arXiv subjects

Jean Spièce

Publications and source records attributed to Jean Spièce.

6 recordsLinked to original sources

arXiv2026

Direct Nanoscale Pyroelectric Characterization of a CuInP${}_2$S${}_6$ van der Waals Nanogenerator

Pyroelectric energy conversion offers a route for harvesting time-dependent thermalfluctuations that are abundant in natural and technological environments. Twodimensional ferroelectrics are particularly attractive for this purpose because reduced dimensionality enables ultrathin, mechanically compliant device architectures. Here, we demonstrate direct nanoscale pyroelectric characterization of an out-of-plane van der Waals nanogenerator based on CuInP2S6 (CIPS) encapsulated between few-layer graphene electrodes. A scanning thermal microscopy (SThM) probe is employed as a localized nanoscale heat source while the electrically generated response is measured in situ through the device electrodes. Harmonic detection isolates the pyroelectric signal from parasitic first-harmonic electromechanical contributions, while finite-element thermal modeling combined with probe calibration enables direct determination of the local pyroelectric coefficient from the measured electrical response. Beyond quantitative characterization, the spatially resolved measurements directly identify electrically inactive regions associated with device defects, revealing local performance-limiting features that remain hidden in conventional spatially averaged pyroelectric measurements. The presented approach establishes a versatile platform for quantitative nanoscale pyroelectric characterization and the optimization of van der Waals pyroelectric devices.

cond-mat.mes-hall↗

arXiv2025

Characterization of heat transfer in 3D CMOS structures using Sideband Scanning Thermal Wave Microscopy

Efficient thermal management is critical for cryogenic CMOS circuits, where local heating can compromise device performance and qubit coherence. Understanding heat flow at the nanoscale in these multilayer architectures requires localized, high-resolution thermal probing techniques capable of accessing buried structures. Here, we introduce a sideband thermal wave detection scheme for Scanning Thermal Microscopy, S-STWM, to probe deeply buried heater structures within CMOS dies. By extracting the phase of propagating thermal waves, this method provides spatially resolved insight into heat dissipation pathways through complex multilayer structures. Our approach enables quantitative evaluation of thermal management strategies, informs the design of cryo-CMOS circuits, and establishes a foundation for in situ thermal characterization under cryogenic operating conditions.

cond-mat.other↗

arXiv2024

Direct measurement of the local electrocaloric effect in 2D ferroelectric In${}_2$Se${}_3$ by Scanning Electrocaloric Thermometry

The electrocaloric effect refers to the temperature change in a material when an electric field is applied or removed. Significant breakthroughs revealed its potential for solid-state cooling technologies in past decades. These devices offer a sustainable alternative to traditional vapor compression refrigeration, with advantages such as compactness, silent operation, and the absence of moving parts or refrigerants. Electrocaloric effects are typically studied using indirect methods using polarization data, and which suffer from inaccuracies related to assumptions about heat capacity. Direct methods, although more precise, require device fabrication and face challenges in studying meso- or nanoscale systems, like 2D materials, and materials with non-uniform polarization textures where high spatial resolution is required. In this study, a novel technique, Scanning Electrocaloric Thermometry, is introduced for characterizing the local electrocaloric effect in nanomaterials. This approach achieves high spatial resolution by locally applying electric fields and by simultaneously measuring the resulting temperature change. By employing AC excitation, the measurement sensitivity is further enhanced and the electrocaloric effect is disentangled from other heating mechanisms such as Joule heating and dielectric losses. The effectiveness of the method is demonstrated by examining electrocaloric and heat dissipation phenomena in two-dimensional In${}_2$Se${}_3$ micrometer-sized flakes.

cond-mat.mes-hall↗

arXiv2024

Versatile polymer method to dry-flip two-dimensional moiré hetero structures for nanoscale surface characterization

The recent discovery of magic angle twisted bilayer graphene (MATBG), in which two sheets of monolayer graphene are precisely stacked to a specific angle, has opened up a plethora of new opportunities in the field of topology, superconductivity, and other strongly correlated effects. Most conventional ways of preparing twisted bilayer devices require the use of high process temperatures and solvents and are not well-suited for preparing samples which need to be flipped to be compatible with characterization techniques like STM, ARPES, PFM, SThM etc. Here, we demonstrate a very simple polymer-based method using Polyvinyl Chloride (PVC), which can be used for making flipped twisted bilayer graphene devices. This allowed us to produce flipped twisted samples without the need of any solvents and with high quality as confirmed by Piezoresponse Force Microscopy. We believe that this dry flip technique can be readily extended to twist 2D materials beyond graphene, especially air-sensitive materials which require operation under inert atmosphere, where often solvents cannot be used.

cond-mat.mes-hall↗

arXiv2024

Quantifying the local mechanical properties of twisted double bilayer graphene

Nanomechanical measurements of minimally twisted van der Waals materials remained elusive despite their fundamental importance for device realisation. Here, we use Ultrasonic Force Microscopy (UFM) to locally quantify the variation of out-of-plane Young's modulus in minimally twisted double bilayer graphene (TDBG). We reveal a softening of the Young's modulus by 7\% and 17\% along single and double domain walls, respectively. Our experimental results are confirmed by force-field relaxation models. This study highlights the strong tunability of nanomechanical properties in engineered twisted materials, and paves the way for future applications of designer 2D nanomechanical systems.

cond-mat.mes-hall↗

arXiv2017

Field-Effect Control of Graphene-Fullerene Thermoelectric Nanodevices

Although it was demonstrated that discrete molecular levels determine the sign and magnitude of the thermoelectric effect in single-molecule junctions, full electrostatic control of these levels has not been achieved to date. Here, we show that graphene nanogaps combined with gold microheaters serve as a testbed for studying single-molecule thermoelectricity. Reduced screening of the gate electric field compared to conventional metal electrodes allows control of the position of the dominant transport orbital by hundreds of meV. We find that the power factor of graphene-fullerene junctions can be tuned over several orders of magnitude to a value close to the theoretical limit of an isolated Breit-Wigner resonance. Furthermore, our data suggest that the power factor of an isolated level is only given by the tunnel coupling to the leads and temperature. These results open up new avenues for exploring thermoelectricity and charge transport in individual molecules and highlight the importance of level alignment and coupling to the electrodes for optimum energy conversion in organic thermoelectric materials.

cond-mat.mes-hall↗