused by Rayleigh scattering due to uniformly-distributed aerosols, it would imply an unphysically high temperature of 6810+/-1530K. One alternative explanation for the short-wavelength rise is absorption due to SH (mercapto radical), which has been predicted as an important product of non-equilibrium chemistry in hot Jupiter atmospheres. Irrespective of the identity of the NUV absorber, it likely captures a significant amount of incident stellar radiation at low pressures, thus playing a significant role in the overall energy budget, thermal structure, and circulation of the atmosphere.

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